An one dimensional atmosphere-canopy-soil interaction model is developed to estimate of the heat budget parameter in the atmospheric boundary layer. The canopy model is composed of the three balance equations of energy, temperature, moisture at ground surface and canopy layer with three independent variables of T_f(foliage temperature), T_g(ground temperature), and q_g(ground specific humidity). The model was verified by comparative study with OSUID(Oregon State University One Dimensional Model) proved in HAPEX-MOBILHY experiment. Also we applied this model in two dimensional land-sea breeze circulation. According to the results of this study, surface characteristics considering canopy acted importantly upon the simulation of meso-scale circulation. The factors which used in the numerical experiment are as follows ; the change for a sort of soll(sand and peat), the change for shielding factor, and the change for a kind of vegetation.

A global carbon cycle model (GCCM), that incorporates interaction among the terrestrial biosphere, ocean, and atmosphere, was developed to study the carbon cycling and global carbon budget, especially due to anthropogenic CO2 emission. The model that is based on C, ^13C and ^14C mass balance, was calibrated with the observed CO2 concentration, δ^13C and Δ^14C in the atmosphere, Δ^14C in the soil, and Δ^14C in the ocean. Also, GCCM was constrained by the literature values of oceanic carbon uptake and CO2 emissions from deforestation. Inputs (forcing functions in the model) were the C, ^13C and ^14C as CO2 emissions from fossil fuel use, and ^14C infection into the stratosphere by bomb-tests. The simulated annual carbon budget of 1980s due to anthropogenic CO2 shows that the global sources were 5.43 Gt-C/yr from fossil fuel use and 0.91 Gt-C/yr from deforestation, and the sinks were 3.29 Gt-C/yr in the atmosphere, 0.90 Gt-C/yr in the terrestrial biosphere and 2.15 Gt-C/yr in the ocean. The terrestrial biosphere is currently at zero net exchange with the atmosphere, but carbon is lost via organic carbon runoff to the ocean. The model could be utilized for a variety of studies in CO_2 policy and management, climate modeling, CO2 impacts, and crop models.

The adsorption of the anionic surfactants, sodium lauryl sulfate (SLS) and sodium dodecylbenzene sulfonate (SDBS) anion surfactants from aqueous solutions with nonionic resins, Amberlite XAD-2, XAD-4 and XAD-7 at temperatures in 15∼45℃ range was studied. Several adsorption isotherm models were used to fit the experimental data. The best results were obtained with the Redlich-Peterson equation and the Freundlich model provided remarkably good fits. For a particular resin at a particular temperature, SDBS was more extensively adsorbed than SLS. The highest adsorption were obtained with XAD-4 resin and the specific surface area of the resins plays a major role in adsorption of the surfactants. Estimations of the isosteric heat of adsorption were indicative of an exothermic process, and their magnitudes manifested a physisorption process.

Surface heat balance of the northern sea of Cheju Island for summer in 1993 and 1994 is analyzed using the observation data obtained by Marine Research Institute, Cheju National University. Each flux elements at the sea surface is derived from the marine meteorological reports with application of an aerodynamical bulk method for the turbulent heat fluxes, and empirical formulae for the long-wave radiation heat fluxes. The flux divergence of oceanic heat transport and the rate of heat storage in the ocean are estimated as residual. The features of the surface heat balance are mainly decided by the solar radiation flux and the latent heat flux for 1994. But the Bowen Ratios were large for 1993. This means that the sensible heat fluxes were nearly equal to the latent heat fluxes for 1993. In this period, mean flux divergence of oceanic heat transport is about 130 W/㎡.

It is very important to assess accurately the terms which are included in the heat budget equation of soil surface because they are used in the GCM and meso-scale circulation modeling as well as in the micrometeorological studies. Each terms in the heat budget equation change according to the soil moisture content. So, it is necessary to specify clearly the relations between soil moisture content and these terms. Special experiment with ricrometeorological measurements was executed to study these relations at Environmental Research Center of Tsukuba University, Japan. The results are as follow: 1. The soil moisture contents of 1 ㎝ and 4 ㎝ depth are oscillated with one day period in drying process and the amplitude of variation of l cm depth is greater than that of 4 ㎝. 2. Increase in soil moisture contents due to precipitation result in decrease of albedo with step function. 3. Sensible heat is in reverse proportion to the soil moisture content and latent heat is in direct proportion to it. Latent heat is more sensitive than sensible heat according to the soil moisture variation. Net long wave radiation have high correlation with soil moisture. 4. Comparing with the radiative term with the flux term in wetting process due to precipitation, the energy transfer of the aero and thermodynamic flux is greater than that of the radiative heat flux.