YAG (Yttrium Aluminum Garnet, Y3Al5O12) has excellent plasma resistance and recently has been used as an alternative to Y2O3 as a chamber coating material in the semiconductor process. However, due to the presence of an impurity phase and difficulties in synthesis and densification, many studies on YAG are being conducted. In this study, YAG powder is synthesized by an organic-inorganic complex solution synthesis method using PVA polymer. The PVA solution is added to the sol in which the metal nitrate salts are dissolved, and the precursor is calcined into a porous and soft YAG powder. By controlling the molecular weight and the amount of PVA polymer, the effect on the particle size and particle shape of the synthesized YAG powder is evaluated. The sintering behavior of the YAG powder compact according to PVA type and grinding time is studied through an examination of its microstructure. Single phase YAG is synthesized at relatively low temperature of 1,000 ℃ and can be pulverized to sub-micron size by ball milling. In addition, sintered YAG with a relative density of about 98 % is obtained by sintering at 1,650 ℃.
본 연구에서는 점근해석 및 논로컬 이론에서 요구하는 4차 이상의 고차 미분근사를 수행하기 위하여 계방정식에 혼합변분이론을 적용하여 MLS 차분법으로부터 구해지는 고차 미분근사의 정확도를 큰 폭으로 향상시킨다. 또한, MLS 차분법에 존재하는 세 가지 조건변수에 따른 고차미분근사의 정확도를 비교·분석한다. 혼합변분이론의 합응력을 후처리하여 변위의 미분을 근사할 경우 기존의 변위장 기반 계방정식의 차분 결과에 비해 미분 차수가 2차 낮아진다. 해석 범위내 절점 수가 과도하게 많거나 기저 차수가 클 경우 MLS 차분법의 영향영역 내에서 과적합(overfitting)이 발생한다. 또한 영향영역이 최적 범위 이상으로 넓어질 경우 근사의 정확도가 떨어진다. 위 내용을 사인 하중을 받는 단순지지보 수치예제로부터 확인하였다.
Recognition that R&D (Research and Development) project is important for national competitiveness and sustainable economic growth has been extended all over the world, and the government financial support for R&D projects has increased. Therefore, government needs to make a decision about whether it invests in any project or not, and this decision-making complies with evaluation of the relevant experts. In this study, we improve project selection methods and procedures based on outranking methods which have mainly focused on general project environmental analysis in order to apply to the government support R&D project selection, and suggest R&D project selection methods and procedures that meet the purpose of government support. Therefore, it demonstrates that improved methods organize more profitable project groups to the purpose of the selecting government support R&D project than existing methods. Also, it illustrates that it is possible for decision makers to analyze variously by changing composition of selecting project group with variation of α.
Evidence of liquefaction during the 2017 Pohang earthquake has highlighted the urgent need to evaluate the current seismic design standard for liquefaction in Korea, particularly the liquefaction triggering standard. With the simplified method, which is the most popular method for evaluating liquefaction triggering, the factor of safety for liquefaction triggering is calculated via the cyclic stress ratio (CSR) and the cyclic resistance ratio (CRR). The parameters in the CSR and CRR have undergone changes over time based on new research findings and lessons learned from liquefaction case-histories. Hence, the current design standard for liquefaction triggering evaluation in Korea should also reflect these changes to achieve seismic safety during future earthquakes. In this study, liquefaction susceptibility criteria were discussed initially and this was followed by a review of the current liquefaction triggering codes/guidelines in other countries and Korea. Next, the parameters associated with the CSR such as the maximum ground acceleration, stress reduction factor, magnitude scaling factor, and overburden correction factor were discussed in detail. Then, the evaluation of the CRR using the SPT N-value and CPT qc-value was elaborated along with overburden and clean-sand correction factors. Based on this review of liquefaction triggering evaluation standards, recommendations are made for improving the current seismic design standard related to liquefaction triggering in Korea.
This study analyzed the appropriate placement method by floor for evacuating all occupants during the nighttime through evacuation simulation. The analysis results are as follows. First, when non-self evacuating patients were placed on the first floor, 266 patients and 6 workers were found to be evacuated after 460 seconds. This result shows that it is meaningful to place non-self evacuating patients on the lower floor with a time that is faster than 540 seconds, which is an evaluation criterion set using life Safety standards for human. This result is a time faster than the evaluation criteria of 540 seconds, which is set using the life safety standards, and it can be confirmed that it is meaningful to place non-self evacuating patients on the lower floor. Next, as a result of placing non-self evacuating patients from the first floor to the fourth floor, it was found that evacuation of all occupants required 460 seconds for the first floor, 834 seconds for the second floor, 1,508 seconds for the third floor, and 1,915 seconds for the fourth floor. These results indicate that the placement of non-self evacuating patients on the rest of the floors, except for the first floor, can lead to dangerous results in excess of 540 seconds, which is a flashover time. As a result, it is necessary to place non-self evacuating patients on a lower floor for safe evacuation. The study has limitations except for comparative analysis of changes in evacuation time due to changes in the number of workers at eldery care hospitals and situations in which fire-fighting facilities such as sprinkler facilities operated. It is necessary to study the evacuation time linked to the operation of the fire-fighting facilities and the evacuation time according to the change in the number of workers in the future.
