This study was aimed to improve the productivity and income of mushroom farming by developing a new casing material as a substitute for clay loam casing soil, which is becoming more difficult to acquire. When the new casing materials were used for the stable production of button mushroom (Agaricus bisporus), a 1:1 mixture of clay loam and button mushroom media obtained after harvest supported 13% greater mycelial growth (32.0 kg/3.3 m²). This material was better than clay loam soil in preventing contamination with environmental compounds and pests. The use of an inexpensive 1:1 mixture of peat moss and coco peat resulted superior mycelial growth with 4% better yield (32.9 kg/3.3 m²) compared with conventional clay loam soil. Advantages of these casing materials included ready availability and improved productivity. Mixtures of peat moss + coco peat + zeolite (50%:30%:20%) and coco peat + coal ash (75%:25%) could substitute for conventional casing soil. Additionally, the novel mixtures containing material obtained after cultivation might be used to produce organic fertilizer.
본 연구는 고대의 ‘命’에 대한 운명적⋅도덕적인 관념과 육체적, 정신적, 사회적으로 완벽한 상태를 ‘건강’으로 규정한 현대의 정의를 비교 및 종합하여 현대인들에게 유용한 ‘運命論’의 새로운 활용법을 모색해 본 것이다. ‘神’이 관념의 중심인 운명론에서는 인간의 육체적, 정신적, 사회적 상태에서의 ‘人’의 선택과 행동이 철저히 제한된다. 반면 ‘人’이 관념의 중심인 도덕적 측면에서는 높은 도덕성과 육체적, 정신적, 사회적 상태의 초월을 요구 한다. 본 연구에서는 이들의 장단점을 정리하고 운명론을 비판한 묵자의 非 命의 구조를 파악하여 인간의 주동적 삶의 자세를 유도하는 운명론의 활용 방안을 찾아보았다. 그 결과 ‘예언’은 경계하되 ‘예측(해석)’과 길⋅흉(命)의 ‘가변성’ 등을 강조하여 ‘人’의 주동적 역할을 유도하는 새로운 운명론의 활 용방안을 제안해 보았다.
In this paper, a new Co10Fe10Mn35Ni35Zn10 high entropy alloy (HEA) is identified as a strong candidate for the single face-centered cubic (FCC) structure screened using the upgraded TCFE2000 thermodynamic CALPHAD database. The Co10Fe10Mn35Ni35Zn10 HEA is fabricated using the mechanical (MA) procedure and pressure-less sintering method. The Co10Fe10Mn35Ni35Zn10 HEA, which consists of elements with a large difference in melting point and atomic size, is successfully fabricated using powder metallurgy techniques. The MA behavior, microstructure, and mechanical properties of the Co10Fe10Mn35Ni35Zn10 HEA are systematically studied to understand the MA behavior and develop advanced techniques for fabricating HEA products. After MA, a single FCC phase is found. After sintering at 900℃, the microstructure has an FCC single phase with an average grain size of 18 μm. Finally, the Co10Fe10Mn35Ni35Zn10 HEA has a compressive yield strength of 302 MPa.
목적: 본 연구는 망막 영상의 혈관 분할을 위한 새로운 심층 인공 학습 시스템을 구축하는데 목적이 있 다. 기존 CNN (Convolutional Neural Network) 아키텍처를 제시하고, CNN 방식을 토대로 성능을 개선한 DirectNet을 고안하는데 있다. 특히, 기존 CNN에 비해 처리 시간을 크게 단축시키는데 있다.
방법: 제안된 DirectNet 아키텍처는 피라미드 형식의 블록(Block)들로 구성되며 각 블록은 컨볼루션레이 어 (Convolution layer) 묶음을 포함한다. 하나의 블록은 학습 결과를 보존(저장)하는 단위이다. 블록들은 순차적으로 하나씩 증가하며 피라미드 형식으로 쌓이게 되고 이를 통해 초기 학습 결과가 소멸되지 않고 최종 분석에 활용될 수 있도록 하였다. DirectNet은 패치(Patch) 추출과 Pooling 과정 없이 이미지를 학습하여 학습 층을 거듭하여도 원본 이미지와 동일하게 유지되는 것이 특징이다. 또한 다양한 커널사이즈를 활용 하되 Depthwise Separable Convolution(DSC)을 활용하여 색을 구성하는 RGB(Red, Green, Blue)픽셀로 부터 혈관 모양을 인식 및 탐지한다.
결과: DirectNet은 최첨단 패치 기반 CNN 접근 방식 (0.9538 vs 0.9327, 0.7851 vs 0.7346, 0.9782 vs 0.9730, 0.8458 vs 0.7987)과 비교하여 더 높은 정확도, 감도, 특이도 및 정밀도 값을 제공하였다. Direct Net의 학습 시간은 8시간에서 1시간, 테스트에 소요된 시간은 1시간에서 이미지 당 6초로 크게 단축하였다.
