본 연구는 지속 가능한 발전과 환경보호를 위한 ESG의 핵심 과제인 탄소중립을 달성하기 위해 최근 철강산업에서 추진 중인 탄소중립 시나리오를 조사하고 그 현실성에 대하여 검토하였다. 2050년까지 탄소중립을 실현하기 위한 시나리오에서 철강산업이 차지하는 비중과 그 계획을 점검하고, 온실가스 감축 단계 및 수소 환원 제철 기술개발 단계에서도 중요한 역할을 하게 될 전기로 제강법의 역할과 과제에 대하여 살펴보았다. 전기로 제강법은 기존의 일반강을 생산하는 단계에서 향후 일관제철소의 전로제강을 대체하는 중요한 역할을 담당해야 한다. 다만 전기로는 전로제강 대비 탄소의 사용은 적으나 전기 에너지가 많이 소비되므로 이에 대한 대응 방안을 마련할 필요가 있다. 이에 논문에서는 전기로의 대체에 따른 전기 에너지의 사용량 증가에 대한 문제점을 도출하고 해결 방안을 제시해 보았다. 향후 철강산업의 탄소중립을 위한 전기로 설비 대체와 전기 에너지의 효율적 사용은 중요한 과제가 될 것이며 사업장 ESG 전략 수립에 필수적인 요소가 될 것으로 기대한다.

The primary heat transport system consists mainly of the in-core fuel channels connected to the steam generators by a system of feeder pipes and headers. The feeders and headers are made of carbon steel. Feeders run vertically upwards from the fuel channels across the face of the reactor and horizontally over the refueling machine to the headers. Structural materials of the primary systems of nuclear power plants (NPPs) are exposed to high temperature and pressure conditions, so that the materials employed in these plants have to take into accounts a useful design life of at least 30 years. The corrosion products, mainly iron oxides, are generated from the carbon steel corrosion which is the main constituent of the feeder pipes and headers of this circuit. Typical film thickness on CANDU-PHWR surface is 75μm or 30mg/cm2. Deposits on PHWR tends to be much thicker than PWR due to use of carbon steel and also for the source of corrosion products available on the carbon steel surface. Degradation of carbon steel for the feeder pipes transferring the primary system coolant by flow-assisted corrosion in high temperature has been reported in CANDU reactors including Point Lapreau, Gentully-2, Darlington and Bruce NPPs. The formation of Fe3O4 film on a carbon steel surface reduces the dissolution rate of steel substantially. The protectiveness of the Fe3O4 film over the carbon steel is affected by the environmental factors and the operational parameters of the feeder pipes, including the velocity, wall shear stress, solution pH, temperature, concentration of dissolved iron, quality of solution, etc. For effective chemical decontamination of these thick oxides containing radionuclides such as Co-60, it is necessary to understand the corrosion behaviors of feeder pipes and the characteristics of oxide formed on it. In this work, we investigated the growth of oxide films that develop on type SA-107 Gr. B carbon steel in high temperature water and steam environment by scanning electron microscopy (SEM) and glow discharge optical emission spectrometry (GD-OES) for the quantification and the solidstate speciation of metal oxide films. This study was especially focused to set the experimental tests conditions how to increase the oxide thickness up to 50 m by changing the oxidation conditions, such as solution chemistry and thermo-hydraulic conditions both temperature and pressure and so on.

The carbon concentration in the carburized steels was measured by electron probe microanalysis (EPMA) for a range of soluted carbon content in austenite from 0.1 to 1.2 wt%. This study demonstrates the problems in carbon quantitative analysis using the existing calibration curve derived from pure iron (0.008 wt%C) and graphite (99.98 wt%C) as standard specimens. In order to derive an improved calibration curve, carbon homogenization treatment was performed to produce a uniform Kα intensity in selected standard samples (AISI 8620, AISI 4140, AISI 1065, AISI 52100 steel). The trend of detection intensity was identified according to the analysis condition, such as accelerating voltage (10, 15, 30 keV), and beam current (20, 50 nA). The appropriate analysis conditions (15 keV, 20 nA) were derived. When the carbon concentration depth profile of the carburized specimen was measured for a short carburizing time using the improved calibration curve, it proved to be a more reliable and accurate analysis method compared to the conventional analysis method.

