4-Nitrophenol (4NP) is a vital intermediate in organic industries, and its exploitation creates serious environmental issues. We propose a fluorescence quenching-based strategy with nitrogen and sulfur co-doped carbon dots (NS-CDs) for highly sensitive 4NP detection with excellent selectivity. The NS-CDs are produced through the hydrothermal process, in which citric acid serves as a carbon source and cysteamine hydrochloride as a source of N and S. The effect of doping was also studied by synthesizing undoped CDs and examining their properties. As-developed NS-CDs exhibit a bright cyan blue color with maximum emission centered at 465 nm. The fluorescence of NS-CDs is significantly quenched in an approximately linear fashion with increasing 4NP concentration (7.5–97.5 μM). The inner filter effect (IFE) and static quenching (SQ) between NS-CDs and 4NP are responsible for such fluorescence reduction. The fluorimetry technique enables the quantification of 4NP with a limit of detection (LOD) of about 0.028 μM. Moreover, the fluorescence quenching is tested for several other chemical compounds but they generate false quenching signals; only 4NP leads to fluorescence quenching of NS-CDs, demonstrating excellent selectivity. The “turn-off” fluorescence properties and visually apparent color change of the fluorescent probe reveal the excellent performance for 4NP sensing. The NS-CDs’ capability of quantifying 4NP in real water samples (tap water and drinking water) produces an excellent recovery rate ranging between 96.24 and 98.36%.

지진취약도를 산정하기 위해서는 목표 부지의 특성을 제대로 표현할 수 있는 입력 지진파의 산정이 중요하다. 본 논문에서는 국내 외 강진 및 중‧약진 지역에서의 입력 지진파에 대한 단자유도 모델의 지진취약도를 분석하였다. 분석을 위한 첫 번째 단계로, 국외 강 진 기록 중 근/원거리에서 측정한 2개의 입력 지진파 세트와 국내 중·약진 지역 특성에 적합한 입력 지진파 2개의 세트, 총 4개의 입력 지진파 세트를 선정하였다. 대상 구조물로는 3가지 고유주기에 대한 비선형 단자유도 모델을 적용하였고, 취약도 분석을 위해 증분동 적해석을 이용하였다. 또한, 4가지 손상 상태를 정의하고, 손상 상태 각각에 대해 4가지 입력 지진파 세트의 고유주기별 지진취약도 결과를 제시하였다.

The process of carbonization followed by a high-temperature halogenation removal of radionuclides is a promising approach to convert low-radioactivity spent ion-exchange (IE) resins into freereleasable non-radioactive waste. The first step of this process is to convert spent ion-exchange resins into the carbon granules that are stable under high-temperature and corrosive-gas flowing conditions. This study investigated the kinetics of carbonization of cation exchange resin (CER) and the changes in structures during the course of carbonization to 1,273 K. Both of model-free and modelfitted kinetic analysis of mixed reactions occurring during the course of carbonization were first conducted based on the non-isothermal TGAs and TGA-FTIR analysis of CER to 1,272 K. The structural changes during the course of carbonization were investigated using the high-resolution FTIR and C-13 NMR of CER samples pyrolyzed to the peak temperature of each reaction steps established by the kinetic analysis. Four individual reaction steps were identified during the course of carbonization to 1,273 K. The first and the third steps were identified as the dehydration and the dissociation of the functional group of —SO3-H+ into SO2 and H2O, respectively. The second and the fourth steps were identified as the cleavage of styrene divinyl benzene copolymer and carbonization of pyrolysis product after the cleavage, respectively. The temperature and time positions of the peaks in the DTG plot are nearly identical to those of the peaks of the Gram Schmidt intensity of FTIR. The structural changes in carbonization identified by high-resolution FTIR and DTG are in agreement with those by C-13 NMR. The results of a detailed examination of the structural changes according to NMR and FTIR were in agreement with the pyrolysis gas evolution characteristics as examined by TGA-FTIR.

