The density of molten salts is the most important property in the development of molten salt reactor (MSR). The density value measured through the experiment is also very valuable as a gold standard for the validation of the prediction models based on molecular dynamics or other computational methods. To the best of our knowledge, the experimental density data of the ternary NaCl-MgCl2- UCl3 salt system as a MSR candidate fuel salt have never been reported previously. In this study, density measurement experiment of high-temperature molten salt of NaCl-MgCl2 and NaCl-MgCl2- UCl3 was conducted using a previously-developed density measurement system based on the maximum bubble pressure (MPB) method. As a result of the experiment, the density value of 62NaCl- 18MgCl2-20UCl3 molten salt at 873 K was 2.62 g/cm3. A density prediction value of 2.65 g/cm3 at 873 K was derived from the obtained results based on the rule of additivity of molar volume method. The predictred density of 62NaCl-18MgCl2-20UCl3 was consistent with the experimental value within 1%. The density measuring system used in this study is promising for the validation of other multicomponent molten salt systems.

Viscosity of molten salts is an essential property for the thermal hydraulic design and evaluation of molten salt reactor (MSR). Therefore, viscosity data is one of the fundamental physical property data required for safe process operation and countermeasures to severe accidents. In this study, based on our experience of developing a viscosity measurement system for high-temperature LiCl-KCl molten salt system, the viscosity of NaCl-MgCl2 and NaCl-MgCl2-UCl3 molten salts, which are considered promising salts in MSR, was measured. In order to investigate the physical properties of uranium in high-temperature NaCl-MgCl2 molten salt, a viscometer system for high-temperature viscosity measurement was specially designed. As a result of the measurement, the viscosity of the 58NaCl- 42MgCl2 molten salt was 2.73 cP at 838 K, 2.15 cP at 889 K, and 1.68 cP at 940 K. And the viscosity of 73NaCl-21MgCl2-6UCl3 molten salt was 3.79 cP at 877 K, 3.58 cP at 897 K, and 1.63 cP at 941 K. The repeatability of the measurement showed a precision of less than 3%. Although sufficientlyverified starting materials were not used, viscosity data were reported for the first time for NaCl- MgCl2-UCl3 molten salts.

Molten salts have gained significant attention as a potential medium for heat transfer or energy storage and as liquid nuclear fuel, owing to their superior thermal properties. Various fluoride- and chloride-based salts are being explored as potential liquid fuels for several types of molten salt reactors (MSRs). Among these, chloride-based salts have recently received attention in MSR development due to their high solubility in actinides, which has the potential to increase fuel burnup and reduce nuclear water production. Accurate knowledge of the thermal physical properties of molten salts, such as density, viscosity, thermal conductivity, and heat capacity, is critical for the design, licensing, and operation of MSRs. Various experimental techniques have been used to determine the thermal properties of molten salts, and more recently, computational methods such as molecular dynamics simulations have also been utilized to predict these properties. However, information on the thermal physical properties of salts containing actinides is still limited and unreliable. In this study, we analyzed the available thermal physical property database of chloride salts to develop accurate models and simulations that can predict the behavior of molten salts under various operating conditions. Furthermore, we conducted experiments to improve our understanding of the behavior of molten salts. The results of this study are expected to contribute to the development of safer and more efficient MSRs.

Natural uranium-contaminated soil in Korea Atomic Energy Research Institute (KAERI) was generated by decommissioning of the natural uranium conversion facility in 2010. Some of the contaminated soil was expected to be clearance level, however the disposal cost burden is increasing because it is not classified in advance. In this study, pre-classification method is presented according to the ratio of naturally occurring radioactive material (NORM) and contaminated uranium in the soil. To verify the validity of the method, the verification of the uranium radioactivity concentration estimation method through γ-ray analysis results corrected by self-absorption using MCNP6.2, and the validity of the pre-classification method according to the net peak area ratio were evaluated. Estimating concentration for 238U and 235U with γ-ray analysis using HPGe (GC3018) and MCNP6.2 was verified by 􀟙-spectrometry. The analysis results of different methods were within the deviation range. Clearance screening factors (CSFs) were derived through MCNP6.2, and net peak area ratio were calculated at 295.21 keV, 351.92 keV(214Pb), 609.31 keV, 1120.28 keV, 1764.49 keV(214Bi) of to the 92.59 keV. CSFs for contaminated soil and natural soil were compared with U/Pb ratio. CSFs and radioactivity concentrations were measured, and the deviation from the 60 minute measurement results was compared in natural soil. Pre-classification is possible using by CSFs measured for more than 5 minutes to the average concentration of 214Pb or 214Bi in contaminated soil. In this study, the pre-classification method of clearance determination in contaminated soil was evaluated, and it was relatively accurate in a shorter measurement time than the method using the concentrations. This method is expected to be used as a simple pre-classification method through additional research.

