목적 : 본 연구는 항균 기능을 갖춘 안경테의 필요성에 주목하여 고분자 물질인 Polyvinylpyrrolidone(PVP)을 사용하여 은 나노 입자를 합성하고, 금속 안경테 소재에 코팅하여 항균성과 코팅 특성을 평가해 보고자 한다. 방법 : 안정성이 높은 고분자 물질인 PVP를 환원제, 분산제, 안정제로 사용하고 합성 온도를 달리하여 은 나노 입자를 합성하였다. 합성한 시료의 특성은 UV-visible spectrophotometer, SEM, EDS를 사용하여 분석하였으 며 paper disk diffusion method로 항균성을 평가하였다. 합성한 은 나노콜로이드를 금속 안경테 소재인 티타 늄, 스테인리스스틸 기판에 코팅하고 코팅막의 특성과 항균성을 측정하였다. 결과 : PVP를 사용하여 합성한 시료 모두에서 은(Ag)이 검출되어 은 나노 입자의 생성을 확인할 수 있었다. 합성 온도에 따른 은 나노 입자의 크기는 차이를 보였으며 Escherichia coli, Pseudomonas aeruginosa, Aspergillus brasiliensis의 경우 45℃에서 합성한 은 나노콜로이드의 항균활성이 가장 크게 나타났다. 이를 금속 안경테 소재 기판에 코팅한 후 항균성을 확인한 결과 코팅막의 항균력을 확인할 수 있었다. 결론 : PVP를 사용하여 합성한 은 나노콜로이드를 금속 안경테 소재 기판에 코팅한 결과 코팅막의 항균성이 확인되어 항균 기능을 가진 안경테 제작 시 항균 물질로 활용될 수 있을 것이라 사료된다.

Recent Engineered nanoparticles were increasingly exposed to environmental system with the wide application and production of nanomaterials, concerns are increasing about their environmental risk to soil and groundwater system. In order to assess the transport behavior of silver nanoparticles (AgNPs), a saturated packed column experiments were examined. Inductively coupled plasma-mass spectrometry and a DLS detector was used for concentration and size measurement of AgNPs. The column experiment results showed that solution chemistry had a considerable temporal deposition of AgNPs on the porous media of solid glass beads. In column experiment, comparable mobility improvement of AgNPs were observed by changing solution chemistry conditions from salts (in both NaCl and CaCl2 solutions) to DI conditions, but in much lower ionic strength (IS) with CaCl2. Additionally, the fitted parameters with two-site kinetic attachment model form the experimental breakthrough curves (BTCs) were associated that the retention rates of the AgNPs aggregates were enhanced with increasing IS under both NaCl and CaCl2 solutions.

올레핀/파라핀 혼합 기체의 분리를 위한 올레핀 촉진 수송 분리막의 제조를 위해 amide 작용기를 가지며 glassy한 특성을 보이는 polyvinylpyrrolidone (PVP) 고분자를 분리막의 matrix로서 사용하였다. 분리막의 기체 투과 실험은 propylene 과 propane 50 : 50의 부피비로 혼합된 기체를 사용하였고, bubble meter와 gas chromatography를 사용해 투과도와 선택도를 측정하였다. 또한 SEM image와 FT-IR을 통해 막의 특성을 조사하였다. 100시간의 장시간 성능 측정 결과 선택도는 약 15, 투과도는 약 1.3 GPU 이상을 각각 유지하였다. 기존의 poly(2-ethyl-2-oxazoline) (POZ)/AgBF4/Al(NO3)3 분리막과 비교함으 로써, 고분자 matrix로서의 PVP 특성을 확인하였다.

