금속제련공학 및 환경과학 분야에 있어서 물질전체를 구성하고 있는 화학적 조성이 중요한 요소이나, 입자 표면의 화학조성과 미분화된 입자들의 표면 반응성을 제어함과 동시에, 입자 계면에서 일어나는 중금속과 유기물질등의 반응은 제련공정과 환경오염에 중요한 역할을 한다. 그러므로, 수용액상에 존재하는 여러 종류의 화학 물질과 광물입자 표면 사이에서 일어나는 계면반응 과정의 이해는 상당히 중요한 것이다. 일반적으로 입자 표면 분석에는 ex-situ 법을 사용하는 X-ray photo-electron spectroscopy (XPS) 분석 방법이 많이 적용되고 있으나, 이는 분석대상시료의 크기가 보통 100 마이크론에서 1 cm 정도의 범위 안에 혼재-혼합되어있는 고체 입자들을 분석하기 때문에 채취 분석된 X-ray의 원래 발산한 입자표면을 분석할 수는 없다. 그래서 본 연구에서는 Time-of-Flight Secondary-Ion Mass Spectroscopy (TOF-SIMS)를 응용하여 황화광물의 부유선광 공정 중 생성된 미세한 유화광물입자(30~75 microns) 표면에 형성된 무기, 유기물의 반응 관찰을 통해 이들의 정성분석 및 상대적 정량분석법을 연구하고자 하였다.

Mass selection (MS) is an efficient selection method to directly improve highly heritable traits. In the present study, two cycles of MS for ear length were conducted on two sweet corn populations, BC2-l0 and BC1-10~timesSyn-II after introgression of exotic germplasm. The improved populations generated from these selections were evaluated in comparison with the base populations at two locations, to determine the genetic gains and performance of the improved populations. The two base populations showed varied average realized responses to MS. In BC2-l0 derived population, the realized responses were 9.1~% in BC2-l0 C1 and 1.2~% in BC2-l0 C2, whereas inBC1-10~timesSyn-II derived population, the realized responses were 5.6~% in BC1-10~timesSyn-II C1 and 2.9~% in BC1-10~timesSyn-II C2. All the improved populations showed longer ears than their respective base populations and the check varieties. Ear length, which was used as the selection criterion in this study, showed high broad-sense heritability in the BC2-l0 and BC1-10~timesSyn-II derived populations, while fresh ear yield revealed low heritability, indicating that selection for ear length in these populations would be more effective than direct selection for yield. Results of this study indicate that MS conducted on BC2­10 and BC1-10~timesSyn-II had significantly increased ear length and fresh ear yield in both populations. The improved populations obtained would serve as better germplasm sources and further selection in these populations could offer better responses.

Isotopes of alkali and alkaline earth metals (AM and AEM) are the main contributors to the heat load and the radiotoxicity of spent fuel (SF) . These components are separated from the SF and dissolved in a molten LiCl in an electrolytic reduction process. A mass transfer model is developed to describe the diffusion behavior of Cs, Sr, and Ba in the SF into the molten salt. The model is an analytical solution of Fick's second law of diffusion for a cylinder which is the shape of a cathode in the electrolytic reduction process. And the model is also applied to depict the concentration profile of the oxygen ion which is produced by the electrolysis of LiO. The regressed diffusion coefficients of the model correlating the experimentally measured data are evaluated to be greater in the order of Ba, Cs, and Sr for the metal ions and the diffusion of the oxygen ion is slower than the metal ions which implies that different mechanisms govern the diffusion of the metal ions and the oxygen ions in a molten LiCl.

본 연구의 목적은 매스-마라톤에 참가하는 동호인의 참가동기를 분석하고 이러한 참가동기가 성과 연령 및 참가정도에 따라 차이가 있는지를 규명하는데 있었다. 연구대상은 수도권 지역의 매스-마라톤 동호인 중 최근 6개월 이내에 대회에 참가 경험이 있는 만 20세 이상의 성인 남여 총 943명을 연구 자료로 채택하였으며, 성별, 연령 및 참가정도와 참가동기 수준을 알아보기 위하여 빈도분석, 기술통계분석, 이원다변량분석과 일원다변량분석을 실시하였다. 이에 통계적 유의성이 나타난 변인에 대해서는 일원분산분석 및 Scheffe' method의 사후검증을 실시하여 다음과 같은 결론을 얻었다. 첫째, 매스-마라톤 동호인의 참가동기는 성별에 따라 차이가 없었으나 연령에 있어서는 차이가 있었다. 즉 20-30대에 비해 40대이상 연령이 높을수록 참가동기 수준은 높았다. 둘째, 매스-마라톤 동호인의 참가기간, 참가빈도, 참가강도, 참가종목, 주당평균주행거리에 따라 참가동기수준은 차이가 있었다. 구체적으로 참가기간에 따라 자율성동기와 친화동기의 수준이 높았으며, 참가빈도에 따라서는 건강 및 체력증진동기와 자율성동기 및 자극추구동기의 수준이 높았고, 참가강도에 따라서는 건강 및 체력증진동기와 자극추구동기, 친화동기, 성취동기의 수준이 높았다. 또한 참가종목에 따라서는 건강 및 체력증진동기, 정화동기, 자극추구동기, 성취동기의 수준이 높았으며, 주당평균주행거리에 따라서는 자율성동기의 수준이 높았다. 이러한 결과는 매스-마라톤에 참가하는 동호인들이 건강과 체력을 증진시키고자 하는 동기가 젊은층 보다는 연령이 높을수록 더욱 두드러지게 나타나는 것으로 보인다.