결론: 제안 된 심층 학습 아키텍처는 기존의 CNN 방식으로 진행한 학습 시간에 비해 8배, 테스트에서 600배 빠른 속도로 결과를 제공한다. DirectNet은 CNN에 비해 2.11%의 약간 높은 정확도를 보였으며, 다 른 측정 항목에서도 동등하거나 그 이상의 결과를 보여 분석 시간 효율을 크게 높였다.
본 연구에서 우리는 국가문화의 기술혁신활동에의 영향을 탐색해 보았다. 먼저 (국가)문화의 개념을 정리하였고, 다양한 세부 국가문화지표들에 대한 논의도 추가하였다. 다음으로 국가문화가 기술혁신 활동 및 성과에 영향을 미치는 이론적 메커니즘을 기존 문헌 을 통하여 정리하였다. 국가문화는 국가 사회를 구성하는 근저를 이루는 틀을 형성하는 다양 한 개념을 종합한 것이기 때문에 각 개념별로 기술혁신시스템에 미치는 영향은 크게 다름을 알 수 있었다. 마지막으로 국가문화가 기술의 특성, 사회제도, 정책 등과 어떻게 상호작용을 하면서 기술혁신활동에 영향을 미치는 지를 탐색해 보았다. 관련 문헌, 이론 및 실증분석을 정리하면서 동시에 이에 기반 하여 새로운 논의를 제안하고 다양한 미래연구 가능성을 제시 하였다. 이를 통한 기술혁신이론에의 시사점도 정리하였다.
Two different emitting compounds, 1-[1,1;3,1]Terphenyl-5-yl-6-(10-[1,1;3,1]terphenyl-5-ylanthracen-9-yl)-pyrene (TP-AP-TP) and Poly-phenylene vinylene derivative (PDY 132) were used to white OLED device. By incorporating adjacent blue and yellow emitting layers in a multi-layered structure, highly efficient white emission has been attained. The device was fabricated with a hybrid configuration structure: ITO/PEDOT (40 nm)/PDY-132 (8∼50 nm)/NPB (10 nm)/TP-AP-TP (30 nm)/Alq3 (20 nm)/LiF (1 nm)/Al (200 nm). After fixing TP-AP-TP thickness of 30 nm by evaporation, PDY-132 thickness varied with 8, 15, 35, and 50 nm by spin coating in device. The luminance efficiency of the white devices at 10 mA/cm2 were 2.93 cd/A∼6.55 cd/A. One of white devices showed 6.55 cd/A and white color of (0.290, 0.331).
4-Methyl-7-(10-phenyl-anthracen-9-yl)-chromen-2-one (PhAC), 4-Methyl-7-(10-naphthalen-1-yl-anthracen-9-yl)-chromen-2-one (1-NAC), 4-Methyl-7-(10-naphthalen-2-yl-anthracen-9-yl)-chromen-2-one (2-NAC), and 7-Anthracen-9-yl-4-methyl-chromen-2-one (AC) were synthesized through Suzuki aryl-aryl coupling reaction. Four compounds were used as emitting layer (EMLs) in non-doped OLEDs with the following structures: ITO/2-TNATA (60 nm)/NPB (15 nm)/EMLs (35 nm)/Alq3 (20 nm)/LiF (1 nm)/Al (200 nm). Non-doped devices showed luminescence efficiency of 2.14, 2.07, 1.52, and 1.12 cd/A at a current density of 10 mA/cm2.
New three emitting compounds, AK-1, AK-2 and AK-3 including diazocine moiety were synthesized through Suzuki-coupling reaction. Physical properties such as optical, electroluminescent properties were investigated. UV-visible spectrum of AK-1, AK-2 and AK-3 in film state showed maximum 392, 393 and 401 nm. PL spectrum of AK-1, AK-2 and AK-3 showed maximum emission wavelength of 472, 473 and 435 nm. Three compounds were used as EML in OLED device: ITO/2-TNATA (60 nm)/NPB (15 nm)/EML (35 nm)/Alq3 (20 nm)/LiF (1 nm)/Al (200 nm). AK-3 OLED device showed C.I.E value of (0.18, 0.26) and luminance efficiency of 0.51 cd/A at 10 mA/cm2. New derivatives including diazocine moiety were introduced as OLED emitting material and the EL efficiency was increased by the proper combination of core and side group.
New carbazole derivatives including coumarin moiety, 7-(3-Carbazol-9-yl-phenyl)-chromen-2-one (C-PCa), 7-(9-Phenyl-9H-carbazol-3-yl)-chromen-2-one (PCa-C), 7-[9-(3-Carbazol-9-yl-phenyl)-9H-carbazol-3-yl]-chromen-2-one (PDCa-C) were synthesized by Suzuki reaction. In film state, maximum UV-Vis absorption of three synthesized compounds appeared in the range 331 to 345 nm. PL spectrum of C-PCa, PCa-C and PDCa-C showed miximum emission wavelength of 449, 467 and 467 nm, respectively. C-PCa showed white emission of current efficiency of 1.16 cd/A, power efficiency of 0.59 lm/W and C.I.E of (0.26, 0.33). PCa-C showed current efficiency of 1.13 cd/A, power efficiency of 0.62 lm/W and C.I.E of (0.19, 0.27). PDCa-C showed the highest current efficiency of 1.34 cd/A, power efficiency of 0.62 lm/W and C.I.E of (0.18, 0.23).
