We conducted a study on excessive doping of the Cr and In elements in Bi-Sb-Te materials satisfying the Hume- Rothery rule, and investigated the resulting electrical and thermal properties. From X-ray diffraction (XRD) results, we confirmed the formation of a single phase even with excessive doping. Through analysis of electrical properties, we observed the highest enhancement in electrical characteristics at y = 0.2, suggesting that the appropriate ratio of Bi-Sb significantly influences this enhancement. Using the Callaway-von Baeyer (CvB) model to assess scattering due to point defects, we calculated the experimental point defect scattering factor (ΓCvB.exp), which was notably high due to the substantial differences in volume and atomic weight between the substituted (Cr, In) and original (Bi, Sb) elements. Additionally, we conducted a single parabolic band (SPB) modeling analysis of materials with compositions y = 0.1 and 0.2, where, despite a decrease in densityof- states effective mass (md *) during the enhancement process from y = 0.1 to 0.2, a sharp increase in non-degenerate mobility (μ0) led to an 88 % increase in weighted mobility (μw). Furthermore, analyzing zT with respect to nH revealed a 51 % increase in zT at a composition of y = 0.2. This study confirmed a significant reduction in lattice thermal conductivity with the co-doping strategy, and with further compositional studies to improve electrical properties, we anticipate achieving high zT.

We report the effect of plastic deformation on the thermoelectric properties of n-type Bi2Te2.5Se0.5 compounds. N-type Bi2Te2.5Se0.5 powders are synthesized by an oxide-reduction process and consolidated via sparkplasma sintering. To explore the effect of plastic deformation on the thermoelectric properties, the sintered bodies are subjected to uniaxial pressure to induce a controlled amount of compressive strains (-0.2, -0.3, and -0.4). The shaping temperature is set using a thermochemical analyzer, and the plastic deformation effect is assessed without altering the material composition through differential scanning calorimetry. This strategy is crucial because the conventional hotforging process can often lead to alterations in material composition due to the high volatility of chalcogen elements. With increasing compressive strain, the (00l) planes become aligned in the direction perpendicular to the pressure axis. Furthermore, an increase in the carrier concentration is observed upon compressive plastic deformation, i.e., the donorlike effect of the plastic deformation in n-type Bi2Te2.5Se0.5 compounds. Owing to the increased electrical conductivity through the preferred orientation and the donor-like effect, an improved ZT is achieved in n-type Bi2Te2.5Se0.5 through the compressive-forming process.

Thermoelectric (TE) energy harvesting, which converts available thermal resources into electrical energy, is attracting significant attention, as it facilitates wireless and self-powered electronics. Recently, as demand for portable/wearable electronic devices and sensors increases, organic-inorganic TE films with polymeric matrix are being studied to realize flexible thermoelectric energy harvesters (f-TEHs). Here, we developed flexible organic-inorganic TE films with p-type Bi0.5Sb1.5Te3 powder and polymeric matrices such as poly(3,4-eethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and poly (vinylidene fluoride) (PVDF). The fabricated TE films with a PEDOT:PSS matrix and 1 wt% of multi-walled carbon nanotube (MWCNT) exhibited a power factor value of 3.96 μW ‧ m-1 ‧ K-2 which is about 2.8 times higher than that of PVDF-based TE film. We also fabricated f-TEHs using both types of TE films and investigated the TE output performance. The f-TEH made of PEDOT:PSS-based TE films harvested the maximum load voltage of 3.4 mV, with a load current of 17.4 μA, and output power of 15.7 nW at a temperature difference of 25 K, whereas the f-TEH with PVDF-based TE films generated values of 0.6 mV, 3.3 μA, and 0.54 nW. This study will broaden the fields of the research on methods to improve TE efficiency and the development of flexible organic-inorganic TE films and f-TEH.

