To analyze the radioactivity of 3H and 14C in miscellaneous radioactive wastes generated from nuclear power plants, a wet digestion method using sulfuric acid is currently used. However, sulfuric acid is classified as a special management material, and there is no disposal method for contaminated radioactive waste. Therefore, research on a thermal decomposition method that can analyze the DAW radioactive waste samples without using sulfuric acid is necessary. In this study, we will cover the final sample amount, sample injection method, and prevention of organic ignition to meet the minimum detection limit requirements of the analysis equipment. Through this research, optimal conditions for the thermal decomposition method for analyzing the radioactivity of 3H and 14C in DAW radioactive wastes generated from nuclear power plants can be derived.

Boric acid-containing B-10 is used in a nuclear reactor as a coolant and absorbs thermal neutrons generated during nuclear fission in the primary circuit. Boron-containing coolant water waste is generated from maintenance, floor drain, decontamination, and reactor letdown flows. There are two options for aqueous solution waste of boric acid. One is recycling and discharge through filtration, ion exchange, and reverse osmosis. The other is immobilization after evaporation and crystallization processes. The dry powder of boric acid waste liquid can be immobilized by cement, polymer, etc. Before the mid-1990s, concentrated boric acid waste was solidified with a cement matrix. To overcome the disadvantage of low waste loading of cement waste form, a method of solidifying with paraffin was adopted. However, paraffin solids were insufficient to be disposed of as final waste. Paraffin is a kind of soft solidified material and has low compressive strength and poor leaching resistance. As a result, it was decided as an unsuitable form for disposal. In KOREA, paraffin waste form was adopted for boric acid waste treatment in the 1990s. A large amount of paraffin waste forms about 20,000 drums (200 l drum) were generated to treat boric acid waste and were stored in nuclear power sites without disposal. In this study, we want to obtain high-purity boric acid waste by oxidizing and decomposing solid paraffin waste form through a boric acid catalytic reaction. In this reaction, paraffin is separated in the form of various by-products, which can then be treated through a liquid waste treatment device or an exhaust gas treatment device. The proper temperature for sample decomposition during the catalytic reaction was set through TGA analysis. Compositions of by-products and residues generated at each stage of the reaction could be analyzed to determine the state during the reaction. Finally, the boric acid waste powder was perfectly separated from paraffin waste form with disposable products through this pyrolysis process.

In this paper, the characteristic of intrinsic mode function(IMF) and its orthogonalization of ensemble empirical mode decomposition(EEMD), which is often used in the analysis of the non-linear or non-stationary signal, has been studied. In the decomposition process, the orthogonal IMF of EEMD was obtained by applying the Gram-Schmidt(G-S) orthogonalization method, and was compared with the IMF of orthogonal EMD(OEMD). Two signals for comparison analysis are adopted as the analytical test function and El Centro seismic wave. These target signals were compared by calculating the index of orthogonality(IO) and the spectral energy of the IMF. As a result of the analysis, an IMF with a high IO was obtained by GSO method, and the orthogonal EEMD using white noise was decomposed into orthogonal IMF with energy closer to the original signal than conventional OEMD.

The New Vacuum Solar Telescope (NVST) is the largest solar telescope in China. When using CCDs for imaging, equal-thickness fringes caused by thin-film interference can occur. Such fringes reduce the quality of NVST data but cannot be removed using standard flat fielding. In this paper, a correction method based on multi-scale decomposition and adaptive partitioning is proposed. The original image is decomposed into several sub-scales by multi-scale decomposition. The region containing fringes is found and divided by an adaptive partitioning method. The interference fringes are then filtered by a frequency-domain Gaussian filter on every partitioned image. Our analysis shows that this method can effectively remove the interference fringes from a solar image while preserving useful information.

본 논문에서는 새로운 비중첩 영역 분할 기법을 바탕으로 한 병렬해석의 정확도 분석이 수행된다. Tak 등(2013)에 의해 제안된 이 방법에서 분할된 하위도메인들은 서로 중첩되지 않으며 계면요소(interfacial element)라 불리는 가상연결유한요소를 통해 서로 간의 관계가 결정된다. 이 접근법의 주요 장점은 영역 분할시 floating 도메인에서 발생할 수 있는 특이강성행렬(singular stiffness matrix)을 계면요소의 결합을 이용하여 가역행렬(invertible matrix)로 변환할 수 있다는 것과 기존의 FETI법에 비하여 해석시간과 스토리지(storage) 사용을 줄일 수 있다는 것이다. 반면에 3개 이상의 하위도메인들이 한 점에서 연결되는 경우를 의미하는 cross point에서는 해석의 정확도가 저하되는 경향이 나타났다. 따라서 본 논문에서는 새로운 비중첩 영역 분할기법에 대해 다양한 영역분할의 경우에 따라 발생하는 하나의 cross point에 접촉하는 하위도메인의 개수에 따른 정확도 분석이 수행되고 정확도가 저하되는 원인분석 및 대책이 논의된다.