In the last years, we have witnessed the consolidation of an increasing number of media channels including but not limited to, social media, brand sites, podcasts and the recent developments into the metaverse (Blazquez, 2023). Consumers are exposed to multiple stimuli with shorter attention spans which makes challenging for brands to create meaningful relationships that can sustain brand loyalty. It is important to revisit the role of campaigns that communicate brand-related messages and aim to affect brand image. Christmas advertising has become a part of consumers’ festive rituals (Cartwright et al., 2016) and engendering a positive response is particularly important at this time of year given that it is associated with love, friendship and reconciliation. These campaigns that appeal to a wider target audience, find in traditional media an important channel to get to their customers but also use digital channels which make them more inclusive.

In the deep geological repository, a considerable quantity of cementitious materials is generally used for structural stability of subcomponents such as grout and concrete plug of disposition tunnel. Strong alkaline leachates (pH>13) are produced after cement is dissolved by groundwater inflow from bedrock. When the leachates are transported to bentonite porewater (e.g. buffer and backfill) and thereby water exchange occurs, the physical properties of bentonite such as swelling capacity and hydraulic conductivity are changed, which eventually affects the safety function and long-term stability of engineered barrier system (EBS). Thus, in this paper, we reviewed the performance assessment methodology for cement-bentonite interaction in the operating license application for the Finnish deep geological repository, and suggested what to prepare for the analysis on the domestic disposal facility. In Finland, thermal-hydraulic-chemical analysis for dissolution of montmorillonite by alkaline leachates resulting from cement degradation during the saturation of bentonite was carried out using PRECIP code. From this analysis, it was confirmed that effect on pH was considered to be more significant than that on temperature and bentonite saturation. As a result of this analysis, it was predicted that all primary minerals (including montmorillonite, quartz, and calcite) were dissolved and some secondary minerals (e.g. chalcedony and celadonite) was precipitated by alkaline cement leachates transported to the bentonite. In addition, it was shown that silica was preferentially released while the montmorillonite was dissolved, thus cementation of the bentonite was occurred. Through this phenomenon, the swelling capacity of bentonite is reduced and the hydraulic conductivity of bentonite is increased, which have a significant impact on the performance of the buffer and backfill. Considering this, study on spreading of alkaline leachates, which is a condition for dissolution of montmorillonite, is necessary for the performance assessment of the domestic deep geological repository. However, this requires the site-specific data for the following in the disposal site: (a) distribution in fractured bedrock and pore structure (e.g. porosity, pore size distribution and pore morphology) in the bedrock, (b) hydraulic gradient and salinity concentration of groundwater, and (c) flux and velocity of groundwater. Results of this study is considered to be directly utilized to the conceptual design and performance assessment of the deep geological repository in Korea, provided that additional data on microbiological properties of groundwater are obtained for the site selected.

Strong acidic wastewater containing a radionuclide is generated from the decontamination of radioactively contaminated wastes or equipment. This wastewater is generally treated though a precipitation process using an alkali (alkali earth) hydroxides. In this precipitation process, a significant amount of alkali (alkali earth) sulfates are generated, which is the reason for the increase in the radioactive waste generation. In this study, a method for separating only radionuclides and metal ions from the wastewater was evaluated. For this reason, precipitation behaviors of radionuclides and metal ions by hydrazine injections were investigated using equilibrium calculations. In addition, behaviors of hydrazine decomposition after removal of radionuclides and metal ions were analyzed for recycling the wastewater.