The Korean government has been carrying out the marine ranch development project since 1998 with the purpose of responding to the decrease in coastal fishery resources and fishery income, preparing a systematic management system for the sustainable use of fishery resources and realizing advanced fisheries power by expanding and upgrading fisheries resource development projects. In addition, the government established the Korea Fisheries Resources Agency and promoted projects for the protection and management of fishery resources by increasing basic productivity by artificially creating marine forests in areas where whitening events occur. Since the project of building marine ranches and marine forests requires immense government financial support, it is important to estimate the economic value and thoroughly evaluate the feasibility of the project. In this paper, the project of non-market economic value of the development of marine ranches and the development of marine forests was estimated. CVM (Contingent Valuation Method) was applied as a methodology for benefits estimation. Prior to the analysis, a one-on-one interview survey was conducted with participation of 512 residents and 514 residents respectively for the project of creating a marine ranch and developing a marine forest. A DBDC (Double-Bounded Dichotumous Choice) model was applied in the WTP (Willingness To Pay) analysis model and the socioeconomic variables of the surveyor, such as sex, age, education and income, were reflected in the model. The economic benefits from the two projects, namely, building of marine ranches and developing marine forests were estimated to be equal to 4,608 won and 7,772 won per household per year, respectively. According to the results of the survey, it seems that respondents think that marine forests are more valuable than marine ranches. This is as a result of ordinary citizens’ thought that the marine ranches are more cost-effective than the marine forests. The benefits estimated through this study can be used for analysis of economic feasibility prior to carrying out the project of building marine ranches and developing marine forests, and are considered to be the valuable for policy-making purposes and finding social and economic consensus.
In this paper, AgCl/Ag3PO4/diatomite photocatalyst is successfully synthesized by microemulsion method and anion in situ substitution method. X-ray diffraction (XRD), photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), and ultraviolet-visible spectroscopy (UV-Vis) are used to study the structural and physicochemical characteristics of the AgCl/Ag3PO4/diatomite composite. Using rhodamine B (RhB) as a simulated pollutant, the photocatalytic activity and stability of the AgCl/Ag3PO4/diatomite composite under visible light are evaluated. In the AgCl/Ag3PO4/diatomite visible light system, RhB is nearly 100 % degraded within 15 minutes. And, after five cycles of operation, the photocatalytic activity of AgCl/Ag3PO4/diatomite remains at 95 % of the original level, much higher than that of pure Ag3PO4 (40 %). In addition, the mechanism of enhanced catalytic performance is discussed. The high photocatalytic performance of AgCl/Ag3PO4/diatomite composites can be attributed to the synergistic effect of Ag3PO4, diatomite and AgCl nanoparticles. Free radical trapping experiments are used to show that holes and oxygen are the main active species. This material can quickly react with dye molecules adsorbed on the surface of diatomite to degrade RhB dye to CO2 and H2O. Even more remarkably, AgCl/Ag3PO4/diatomite can maintain above 95 % photo-degradation activity after five cycles.
여러 센서를 이용한 구조물의 구조 응답을 모니터링하는 사례가 증가하고 있다. 그러나 비용과 관리 문제로 인해 제한된 센서만이 구조물에 설치되어 일부의 구조 응답만을 수집하는 경우가 대부분이다. 이는 구조물의 전체 거동을 분석하는데 장애요소로 작용하게 된다. 따라서 제한된 센서를 이용해 센서가 설치되지 않은 위치에서의 응답을 신뢰할 수 있는 수준으로 예측하는 기술이 필요하다. 본 연구에서는 제한된 정보를 이용해 저층 건물 구조물의 지진 응답을 예측하는 해석적 연구를 수행한다. 활용 가능한 응답 정보는 1층과 최상층의 가속도 응답만을 사용할 수 있다고 가정한다. 두 정보를 이용하면 구조물의 1차 고유진동수를 얻을 수 있다. 1층 가속도 정보는 구조물의 가력 정보로 활용한다. 최상층의 가속도이력응답에 대한 오차와 대상 구조물의 1차 고유진동수 오차를 최소화하는 구조물의 질량과 강성 정보를 유전자알고리즘을 이용해 예측하는 기법을 제시한다. 제약조건은 고려하지 않는다. 탐색공간을 의미하는 설계변수의 범위를 결정하기 위해 인공신경망 기반의 파라미터 예측기법을 제시한다. 또한 유전자알고리즘을 통해 얻게 되는 해를 개선시키기 위해 앞서 언급한 인공신경망을 활용한다. 제시한 기법을 검증하기 위해 5층 구조물 예제를 사용한다.