Thermoelectric materials and devices are energy-harvesting devices that can effectively recycle waste heat into electricity. Thermoelectric power generation is widely used in factories, engines, and even in human bodies as they continuously generate heat. However, thermoelectric elements exhibit poor performance and low energy efficiency; research is being conducted to find new materials or improve the thermoelectric performance of existing materials, that is, by ensuring a high figure-of-merit (zT) value. For increasing zT, higher σ (electrical conductivity) and S (Seebeck coefficient) and a lower к (thermal conductivity) are required. Here, interface engineering by atomic layer deposition (ALD) is used to increase zT of n-type BiTeSe (BTS) thermoelectric powders. ALD of the BTS powders is performed in a rotary-type ALD reactor, and 40 to 100 ALD cycles of ZnO thin films are conducted at 100oC. The physical and chemical properties and thermoelectric performance of the ALD-coated BTS powders and pellets are characterized. It is revealed that electrical conductivity and thermal conductivity are decoupled, and thus, zT of ALD-coated BTS pellets is increased by more than 60% compared to that of the uncoated BTS pellets. This result can be utilized in a novel method for improving the thermoelectric efficiency in materials processing.

High-temperature and high-pressure post-processing applied to sintered thermoelectric materials can create nanoscale defects, thereby enhancing their thermoelectric performance. Here, we investigate the effect of hot isostatic pressing (HIP) as a post-processing treatment on the thermoelectric properties of p-type Bi0.5Sb1.5Te3.0 compounds sintered via spark plasma sintering. The sample post-processed via HIP maintains its electronic transport properties despite the reduced microstructural texturing. Moreover, lattice thermal conductivity is significantly reduced owing to activated phonon scattering, which can be attributed to the nanoscale defects created during HIP, resulting in an ~18% increase in peak zT value, which reaches ~1.43 at 100oC. This study validates that HIP enhances the thermoelectric performance by controlling the thermal transport without having any detrimental effects on the electronic transport properties of thermoelectric materials.

PURPOSES : In this study, the thermal conductivity properties and mechanical performance of a thermally conductive asphalt mixture that can be applied to increase the efficiency of deicing asphalt pavements are evaluated. METHODS : Graphite powder and carbon fiber, which are inexpensive carbon materials, were added to the asphalt mixture to its conductivity. To determine the optimal mixing ratio of the carbon materials, the dispersibility, thermal conductivity, and performance of the conductive asphalt mixture were evaluated. The performance of the mixture was evaluated in terms of its volume characteristics, Marshall stability, dynamic modulus, indirect tensile strength (IDT), and wheel-tracking tests. RESULTS : The thermal conductivity of the asphalt mixture containing 2% graphite is 1.81 W/mK, which is approximately twice (0.94 W/mK) that of a general asphalt mixture. Meanwhile, the graphite-added asphalt mixture indicates a much higher temperature increase rate than the general asphalt mixture, and its surface temperature after 60 min is 7.5 ℃ higher. In addition, it reaches 0 ℃ from -10 ℃ at a rate 1.5 times higher than that required by the general asphalt mixture. When both 2% graphite and 1% carbon fiber are added, the thermal conductivity improves to 2.03 W/mK, and the conductivity is similar at all locations of the slab specimen location, which indicates no dispersibility issue. The results of the mechanical performance evaluation shows that the higher the ratio of the carbon material, the lower is the dynamic modulus and IDT at 20 ℃, which decreases the crack resistance. Meanwhile, the results of the Hamburg wheel-tracking test at 50 ℃ show an improvement in the permanent deformation resistance. CONCLUSIONS : The results of the conductivity and performance evaluation show that the optimal ratio is the combination of 2% graphite and 0.5% carbon fiber. This suggests that the conductive asphalt mixture incorporated with carbon materials can efficiently transfer heat generated from the heating layer at the bottom of the pavement to the pavement surface.

Thermoelectric materials can reversely convert heat and electricity into each other; therefore, they can be very useful for energy harvesting from heat waste. Among many thermoelectrical materials, SnSe exhibits outstanding thermoelectric performance along the particular direction of a single crystal. However, single-crystal SnSe has poor mechanical properties and thus it is difficult to apply for mass production. Therefore, polycrystalline SnSe materials may be used to replace single-crystal SnSe by overcoming its inferior thermoelectric performance owing to surface oxidation. Considerable efforts are currently focused on enhancing the thermoelectric performance of polycrystalline SnSe. In this study, we briefly review various enhancement methods for SnSe thermoelectric materials, including doping, texturing, and nano-structuring. Finally, we discuss the future prospects of SnSe thermoelectric powder materials.

