As a promising anode for sodium-ion batteries (SIBs), cobalt sulfide ( CoS2) has attracted extensive attention due to its high theoretical capacity, easy preparation, and superior electrochemical activity. However, its intrinsic low conductivity and large volume expansion result in poor cycling ability. Herein, nitrogen-doped carbon-coated CoS2 nanoparticles (N–C@ CoS2) were prepared by a C3N4 soft-template-assisted method. Carbon coating improves the conductivity and prevents the aggregation of CoS2 nanoparticles. In addition, the C3N4 template provides a porous graphene-like structure as a conductive framework, affording a fast and constant transport path for electrons and void space for buffering the volume change of CoS2 nanoparticles. Benefitting from the superiorities, the Na-storage properties of the N–C@CoS2 electrode are remarkably boosted. The advanced anode delivers a long-term capacity of 376.27 mAh g− 1 at 0.1 A g− 1 after 500 cycles. This method can also apply to preparing other metal sulfide materials for SIBs and provides the relevant experimental basis for the further development of energy storage materials.

The thermocatalytic decomposition of methane is a promising method for hydrogen production. To determine the cause of carbonaceous catalyst deactivation and to produce high-value carbon, methane decomposition behavior and deactivated catalysts were analyzed. The surface properties and crystallinity of a commercial activated carbon material, MSP20, used as a methane decomposition catalyst, varied with the reaction time at a reaction temperature of 900 °C. During the initial reaction, MSP20 provided a methane conversion of ≥ 50%; however, the catalyst exhibited rapid deactivation as crystalline carbon grew at surface defects; after 15 min of reaction, approximately 33% methane conversion was maintained. With increasing reaction time, the specific surface area of the catalyst decreased, whereas crystallinity increased. The R-square value of the conversion–crystallinity relationship was significantly higher than that of the conversion–specific surface area relationship; however, neither profile was linear. The activity of the activated carbon catalyst for methane decomposition is mainly determined by the complex actions of the specific surface area and defect sites. The activity was maintained after an initial sharp decline caused by the continuous growth of crystalline carbon product. This study presents the application of carbonaceous catalysts for the decomposition reaction of methane to form COx- free hydrogen, while simultaneously yielding porous carbon materials with an improved electrical conductivity.

To study the effect of inorganic electrolyte solution on graphite flotation, 19 kinds of inorganic electrolytes, including nitrate, chloride and sulfate were selected as experimental electrolytes. The flotation experiment was carried out on graphite and the contact angle and surface potential of the interaction between inorganic electrolyte solution and graphite were studied. The results show that flotation effect and flotation rate of the three ion valence inorganic electrolytes follow the order: nitrate < chloride < sulfate and univalent < bivalent < trivalent (except Ba(NO3)2 and Pb(NO3)2). When the ion valence are the same, the larger the ion atomic number, the better effect on graphite flotation. Cations in inorganic electrolyte solutions are the main factors affecting mineral flotation. When the cationic type and concentration are the same, different flotation effects are attributed to different anions. For low ion valence inorganic electrolyte solution with weak foaming effect, a certain dose of frother can be added appropriately to improve the flotation effect of graphite. The high ion valence inorganic electrolyte solution has strong foaming effect, and it is not necessary to add a frother. The principle of inorganic electrolyte solution promoting graphite flotation is analyzed from the aspects of liquid phase property, gas–liquid interface property, contact angle and surface potential. It is proved that inorganic electrolyte solution as flotation medium can promote the effective flotation of graphite.

시설 재배 시, 미세먼지의 잦은 발생은 피복재의 광투과율을 감소시키고 이는 작물의 생육에 간접적인 영 향을 미칠 수 있다. 본 연구에서는 미세먼지 발생에 따른 폴리에틸렌(PE)과 폴리올레핀(PO) 필름의 광투과율 변화 를 조사하고, 피복재의 광투과율 감소에 따른 봄철 재배 오이의 생육 변화를 확인하였다. 미세먼지 발생 챔버를 이 용하여 PE와 PO 필름을 지속적으로 미세먼지에 노출시켰을 때, PE 필름에서 미세먼지 발생에 의한 광투과율 감소 가 PO 필름보다 크게 나타났다. PE 필름에 인위적으로 먼지를 부착시켜서 대조구 대비 10, 20 및 30% 광투과율 감 소 처리구를 설정한 후 오이를 재배하였을 때, 3월 말 이후 재배 후반기에서의 오이 생육은 광투과율 감소 처리구에 서 증가하였으나, 누적 수확량은 대조구에서 가장 높았다. 봄철 오이 재배에서 미세먼지 발생에 의한 광투과율 감 소는 3월 말 이후 시설 내 고온 노출에 의한 생육 지연을 줄일 수 있었으나, 전 생육 기간 동안의 광투과율 감소는 입 사광량의 감소 및 광합성의 저하로 오이의 총 수확량을 감소시켰다.

The effect of the surrounding vegetation on the seed germination and growth of mountain-cultivated ginseng (MCG, Panax ginseng C.A. Meyer) was investigated. Seed germination rate and growth were tested for allelopathy effects on four forest tree species after treatment with fallen leaves and leaf extracts. In the case of soil treatment through fallen leaves and crushed leaves, the germination rate was lower in the Quercus myrsinifolia treatments, and the average germination time was slower when Chamaecyparis obtusa was treated. In the case of Pinus densiflora and Quercus variabilis, which are used in most of the MCG cultivation areas, they did not have a significant effect on seed germination. In the fallen leaves treatments, the stem showed a tendency to lengthen. The hot water extract treatment showed a higher germination percentage than the cold water extract treatment. The extract treatment showed a deficient germination percentage of some MCG seeds. However, in the case of the treatments except for this, the germination percentage was similar to that of the control treatment. However, the Mean Germination Time, germination rate, and germination value were faster and higher than the control treatment. As a result of calculating the allelopathic index (AI) of MCG according to the extract treatment of 4 species, most had a negative effect on germination, and P. densiflora and Q. variabilis extracts showed the most significant effect. The ginsenoside content was higher in the fallen leaves treatment than in the control. The above results will help select and manage MCG plantations.

