Recent industrial developments have increased the use of Volatile Organic Compounds (VOCs). Odors (e.g., are hydrogen sulfide, mercaptan- type, amine- type and other irritating pungent gaseous or volatile substances)., which are disgusting and disgusting to humans. Currently, regenerative thermal oxidation (RTO), regenerative catalytic oxidation (RCO), Carbon Adsorption Tower, etc. are used for their control to remove VOCs. In this experiment, we report the use of silicon carbide (SiC) for the control of four common VOCs called BTEX (i.e., benzene, toluene, ethyl benzene and, xylene (BTEX))., which is a representative material of VOCs, was removed by using silicon carbide (SiC). The heating SiC was heated be tween 400oC and 700oC in a microwave,. As a result, we observed the removal efficiency of BTEX from 10 ppm to 50 ppm was. At 400oC and 500oC, 0.6~60.3% and 11~64.7% the removal efficiency were achieved, with exponential increase at the temperature from 500oC. At 600oC, it showed more than 69.0~100% removal efficiency of most BTEX materials. Finally, At 700oC, it was confirmed that all BTEX materials were completely removed.
This study was carried out to investigate the effect of malodor and VOCs reduction that could be achieved through the installation of a vapor recovery system (VRS) in a gas station. It was revealed that the reduction efficiencies of malodor by running VRS were about 93% around the oil feeder, 32% in the office and 45% in the site boundary. Specifically, it was remarkable that reduction efficiencies of BTEX over 90% were recorded through VRS operation. In addition, the results of continuous monitoring of THC around the oil feeder device provided good evidence of the inhibition of oil mist diffusion after running VRS.
Two major enzymes, monooxygenase and dioxygenase, were exampled and explained to understand the microbial degradation mechanisms of BTEX (benzene, toluene, ethylbenzene, and xylene). And we investigated and reported the related microbial species of each enzyme. In addition, we reviewed the degradation mechanism and pathway of each substrate. Lastly, we added the microbial degradation properties under the various conditions.
To date, carbon and nitrogen co-doped photocatalysts (CN-TiO2) for environmental application focused mainly on the aqueous phase to investigate the decomposition of water pollutants. Accordingly, the present study explored the photocatalytic performance of CN-TiO2 photocatalysts for the purification of indoor-level gas-phase aromatic species under different operational conditions. The characteristics of prepared photocatalysts were investigated using X-ray diffraction, scanning emission microscope, diffuse reflectance UV-VIS-NIR analysis, and Fourier transform infrared (FTIR) analysis. In most cases, the decomposition efficiency for the target compounds exhibited a decreasing trend as input concentration (IC) increased. Specifically, the average decomposition efficiencies for benzene, toluene, ethyl benzene, and xylene (BTEX) over a 3-h process decreased from 29% to close to zero, 80 to 5%, 95 to 19%, and 99 to 32%, respectively, as the IC increased from 0.1 to 2.0 ppm. The decomposition efficiencies obtained from the CN-TiO2 photocatalytic system were higher than those of the TiO2 system. As relative humidity (RH) increased from 20 to 95%, the decomposition efficiencies for BTEX decreased from 39 to 5%, 97 to 59%, 100 to 87%, and 100 to 92%, respectively. In addition, as the stream flow rates (SFRs) decreased from 3.0 to 1.0 L min-1, the average efficiencies for BTEX increased from 0 to 58%, 63 to 100%, 69 to 100%, and 68 to 100%, respectively. Taken together, these findings suggest that three (IC, RH, and SFR) should be considered for better BTEX decomposition efficiencies when applying CN-TiO2 photocatalytic technology to purification of indoor air BTEX.
Only limited information is available on the measured exposure levels of residents according to the construction age of apartments. As such, present study was conducted to measure and to compare the bedroom, living-room, and outdoor air levels of MTBE and benzene, toluene, ethyl benzene and m,p-xylene(BTEX) in both newer and older apartments. For both newer and older apartments, all the compounds except for MTBE showed significantly higher levels in bedrooms or living-rooms as compared to the outdoor concentrations. The ratio of bedroom or living-room median concentration to outdoor concentration was close to 1 for MTBE, whereas it was larger than 1 for other target compounds. It was also found that the bedroom and living-room appeared to have similar indoor sources and sinks for BTEX, but not for MTBE. The median concentration ratios of the newer apartments to the older apartments ranged from 1.63 to 1.81, depending upon the compounds. In contrast, the MTBE concentrations did not differ significantly between the newer and older apartments, thereby suggesting that although newer buildings could emit more VOCs, this is not applicable to all VOCs. Conclusively, the findings of present study should be considered, when designing exposure studies associated with VOC emissions in buildings and/or managing indoor air quality according to construction age of buildings.
This study assessed the characteristic of BTEX (Benzene, Toluene, Ethylbenzene, Xylene) concentration ratios of industrial emission sources and the neighborhoods of industrial area, fuel such as gasoline, light oil, LPG, and similar gasoline, and ambient air in Daegu. The BTEX in aromatic compounds was the most abundant VOC in Daegu. The BTEX ratios were (0.2:2.6:1.0:1.8) for the neighborhoods of industrial area, (2.6:11.3:1.0:1.2) for residential area, (2.2:11.0:1.0:1.6) for commercial area, (1.0:14.9:1.0:1.3) for industrial area, and (0.2:2.6:1.0:1.8) for the neighborhoods of industrial area. Average BTEX ratios in Daegu were B/T ratio (0.1), B/EB ratio (1.5), B/X ratio (1.1), T/EB ratio (12.6), T/X ratio(10), EB/X ratio (0.7). Expecially, B/T ratio in Daegu was similar as the other cities, Bangkok, Manila, and Hongkong. Comparing other cities with B/T ratio, the main sources of VOC were vehicular exhaust and emission of industrial facilities. Furthermore, BTEX correlation were evaluated at the emission sources and regional areas. Results showed that correlation coefficient values of emission sources, fuels and neighborhood of industry were significant magnitude above 0.65(p<0.01). Also, there showed highly significant correlations among BTEX. Calculated correlation coefficients of ambient air sampling sites were 0.61~0.954 for commercial /residential area and 0.613~0.998 for industrial area. However, they showed different correlation between commercial/residental area and industrial area. It implied that the emission sources were different from each area.
The research in this paper was carried out to examine the BTEX(Benzene, Toluene, Ethylbenzene, Xylene) concentrations in Seongseo Industrial Complex. These compounds are the major constituents, more than 60% in composition of total VOCs, mainly charging in ambient air. BTEX samples were collected from the 38 sites, 10 for the source points and 18 for the boundary sites, and were analyzed by canister-GC/MS. The mean concentrations of BTEX were 33 ppbv for benzene, 214 ppbv for toluene, 89 ppbv for ethylbenzene, 77 ppbv for xylene. Among the BTEX, toluene had the highest concentration in the source points and boundary sites. In the source points, BTEX concentration of incineration facility for hazardous wastewater appeared highly in the range of 220~350 ppbv. BTEX concentrations in source boundary sites appeared in the order of toluene>ethylbenzene>xylene>benzene. As a result of the correlation analysis, the concentration of the source points was related to those of the boundary sites. Correlation of ethylbenzene and xylene was presented to 0.7991(P<0.01), 0.6329(P<0.05) as the correlation coefficient, respectively.