This study evaluated the potential of two unmodified seaweeds, Sargassum fulvellumand Ishige okamurae, as low-cost adsorbents for aqueous phosphate removal under low phosphorus conditions. Batch tests (25±1°C; initial phosphorus concentration, approximately 0.67 mg/L) were performed for up to 72 h at adsorbent doses of 1.0, 5.0. and 10.0 g/L, and time-series concentration profiles showed a rapid decrease within the first 12-24 h, followed by an approach to equilibrium. The removal efficiency increased with the seaweed dose; after 72 h, the maxima were approximately 12.0% for I. okamuraeand 12.4% for S. fulvellum, the mass-specific adsorption capacity (q) was relatively higher for I. okamuraeat the lowest dose. The adsorption data were obtained at a single initial concentration, equilibrium isotherm analysis was performed on an exploratory basis. The Freundlich and Langmuir isotherms yielded low coefficients of determination, establishing the basic performance of unmodified seaweeds at low phosphate levels. Overall, these results indicate the need forkinetic analysis using time-dependent models, together with material optimization (i.e., surface modification), to enhance the capacity and practical applicability of seaweeds for phosphorus adsorption.

생태계에서 인산염은 중요한 영양물질이지만, 일정 농도 이상일 경우 부영양화의 원인이 된다. 본 연구는 수중 인산염의 제거효율 향상을 위해 Cu(Ⅱ)용액을 이용하여 분말활성탄의 표면개질을 진행하였으며, 회분식 실험을 통해 인산염의 흡착 특성을 분석하였다. SEM 분석을 통해 PAC-Cu 표면에 구리 기반의 결정을 보았고, 용출실험 결과 구리가 정량적으로 24 mg/g 용출된 것을 제시하였다. BET 분석결과 개질 후 비표면적과 기공 부피가 각각 7.53%, 8.66%로 유사하게 감소하였다. 제거 효율 실험에서 PAC-Cu는 PAC대비, 중성인 pH조건에서 최대 3.46배 높은 인산염 흡착능을 보였다. pH 실험에서 PAC의 경우 pH 6에서 최대 효율을 나타내고 있으나, PAC-Cu는 넓은 pH 범위(pH 5~8)에서 일정한 제거효율을 보였다. 등온흡착 모델링 결과, Langmuir와 Sip모델 적용했을 때 최대흡착량은 각각 52.3 mg/g과 126 mg/g으로 PAC의 9.48 mg/g과 31.6 mg/g보다 높은 값을 나타내고 있다. 반응속도실험의 경우, PAC-Cu와 PAC모두에서 30분 이내에서 모두 평형에 도달하였으나, PAC-Cu가 PFO 및 PSO 모델 적용시 높은 k값을 가진다.

This study examined the simultaneous application of absorption and adsorption by adding granular activated carbon to tap water (Absorbent-A) and sodium hypochlorite (Absorbent-B), with the aim of improving the removal performance of gaseous acetaldehyde applying hybrid process. Prior to the main experiment, preliminary tests were conducted to assess the effects of HOCl concentration (50~150 ppm) and reactor temperature (25~35oC). In the main experiment, the removal performance under activated carbon-added conditions was compared using the concentration ratio (Co/ Ci) and its rate of change over time. As a result, the addition of activated carbon led to a more gradual saturation and concentration change compared to the non-addition condition, with the addition showing the most stable trend. This study suggests a basic reference for improving the performance of conventional absorbents enhancing the durability and efficiency with the activated carbon as an auxiliary material for future field applications.

후쿠시마 원자력 발전소 사고 이후 3.3 × 1016 Bq의 세슘(Cs)이 환경에 노출되면서, 수원으로부터 방사성 세슘 (Cs)을 제거하는 것에 대한 관심이 증대되었다. 지속 가능한 개발과 환경 안전 측면에서 오염된 환경을 복원하는 것은 매우 중요한 이슈이다. 유해 오염물질을 효과적으로 제거하기 위해 분리막 기반의 분리/정제 기술은 매우 각광받는 기술 중 하나 이다. 특히 막 흡착(membrane adsorber) 기술은 흡착과 막 분리를 결합할 수 있는 기술로 수용액에서 오염물질을 제거하는 데 매우 유용한 기술이다. 특히 전기방사 분리막은 높은 기공률, 다양한 고분자 활용가능 그리고 다양한 응용 분야 등의 특징 으로 지난 수십 년 동안 많은 연구가 수행되어 왔다. 본 리뷰 논문은 오염된 물에서 세슘을 제거하기 위한 프러시안 블루 (Prussian blue)가 포함된 전기방사 기반 막 흡착 소재 제조에 대한 다양한 기술을 리뷰하였다.

