Lubricant oil waste contaminated with radioactive materials generated at nuclear facilities can be disposed of as industrial waste in accordance with self-disposal standards if only radioactive materials are removed. Lubricant oil used in nuclear facilities consists of oil of 75-85% and additives of 15-25%, and lubricant oil waste contains heavy metals, carbon, glycol, etc. In addition, lubricant oil waste from nuclear facilities contains metallic gamma-ray emission radionuclides including Co-60, Cs-137 and volatile beta-ray emission radionuclides such as C-14 and H-3, which are not present in lubricant oil waste from general industries and these radionuclides must be eliminated according to the Atomic Energy Act. In general industries, the wet treatment technologies such as acid-white soil treatment, ion purification, thin film distillation, high temperature pyrolysis, etc. are used as the refining technology of lubricant oil waste, but it is difficult to apply these technologies to nuclear industrial sites due to restrictions related with controlling the generation of secondary radioactive waste in sludge condition containing radionuclides of metal components, and limiting the concentration of volatile radioactive elements contained in refined oil to be below the legal threshold. In view of these characteristics, the refinement system capable of efficiently refining and treating lubricant oil waste contaminated with radioactive materials generated in nuclear facilities has been developed. The treatment process of this R&D system is as follows. First, the moisture in the radioactive lubricant oil waste pretreated through the preprocessing system is removed by the heated evaporating system, and the beta-emission radionuclides of H-3 and C-14 can be easily removed in this process. Second, the heated lubricant oil waste by the heated evaporating system is cooled through the heat exchanging system. Third, the particulate matters with gamma-ray emission radionuclides are removed through the electrostatic ionizing system. Forth, the lubricant oil waste is stored in the storage tank and the purified lubricant oil waste is discharged to the outside after sampling and checking from the upper, middle and lower positions of the lubricant oil waste stored in the storage tank. Using this R&D system, it is expected that the amount of radioactive waste can be reduced by efficiently refining and treating lubricant oil waste in the form of organic compounds contaminated with radioactive materials generated in nuclear facilities.

There are various types of level gauging method such as using float, differential pressure, hypersonic, displacement and so on. In this study, among them, the method utilizing the differential pressure was reviewed. The strengths include: the differential pressure type level gauge can measure the level without direct contact of the sensor with media. That is to say, the level can be measured even if the sensor is far away from the tank. And regardless of the size of the tank, the level can be measured if the pneumatic pipes are installed. The weaknesses include: the sensor needs intermedium to recognize the level. The intermedium utilizes a fluid, which is compressed air. It is difficult to handle that compressed air has the properties of a gas. And to make compressed air needs compressor, tank and pneumatic pipes. So if you have many tanks, you need to install exponentially the pneumatic pipes. As well, level measurement range is limited to the points where the pneumatic pipes of the tank is installed. And if a compressed air that supplies to the sensor leaks, uncertainty will increase. A compressed air is colorless and odorless, so it’s difficult to pinpoint the leak. Finally, events like cracks and clogging can cause inaccurate measurement. Rather than using only differential pressure, it is better to use another measurement method according to the situation of the facility.

Following a radioactive waste criterion and clearance level radioactive waste Act Article 2. “The radioactive wastes confirmed by the Commission as having concentration by nuclide not exceeding the value determined by the Commission through incineration, reclamation, recycling, etc”. The combustible clearance level radioactive wastes like lumbers are incinerated and non-combustible wastes like concreted are buried. The metals clearance level radioactive wastes are recycled after being re-molded. However, the clearance level radioactive waste with keeping its original forms is not common. Due to the nature of KAERI, the equipment are brought into the radiation-controlled zone for experiments. Those equipment are conservatively considered contaminated and categorized with radioactive waste following nuclear safety acts. In this case, the spectroscopy device which is clearance level radioactive waste is self-disposed for use in non-controlled areas. The 4 devices are composed of 3 gamma-ray spectroscopy and 1 alpha, beta counting system. Those devices were used for clearance level radioactive waste’s radioisotope analysis in Radioactive Waste Form Test Facility which is used in a separated room for analysis. This room will be released in nonradiation controlled area, therefore those devices will be moved to non-controlled area and keep using. Last April self-disposal was reported to the regulatory body and got acceptance last May. Those devices were moved to non-controlled area last July. This case will be good example for reuse equipment which stop using in radiation controlled area but can keep used.