In this paper, a finite element domain decomposition method using local and mixed Lagrange multipliers for a large scal structural analysis is presented. The proposed algorithms use local and mixed Lagrange multipliers to improve computational efficiency. In the original FETI method, classical Lagrange multiplier technique was used. In the dual-primal FETI method, the interface nodes are used at the corner nodes of each sub-domain. On the other hand, the proposed FETI-local analysis adopts localized Lagrange multipliers and the proposed FETI-mixed analysis uses both global and local Lagrange multipliers. The numerical analysis results by the proposed algorithms are compared with those obtained by dual-primal FETI method.

Lotus-type porous nickel with cylindrical pores was fabricated by unidirectional solidification under an Ar gas atmosphere using the thermal decomposition method of the compounds such as sodium hydroxide, calcium hydroxide, calcium carbonate, and titanium hydride. The decomposed gas does form the pores in liquid nickel, and then, the pores become the cylindrical pores during unidirectional solidification. The decomposed particles from the compounds do play a rule on nucleation sites of the pores. The behavior of pore growth was controlled by atmosphere pressure, which can be explained by Boyle's law. The porosity and pore size decreased with increasing Ar gas pressure when the pores contain hydrogen gas decomposed from calcium and sodium hydroxide and titanium hydride, ; however it they did not change when the pores contain containing carbon dioxide decomposed from calcium carbonate. These results indicate that nickel does not have the solubility of carbon dioxide. Lotus-type porous metals can be easily fabricated by the thermal decomposition method, which is superior to the conventional fabrication method used to pressurized gas atmospheres.

  Exact solutions for practical-size problems in job shop will be highly inefficient. Scheduling heuristics, therefore, are typically found in the literature. If we consider real-life situations such as machine breakdowns, the existing scheduling methods

An aqueous solution of a commercial liquid synthetic detergent for kitchen use was photodecomposed in the presence of titanium dioxides powder under an atmosphere of air at room temperature. Titanium dioxides were prepared by sol-gel method from titanium iso-propoxide at different R ratio(H2O/titanium iso-propoxide) and calcined at 500℃. All titanium dioxides were characterized by XRD, BET surface area analyzer and UV-VIS spectrometer. The surface area of titanium dioxides prepared at R ratio=6 appeared higher volume about 20% than commercial TiO2 catalysts. XRD patterns of titania particles were observed mixing phase together with rutile and anatase type. Titanium dioxides prepared by sol-gel method show higher activity about 6% than commercial TiO2 catalysts on the photocatalytic degradation of a commercial liquid synthetic detergent for kitchen. The concentration of the detergent decreased to about 90% of its initial value at illumination times of 2 hour. Illumination for 30 minutes decreased the concentration of oxygen to about one-fifth of the initial value.

산소 결핍 페라이트 (oxygen deficient ferrites, ODF) MeFe2O4-δ는 약 300˚C의 낮은 온도에서 CO2를 C와 O2로 분해한다. 본 연구에서는 (Nix, Zn1-xFe24 초미세 페라이트 분말을 수열합성법으로 제조하여 CO2 분해특성을 살펴보았다. 제조된 페라이트는 XRD 분석 결과, 페라이트의 전형적인 스피넬 구조를 보여주고 있으며, ICP-AES, EDS 정량분석에 의하여 초기 혼합 조성비와 거의 동일한 조성비로 합성되었음을 알 수 있었다. 제조된 (Ni, Zn)-ferrites 분말의 BET 비표면적은 약 110mg2/g 이상의 큰 값으로 나타났으며, 입자크기는 약 5~10nm로 매우 작았다. 산소결핍 페라이트 (Nix, Zn1-x)Fe2O4-δ</TEX>의 CO2 분해 효율은 조성에 따라 큰 차이를 보이지 않았으며 3원계 (Ni, Zn)-ferrite가 Ni-ferrite보다 더 높았다.

YIG 전구체 분말은 요소의 열분해반응을 이용한 균일침전법에 의해서 질산염으로부터 제조하였다. 침전은 철이온이 먼저 침전한 후 이트륨이온이 침전하는 과정으로 이루어졌다. YGI전구체 분말은 철산화물과 비정질로 구성되어 있으며 그 분말의 대략적인 화학식은 2.5Fe2O3.Y3(OH)9-2x(CO3)x.nH2O로 되어있다. YIG 전구체 분말의 열분해과정은 dehydration, 철산화물의 recrystallization, yttrium carbonate 및 yttrium oxide의 형성과 고상반응등 여러단계로 구성되어 있다. 열처리온도가 증가함에 따라 Y2O3와 Fe2O3의 고상반응에 의해 YFeO3 intermediate을 경유해서 YIG상이 형성됨을 확인하였다. 단일상의 YIG는 1200˚C에서 6시간 공기중에서 소성함에 의해서 얻을 수 있었다.