Korea is a major chestnut producer, and about half of its production is discarded as chestnut shells. This study aimed to manufacture an environmentally friendly adsorbent using these wastes. For this purpose, the optimum carbonization temperature of chestnut shells was derived through thermogravimetric analysis, with structural change confirmed through SEM analysis. The results showed that the sample that carbonized at 350oC for 60 min after phosphorylation had both the highest initial acetaldehyde removal rate and the longest duration compared to other samples. As a result, an eco-friendly adsorbent for acetaldehyde was produced from chestnut shell biomass. Through this research, it was confirmed that the adsorbent can be effectively used for acetaldehyde control while addressing the issue of recycling chestnut shell wastes.

This study aims to prepare bamboo-based activated carbons with surface modifications, focusing on carbon dioxide (CO2) capture in public indoor spaces. The surface of the activated carbon adsorbents was chemically modified through three steps: carbonization, steam activation, and chemical treatment using potassium hydroxide (KOH) and potassium sulfamate (KSO3NH2). The specific surface area and pore volume of the obtained adsorbent (BSAC-KN) were 1,246 m2/g and 0.74 cm3/g, respectively. The surface modification resulted in an adsorption capacity of up to 3.79 mmol-CO2/ g-AC for carbon dioxide. In addition, the expansion of the specific surface area and the enhanced physico-chemical interaction between the weak acidic CO2 molecules and the basic AC surface improved adsorption capacity.

The focus of this study was on the preparation of a clinoptilolite-based adsorbent, utilizing natural zeolite, to adsorb and remove ammonia (NH3) emitted from various environmental facilities, and to evaluate its performance. To create an adsorbent suitable for humid environments, hydrophobicity was introduced through HCl acid treatment. The impact of acid concentration and treatment time was analyzed to optimize the preparation conditions. As a result, the adsorbent treated with 0.5 M HCl for 2 hours demonstrated the highest NH3 adsorption performance. These findings suggest that the developed adsorbent could serve as an effective solution for controlling NH3 emissions in humid environments, contributing to the mitigation of environmental pollution and odor issues.

In this study, copper oxide, manganese oxide and zeolite, clays containing catalysts were prepared to remove hydrogen sulfide emitted in odor of industry. In order to change the heat treatment temperature, a catalyst was prepared 100 degrees from 600 degrees to 1,000 degrees. GC-MS was used to confirm the hydrogen sulfide removal performance. Although the removal performance produced at 600 degrees was maintained by and large, the removal performance decreased as the temperature increased. In particular, the catalyst manufactured at 900 and 1000 degrees had low removal performance. To find out the cause of the decrease in removal performance, the analytical devices XRD, BET, XRF were used. In order to confirm the properties of the catalyst before and after adsorption, SEM-EDS and CS were used. As a result of analyzing the Cu-Mn catalyst, it was confirmed that the material was adsorbed on the surface. To confirm the adsorbent material, SEM-Mapping was employed. And it was verified that the sulfur was adsorbed. Measuring the SEM-EDS 3Point, it was confirmed to be about 25.09%. Another test method CS analyzer (Carbon/Sulfur Detector) was also deployed. As a result of the test, sulfur was confirmed to be about 27.2%. So comparing the two sets of data, it was verified that sulfur was adsorbed on the surface.

높은 종횡비와 원자 수준의 얇은 두께를 갖는 다공성 2D 소재는 고성능 분리막 제작에 활용된다. 이를 위해서는 다공성 2D 소재를 다공성 지지체 위에 균일하게 도포할 수 있는 코팅법이 필수이다. 본 연구는 이를 위한 제올라이트 MFI 나노막의 간단하면서도 효과적인 코팅법을 제시한다. 직접합성법으로 합성된 제올라이트 MFI 나노막은 물에 분산되면서 동 시에 표면 활성을 보여, 이 특성을 활용하여 소수성 계면에 흡착시키는 것이 가능하다. 소수성 개질을 다양한 형태의 지지체 에 적용하여, 이들 표면에 고밀도의 나노막 흡착 코팅이 가능함을 보였다. 또한, 이 흡착코팅의 반복 수행을 통해 나노막의 완전피복을 달성하고, 이를 연속적인 MFI 필름 및 멤브레인으로 성장시킬 수 있었다. 이 간단한 코팅법은 제올라이트 나노막 뿐만 아니라, 표면활성을 보이는 다른 2D 소재에도 적용 가능할 것으로 보이며, 2D 소재의 활용도를 제고할 수 있을 것이다.