목적: 본 연구는 하이드로젤 콘택트렌즈 재료에 iron (Ⅱ) phthalocyanine와 magnesium phthalocynin을 첨가하여 친수성 안의료용 콘택트렌즈를 중합한 후 물리적 및 광학적 특성을 평가하였다. 방법: 첨가제를 HEMA, NVP, MMA와 함께 공중합하였으며, 교차결합제로 EGDMA를 사용하였다. 또한 개시제로 AIBN을 사용하였다. 그리고 제조된 렌즈의 물리적, 광학적 특성을 평가하기 위해 굴절률, 함수율, 분광투과율, 인장강도 및 접촉각을 측정하였다. 또한 제조된 고분자의 자외선 차단성과 친수성 착색 콘택트렌즈의 기능성 염료로서의 활용도를 알아보았다. 결과: 제조된 콘택트렌즈의 물리적 특성을 측정한 결과 굴절률은 1.4320∼1.4330, 함수율은 38.53∼39.34%, UV-B 투과율은 33.8∼65.5%, 접촉각은 53.89∼64.45° 그리고 인장강도는 0.2790∼0.3137 kgf의 범위로 각각 측정되었다. 측정결과 magnesium phthalocyanine와 iron (Ⅱ) phthalocyanine의 첨가가 자외선의 투과율을 감소시키는 것으로 나타났으며, reference와 비교하여 접촉각은 증가되는 것으로 나타났다. 결론: Iron (Ⅱ) phthalocyanine와 magnesium phthalocyanine를 첨가한 고분자의 경우, 함수율과 굴절률을 변화시키지 않으면서 자외선을 차단할 수 있는 재료로 활용될 수 있을 것으로 기대된다.

본 연구는 무금속프탈로시아닌 색소계를 이용한 전자사진 감광체의 개발에 관한 것이다. 전하발생물질로서는 각종 형태의 무금속프탈로시아닌을 사용했고, 결합제로서는 각종 폴리머를 사용했으며, 전하이동물질로서는 히드라존유도체나 아연착화합물을 사용했다. 전하발생물질로서 사용한 α-, β-, x형의 프탈로시아닌중에서는 x형의 무금속프탈로시아닌(x-H2Pc)의 경우가 가장 좋은 감도를 보였다. 전하발생물질로서는 x-H2Pc를, 전하수송물질로서는 히드라존유도체를 사용했을 때, 다른 감광체들과 비교하여 73.1%의 높은 1.50lux·sec의 좋은 감도를 보였다.

Interfacial properties of electrode and organic thin layer is one of the most important factor in performing a Light Emitting Diodes(LED). Phthalocyanine copper was used as a buffer layer to improve interface characteristic, so that device efficiency was improved. In this study, LEDs were fabricated as like structures of Indium-Tin-Oxide (ITO) / N,N' -Diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) / 8-Hydroxyquinoline aluminum(Alq) / Aluminum(Al) and Indium-Tin-Oxide(ITO) / N,N'-Diphenyl-N,N' -di(m-tolyl)-benzidine(TPD) / 2-(4-Biphenylyl)-5(4-tert-butyl-phenyl)-1,3,4-oxadiazole(PBD) / Aluminum(Al). In these devices, CuPC was layered at electrode/organic layer interface. As position is changing and thickness is changing, devices showed characteristic luminescence efficiency and luminescence inensity respectively. We showed in this study that luminescence efficiency was improved with CuPC layer in LEDs. The efficiency of device with layer CuPC is higher than that of 2 layer CuPC. However, the luminescence of 2 layer CuPC device got higher value.

It is well known that the metallo-phthalocyanine(MPcs) are sensitive to toxic gaseous molecules such as NO2 and also chemically and thermally stable. Therefore, lots of MPcs have been studied for the potential chemical sensor for NO2 gas using quartz crystal microbalance or electrical conductivity. In this study, 2,3,9,10,16,17,23,24-[octa-(dodecyloxy)] copper phthalocyanine and 2,3,9,10,16,17,23,24-[octa-(octyloxy)] copper phthalocyanine were synthesized and their possibility of LB film preparation were tested. It was confirmed by using FT-IR, DSC, NMR, UV-Vis absorption spectroscopy and Elemental Analysis that CuPc derivatives were successfully synthesized. From the π-A characteristics and limiting areas of two CuPc derivatives it was found that the preparation of LB films with these CuPc derivatives is possible.

It is well known that the metallo- phthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as NO2 and also chemically and thermally stable, Therefore, lots of MPcs have been studied for the potential chemical sensor for NO2 gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, ultra-thin films of octa(2-ethylhexyloxy)copper-phthalocyanine were prepared by Langmuir-Blodgett method and characterized by using UV-VIS absortion spectroscopy and ellipsometry. Transfer condition, and characterization of LB films were investigated and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO2 gas as a function of film thickness and temperature were discussed.

Ultra thin films of HDSM-CuPc(Tetra-3-hexadecylsulphamoylcopperphthalocya-nine) were formed on various substrates by Langmuir-Blodgett method, where HDSM-CuPc was synthesized by attaching long-chain alkylamine(hexa-decylamine) to CuPc. The reaction product was identified with FT- IR, UV-visible absorption spectroscopies, elemental analysis and thin layer chromatography. The formation of ultrathin films of HDSM-CuPc was confirmed by FT-IR and UV-visible spectroscpies.