이 연구에서는 새로운 웰要素分解의 方法을 定立하고， 이에 의거하여 간단하고， 효율성이 높고， 普遍性 이 큰 웰 有限要素룹 개발하고자 하였다. 實際의 要素는 廠念的인 Translational Element 와 Difference Element 로 分解되며， 要素의 영알f立벼힘훌t는 이 두 成分要-素의 變{立며힘~를 결합하여 얻는다. 要素分解의 基#ζ假定블 단리 함에 따라서 세 가지 의 基本形要素에 도달헬 수 있다 基本形要素칠 보완하여 Locking現像을 제가하고 수렴성을 높히는 방안으로서 減훌積分， 內部自有度의 追加및 Mixed Fomulation을 검토하였으며， 要素의 Spurious Mode를 힘j뼈하는 방법을 고안하였다. 혔植 分析을 통해서 要素의 有效性과 했率性을 검정하였다.

The Stockholm Convention, which was adopted in Sweden in 2001 to protect human health and the environment, includes regulations for Persistent Organic Pollutant Rotors such as toxic and bioaccumulatives. Currently, there are 28 types of materials. This prohibits and limits the production, use, and manufacture of products. Korea is a member of the Convention, and it is necessary to prepare management and treatment plans to address the POP trends. Thus, we experimentally investigate whether the environmentally stable incineration is achieved when the sample is thermally treated using the Lab-scale (1 kg/hr). The target samples is pesticides in liquid phase and solid phase. In this study, organic chlorinated pesticides and their thermal characteristics were analyzed. We calculated the theoretical air volume based on the element analysis results. Because the interior of the reactor is small, more than 10 times of the air ratio was injected. The retention time was set to at least 4 seconds using a margin. The incineration temperature was 850℃ and 1100℃. Thus, we experimentally investigated whether the environmentally stable incineration was achieved when the sample was thermally treated using the Lab-scale (1 kg/hr). We analyzed five types of exhaust gas; the 02 concentration was high, but the CO amount decreased. Complete combustion is difficult because of the small size of the furnace due to the nature of Lab-scale. The organic chlorine-containing pesticide had an average decomposition rate of 99.9935%. Considering the decomposition rates of organic chlorine-containing pesticide in this study, the incineration treatment at over 2 ton/hour, which is typical for a conventional incinerator, is possible. Considering the occurrence of dioxins and unintentional persistent organic pollutants, it can operate at more than 1,100℃.

본 연구에서는 공간규모분할 기법(SCDM)을 적용하여 레이더 예측강우를 산정하고, 도시홍수예보 관점에서 기상청 현업 레이더 예측강우 (MAPLE 및 KONOS)와 함께 수문학적 활용성을 평가하였다. 본 연구에서 제시한 공간규모분할 기법은 강우를 층운형과 대류성 강우로 분리하여 각각의 이동속도를 고려하여 개별예측 및 재합성하는 것이다. 수도권 영역의 세 호우 사례를 대상으로 기상청 MAPLE 및 KONOS와의 예측강우 정확도를 평가한 결과, 본 연구에서 적용한 예측기법은 기법의 단순함에 비해 양호한 예측 정확도를 보였다. 또한, 강남유역을 대상으로 각 예측강 우의 수심모의 정확도를 평가한 결과, MAPLE 및 SCDM에 비하여 KONOS가 첨두수심을 보다 정확하게 모의하였으나, 호우의 시간적 패턴 구현 의 정확도가 높지 않았다. SCDM의 경우 정량적인 오차는 다소 크게 나타났지만, 전체적으로 관측수심과 유사한 모의 양상을 보였다. 추후 부족한 정량적 정확도를 보정 기법 및 수치예보자료와의 결합을 통해 개선한다면 SCDM의 예측강우가 홍수예보를 위한 입력자료로 유용하게 활용될 수 있을 것으로 판단된다.

