초고성능 콘크리트의 시멘트량 저감을 위해 시멘트와 치환하여 사용가능한 시멘트계 재료를 사용한 연구를 사전 조사하여 플라이애시와 고로슬래그를 선정하였다. 시멘트와 실리카흄 조합으로 120 MPa 이상의 압축강도를 보인 배합을 사용해 바인더조합의 변화에 따른 압축강도, 휨강도를 평가하였다. 플 라이애시와 고로슬래그를 사용한 배합은 유동성이 향상되었으며, 플라이애시는 압축강도가 실리카흄만 사용한 경우보다 다소 감소하였으나, 고로슬래그를 사용한 실험체는 실리카흄만 사용한 실험체와 유사 한 결과를 나타내었다.

초고성능 콘크리트의 충전밀도 향상을 위해 잔골재보다 미세한 실리카플라워를 사용하여 물리적 특 성변화를 분석하였다. 평균입경 300㎛의 규사를 100㎛인 실리카플라워로 일부 치환하여 압축강도, 휨 강도 변화와 유동성 변화를 측정하였다. 실리카플라워 사용으로 인해 압축강도와 휨강도가 향상되었으 나 유동성 저하로 인해 동일한 유동성을 확보하기 위해 추가적인 고성능감수제의 투입이 필요하였다. 유동성 저하는 바인더 차이에는 큰 영향을 받지 않았으며, 추가적인 고성능감수제 투입은 유사하게 나 타났다.

현장에 적용하는 콘크리트 강도가 증가함에 따라 초고성능 콘크리트의 적용 분야가 넓어지고 있다. 초고성능 콘크리 트에는 강섬유를 일반적으로 사용하고 있지만, 이를 대체하기 위해 다양한 섬유를 연구에 적용하고 있다. 대표적으로 슈퍼섬유 라고 알려진 아라미드 섬유가 있다. 본 연구에서는 초고성능 콘크리트의 특성이 구조물 보수보강 및 내진보강에 적용하기에 적 합하다고 판단하여, 슈퍼섬유 중 하나인 파라아리미드 섬유와 조합한 복합섬유를 혼입한 초고성능 콘크리트를 보-기둥 접합부에 내진보강재로 활용하여 특성을 분석하였다. 초고성능 콘크리트의 내진보강 효과를 확인하였으며 내진상세를 적용한 실험체와 유사한 거동을 확인하였다. 초고성능 콘크리트의 높은 강도로 인해 기존 콘크리트가 파괴되는 양상이 나타나 초고성능 콘크리 트의 보수보강 효과를 모두 발휘하지 못하고 있어 추가 연구를 통해 최적의 보강단면을 설정한다면 내진보강재료로 활용할 수 있을 것으로 판단된다.

건축 및 토목 구조물의 대표 재료인 콘크리트의 핵심지표인 구조 성능을 개선하기 위해 많은 연구가 진행되고 있다. 아울러 구조물의 크기가 커질수록 강도가 높은 고기능 콘크리트의 필요성이 높아지고 있으며, 특히 내구성과 내후성이 우수한 콘크리트 재료의 개발이 필요한 실정이다. 따라서, 본 연구에서는 강섬유와 함께 파라-아라미드 원사를 이용하여 피복 및 꼬임, 원사 데니어 및 섬유 길이에 대한 차별화된 원사가공을 적용한 복합재료인 슈퍼섬유를 콘크리트에 혼입하여 구조적인 성능을 평가하고자 하였다. 본 연구를 통해 최적화된 슈퍼 섬유로 보강된 슈퍼 콘크리트는 도로, 교량, 상수도 및 하수도 등 기존 SOC 의 수리 및 보강에 적용될 유망한 성장 기술 분야가 될 것으로 예상된다.