Atomic layer deposition (ALD) is a promising technology for the uniform deposition of thin films. ALD is based on a self-limiting mechanism, which can effectively deposit thin films on the surfaces of powders of various sizes. Numerous studies are underway to improve the performance of thermoelectric materials by forming core-shell structures in which various materials are deposited on the powder surface using ALD. Thermoelectric materials are especially relevant as clean energy storage materials due to their ability to interconvert between thermal and electrical energy by the Seebeck and Peltier effects. Herein, we introduce a surface and interface modification strategy based on ALD to control the performance of thermoelectric materials. We also discuss the properties of the interface between various deposition materials and thermoelectric materials.

PURPOSES : In this study, we aimed to investigate the heat transfer characteristics of asphalt mixtures by water saturation. METHODS : On the basis of the literature review, the heat transfer characteristics of the samples were analyzed using a thermal accumulation experiment. The types of samples used were WC2 (dense asphalt mixture), ReWC2 (used 30% recycled aggregate), and PA13 (drainage asphalt mixture). The samples were compacted using a gyratory compactor. An infrared lamp simulating insolation was used to continuously heat the asphalt sample. Through this experiment, the upper and lower temperatures and heat flux of the specimen according to its thickness and condition were measured, and the change in its thermal conductivity was analyzed. RESULTS : The results of the laboratory experiment indicated that the dry sample showed lower thermal conductivity than the saturated sample. The amount of evaporation varied depending on the internal pores of the sample. Additionally, the amount of evaporation changed the heat transfer characteristics of the specimen. CONCLUSIONS : An asphalt mixture with high porosity decreased the degree of increase in thermal conductivity, compared to mixtures with low porosity, under semi-saturated conditions; this was attributed to the difference in thermal conductivity between air and water during saturation. The results of this study on the heat transfer characteristics of asphalt pavements could be used as basic data for thermal energy harvesting of asphalt pavements.

‘협의’는 제도적으로 만들어진 것이 아니라 대체로 동란의 시대에 자생적으로 형성 된 것이라 본질상 ‘탈중심적’이고 ‘반사회적’인 성향을 지닌다. 본고는 협의 서사가 ‘탈중심’적이고 ‘반사회’적 성질을 보유하고 있는 사기의 ｢자객열전｣과 ｢유협열전｣ 의 협의 서사를 궁구한다. 상기한 협의 고사에서 인물들 사이에서 일어나는 행동의 연쇄를 살피면, 혹은 ‘(조건 걸기)–주고–받고–답례하기’라는 조건부 증여가 서사를 끌어가고 혹은 ‘주고-받기’라는 순수 증여가 반복되는 것을 발견할 수 있다. 따라서 ‘답례’의 발생 여부에 주의하여 ‘주고–받기’의 과정에 천착해서 조건부 증여와 순수 증여가 어떻게 서술되어 의미를 형성하는지를 규명하고자 한다.

본 연구는 효과적인 열전도를위한 거시적 구조 구성과 단위 구조 변화의 동시 설계를 위한 위상 최적화 방법을 제시한다. 거시적 규모의 구조 내에서 위치에 따른 단위 구조의 형태 변화는 거시적 규모뿐만 아니라 미시적 단위의 설계도 가능하며 등방성 단위 구조를 사용하는 것보다 더 나은 성능을 제공할 수 있다. 이 결과로 두 구성을 결합한 기능적으로 등급의 복합 구조가 생성된다. 대표 체적 요소 (RVE) 방법은 형태 변화에 따른 다중 재료 기반 단위 구조의 다양한 열전도 특성을 얻기 위해 적용된다. RVE 분석 결과를 바탕으 로 머신 러닝 기법을 이용하여 특정 형태의 단위 구조물의 물성치를 도출할 수 있다. 거시적 위상 최적화는 기존의 SIMP 방법을 사용하여 수행되며, 거시 구조를 구성하는 단위 구조는 동시 최적화 과정에 따라 열전도 성능을 향상시키기 위한 다양한 형태를 가질 수 있다. 제안된 방법의 효과를 확인하기 위해 열 컴플라이언스 최소화 문제의 수치예가 제공된다.