강진은 적절한 내진 설계 기술이 적용되지 않으면 건물 붕괴로 인하여 극심한 피해가 발생할 수 있다. 이를 해결할 수 있는 면진 기술은 구조물과 지반 사이에 베어링 장치를 적용하여 지진 에너지를 흡수하고 건물에 전달되는 진동을 감쇠한 다. 본 연구는 고무 마찰 베어링 장치의 구조물 적용성을 검증하고 지진으로부터 안전성을 확보하기 위하여 고무 마찰 베어링 프레임 구조물에 대한 수치해석을 수행하였다. 수치해석 결과로써 최대 지붕 가속도와 총 밑면 전단력이 감소되어 내진 성능을 확인하였다. 또한, 최대 층간 변위 및 최대 잔류 층간 변위에 대한 분석 결과로 프레임 구조물을 경제적 복구 수준의 결과를 도 출하여 고무 마찰 베어링 장치의 우수한 내진 성능을 확인하였다.

This study proposes a low-cycle fatigue life derived from measurement points on pipe elbows, which are components that are vulnerable to seismic load in the interface piping systems of nuclear power plants that use seismic isolation systems. In order to quantitatively define limit states regarding leakage, i.e., actual failure caused by low-cycle fatigue, in-plane cyclic loading tests were performed using a sine wave of constant amplitude. The test specimens consisted of SCH40 6-inch carbon steel pipe elbows and straight pipes, and an image processing method was used to measure the nonlinear behavior of the test specimens. The leakage lines caused by low-cycle fatigue and the low-cycle fatigue curves were compared and analyzed using the relationship between the relative deformation angles, which were measured based on each of the measurement points on the straight pipe, and the moment, which was measured at the center of the pipe elbow. Damage indices based on the combination of ductility and dissipation energy at each measurement point were used to quantitatively express the time at which leakage occurs due to through-wall cracking in the pipe elbow.

Laser cladding a surface treatment process that grants superior characteristics such as toughness, hardness, and corrosion resistance to the surface, and rebuilds cracked molds; as such, it can be a strong tool to prolong service life of mold steel. Furthermore, compared with the other similar coating processes – thermal spray, etc., laser cladding provides superior bonding strength and precision coating on a local area. In this study, surface characteristics are studied after laser cladding of low carbon steel using 18%Cr-2.5%Ni-Fe powder (Rockit404), known for its high hardness and excellent corrosion resistance. A diode laser with wavelength of 900-1070 nm is adopted as laser source under argon atmosphere; electrical power for the laser cladding process is 5, 6, and 10 kW. Fundamental surface characteristics such as crossectional microstructure and hardness profile are observed and measured, and special evaluation, such as a soldering test with molten ALDC12 alloy, is conducted to investigate the corrosion resistance characteristics. As a result of the die-soldering test by immersion of low carbon alloy steel in ALDC12 molten metal, the clad layer's soldering thickness decreases.

Here, the stability of stainless steel 316 (SS-316) was investigated to identify its applicability in the oxide reduction process, as a component in related equipment, to produce a complicated gas mixture composed of O2 and Cl2 under an argon (Ar) atmosphere. The effects of the mixed gas composition were investigated at flow rates of 30 mL/min O2, 20 mL/min O2 + 10 mL/min Cl2, 10 mL/min O2 + 20 mL/ min Cl2, and 30 mL/min Cl2, each at 600℃, during a constant argon flow rate of 170 mL/min. It was found that the corrosion of SS-316 by the chlorine gas was suppressed by the presence of oxygen, while the reaction proceeded linearly with the reaction time regardless of gas composition. Surface observation results revealed an uneven surface with circular pits in the samples that were fed mixed gases. Thermodynamic calculations proposed the combination of Fe and Ni chlorination reactions as an explanation for this pit formation phenomenon. An exponential increase in the corrosion rate was observed with an increase in the reaction temperature in a range of 300 ~ 600℃ under a flow of 30 mL/min Cl2 + 170 mL/min Ar.

본 논문에서는 풍하중에 노출된 강재 및 CFRP로 구성된 비닐하우스에 대한 확률론적 성능비교를 하였다. 풍하중에 대한 취약성은 강풍에 노출된 온실의 파괴확률을 추정하기 위해 사용되었으며 단동 비닐하우스의 유한요소 모델링은 한국농촌 경제연구원에서 발간한 설계도를 적용하였다. 해석결과를 구조물의 한계상태와 비교함으로써 비닐하우스의 파괴상태를 결정할 수 있다. 기본적으로 몬테카를로 시뮬레이션은 풍속에 따른 파괴확률을 도출하기 위해 가상의 풍하중에 대하여 적용하지만 본 논문에서는 전체에 대한 수직 및 수평 변형한계상태를 고려하였다. 그 결과, 강재 비닐하우스가 가장 높은 성능을 보였으며 수평 변형 한계상태가 하중조건에 대한 단동비닐하우스의 파괴원인임을 확인하였다.

