X-ray diffraction is widely used as a non-destructive method for measuring residual stress in crystalline materials, and is particularly useful as a technique for controlling residual stress that has been introduced during the heat treatment or surface treatment of metallic materials. Neutron stress measurement is gaining attention as an internal material measurement method. It complements the demerits of the X-ray method in that it measures stress in a very thin surface layer. The neutron stress measurement method, like the X-ray method, is based on the principle of crystal diffraction, and its penetration depth is about 1,000 times greater than that of the X-ray method and is suitable for measuring the inside of a material. This study investigated the residual stress measurement method using the sin2ψ method using shot-peened mechanical structural carbon steel. The non-destructive measurement using high-energy X-rays was compared with the residual stress measured using conventional laboratory X-rays, and the following results were obtained. The high intensity diffraction angles using highenergy X-rays are low, but can be measured with sufficient precision. Interpreting the three diffractions 633, 552, and 721 as a single diffraction profile allowed stress measurements to be made, and the calculated value was close to the weighted average of the intensity ratios. The results of the high-energy X-ray residual stress measurements were in good agreement with the results from laboratory X-rays, confirming the usefulness of this method as a non-destructive method of assessing stress deep inside materials.

The feeder pipes of the primary cooling system in a pressurized heavy water reactor (PHWR) are composed of carbon steel SA 106 GR.B. On the surface of this structural material, corrosion oxide layers including radionuclides are formed due to the presence of active species from water decomposition products caused by radiation, as well as the high temperature and high-pressure environment. These oxide layers decrease the heat transfer efficiency of the primary cooling system and pose a risk of radiation exposure to workers and the environment during maintenance and decommissioning, making effective decontamination essential. In this study, we simulated the formation of the corrosion oxide layer on the surface of carbon steel SA 106 GR.B, characterized the formed corrosion oxide layer, and investigated the dissolution characteristics of the corrosion oxide layer using oxalic acid (OA), a commercial chemical decontamination agent. The corrosion oxide layer formed has a thickness of approximately 4 μm and consists of hematite ( Fe2O3) and magnetite ( Fe3O4). The carbon steel coupons with formed oxide layers were dissolved in 10 mM and 20 mM OA solutions, resulting in iron ion concentrations of 220 ppm and 276 ppm in the OA respectively. In 10 mM and 20 mM OA, the corrosion depths of the coupons were 8.93 μm and 10.22 μm, with corrosion rates of 0.39 mg/cm2·h and 0.45 mg/cm2·h, respectively. Thus, this demonstrates that higher OA concentrations lead to increased dissolution and corrosion of steel.

본 연구는 지속 가능한 발전과 환경보호를 위한 ESG의 핵심 과제인 탄소중립을 달성하기 위해 최근 철강산업에서 추진 중인 탄소중립 시나리오를 조사하고 그 현실성에 대하여 검토하였다. 2050년까지 탄소중립을 실현하기 위한 시나리오에서 철강산업이 차지하는 비중과 그 계획을 점검하고, 온실가스 감축 단계 및 수소 환원 제철 기술개발 단계에서도 중요한 역할을 하게 될 전기로 제강법의 역할과 과제에 대하여 살펴보았다. 전기로 제강법은 기존의 일반강을 생산하는 단계에서 향후 일관제철소의 전로제강을 대체하는 중요한 역할을 담당해야 한다. 다만 전기로는 전로제강 대비 탄소의 사용은 적으나 전기 에너지가 많이 소비되므로 이에 대한 대응 방안을 마련할 필요가 있다. 이에 논문에서는 전기로의 대체에 따른 전기 에너지의 사용량 증가에 대한 문제점을 도출하고 해결 방안을 제시해 보았다. 향후 철강산업의 탄소중립을 위한 전기로 설비 대체와 전기 에너지의 효율적 사용은 중요한 과제가 될 것이며 사업장 ESG 전략 수립에 필수적인 요소가 될 것으로 기대한다.