본 연구는 2006년 MBC 게임에서 제작한 게임 관련 모큐멘터리 (페이크 다큐멘터리) “철권열전” 시즌 1을 세밀하게 분석한다. 게임 산업이 발달하고 진화함에 따라, 경쟁, 게임 조사, 인터뷰 등과 같은 게임 관련 영상과 비디오들 또한 제작되고 있다. 오늘날에는 많은 사람들이 이러한 게임 관련 미디어를 온라인과 오프라인에서 시청하며, 게임 관련 미디어는 여가를 위한 그들의 생활의 일부가 되었다. 하지만, 게임 관련 모큐멘터리는 아직까지 전 세계적으로 많이 제작되지 않았으며, 그러므로 연구도 충분치 않다. 그러므로 본 연구는 모큐멘터리의 특징을 분석하고 탐구하는 것을 시도한다. 구체적으로, 본 연구는 일본 반다이 남코에서 제작한 대전액션게임 철권을 기반으로 하는 게임 관련 모큐멘터리 “철권열전”의 다양한 특징들을 탐구하며 구체적으로 1) 스토리 2) 영상 타입 3) 허구성 항목으로 조사한다. 이를 통해, 조사되지 않은 분야를 탐구하는 게임 관련 모큐멘터리의 질적 연구를 실시할 뿐만 아니라, 게임과 미디어 산업에 유의미한 함축성들을 제공한다.

Boundary element solution method is introduced for radiation heat transfer problem with objects inside a 2-D enclosure, where shadow zone exists. Surfaces are assumed as diffuse gray in a transparent medium. Boundary integral and boundary element equations were derived from radiation transfer equation, and their theory is reviewed. Also the process of solution methods to implement the boundary element method is analysed and explained with consideration of shadow effects. BEM solution results are compared with two test problems and are found to be good agreements with the both analytic and ANSYS Fluent numerical solutions. Therefore the current BEM analysis for radiation heat transfer problem can be considered as verified, and their efficacy with engineering applicability is established as a result.

Nanoparticles of PbTe are prepared via chemical reaction of the equimolar aqueous solutions of Pb(CH3COO)2 and Te at 120°C. The size of the obtained particles is 100 nm after calcination in a hydrogen atmosphere. Dense specimens for the thermoelectric characterization are produced by spark plasma sintering of prepared powders at 400°C to 500°C under 80 MPa for 5 min. The relative densities of the prepared specimens reach approximately 97% and are identified as cubic based on X-ray diffraction analyses. The thermoelectric properties are evaluated between 100°C and 300°C via electrical conductivity, Seebeck coefficient, and thermal conductivity. Compared with PbTe ingot, the reduction of the thermal conductivities by more than 30% is verified via phonon scattering at the grain boundaries, which thus contributes to the increase in the figure of merit.

In this study, we developed a thermoelectric generation system for coastal fishing boats that allows for a high-density arrangement of thermoelectric modules, verified the improvement in performance by conducting comparative analysis between field test results and results from previous studies. The developed thermoelectric generation system was installed in a 3-ton gill-netter to analyze the engine revolutions per minute and energy production per day for each fishing process over a period of 20 days. From the experimental results, the maximum electric energy generated was 207.1 Wh, the minimum was 53.93 Wh and the average electric energy was 129.98 Wh. In accordance with the increasing of the engine r.p.m., the maximum electric production was 183 W at 1,500 r.p.m. It was approximately 80.5% of designed capacity, 227.2 W. Considering the result in the earlier research was 50.7% of designed capacity, 115.8 W. It was improved by 30% compared to the earlier one. The fishing operation was classified as departure, fishing and arrival. From the result on production analysis of electric energy, the composition of energy was 63% in fishing, 19.5% in departure and 17.5% in arrival. The electric energy production per unit hour was 42.8% in arrival, 32.9% in departure and 24.3% in fishing.