유색칼라 미숙배 배양에 의한 급속 증식체계를 확립 하고자 Southern Light 품종을 자가수분 시켜 배발육단계 및 식물생장조절제 종류와 농도가 다량의식물체 재분화에 미치는 효과를 조사하였다. 배 발육단계 별로 MS 기본배지 에 배양한 결과 globular 단계 미숙배는 반응이 없었고 몇 개의 어뢰형 배 및 초기 자업기배는 팽대 및 발아되었는데 어린 자엽기 미숙배가 87.5% 발아율을 보여 가장 효과적이었다. 한편 어린 자엽기 미숙배를 2,4-D, NAA및 BA를 단용 또는 혼용처리한 결과 2,4-D 단용 및 BA와 혼용처리배지에서는 유백색의 점액성 캘러스만이 8개월까지 증식되었고 NAA와 BA혼용처리 배지에서는 담황색의 단단한 배발생적 캘러스가 증식되어 모두 식물체로 재분화되었는데 특히 0.5 mg/L NAA와 1.0 mg/L BA혼용처리 하였을때 한개 자엽기 미숙배로 부터 25-30개의 식물체가 재분화 되었으며 동일배지에 10% coconut water를 첨가하므로 기내 식물의 급속생장이 효과적이었다. 배유래 재분화된 식물체는 vermiculite, perlite 및 모래를 1:1:1로 혼합한 토양에 이식하였으며 100% 정상식물체로 자라고 있다.

This study was performed to research ozone concentration related to airmass thunderstorm using 12 years meteorological data(1990～2001) at Busan. The occurrence frequency of thunderstorm during 12 years was 156 days(annual mean 13days). The airmass thunderstorm frequency was 14 days, most of those occurrence at summertime(59%). In case August 4, 1996, increase of ozone concentration was simultaneous with the decrease of temperature and increase of relative humidity. In case July 23, 1997, ozone concentration of western site at Busan increased, while its of eastern site decreased as airmass thunderstorm occurred(about 1500LST). It is supposed that these ozone increases are the effect of ozone rich air that is brought down by cumulus downdrafts from height levels where the ozone mixing ratio is larger. Thunderstorms can cause downward transport of ozone from the reservoir layer in the upper troposphere into planetary boundary layer(PBL). This complex interaction of source and sink processes can result in large variability for vertical and horizontal ozone distributions. Thus a variety of meteorological processes can act to enhance vertical mixing between the earth's surface and the atmospheric in the manner described for thunderstorm.

새우난초의 대량 증식 시스템을 확립하기 위하여 새우난초 종자 무균파종 및 순화 방법에 따른 생육특성 을 조사하였다. 발아율은 MS배지 에서 65% 이상이었고 유묘의 대량증식이 가능하였다. 계대배양한 유묘의 증식은 고체배지 보다는 액체배지에서 생육상태 가 더 양호한 경향을 보였다. 순화실험 결과, 70%차광조건에서 플라스틱 멀칭으로 습도를 80% 이상 유지하였을 때 100% 순화 생존하였다. 기내 육성된 배양묘는 백태로 뿌리를 감싸 심었을 때 발근이 가장 잘 이루어졌으나 순화과정 중에서 백태 대신에 질석과 펄라이트를 1:1 부피비로 이용한 경우에도 88%의 비교적 높은 생존율을 보였다.

For the economical mass production of the interspecific hybridization, we developed the modified system of mass pollination where controlled pollination was done with pollen mix from good father trees and without pollination bags in a closed greenhouse. U

The absorption of benzene in nonpolar solution was studied in a laboratory-scale of bubble column varying of gas flow rates and gas-to-liquid ratios. A bubble column had a 0.8～1×10-3 m3 total volume (height 1500 mm, diameter 50 mm). Solution analysis was performed by GC-FID and GC-MSD. The objectives of this research were to select the best absorption fluid and to evaluate the mass transfer characteristics under specific conditions of each absorption. The results of this research were follow as: First, the heat transfer fluid is more efficient than the other nonpolar solution in removing VOC. Second, The benzene removal efficiency improved according to an increasing rate of gas flow. Also, volumetric mass transfer rate of column can be enhanced by increasing gas flow rate. Finally, the relation of gas flow rates, liquid amount, and volumetric mass transfer coefficient was obtained as follows. Kya=0.5906(Vg/L)0.7611 The following correlation of mass transfer coefficient and efficiency was proposed. η=0.06078 Kya0.2444

The total hydrocarbon distribution of oil products obtained from the pyrolysis of four kinds of mixtures of polyethylene-polystyrene waste has been studied by multidimensional chromatography(high performance liquid chromatography followed by capillary gas chromatography)/mass spectrometry. Saturated, unsaturated and aromatic hydrocarbons in oil products were selectively pre-separated according to structural groups by HPLC and the weight fraction of each group was estimated by analysis of each component using GC-FID response factors. The hydrocarbon distribution of aliphatic fraction consists of C5 to C25 saturated and unsaturated hydrocarbons. And that of aromatics fraction consists of benzene, toluene, xylene, styrene, propenyl benzene, naphthalene, and some of derivatives. Pyrolysis temperature did not affect the ratio of total weight fraction of aliphatic over aromatic hydrocarbon distribution in case of PS only and PE-PS mixtures (1:1 and 1:4 wt. ratio) as a feed while affected the ratio of total wt. fraction in case of PE only. The optimal temperature for the maximum oil production was 600℃ for pyrolysis of PS and 1:1 and 1:4 mixtures of PE and PS. The optimal condition for aromatic recovery was 600℃ with 1:1 mixture of PE and PS. In this condition, aromatic was produced up to 90% of total oil product. The maximum yield of toluene, xylene, styrene, and propenyl benzene were 8.6, 8.9, 51.0 and 7.4% of feed for pyrolysis PS at 700℃, respectively. However, only 1.3% naphthalene was recovered at 700℃ with 1:1 PE:PS(by wt.).