The carbon concentration in the carburized steels was measured by electron probe microanalysis (EPMA) for a range of soluted carbon content in austenite from 0.1 to 1.2 wt%. This study demonstrates the problems in carbon quantitative analysis using the existing calibration curve derived from pure iron (0.008 wt%C) and graphite (99.98 wt%C) as standard specimens. In order to derive an improved calibration curve, carbon homogenization treatment was performed to produce a uniform Kα intensity in selected standard samples (AISI 8620, AISI 4140, AISI 1065, AISI 52100 steel). The trend of detection intensity was identified according to the analysis condition, such as accelerating voltage (10, 15, 30 keV), and beam current (20, 50 nA). The appropriate analysis conditions (15 keV, 20 nA) were derived. When the carbon concentration depth profile of the carburized specimen was measured for a short carburizing time using the improved calibration curve, it proved to be a more reliable and accurate analysis method compared to the conventional analysis method.

강진은 적절한 내진 설계 기술이 적용되지 않으면 건물 붕괴로 인하여 극심한 피해가 발생할 수 있다. 이를 해결할 수 있는 면진 기술은 구조물과 지반 사이에 베어링 장치를 적용하여 지진 에너지를 흡수하고 건물에 전달되는 진동을 감쇠한 다. 본 연구는 고무 마찰 베어링 장치의 구조물 적용성을 검증하고 지진으로부터 안전성을 확보하기 위하여 고무 마찰 베어링 프레임 구조물에 대한 수치해석을 수행하였다. 수치해석 결과로써 최대 지붕 가속도와 총 밑면 전단력이 감소되어 내진 성능을 확인하였다. 또한, 최대 층간 변위 및 최대 잔류 층간 변위에 대한 분석 결과로 프레임 구조물을 경제적 복구 수준의 결과를 도 출하여 고무 마찰 베어링 장치의 우수한 내진 성능을 확인하였다.

This study proposes a low-cycle fatigue life derived from measurement points on pipe elbows, which are components that are vulnerable to seismic load in the interface piping systems of nuclear power plants that use seismic isolation systems. In order to quantitatively define limit states regarding leakage, i.e., actual failure caused by low-cycle fatigue, in-plane cyclic loading tests were performed using a sine wave of constant amplitude. The test specimens consisted of SCH40 6-inch carbon steel pipe elbows and straight pipes, and an image processing method was used to measure the nonlinear behavior of the test specimens. The leakage lines caused by low-cycle fatigue and the low-cycle fatigue curves were compared and analyzed using the relationship between the relative deformation angles, which were measured based on each of the measurement points on the straight pipe, and the moment, which was measured at the center of the pipe elbow. Damage indices based on the combination of ductility and dissipation energy at each measurement point were used to quantitatively express the time at which leakage occurs due to through-wall cracking in the pipe elbow.

Laser cladding a surface treatment process that grants superior characteristics such as toughness, hardness, and corrosion resistance to the surface, and rebuilds cracked molds; as such, it can be a strong tool to prolong service life of mold steel. Furthermore, compared with the other similar coating processes – thermal spray, etc., laser cladding provides superior bonding strength and precision coating on a local area. In this study, surface characteristics are studied after laser cladding of low carbon steel using 18%Cr-2.5%Ni-Fe powder (Rockit404), known for its high hardness and excellent corrosion resistance. A diode laser with wavelength of 900-1070 nm is adopted as laser source under argon atmosphere; electrical power for the laser cladding process is 5, 6, and 10 kW. Fundamental surface characteristics such as crossectional microstructure and hardness profile are observed and measured, and special evaluation, such as a soldering test with molten ALDC12 alloy, is conducted to investigate the corrosion resistance characteristics. As a result of the die-soldering test by immersion of low carbon alloy steel in ALDC12 molten metal, the clad layer's soldering thickness decreases.

본 논문에서는 풍하중에 노출된 강재 및 CFRP로 구성된 비닐하우스에 대한 확률론적 성능비교를 하였다. 풍하중에 대한 취약성은 강풍에 노출된 온실의 파괴확률을 추정하기 위해 사용되었으며 단동 비닐하우스의 유한요소 모델링은 한국농촌 경제연구원에서 발간한 설계도를 적용하였다. 해석결과를 구조물의 한계상태와 비교함으로써 비닐하우스의 파괴상태를 결정할 수 있다. 기본적으로 몬테카를로 시뮬레이션은 풍속에 따른 파괴확률을 도출하기 위해 가상의 풍하중에 대하여 적용하지만 본 논문에서는 전체에 대한 수직 및 수평 변형한계상태를 고려하였다. 그 결과, 강재 비닐하우스가 가장 높은 성능을 보였으며 수평 변형 한계상태가 하중조건에 대한 단동비닐하우스의 파괴원인임을 확인하였다.