In the case of decommissioning of a nuclear power plant, it is expected that a significant amount of VLLW and LLW that need to be disposed of are also expected. Conventional reduction technology is a method of extracting or removing radionuclides from waste, but this project is being carried out for the purpose of obtaining a reduction effect through the development of a material that treats another radioactive waste using radioactive waste. In this paper, the technology of impregnating LiOH capable of adsorbing radiocarbon to the gas filter material manufactured from concrete and soil waste as raw materials and the radiocarbon removal performance were reviewed. In this study, a raw material of ceramic filter was prepared by mixing concrete and soil waste with a powder of 40 m or less, and after sintering at 1,250°C, 5wt% to 40wt% of LiOH is impregnated with a filter capable of adsorbing carbon dioxide. was prepared. The prepared filter used ICP-OES and XRD to confirm the LiOH deposition result, and the concentration of carbon dioxide discharged through the carbon dioxide adsorption device was confirmed. It was possible to obtain the result that the amount of adsorption was changed depending on the flow rate of carbon dioxide supplied and the amount of material. Through this, it was possible to confirm the possibility of power generation in the adsorption performance of gas. In this study, after crushing waste concrete and waste soil, powders of 40 m or less were mixed with other additives to prepare raw materials for ceramic filters, and sintered at 1,250°C to manufacture filters. 5wt% to 40wt% of LiOH was impregnated on the prepared filter to give functionality to enable carbon dioxide adsorption. The results of LiOH deposition were confirmed using ICP-OES and XRD, and the change in the concentration of carbon dioxide emitted through a separately prepared adsorption device was confirmed. It was possible to obtain the result that the amount of adsorption was changed according to the flow rate of carbon dioxide supplied and the amount of material, and the possibility of developing a material for radioactive waste treatment using radioactive waste was confirmed when the porosity and specific surface area of the filter material were increased.

Regulations on the concentration of boron discharged from industrial facilities, including nuclear power plants, are increasingly being strengthened worldwide. Since boron exists as boric acid at pH 7 or lower, it is very difficult to remove it in the existing LRS (Liquid Radwaste System) using RO and ion exchange resin. As an alternative technology for removing boron emitted from nuclear power plants, the electrochemical boron removal technology, which has been experimentally applied at the Ringhal Power Plant in Sweden, was introduced in the last presentation. In this study, the internal structure of the electrochemical module was improved to reduce the boron concentration to 5 mg/L or less in the 50 mg/L level of boron-containing waste liquid. In addition, the applicability of the electrochemical boron removal technology was evaluated by increasing the capacity of the unit module to 1 m3/hr in consideration of the actual capacity of the monitor tank of the nuclear power plant. By applying various experimental conditions such as flow rate and pressure, the optimum boron removal conditions using electrochemical technology were confirmed, and various operating conditions necessary for actual operation were established by configuring a concentrated water recirculation system to minimize secondary waste generation. The optimal arrangement method of the 1 m3/hr unit module developed in this study was reviewed by performing mathematical modeling based on the actual capacity of monitor tank and discharge characteristics of nuclear power plant.

The integrity of the disposal repository structure must be guaranteed for few hundreds to few hundred thousand years until toxicity of radioactive waste is surely degraded. Acoustic emission (AE) method is widely utilized to evaluate the integrity of the structure because it can detect crack wave signals of the structures. It is well known that the cracking AE energy is proportional to the volume of the structure (Fractal theory). However, it is hard to destroy whole structures for obtaining AE energy. Therefore, the scaled specimens are prepared to obtain the relationship between volume of the structure and AE energy. The specimens are prepared with same of Wolsong Low and Intermediate Level Radioactive Waste Disposal Center (WLDC) silo concrete recipe. Their diameters are from 50 mm to 150 mm in each 10 mm and their heights are twice of the diameter. One set of 50 mm to 150 mm specimens (11 specimens in one set) are made in single mixers to maintain uniformity. Surface of the specimens are flatten with cement milk to prevent from applying load with eccentricity. The uniaxial compression test is performed by controlling displacement as 0.1 mm/min. The fractal constant is obtained using least square function from volume-cumulative AE energy relationship.

Various radionuclides are released and contaminate soils by the nuclear accidents, nuclear tests and disposal of radioactive waste. Among radionuclides, 137Cs is a harmful radioactive element that emits high-energy β particles and γ rays with a half-life of 30.2 years. 137Cs is difficult to extract because it is fixed to soil particles. For the volume reduction technology development of contaminated soil, this study tried to evaluate the irreversible Cs adsorption capacity of granite-originated soil. The soil sample used in the study was collected from C horizon of the soil developed in Mesozoic mica granite. The soil texture, mineralogy, organic content, pH, EC, cation exchange capacity (CEC), water-soluble cation and anion content of the soil samples were determined. A kinetic adsorption experiment and an isotherm adsorption experiment were performed to understand the overall Cs adsorption characteristics using 133Cs. The desorption of Cs by 0.1 mM KCl was also tested for the sample spiked with 133Cs and 137Cs. The soil sample showed a pH of 6.73, EC of 24.50 μS cm-1, and CEC of 1.34 cmolc kg-1, organic matter of 0.53% and sandy loam in texture. Quartz, feldspar and mica were identified as the major mineral components of bulk sample. The clay fraction consists of mica, hydroxyl-interlayer vermiculite (HIV), vermiculite and kaolinite. In the kinetic adsorption experiment, the Cs adsorption showed fast adsorption rates at the initial stage (6 hours) regardless of the 133Cs concentration, and the adsorption equilibrium state was reached after 48 hours. It was the most suitable for the pseudo second-order model. The 133Cs adsorption increased nonlinearly from low to high concentration, which was well match with the dual site Langmuir model. As a result of the desorption experiment, desorption was not performed up to 1.1 mg kg-1 in the presence of competitive ions K+, which is about 0.035% of CEC calculated by the isotherm model. The adsorption of Cs was controlled by frayed edge sites (FES) at a low concentrations and by basal sites or interlayer sites at a high concentration. Irreversible Cs fixation of by FES may be contributed by mainly weathered mica, and when these minerals are separated from the granite origin soil, the possibility of reducing the contamination concentration and volume of radioactive soil waste can be expected.