4-methyl-7-(10-(pyren-1-yl)anthracen-9-yl)-2H-chromen-2-one (PAC), 7,7’-(anthracene-9,10-diyl)bis(4- methyl-2H-chromen-2-one) (CAC), 7-Anthracen-9-yl-4-methyl-chromen-2-one(AC), and 7-(naphthalen-1-yl)-2Hchromen-2-one (NC) were synthesized through Suzuki aryl-aryl coupling reaction. Optical and electroluminescence (EL) properties were evaluated by UV-visible absorption, photoluminescence (PL) spectra, and EL devices. Synthesized compounds were used as an emitting layer (EML) in non-doped device with the following structures: ITO/2-TNATA (60 nm)/NPB (15 nm)/synthesized compounds (35 nm)/Alq3 (20 nm)/LiF (1 nm)/Al (200 nm). Non-doped devices showed luminance efficiency (L.E.) of 1.38, 1.03, 1.12, and 0.39 cd/A at a current density of 10 mA/cm2.
Two new synergists are proposed for pigment dispersion in pigment ink. Benzoic acid was applied to Pigment Yellow 74 (PY-74) and Pigment Yellow 150 (PY-150) as a hydrophilic functional group to synthesize (E)-4-(((3-(2-(2-methoxy-4-nitrophenyl)hydrazono)-4-oxopent-1-en-2-yl)(2-methoxyph enyl)am-ino)methyl)benzoic acid (PY-74BA) and (E)-4-((2,4,6-trioxo-5-((2,4,6-trioxohexahydropyrimidin-5-yl)di-azenyl)tetrahydropyrimidin-1(2H)-yl)methyl)ben zoic acid (PY-150BA). Whereas pigment showed extremely low solubility in water and organic solvents like DMSO, DMF and methanol, two synergists were found to have higher solubility than pigment. This result can be interpreted as reduction of particle aggregation by increased polarity. Two synergists applied to pigment ink are expected to improve dispersion property and storage stability of ink.
7-(4-([1,1-biphenyl]-4-yl(9,9-dimethyl-9H-fluoren-2-yl)amino)phenyl)-4-methyl-2H-chromen-2-one (BPFA-C) including coumarin moiety was synthesized through Suzuki aryl-aryl coupling reaction. Optical and electrical properties were examined by UV-visible absorption spectra, PL spectra, and AC-2. UV-visible spectrum of BPFA-C in a film state showed maximum absorption wavelength of 367 nm. PL spectrum of BPFA-C show maximum emission wavelength of 511 nm. BPFA-C showed highly efficient luminescence property. EL spectrum of BPFA-C exhibited a maximum value of 504 nm and BPFA-C device provided luminescence efficiency of 4.59 cd/A, power efficiency of 3.17 lm/W, and CIE (x,y) of (0.25, 0.53) at a current density of 10 mA/cm².
A new green light emitting compound based on tris (N-methylindolo) benzene (NMTI), anthracene and pyrene was synthesized. NMTI-An and NMTI-Py were used as the light emitting layer of the OLED element to investigate the luminescence characteristics. The OLED device containing NMTI - NPB luminescent layer and hole transport layer (HTL) showed superior characteristics compared to NMTI-Py. The device exhibited maximum EL emission at 502 nm and 550 nm, CIE coordinates (0.38, 0.48) and a luminance efficiency of 2.06 cd/A. Also, when NMTI and NMTI-An were used as HTL instead of NPB, the device containing NMTI-An emitter showed 2.67 cd/A and 2.29 cd/A in luminescence efficiency.
Three new compounds are synthesized as color filter dyes by substituting a pyridine group into 1,4-position, 1,5-position, and 1,8-position of anthraquinone core moiety. Changes in physical properties of the synthesized compounds according to the substitution position are systematically investigated in terms of optical properties and thermal properties. The extinction coefficient value (ε) of the synthesized materials is extremely high and is above 4.22 in a log scale, and Td is above 300°C with high thermal stability.
Two emitting compounds, 9,10-bis-[1,1;3,1]terphenyl-5-yl-1,5-di-o-tolyl- anthracene [TP-DTA-TP] and 9,10-bis-phenyl[1,1;3,1]triphenyl-5-yl-1,5-di-o- tolylanthracene[ TPB-DTA-TPB] based on newtwisted core moiety were synthesized through boration, Suzuki reaction, and Sandmeyer reactions. EL performance was improved by varying the chemical structure of the side group. Physical properties such as optical, electrochemical, and electroluminescent properties were investigated. Synthesized compounds were used as an EML in OLED device: ITO/2-TNATA (60 nm)/NPB (15 nm)/TP-DTA-TP or TPB-DTA-TPB (35 nm)/Alq3 (20 nm)/LiF (1 nm)/Al (200 nm). It was found that TPB-DTA-TPB showed higher luminance efficiency and better C.I.E. value than TP-DTA-TP device.