Many companies make considerable efforts in implementing supply chain management systems to increase their competitiveness. In particular, there are significant investments in their ICT (Information and Communication Technology) and supply chain. However, considerable diversity exists in how well firms have been able to assimilate ICT and leverage the business value of it. In addition, studies on supply chains, particularly Real Time Enterprise (RTE) competence, which is cited for rapid information sharing and dynamic capabilities for each role in the supply chain, are insufficient. The purpose of this paper is to explore and evaluate effect of ICT utilization capabilities, including ‘ICT internal cooperative capabilities’ and ‘ICT operational flexibility capabilities’, on RTE capabilities (flexibility, visibility and prediction) and supply chain performance. To validate the research model proposed in the study, survey was conducted on companies using ICT along the supply chain of manufacturing industries. 216 data were used, SPSS and AMOS were used for the analysis methods. Study results showed that ICT internal collaboration capabilities affect agility, one of RTE capabilities, but not visibility and prediction, and ICT operational flexibility capabilities have affected all three RTE capacities. And, RTE capabilities had a huge impact on supply chain performance as expected. In this paper, it has been found that the ICT capabilities in manufacturing are an important factor in improving RTE capabilities that are important in the supply chain and improving the performance of the supply chain.

본 연구는 초고성능 콘크리트의 성능을 보다 향상시키기 위해 현재 콘크리트 보강에 사용하는 섬유들을 조합한 복합 섬유를 제작하여 복합섬유 혼입 초고성능 콘크리트의 강도 특성을 분석하였다. 복합섬유 4종과 단일섬유 3종을 각각 혼입하여 유동성과 압축, 휨강도 실험을 진행하였다. 복합섬유와 단일섬유 혼입 시험체 모두 유동성 평가를 만족하였으며, 단일섬유가 조금 더 우수한 성능을 나타내었다. 강도 평가결과 파라아라미드 섬유와 강섬유를 조합한 복합섬유 2종이 가장 우수한 결과를 나타내었으며, 복합섬유 직경 차이에 따라 압축 및 휨강도 보강효과가 다르게 나타난 것을 확인할 수 있었다. 압축강도 감소를 최소화하며 휨강도를 증가시킨 결과를 통해, 복합섬유는 단일섬유 간의 단점을 서로 보완할 수 있을 것으로 판단되며, 본 연구를 통해 차후 콘크리트의 다양한 재료적 특성을 보강하는 복합섬유도 충분히 제작 가능할 것으로 판단된다.

This paper reviews on nano-materials as part of a study to apply nano-technology related technologies to the construction field. First, the synthesis method of nano-materials was examined. Secondly, the mechanical application method of nano-materials was investigated. Finally, the analysis method of nano-materials was investigated.

Recently, redevelopment and reconstruction projects have caused problems such as depletion of natural aggregates, and the use of recycled aggregate is being reevaluated as an optimal alternative. Therefore, in this study, the mechanical and deformation characteristics of Environment-Friendly Recycled Coarse Aggregate (here after, EFRCA) concrete reinforced with para-aramid fiber with high strength and high elasticity are examined. The experimental main parameters were EFRCA replacement ratio (0, 30 and 50%) and para-aramid fiber volume fraction (0, 0.75 and 1.0%). Experimental results show that the EFRCA concrete has lower compressive strength than plain concrete. However, compared with the natural aggregate, the EFRCA concrete, which exhibited low material properties, showed almost the same performance as plain concrete, such as increased flexural strength and improved ductility by incorporating para-aramid fibers. Through the experiment, it is considered that the most suitable para-aramid volume fraction is 0.75%. Based on these results, the experimental results related to the performance degradation of EFRCA concrete containing para-aramid fibers are secured and basic data for determining the reuse possibility and reinforcement method of structures are presented.

It is a well known that concrete is strong for compression and weak for tension. For reinforcing the weakness and improving the performance about concrete, various methods are used. Fiber reinforced concrete that is one of them has been investigated in this study. The function of fiber in concrete is to improve the stress strain relation and toughness, crack control. It’s applied from normal strength concrete to ultra-high performance concrete. But it is essential to disperse fiber uniformly and to prevent aggregation of fiber in concrete, in order that fiber reinforced concrete show the sufficient performance. The various properties of fiber affect the essential properties, for instance, length and diameter of fiber, source, etc. So, this study evaluated the ultra-high performance concrete with mixed in composite fiber.