The genera Spilonota Stephens, 1834 and Lepteucosma Diakonoff, 1971 are belonging to the tribe Eucosmini, subfamily Olethreutinae. In Korea, there are five species of Spilonota recorded: S. albicana (Motschulsky, 1866), S. eremitana Moriuti, 1972, S. lechriaspis Meyrick, 1932, S. ocellana ([Denis & Schiffermüller], 1775), and S. semirufana (Christoph, 1882). Only one species of Lepteucosma is recorded: L. huebneriana (Kocak, 1980). Both genera are agricultural pests that infest host plants belonging to the family Rosaceae, specifically causing damage to genus Malus (apple trees) and genus Rubus (blackberry plants), respectively. In this study, we provide a checklist of Korean Spilonota and Lepteucosma, with information of host plants and distribution for each examined species.

The subfamily Epipaschiinae belongs to the family Pyralidae in the superfamily Pyraloidea. Moths of the epipaschiine are mostly medium-sized, and around 705 species have been described worldwide, with most of them distributed in Tropical and Temperate Regions (Nuss et al., 2023). In this study, 24 species of 10 genera of the subfamily Epipaschiinae are identified. All of the species are accompanied by distributions, host plants, and collection site information. Illustrations of adults, male and female genitalia are provided.

The subtribe Olethreutae Diakonoff (1973) which is one of the large subtribe in the subfamily Olethreutinae in the Tortricidae. Diakonoff classified the Olethreutae into a total of 27 genera and three genus groups: Olethreutes, Hedya, and Apotomis. According to the check list of insects from Korea (KSAE & ESK, 2021), 62 species from 11 genera of Olethreutae have been recorded in Korea. This study, provided with redescriptions, distribution, host plants, along with illustrations of adults, male and female genitalia are given.

In this study, Bacillus velesensis TJS119, isolated from freshwater, demonstrated growth inhibition against insect pathogenic fungi. The culture medium of the B. velezensis TJS119 strain underwent sequential fractionation with n-hexane, chloroform, ethyl acetate, n-butanol, and water. Notably, the n-butanol fraction exhibited significant antifungal activity against Metarhizium anisopliae and Beauveria bassiana. LC/MS analysis of antifungal peaks identified the production of various lipopeptides by B. velezensis TJS119, including two types of iturin A (C14, C15), four types of fengycin A (C14, C15, C16, C17), and two types of fengycin B (C16, C17). The antifungal efficacy of Iturin A and Fengycin against insect pathogenic fungi was further validated using the paper disc diffusion method. These findings underscore the potential of B. velezensis TJS119 as a promising candidate for future research and applications in the realm of agricultural biological controls against fungal diseases.

Protaetia brevitarsis seulensis larvae from industrial insects are traditionally recognized as functional health foods in South Korea. We evaluated the immuno-modulatory effects of feeding beneficial microorganism (Bacillus velezensis TJS119) to P. brevitarsis larvae as a dietary source. In this study, we investigated the immune-enhancing activities of P. brevitarsis larvae hot-water extract (PLW) and PLW after treatment with B. velezensis TJS119 (PLWB) using the RAW 264.7 macrophage cell line. We examined the effects of PLWB on cell proliferation, cytokine production, and nitric oxide production in RAW264.7 cells. PLWB showed no cytotoxicity at concentrations ranging from 7.8 to 1,000 μg/mL in RAW264.7 cells. Treatment with PLWB increased the production of nitric oxide and pro-inflammatory cytokines [tumor necrosis factor-alpha (TNF-α), interleukin-6 (IL-6), and interleukin-1β (IL-1β)] at doses of 62.5 to 1,000 μ g/mL in RAW264.7 cells. As a result, PLWB exhibited a stronger immune-enhancing effect compared to PLW. In conclusion, the results of this study offer experimental evidence to support the potential utilization of PLWB as an immunity-enhancing nutraceutical ingredient.

Bacillus velezensis TJS119 was isolated from the freshwater, and antagonistic activity against of pathogenic fungi. Strain TJS119 showed a broad spectrum of antagonistic activities many fungal pathogens, including the green muscardine fungus Metarhizium anisopliae. The whole-genome sequence of B. velzensis TJS119 was analyzed using the illumina platform. The genome comprises a 3,809,913 bp chromosome with a G + C content of 46.43%, 3,834 total genes, 10 rRNA and 73 tRNA genes. The genome contained a total of 8 candidate gene clusters (difficidin, fengycin, bacillaene, macrolactin, bacillibactin, bacilysin, surfactin and butirosin) to synthesize secondary metabolite biosynthesis. Overall, our data will aid future studies of the biocontrol mechanisms of B. velezensis TJS119 and promote its application in insect disease control.

Immunity is largely divided into innate immunity and adaptive immunity. We conducted a study using HongJam extract to confirm its innate immunity-enhancing effect. Our data using Natural Killer (NK) cells, which play an important role in innate immunity, confirmed that HongJam extract promotes the proliferation of NK cells and also enhances the function of NK cells to attack and destroy cancer cells. (Grant No. PJ017024022023)

Hongjam is a natural health food that has been shown to have various health-promoting effects, but studies on immunity enhancement have not been done so far. In this study, we investigated whether HongJam extracts could be enhancing innate immunity by protomoting proliferatin of macrophages and their phagocytic or pinocytic abilities to pathogens. (Grant No. PJ017024022023)