(Na, K) NbO3 thick film was successfully achieved using a sol-gel coating process with the addition of polyvinylpyrrolidone (PVP) to a metal alkoxide solution. The transparent coating solution, mixed with Nb:PVP = 1:1 in a molar ration, was synthesized by evaporating the solvent to over 62.5 wt%. Additive PVP increased the viscosity of the solution so that the coating thickness could be enhanced. The thickness of the (Na, K) NbO3 film assisted by PVP was ca. 320 nm at the time of deposition; this value is four times thicker than that of the sample fabricated without PVP. Also, due to PVP binding with the OH groups of the metal alkoxide, the condensation reaction in the film was suppressed. The crystalline size of the (Na, K) NbO3 films assisted by PVP was ca. 15 nm smaller than that of the film fabricated without PVP. After the sintering process at 700˚C, the (Na, K) NbO3 films were mainly composed of randomly oriented (Na, K) NbO3 phase of perovskite crystal structure, including a somewhat secondary phase of K2Nb4O11. However, by adding PVP, the content of the secondary phase became quite smaller than that of the sample without PVP. It was thought that the addition of PVP might have the effect of restraining the loss of potassium and that PVP could hold metalloxane by strong hydrogen bonding before complete decomposition. Therefore, the film thickness of the (Na, K) NbO3 films could be considerably advanced and made more crack-free by the addition of PVP.

Among the various roll-to-roll printing technologies such as gravure, gravure-offset, and reverse offset printing,reverse offset printing has the advantage of fine patterning, with less than 5µm line width. However, it involves complexprocesses, consisting of 1) the coating process, 2) the off process, 3) the patterning process, and 4) the set process of the ink.Each process demands various ink properties, including viscosity, surface tension, stickiness, and adhesion with substrate orcliché; these properties are critical factors for the printing quality of fine patterning. In this study, Ag nano ink was developedfor reverse offset printing and the effect of polyvinylpyrrolidone(PVP), used as a capping agent of Ag nano particles, on theprinting quality was investigated. Ag nano particles with a diameter of ~60nm were synthesized using the conventional polyolsynthesis process. Ethanol and ethylene glycol monopropyl ether(EGPE) were used together as the main solvent in order tocontrol the drying and absorption of the solvents during the printing process. The rheological behavior, especially ink adhesionand stickiness, was controlled with washing processes that have an effect on the offset process and that played a critical rolein the fine patterning. The electrical and thermal behaviors were analyzed according to the content of PVP in the Ag ink. Finally,an Ag mesh pattern with a line width of 10µm was printed using reverse offset printing; this printing showed an electricalresistivity of 36µΩ·cm after sintering at 200oC.

본 연구는 고품질의 돼지 체외 수정란을 생산하기 위하여 체외 성숙 배지에 첨가하는 polyvinylpyrrolidone(PVP)의 분자량, 첨가 농도 및 시간(실험 1)과 체외 성숙 수정 배양 단계에서 PVP의 첨가(실험 2)가 배 발생과 세포수에 미치는 효과를 검토하였다. 돼지 미성숙 난자의 체외 성숙은 NCSU 23 용액, 체외 수정은 mTBM 용액, 체외 배양은 PZM 3 용액을 이용하였다. 체외 성숙용 배지에서 PVP의 분자량, 농도 및 첨가 시

A series of experiments were designed to determine the feasibility of single dose of FSH as an effective superovulation method in rabbits. The superovulation treatments examined comparatively were as follows: 1) a single injection of 100 IU PMSG, 2) Multiple injections of 1 IU Super-OV of 2X daily for 3 days, 3) Multiple injections of 6.6 rng Folltropin-V 2X daily for 3 days, 4) Multiple injections of 13.3 rng Folltropn-V l daily for 3 days, 5) Single injection of 40 mg Folltropin-V solved in 10% PVP, and 6) Single injection of 40 mg Folltropin-V dissolved in 25% PVP. The results obtained were as follows: The nurnher of ovulation points in the single injection of 40 mg Folltropin-V dissolved in 25% PVP and multiple injections of 6.6 mg Folltropin-V 2X daily for 3 days was averaged 44.6 and 39.2, respectively, which were significantly (P<0.05) more than in a single dose of PMSG or multiple doses of Super-OV. The number of total ova recovered in the single injection of 40 mg Folltropin-V dissolved in 25% PVP and multiple injections of 6.6 mg Folltropin-V 2X daily for 3 days was averaged 30.4 and 25.9, respectively, which were significantly (P<0.05) more than in the single dose of PMSG or multiple doses of Super-OV. A similar result was obtained for the number of fertilized ova recovered from the above six treatments. From the above results it was concluded that a single injection of 40 mg Folltropin-V dissolved in 25% PVP could be an effective and simple method for superovulation in rabbits.