Compartment fire tests were performed using kerosene and Jet A-1 as fire sources to evaluate the relationship between flame temperature and opening size. The tests were performed for a fire caused by the release of kerosene owing to vehicle impact, and for a fire caused by the release of Jet-A-1 owing to airplane collision. The compartment fire tests were performed using a 1/3-scale model of a metal storage cask when the flame temperature was deemed to be the highest. We found the combustion time of Jet-A-1 to be shorter than that of kerosene, and consequently, the flame temperature of Jet-A-1 was measured to be higher than that of kerosene. When the opening was installed on the compartment roof, even though the area of the opening was small, the ventilation factor was large, resulting in a high flame temperature and long combustion. Therefore, the position of the opening is a crucial factor that affects the flame temperature. When the metal storage cask was stored in the compartment, the flame temperature decreased proportionally with the energy that the metal storage cask received from the flame.

Green-emitting Ba1.468Sr0.5SiO4 : Eu0.012, Y0.02 phosphor powders under long-wavelength ultraviolet light were prepared via high-temperature flame spray pyrolysis from spray solutions with and without NH4Cl flux. The effects of the temperature of the diffusion flame and the NH4Cl flux on the morphologies, crystal structures and photoluminescence intensities of the Ba1.468Sr0.5SiO4 : Eu0.012, Y0.02 phosphor powders were investigated. The phosphor powders obtained from the spray solution with the NH4Cl flux had higher photoluminescence intensities compared to phosphor powders obtained from the spray solution without the flux. The photoluminescence intensity of the phosphor powders obtained from the spray solution without the flux decreased as the flow rate of the fuel gas increased. On the other hand, the photoluminescence intensity of the phosphor powders obtained from the spray solution with the flux increased as the flow rate of the fuel gas increased. The difference of in the phase purity and morphology of the powders affected the photoluminescence intensities of the phosphor powders.

화염가수분해증착법에 의해 형성된 0.1μm크기의 soot를 실리콘 기판위에 형성하여 1325˚C에서 2시간 동안 고밀화과정후 투명한 후막을 얻을 수 있었다. 고밀화 열처리는 탈수과정, 재배열 과정, 그리고 고밀화 과정으로 구성되었다. 고밀화 공정후의 두께 수축률은 초기 soot의 96%정도였으며, 급속한 두께의 감소는 950˚C부터 시작되었으며, 본격적인 고밀화가 시작되는 온도는 1250˚C임을 알 수 있었다. soot의 TGA와 DTA를 이용한 열분석 결과 탈수과정에 의하여 9/wt%의 질량감소와 1250˚C이상에서 인(P)의 증발에 의한 2wt%의 질량감소를 관찰하였다. DTA곡선에서는 500˚C, 570˚C. 1258˚C에서 흡열반응 피크를 나타내는데, 이는 B2O3, P2O5 등의 도펀트들의 melting과 실리카 입자사이의 기공이 소멸되면서 입자간의 열전도도의 증가에 의해 나타난 것으로 판단된다.

연소화염법을 이용한 다이아몬드 박막합성시 기판표면온도 및 온도분포에 가장 크게 작용하는 공정변수는 탄화수소량을 결정하는 산소/아세틸렌 가스의 혼합비(R=O2C2H2)이다. 본 연구에서는 혼합가스비율 변화 (R=0.87-0.98)에 따른 기판표면온도 및 온도분포를 측정하고, 이들 변수에 따른 다이아몬드 박막의 생성 및 결정형상의 변화과정을 SEM관찰, Raman 분광분석 및 X-선 회절 분석을 통해 조사하였다. 혼합가스비율의 증가에 따라 다이아몬드의 생성입자 수밀도는 감소하였고, 이와 동시에 결정형상도 (111)면과 (100)면이 혼재된 cobo octahedron형에서 octahedron인 (111)면으로 변화되었다. 한편, 기판온도증가에 따라 생성입자의 수밀도가 증가하고 성장속도도 빨라져 조대한 결정을 얻었으며, 생성된 입자형성은 (111)면애 지배적이다가 (100)결정면이 점차 많아지는 양상을 나타내었다.

The purpose of this study is to improve the fire prevention performance using the fire venetian blind louver subjected to burning by fire flame. The investigation is based on testing 2 full scale specimens, which is 3m × 3m module, 850 × 1500mm open, and 900mm × 900mm × 175mm venetian blind louver. Two louver thickness (1.5 and 2.0mm) were adopted. The specimens were exposed to fire flame temperature levels of ISO834 at the lower surface of the fire venetian blind louver specimens with exposure duration of one hour in Korea Institute of Construction Technology (KICT). It was found from the test results that the values of distributed temperature, decreased for all specimens for protecting to fire flame by venetian blind louver. The results of tests were a good fire prevention performance between in initial to 6 mins. At 60 minutes around ISO 834 fire loading, the percentages of distributed temperature in 500mm and 800mm height ranged between 11 and 10% respectively, regardless of louver thickness. This study, therefore, will improve the fire venetian blind louver for fire protection and prevention performance.