Evaluation of the durability and stability of materials used in power plants is of great importance because parts or components for turbines, heat exchangers and compressors are often exposed to extreme environments such as high temperature and pressure. In this work, high-temperature corrosion behavior of 316 L stainless steel in a carbon dioxide environment was studied to examine the applicability of a material for a supercritical carbon dioxide Brayton cycle as the next generation power plant system. The specimens were exposed in a high-purity carbon dioxide environment at temperatures ranging from 500 to 800 oC during 1000 hours. The features of the corroded products were examined by optical microscope and scanning electron microscope, and the chemical compound was determined by x-ray photoelectron spectroscopy. The results show that while the 316 L stainless steel had good corrosion resistance in the range of 500-700 oC in the carbon dioxide environment, the corrosion resistance at 800 oC was very poor due to chipping the corroded products off, which resulted in a considerable loss in weight.

This study synthesized pure anatase carbon doped TiO2 photocatalysts supported on a stainless steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/TiCl4. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The XRD patterns showed that the supported TiO2 nanocrystals are typically anatase, polycrystalline and body-centered tetragonal in structure. The EDS and XPS results complemented one another and confirmed the presence of carbon species in or on the TiO2 layer, and the XPS data suggested the substitution of titanium in TiO2 by carbon. Instead of using calcination, PAN pyrolysis was used to control the carbon content, and the mesoporosity was tailored by the applied temperature. The supported TiO2 nanocrystals prepared by pyrolysis at 300, 350, and 400ºC for 3 h on a stainless steel mesh were actual supported carbon doped TiO2 nanocrystals. Thus, PAN/DMF/TiCl4 offers a facile, robust sol-gel related route for preparing supported carbon doped TiO2 nanocomposites.

In this study, we conducted an interrupted cutting SM20C with lathe and uncoated carbite tool, determined the relationship between Cutting Forces(principal, radial, feed force) by correlation analysis, and predicted the optimum cutting conditions by multiple regression analysis. The result were as follow. : From the correlation analysis, the increase of cutting speed and depth of cut reduces the principal force and radial force. the increase of cutting speed, depth of cut and feed rate will increase the feed force. From multi-regression analysis, we extracted regression equation and the coefficient of determination (R2) was 0.638, 0.692, 0.536 at principal, radial and feed force . It means that the regression equation is not high accuracy. However, it is predictable that the tendency of the forces action the interrupted cutting.

SKD11 (ASTM D2) tool steel is a versatile high-carbon, high-chromium, air-hardening tool steel that is characterized by a relatively high attainable hardness and numerous, large, chromium rich alloy carbide in the microstructure. SKD11 tool steel provides an effective combination of wear resistance and toughness, tool performance, price, and a wide variety of product forms. Adding of CNTs increased the performance of mechanical properties more. 1, 3 vol% CNTs was dispersed in SKD11 matrix by mechanical alloying. SKD11 carbon nanocomposite powder was sintered by spark plasma sintering process. FE-SEM, HR-TEM and Raman analysis were carried out for the SKD11 carbon nanocomposites.

Micro structure observation for low carbon steel base material and heat treatment(annealing), performing a tensile test and impact test, the specimen after the impact test is intended to evaluate the crack propagation characteristics by performing a fractal dimension analysis. The tensile strength of the base materials were observed higher compared to the heat treated materials, impact absorbed energy of heat treated materials was a higher than base materials. Impact Test and fractal dimension of the side of the test specimen was shown significantly more test temperature increases, heat treated material was higher than the base material

SKD11 (ASTM D2) tool steel is a versatile high-carbon, high-chromium, air-hardening tool steel that is charac- terized by a relatively high attainable hardness and numerous, large, chromium rich alloy carbide in the microstructure. SKD11 tool steel provides an effective combination of wear resistance and toughness, tool performance, price, and a wide variety of product forms. The CNTs was good additives to improve the mechanical properties of metal. In this study, 1, 3 vol% CNTs was dispersed in SKD11 matrix by mechanical alloying. The SKD11+ CNT hybrid nanocomposites were investigated by FE-SEM, particle size distribution, hardness and wear resistance. The CNT was well dispersed in the SKD11 matrix and the mechanical properties of the composite were improved by CNTs addition. It shows good fea- sibility as cold work die tool.