기존 주경로 연구는 과거 핵심기술의 진화를 구조화하는데 적합하나, 패러다임 전환기의 잠재적 후보기술 파악과 주류기술 교체를 예측하기는 어렵다. 본 연구는 링크 중요도, 성장 속도 지표, 핵심 루트 방법을 복합해 특허 인용 네트워크로부터 주경로상의 기술을 대체할 잠재적 후보기술들을 파악하는 방법을 제시한다. 링크 중요도에 기반해 주경로를 도 출하고, 성장 속도 지표를 활용해 주경로 대비 고성장하는 잠재적 후보기술 경로들을 도출한다. 성장 속도 지표는 상대적 성장성 평가에 활용되고, 이를 통해 주경로를 교체할 가능성이 높은 잠재적 후보기술을 파악할 수 있다. 차세대 기술 후보들이 다수 등장해 경쟁하고 있는 바이오 연료기술에 적용한 결과 실제 차년도에 주경로상의 기술을 교체하는 후보기술들을 파악할 수 있었다. 기술 패러다임 전환기 후보기술에 대한 정량적 분석을 가능하게 하고, 주 경로 기법의 활용범위를 미래기술 예측으로 확대한 측면에서 학문적 의의가 있다. 실무에서 는 차세대 후보기술 파악의 정확도 제고에 기여할 수 있다.
This study is aimed at improving the plasma resistance of Al2O3 ceramics on which plasma resistant YAS(Y2O3- Al2O3-SiO2) frit is melt-coated using a simple heat-treatment process. For this purpose, the results of phase analysis and microstructural observations of the prepared YAS frits and the coating layers on the Al2O3 ceramics according to the batch compositions are compared and discussed with regard to the results of plasma resistance test. The prepared YAS frits consist of crystalline or amorphous or co-existing crystalline and amorphous phases according to the batch compositions, depending on the role and content of each raw material. The prepared YAS frit is melt-coated on the densely sintered Al2O3 ceramics, resulting in a dense coating layer with a thickness of at least ~ 80 m. The YAS coating layer consists of crystalline YAG(Y3Al5O12), Y2Si2O7, and Al2O3 phases, and YAS glass phase. Plasma resistance of YAS coated Al2O3 ceramics is strongly dependent on the content of the YAG(Y3Al5O12) and Y2Si2O7 crystalline phases in the coating layer, especially on the content of the YAG phase. Comparing the weight loss of YAS coating ceramics with values obtained for commercial Y2O3, Al2O3, and quartz ceramics, the plasma resistance of the YAS coating ceramics is 6 times higher than that of quartz, 2 times higher than that of Al2O3, and 50 % of the resistance of Y2O3.
A variety of composite powders having different aluminum and carbon contents are prepared using various organic solvents having different amounts of carbon atoms in unit volume as ball milling agents for titanium and aluminum ball milling. The effects of substrate temperature and post-heat treatment on the texture and hardness of the coating are investigated by spraying with this reduced pressure plasma spray. The aluminum part of the composite powder evaporates during spraying, so that the film aluminum content is 30.9 mass%~37.4 mass% and the carbon content is 0.64 mass%~1.69 mass%. The main constituent phase of the coating formed on the water-cooled substrate is a non-planar α2 phase, obtained by supersaturated carbon regardless of the alloy composition. When these films are heat-treated at 1123 K, the main constituent phase becomes phase, and fine Ti2AlC precipitates to increase the film hardness. However, when heat treatment is performed at a higher temperature, the hardness is lowered. The main constitutional phase of the coating formed on the preheated substrate is an equilibrium gamma phase, and fine Ti2AlC precipitates. The hardness of this coating is much higher than the hardness of the coating in the sprayed state formed on the water-cooled substrate. When hot pressing is applied to the coating, the porosity decreases but hardness also decreases because Ti2AlC grows. The amount of Ti2AlC in the hot-pressed film is 4.9 vol% to 15.3 vol%, depending on the carbon content of the film.