The Cellulose Nanocrystal (CNC) of dispersion condition is important factor when reinforce concrete or cement composite as CNC, because it is closely related to the strength reinforcement. Before the CNC is utilized to reinforcement of concrete or cement composite, it is essential to evaluate the dispersion properties. Therefore, the objective of the present study is to evaluate the dispersion of CNC. In this experiment, the specimen was prepared to the type of CNC suspension in accordance with weight ratio of CNC and the dispersion time of sonication. The first property, the dispersion properties of CNC, was evaluated by measuring turbidity and absorbance. The second property, the dispersion stability, was measured through the sediment time.

The purpose of this study is to investigate the optimum conditions of dispersion and strength to maximize the mechanical properties of woody cellulose nano–crystal (CNC). As a dispersing method, ultrasonic dispersing machine and magnetic stirrer were used as the mechanical dispersion method. The mixing ratio of cellulose nano-crystals (CNCs) was 0.2% and the dispersion time was 10 minutes. Steam curing was carried out for 6, 24 and 48 hours. Based on the experimental results, we will propose source technology regarding CNC for construction materials.

호박과피는 과육에 비해 매우 높은 16%의 식이섬유를 함유하고 있었고, 이로부터 분리된 호박과피펙틴은 53%의 galactuonic acid를 함량을 나타내었으나, 타 펙틴에 비해 매우 높은 메틸기를 함유한 high methoxyl pectin(HMP)로 확인되었다. 또한 0.34%의 낮은 수준이나, 일부 아세틸기를 함유하고 있어, 기존의 펙틴질과 차별화될 수 있는 구조적 특징을 보유하고 있었다. 담즙산과의 결합능에 있어서는 다른 펙틴질에 비해 비교적 높은 9%의 결합능을 보여, 식품 소재로서의 우수한 특성을 보유하고 있어 향후 식품 소재로서의 개발이 가능할 것으로 판단되었다.

기업에서의 설비 대체에 관한 의사결정의 사례로서 구형설비를 신형설비로 대체함으로써 비용절감이 있음을 분석한다.

Analytical method for preservatives in food was developed using gas chromatography/mass spectrometry (GC/MS). Propionic acid, sorbic acid, benzoic acid, ethyl salicylate, ethyl p-hydroxy benzoate, iso-propyl p-hydro benzoate, n-propyl p-hydroxy benzoate, iso-butyl phydroxy benzoate, n-butyl p-hydroxy benzoate, p-hydroxy benzoic acid and dehydro acetic acid were extracted from cooling beverage with diethyl ether. The polar hydroxyl and carboryl groups of food preservatives were derivatized with N-methyl-N-tent-butyldimethylsilyl-trifluoroacetamide (MTBSTFA) to form the corresponding tert-butyldimethyl-silylated derivatives, and submitted to GC/MS analysis. The mass spectra of the derivatives were investigated for the selection of monitoring ions for multi-residue analysis of 11 preservatives by GC/MS. The macro program was also developed for the qualitative analysis of these preservatives in food.

Analytical method for saccharin in foods was developed using gas chromatography/mass spectrometry(GC/MS). Methylation with diazomethane, acetylation with MBTFA, and silylation with MSTFA and MTBSTFA were compared. Methylation of saccharin produced N- methylated saccharin as the major product and O-methylated saccharin as the minor one. Silylation of saccharin with MSTFA and MTBSTFA resulted in the formation of the corresponding O-silylated products, respectively. The derivatization of saccharin was optimized with MSTFA. The ions at m/z 240, 255, and 166 were monitored to characterize saccharin.

Analytical method for synephrine and octopamine in citrus fruits, drinks containing citrus fruit, and human urine was developed using gas chromatography / mass spectrometry(GC/MS). Silylation with MSTFA, acetylation with MBTFA, and trimethylailylation with MSTFA followed by tritluoroacetylation with MBTFA were compared. The selective derivatization of aynephrine and octopamine was optimized with two derivatizing reagents ; MSTFA and MBTFA. The ion at mlz 267 was monitored to characterize the benzyl group of the both compounds. Synephrine was detected in the concentrations of 0.46-1.88 ug/g for citrus fruits and 1.2-8.1 ug/ml for drinks. The urinary excretion data of aynephrine showed the highest concentration at the period of 8-20 hours after drinking orange juices and total amounts of its urinary excretion calculated as a parent compound was 11-14% of a dose during 48 hours. Octopamine was not detected in citrus fruits, drinks, and human urine.