Evaluation of the durability and stability of materials used in power plants is of great importance because parts or components for turbines, heat exchangers and compressors are often exposed to extreme environments such as high temperature and pressure. In this work, high-temperature corrosion behavior of 316 L stainless steel in a carbon dioxide environment was studied to examine the applicability of a material for a supercritical carbon dioxide Brayton cycle as the next generation power plant system. The specimens were exposed in a high-purity carbon dioxide environment at temperatures ranging from 500 to 800 oC during 1000 hours. The features of the corroded products were examined by optical microscope and scanning electron microscope, and the chemical compound was determined by x-ray photoelectron spectroscopy. The results show that while the 316 L stainless steel had good corrosion resistance in the range of 500-700 oC in the carbon dioxide environment, the corrosion resistance at 800 oC was very poor due to chipping the corroded products off, which resulted in a considerable loss in weight.

This study synthesized pure anatase carbon doped TiO2 photocatalysts supported on a stainless steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/TiCl4. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The XRD patterns showed that the supported TiO2 nanocrystals are typically anatase, polycrystalline and body-centered tetragonal in structure. The EDS and XPS results complemented one another and confirmed the presence of carbon species in or on the TiO2 layer, and the XPS data suggested the substitution of titanium in TiO2 by carbon. Instead of using calcination, PAN pyrolysis was used to control the carbon content, and the mesoporosity was tailored by the applied temperature. The supported TiO2 nanocrystals prepared by pyrolysis at 300, 350, and 400ºC for 3 h on a stainless steel mesh were actual supported carbon doped TiO2 nanocrystals. Thus, PAN/DMF/TiCl4 offers a facile, robust sol-gel related route for preparing supported carbon doped TiO2 nanocomposites.

In this study, we conducted an interrupted cutting SM20C with lathe and uncoated carbite tool, determined the relationship between Cutting Forces(principal, radial, feed force) by correlation analysis, and predicted the optimum cutting conditions by multiple regression analysis. The result were as follow. : From the correlation analysis, the increase of cutting speed and depth of cut reduces the principal force and radial force. the increase of cutting speed, depth of cut and feed rate will increase the feed force. From multi-regression analysis, we extracted regression equation and the coefficient of determination (R2) was 0.638, 0.692, 0.536 at principal, radial and feed force . It means that the regression equation is not high accuracy. However, it is predictable that the tendency of the forces action the interrupted cutting.

SKD11 (ASTM D2) tool steel is a versatile high-carbon, high-chromium, air-hardening tool steel that is characterized by a relatively high attainable hardness and numerous, large, chromium rich alloy carbide in the microstructure. SKD11 tool steel provides an effective combination of wear resistance and toughness, tool performance, price, and a wide variety of product forms. Adding of CNTs increased the performance of mechanical properties more. 1, 3 vol% CNTs was dispersed in SKD11 matrix by mechanical alloying. SKD11 carbon nanocomposite powder was sintered by spark plasma sintering process. FE-SEM, HR-TEM and Raman analysis were carried out for the SKD11 carbon nanocomposites.

Micro structure observation for low carbon steel base material and heat treatment(annealing), performing a tensile test and impact test, the specimen after the impact test is intended to evaluate the crack propagation characteristics by performing a fractal dimension analysis. The tensile strength of the base materials were observed higher compared to the heat treated materials, impact absorbed energy of heat treated materials was a higher than base materials. Impact Test and fractal dimension of the side of the test specimen was shown significantly more test temperature increases, heat treated material was higher than the base material

SKD11 (ASTM D2) tool steel is a versatile high-carbon, high-chromium, air-hardening tool steel that is charac- terized by a relatively high attainable hardness and numerous, large, chromium rich alloy carbide in the microstructure. SKD11 tool steel provides an effective combination of wear resistance and toughness, tool performance, price, and a wide variety of product forms. The CNTs was good additives to improve the mechanical properties of metal. In this study, 1, 3 vol% CNTs was dispersed in SKD11 matrix by mechanical alloying. The SKD11+ CNT hybrid nanocomposites were investigated by FE-SEM, particle size distribution, hardness and wear resistance. The CNT was well dispersed in the SKD11 matrix and the mechanical properties of the composite were improved by CNTs addition. It shows good fea- sibility as cold work die tool.