In a previous paper, ambient vibration tests were conducted on a cable stayed bridge with resilient-friction base isolation systems (R-FBI) to extract the dynamic characteristics of the bridge and compare the results with a seismic analysis model. In this paper, a nonlinear seismic analysis model was established for analysis of the bridge to compare the difference in seismic responses between nonlinear time history analysis and multi-mode spectral analysis methods in the seismic design phase of cable supported bridges. Through these studies, it was confirmed that the seismic design procedures of the “Korean Highway Bridge Design Code (Limit State Design) for Cable Supported Bridges” is not suitable for cable supported bridges installed with R-FBI. Therefore, to reflect the actual dynamic characteristics of the R-FBI installed on cable-supported bridges, an improved seismic design procedure is proposed that applies the seismic analysis method differently depending on the seismic isolation effect of the R-FBI for each seismic performance level.
In this study, a field bridge test was conducted to find the dynamic properties of cable supported bridges with resilient-friction base isolation systems (R-FBI). Various ambient vibration tests were performed to estimate dynamic properties of a test bridge using trucks in a non-transportation state before opening of the bridge and by ordinary traffic loadings about one year later after opening of the bridge. The dynamic properties found from the results of the tests were compared with an analysis model. From the result of the ambient vibration tests of the cable supported bridge with R-FBI, it was confirmed that the dynamic properties were sensitive to the stiffness of the R-FBI in the bridge, and the seismic analysis model of the test bridge using the effective stiffness of the R-FBI was insufficient for reflecting the dynamic behavior of the bridge. In the case of cable supported bridges, the seismic design must follow the “Korean Highway Bridge Design Code (Limit State Design) for Cable supported bridges.” Therefore, in order to reflect the actual behavior characteristics of the R-FBI installed on cable-supported bridges, an improved seismic design procedure should be proposed.
IEC 60079-10-1 edition 2.0, the global standard for hazardous area classification, was newly revised in 2015. There are many differences compared to the previous edition 1.0 version, first released in 2008, so it has caused confusion in the industry. In case of edition 1.0, the hazardous area extent can be derived through the mathematical formula, but in case of edition 2.0, there was the problem that the exact hazardous area extent was not known because of the mathematical formula of the plot for applying the hazardous area extent was not presented. In this study, we converted the plot introduced in edition 2.0 to CAD format and derived the plot as the mathematical equations. Through this, we suggest the hazardous area extent formula of three states (heavy gas, diffusive, jet). As the IEC committee did not provide the mathematical formula of the hazardous area extent according to the release characteristic, it is impossible to apply the exact hazardous area extent. In this study, a mathematical approach was derived for the plot introduced in edition 2.0, which can reduce the confusion of the applying hazardous area extent.
There are several methods of peak-shaving, which reduces grid power demand, electricity bought from electricity utility, through lowering “demand spike” during On-Peak period. An optimization method using linear programming is proposed, which can be used to perform peak-shaving of grid power demand for grid-connected PV+ system. Proposed peak shaving method is based on the forecast data for electricity load and photovoltaic power generation. Results from proposed method are compared with those from On-Off and Real Time methods which do not need forecast data. The results also compared to those from ideal case, an optimization method which use measured data for forecast data, that is, error-free forecast data. To see the effects of forecast error 36 error scenarios are developed, which consider error types of forecast, nMAE (normalizes Mean Absolute Error) for photovoltaic power forecast and MAPE (Mean Absolute Percentage Error) for load demand forecast. And the effects of forecast error are investigated including critical error scenarios which provide worse results compared to those of other scenarios. It is shown that proposed peak shaving method are much better than On-Off and Real Time methods under almost all the scenario of forecast error. And it is also shown that the results from our method are not so bad compared to the ideal case using error-free forecast.
덤프 트럭 데크의 경량화를 통한 연료 소비를 줄이고 에코 친화적인 설계를 위해서는 정확한 구조 분석이 필요하다. 지금까지 데크의 하중은 정수압 또는 토압 이론을 기반으로 계산되었다. 이 방법으로 데크의 하중 불균일을 계산할 수 없다. 하중 분포는 골재 입자의 크기 분포 및 상호 작용에 따라 달라진다. 이산요소법은 유한요소법보다 효과적으로 골재의 거동을 시뮬레이션할 수 있다. 본 논문에 서는 벌크 밀도와 안식각을 측정하여 주요 특성을 얻었다. 15톤 덤프 트럭 데크는 범핑, 브레이킹 및 회전 시의 운동 조건을 적용하여 얻은 하중을 사용했다. 시뮬레이션은 이산요소해석 소프트웨어인 EDEM을 사용했다. 데크의 응력 및 변형 분포는 NASTRAN에 의해 계산되었다. 측정된 값과 비교하였고, 이를 통해 DEM 시뮬레이션의 결과는 수학적 가정에 의한 결과보다 정확함을 확인하였다.