Many countries have been developing their own FEP (Feature, Event, Process) lists to formulate radionuclide release scenarios in deep disposal repository of spent nuclear fuels and to assess the safety. The main issue in developing a FEP list is to ensure its completeness and comprehensiveness in examining all plausible scenarios of radionuclide release in a repository of interest. To this end, the NEA International FEP (IFEP) list as a generic reference have been developed and updated through long-term international collaborations. Leading countries advanced in the research field of deep geologic disposal of spent nuclear fuels have comparatively mapped their project-specific FEP (PFEP) lists with the IFEP list. Recently in 2019, NEA has published an updated version of IFEP list (ver. 3.0) which has a different classification system: the IFEP version 3.0 has the five main categories including the waste package, repository, geosphere, biosphere and external factors while the previous IFEP versions were mainly classified into the external, environmental, and contaminant factors. Most leading countries in this field, Finland and Sweden, recently succeeded to obtain the design and/or construction licenses for deep geologic disposal of spent nuclear fuel. Therefore, their PFEP lists should be good benchmark cases to the following countries. However, their PFEP lists have not comparatively mapped with the most recent version of IFEP and thus some gaps may exist in showing completeness and comprehensiveness in comparison to the IFEP version 3.0. In this study, we comparatively map the PFEP lists of Finland and Sweden to the IFEP version 3.0. The comparatively mapped PFEP list could be used as the basis for verifying the comprehensiveness and completeness of the domestic PFEP list currently under development in Korea.

Compacted bentonite buffer materials are a key component of the engineered barrier system for high-level radioactive waste disposal. The bentonite buffer is saturated via groundwater flow through the excavation damaged zone in the adjacent rock mass. Bentonite saturation results in bentonite swelling, gelation and intrusion into the nearby rock discontinuities. Groundwater flow can cause bentonite erosion and transportation of bentonite colloids. This bentonite mass loss can negatively impact the long-term integrity of the engineered barrier system. Hence, it is necessary to understand the effects of erosion on the properties of the bentonite buffer. In this study, a series of artificial fracture erosion experiments are conducted to investigate the erosion characteristics of compacted Ca-bentonite buffer materials for different initial dry density conditions. Compacted bentonite blocks and bentonite pellets were manufactured using the cold isostatic pressing technique and granulation compactor respectively. The specimens were placed in a custommade transparent artificial fracture cell and the bentonite intrusion characteristics were monitored for two months under free swelling conditions with no groundwater flow. The radial expansion of the bentonite specimens within the artificial fracture was measured using a digital camera. In addition, the swelling pressure, displacement, and saturation were determined using a load cell-piston system, LVDT, and electrical resistivity electrodes respectively. A hydro-mechanical-chemical coupled dynamic bentonite diffusion model was applied to model the bentonite erosion characteristics using COMSOL Multiphysics.

A rock joint exerts significant influences on the rock mass behavior in terms of thermal, hydraulic, and mechanical (THM) aspects. Therefore, its features should be thoroughly investigated in various rock mechanical projects, such as high-level radioactive waste (HLW) disposal repository, tunnel, and rock slope. Meanwhile, it is essential to guarantee the safety of the disposal repository for a very long period of time and it should prepare measures for various risks, which may possibly encounter during that period. In general, direct shear tests for a rock joint are conducted to investigate the possibility of frictional sliding of the joint under specific loading conditions or to predict the shear strength of the joint. However, it is necessary to consider whether regional sliding of a rock joint or reactivation of a fault might occur due to an earthquake or redistribution of the in-situ stresses because the expected operation period of the repository is quite long, and various situations can happen. A slide-hold-slide test for a rock joint is a practical test that can investigate the time-dependent behavior or frictionalhealing of a joint. The test enables an estimation of the stress build-up phenomenon after strain energy release in a quantitative manner. In this study, a series of slide-hold-slide tests were carried out in order to investigate the characteristics. Joint specimens were made from mortar, which is a rock-like and brittle material, so as to consider the effect of joint roughness and to secure the reproducibility of the tests. At the same time, mechanical conditions as well as thermal and hydraulic were applied in order to take the environment of the repository into account. As a result, the behavior of shear stress recovery was observed, and the effects of THM coupled condition on the recovery were investigated. This study presents fundamental results of the experiments, and further research outcomes, including time dependent behavior of a joint, will be presented sequentially.