프리지아 ‘Sunny Gold’는 농촌진흥청 국립원예특작과학원 에서 2010년 노랑색 반겹꽃 프리지아 육성계통 ‘036010’을 모본으로 진노란색 홑꽃 ‘Golden Flame’을 부본으로 교배하여 획득한 종자로부터 2011년 진노란색 겹꽃의 향기가 강한 프리지아 계통을 선발하여 품종화 하였다. 2011년부터 2016년까지 개화 생육특성검을 수행하였으며 핵심수요자의 기호도 평가를 통해 선발되어 2017년 ‘Sunny Gold’ 로 명명되었다. ‘Sunny Gold’는 RHS color chart YO17B의 노란색 겹꽃 프리지아 품종으로 화폭은 6.7cm로 대조품종 ‘Golden Flame’ 6.1cm에 비해 크고, 분지수는 6.5로 다수확성 품종이다. 초장이 101.9cm로 초세가 강하다. ‘Sunny Gold’의 소화수 및 소화장은 각각 13.0개, 9.3cm이며 개화소요일수는 137.7일이다. 이 품종의 절화수명은 약 9일이며 자구번식력은 5.3배로 대조 품종 ‘Golden Flame’ 4.3배에 비해 우수하다. 전자코를 이용한 PCA분석결과 PC1과 PC2는 각각 99.3%와 0.6%로 전체 변이량의 99.9%를 반영하고 있다. Rader plot 분석결과 총 6개 센서에서 모두 ‘Sunny Gold’의 센서값이 향기가 강한 상용품종 ‘Yvonne’의 값에 비해 높게 나타나 ‘Sunny Gold’의 향기가 더 강한 것으로 나타났다.

본 연구는 2020년 3월 18일부터 20일까지 영동지역에 강풍이 발생했던 사례(남고북저형, 대류권계면 접힘에 의해 급격하게 발달하는 저기압)의 종관 및 열역학적/운동학적특성을 조사하기 위해 AWS 관측 자료, 종관 일기도, ECMWF 재분석 자료, 레윈존데, 윈드프로파일러 자료를 이용하였다. 분석결과, 사례 기간 영동지역 5개소에서 관측된 최대 순간 풍속은 20 m s−1 이상으로 나타났으며 대관령(27.7 m s−1)에서 가장 강하게 나타났다. 종관분석에서는 남고북저형의 기압배치와 함께 영동지역으로 등압선의 모양이 사인(sin)파 형태를 보이며 강한 기압경도력에 의해 강풍이 발달 하다가 3월 19일부터는 한반도 북부지역에서 하루 내에 19 hPa 이상의 기압 하강과 함께 발달하는 저기압에 의해 지속적인 강풍이 발달했다. 북강릉 단열선도에서 역전층의 고도는 하층 강풍대와 함께 산 정상의 약 1-3 km 고도에 위치 하였고, 레윈존데 및 수직 측풍 장비(윈드프로파일러)의 연직 바람장 분석 결과와 일치함을 확인할 수 있었다. 특히 열역학적 및 운동학적 연직 분석에서, 하층에서 온위의 연직 경도에 의한 강한 바람과 대류권계면 접힘에 의한 위치 소용돌이도의 발달이 영동지역 강풍 발생에 큰 역할을 한 것으로 사료된다.

The stochastic method is applied to simulate strong ground motions at seismic stations of seven metropolises in South Korea, creating an earthquake scenario based on the causative fault of the 2016 Gyeongju earthquake. Input parameters are established according to what has been revealed so far for the causative fault of the Gyeongju earthquake, while the ratio of differences in response spectra between observed and simulated strong ground motions is assumed to be an adjustment factor. The calculations confirm the applicability and reproducibility of strong ground motion simulations based on the relatively small bias in response spectra between observed and simulated strong ground motions. Based on this result, strong ground motions by a scenario earthquake on the causative fault of the Gyeongju earthquake with moment magnitude 6.5 are simulated, assuming that the ratios of its fault length to width are 2:1, 3:1, and 4:1. The results are similar to those of the empirical Green’s function method. Although actual site response factors of seismic stations should be supplemented later, the simulated strong ground motions can be used as input data for developing ground motion prediction equations and input data for calculating the design response spectra of major facilities in South Korea.