In this study, an HP-mod. type(KHR-45A), which is used as a heater tube material in the pyrolysis process, was evaluated for its carburizing properties. It was confirmed from the microstructural observation of the tubes that the volume fraction of carbide increased and that the coarsening of Cr-carbide generated as a degree of carburization increased. The depth of the hardened layer, which is similar to the thickness of the carburized region of each specimen, due to carburization is confirmed by measurement of the micro-Vickers hardness of the cross section tube, which thickness is similar to that of the carburized region of each specimen. Two types of chromium carbides were identified from the EBSD (electron back-scattered diffraction) image and the EDS (energy-dispersive spectroscopy) analysis: Cr-rich M23C6 in the outer region and Cr-rich M7C3 in the inner region of tubes. The EDS analysis revealed a correlation between the ferromagnetic behavior of the tubes and the chromium depletion in the matrix. The chromium depletion in the austenite matrix is the main cause of the magnetization of the carburized tube. The method used currently for the measurement of the carburization of the tubes is confirmed; carburizing evaluation is useful for magnetic flux density measurement. The volume fraction of the carbide increased as the measuring point moved into the carburized side; this was determined from the calculation of the volume fraction in the cross-section image of the tubes. These results are similar to the trends of carburization measurement when those trends were evaluated by measurement of the magnetic flux density.

A sample of ultra low carbon IF steel was processed by six-layer stack accumulative roll-bonding (ARB) and annealed. The ARB was conducted at ambient temperature after deforming the as-received material to a thickness of 0.5 mm by 50% cold rolling. The ARB was performed for a six-layer stacked, i.e. a 3 mm thick sheet, up to 3 cycles (an equivalent strain of ~7.0). In each ARB cycle, the stacked sheets were, first, deformed to 1.5 mm thickness by 50% rolling and then reduced to 0.5 mm thickness, as the starting thickness, by multi-pass rolling without lubrication. The specimen after 3 cycles was then annealed for 0.5 h at various temperatures ranging from 673 to 973 K. The microstructural evolution with the annealing temperature for the 3-cycle ARB processed IF steel was investigated in detail by transmission electron microscopy observation. The ARB processed IF steel exhibited mainly a dislocation cell lamella structure with relatively high dislocation density in which the subgrains were partially observed. The selected area diffraction (SAD) patterns suggested that the misorientation between neighboring cells or subgrains was very small. The thickness of the grains increased in a gradual way up to 873 K, but above 898 K it increased drastically. As a result, the grains came to have an equiaxed morphology at 898 K, in which the width and the thickness of the grains were almost identical. The grain growth occurred actively at temperatures above 923 K.

Flat rolling of wire is an industrial process used to manufacture electrical flat wire, medical catheters, springs, piston segments and automobile parts, among other products. In a multi-step wire flat rolling process, a wire with a circular crosssection is rolled at room temperature between two flat rolls in several passes to achieve the desired thickness to width ratio. To manufacture a flat wire with a homogeneous microstructure, mechanical and metallurgical properties with an appropriate pass schedule, this study investigated the effect of each pass schedule (1stand ~ 4stand) on the microstructures, mechanical properties and widths of cold rolled high carbon steel wires using four-pass flat rolling process. The evolutions of the microstructures and mechanical properties of the widths of cold rolled wires during three different pass schedules of the flat rolling process of high carbon wires were investigated, and the results were compared with those for a conventional eight-pass schedule. In the width of cold rolled wires, three different pass schedules are clearly distinguished and discussed. The experimental conditions were the same rolling speed, rolling force, roll size, tensile strength of the material and friction coefficient. The experimental results showed that the four-pass flat cold rolling process was feasible for production of designed wire without cracks when appropriate pass schedules were applied.