최근 수문자료에서 비정상성 현상들이 관측됨에 따라 비정상성 빈도해석에 관한 연구들이 활발하게 진행되고 있다. 시간에 따라 변화하는 통계 적 특성을 고려하기 위하여 다양한 형태의 비정상성 확률분포형이 제시되고 있으며, 비정상성 매개변수를 추정할 수 있는 다양한 방법들이 연구되 고 있는 추세이다. 본 연구에서는 앙상블 경험적 모드분해법을 이용한 비정상성 Gumbel 분포형의 매개변수 추정방법을 제시하고 기존에 비정상 성 매개변수 추정방법으로 주로 사용되어온 최우도법과 비교해보고자 하였다. 국내 자료의 적용을 위하여 기상청 지점의 다양한 지속기간에 대해 경향성이 나타나는 연 최대치 강우자료를 사용하였다. 적용 결과 선형적 경향성을 나타내는 자료에 대해서는 두 가지 방법 모두 적절한 모형을 선 정하였으나, 2차 곡선 형태의 경향성이 존재하는 자료에 대해서는 앙상블 경험적 모드분해법의 경우에만 이러한 경향성을 반영하는 비정상성 Gumbel 모형을 선정하였다.

수문 시계열의 분석은 수문자료를 활용한 수자원의 효율적인 운영 및 관리에 필수적인 부분이며, 특히 장기적인 수문량 예측에 널리 활용되고 있다. 이러한 수문 시계열 분석은 전통적으로 하나의 자료계열을 하나의 요인으로 파악하여 자료를 분석하고 예측해왔지만 시계열 자료가 여러 가지 요인으로 혼합되 어 하나의 자료계열로 나타내질 수 있다는 가정 하에 각 요인들을 분해하여 분석하는 방법도 널리 연구되고 있다. 본 연구에서는 경험적 모드분해법을 이용하여 주어진 수문 시계열을 다중 성분으로 분해하고 분해된 각 요소를 시계열 모형으로 재구축한 후, 구축된 요소별 시계열 모형으로부터 예측된 값을 합하여 시계열을 예측하는 방법을 이용하였으며 이를 국내 댐 유입량에 적용한 후 그 결과를 나타내었다. 기존 시계열 모형과 경험적 모드분해법을 이용한 방법의 정확도를 비교한 결과, 기존의 시계열 모형을 이용하여 자료를 예측한 결과보다 경험적 모드분해법을 적용하여 자료를 분해한 후 시계열 자료를 예측한 결과가 주어진 시계열 자료를 더 잘 나타내는 것을 알 수 있었다.

This research aims to identify regional inequitable development through the analysis of facilities distribution pattern. This study describes the concepts underlying the application of the Gini's coefficient and decomposition method to measure the regional inequitable development in Sun-chang County, Jeonbuk Province, Korea. We used the facility data surveyed for three years, from 2010 to 2012 for facility distribution pattern that RDA surveyed. These data have been serviced on the web. The Lorenz Curve presents a graphical view of the inequitable facility distribution and the Gini's Coefficients quantifies the distribution pattern. And furthermore, Gini Decomposition represents intra regional inequalities. These applied techniques can describe how the local development affects other district and change regional inequalities.

The rapid rural urban migration and aging has generated an over-depopulation problems in rural areas since the 1980s. The purpose of this study constructs the marginal size of rural over-depopulated village through the analysis of the residential disparities such as farmer's ratio, basic life service accessibility, and levels of social and economic factors for each village community. This marginal scale could support evaluating diverse rural policies, which have been planned to apply to the rural development programs at the village level. The major challenges for over-depopulated villages are the lack of basic facilities, production infrastructures and inactive communities in the village. Therefore, the quantitative analysis of rural residential disparities according to rural village scale can provide the criteria for rural over-depopulated villages. We utilized Korea Agricultural Survey Data(2010) including specific residential condition of village level. The present study adopt multinomial-logit model for quantitative analysis of different village scales and decomposition techniques to separate the direct effect by the village scale factor from the endowment effects by regional or area characteristics, and residual effect by unknown factors. The present study found that the minimum scale of a rural over-depopulated village was 40 and 60 houses for the respective conditions of farmer's ratios less than 50% and greater than 75%. It was concluded based on the study findings that threshold scale could support evaluating the diverse rural policies, which have been planned to apply to the rural development programs at the village level.

For the destruction of toxic chlorinated organic compounds, this study proposes improved supercritical water oxidation method (multistep oxidation) using sodium nitrate as an oxidizer. This method solves the problems involved in the existing supercritical water oxidation method. Multistep oxidation means that NaNO3 is oxidized to N2 via NaNO2 and NO. Toxic and hard to destroy organic substances like para-dichlorobenzen(4-DCBz), polychlorinate biphenyl(PCB) ware oxidized to non toxic substances in a condition, in which rapid pressure and temperature rise is restrained as much as possible. 4-dichlorobenzene(4-DCBz) and Polychlorinate biphenyl(PCB) in condition(450℃, pw=0.25g/cm3, 30min) Was discomposed perfectly.