Gamma imaging devices that can accurately localize the radioactive contamination could be effectively used during nuclear decommissioning or radioactive waste management. While several hand-held devices have been proposed, their low efficiency due to small sensors have severely limited their application. To overcome this limitation, a high-speed gamma imaging system is under development which comprises two quad-type detectors and a tungsten coded aperture mask. Each quad-type detector consists of four rectangular NaI(Tl) crystals with dimensions of 146×146 mm2 and 72 square-type photomultiplier tubes (PMTs). The detectors are placed in front and back to serve as scatter and absorber, respectively, for Compton imaging. In addition, a coded aperture mask was fabricated in rank 19 modified uniformly redundant array pattern and placed in front of the scatter for coded aperture imaging. The system offers several advanced features including 1) high efficiency achieved by employing large-area NaI(Tl) crystals and 2) broad energy range of imaging by employing a hybrid imaging combining Compton and coded aperture imaging. The imaging performance of the system was evaluated through experiments in various conditions with different gamma energies and source positions. The imaging system provides clear images of the source locations for gamma energies ranging from as low as 59.5 keV (241Am) to as high as 1,330 keV (60Co). The imaging resolution was within the range of 7.5–9.4°, depending on gamma energies, when a hybrid maximum likelihood estimation maximization (MLEM) algorithm was used. The developed system showed high sensitivity, as the 137Cs source at distance, incurring dose rate lower than background level (0.03 μSv/h above background dose rate), could be imaged in approximately 2 seconds. Even under lower dose rate condition (i.e., 0.003 μSv/h above background dose rate), the system was able to image the source within 30 seconds. The system developed in the present study broadens the applicable conditions of the gamma ray imaging in terms of gamma ray energy, dose rate, and imaging speed. The performance demonstrated here suggests a new perspective on radiation imaging in the nuclear decontamination and radioactive waste management field.

Disposal of radioactive waste requires radiological characterization. Carbon-14 (C-14) is a volatile radionuclide with a long half-life, and it is one of the important radionuclides in a radioactive waste management. For the accurate liquid scintillation counter (LSC) analysis of a pure beta-emitting C-14, it should be separated from other beta emitters after extracted from the radioactive wastes since the LSC spectrum signals from C-14 overlaps with those from other beta-emitting nuclides in the extracted solutions. There have been three representative separation methods for the analysis of volatile C-14 such as acid digestion, wet oxidation, and pyrolysis. Each method has its own pros and cons. For example, the acid digestion method is easily accessible, but it involves the use of strong acids and generates large amount of secondary wastes. Moreover, it requires additional time-consuming purification steps and the skillful operators. In this study, more efficient and environment-friendly C-14 analysis method was suggested by adopting the photochemical reactions via in-situ decomposition using UV light source. As an initial step for the demonstration of the feasibility of the proposed method, instead of using radioactive C-14 standards, non-radioactive inorganic and organic standards were investigated to evaluate the recovery of carbon as a preliminary study. These standards were oxidized with chemical oxidants such as H2O2 or K2S2O8 under UV irradiations, and the generated CO2 was collected in Carbo-Sorb E solution. Recovery yield of carbon was measured based on the gravimetric method. As an advanced oxidation process, our photocatalytic oxidation will be promising as a time-saving method with less secondary wastes for the quantitative C-14 analysis in low-level radioactive wastes.

Metakaolin-based geopolymers have shown promise as suitable candidates for 14C immobilization and final disposal. It has been shown that the physicochemical properties of metakaolin wasteforms meet, and often far exceeding, the strict compression strength and leaching acceptance criteria of the South Korea radioactive waste disposal site. However, it is not possible to analyze and characterize the internal structure of the geopolymer wasteform by conventional characterization techniques such as microscopy without destruction of the wasteform; an impractical solution for inspecting wasteforms destined for final disposal. Internal inspection is important for ensuring wastes are homogenously mixed throughout the wasteform and that the wasteform itself does not pose any significant defects that may have formed either during formulation and curing or as a result of testing prior to final disposal. X-ray Computed Tomography (XCT) enables Non-Destructive Evaluation (NDE) of objects, such as final wasteforms, allowing for both their internal and external, characterization without destruction. However, for accurate quantification of an objects dimensions the spatial resolution (length and volume measures) must be know to a high degree of precision and accuracy. This often requires extensive knowledge of the equipment being used, its precise set-up, maintenance and calibration, as well as expert operation to yield the best results. A spatial resolution target consists of manufactured defects of uniformed dimensions and geometries which can be measured to a high degree of accuracy. Implementing the use of a spatial resolution target, the dimensions of which are known and certified independently, would allow for rapid dimensional calibration of XCT systems for the purpose of object metrology. However, for a spatial resolution target to be practical it should be made of the same material as the intended specimen, or at least exhibit comparable X-ray attenuation. In this study, attempts have been made to manufacture spatial resolution targets using geopolymer, silica glass, and alumina rods, as well as 3D printed materials with varying degrees of success. The metakaolin was activated by an alkaline activator KOH to from a geopolymer paste that was moulded into a cylinder (Diameter approx. 25 mm). The solidified geopolymer cylinder as well as both the silica glass rod and alumina rod (Diameter approx. 25 mm) we cut to approximately 4 mm ± 0.5 mm height with additional end caps cut measuring 17.5 mm ± 2.5 mm height. All parts were then polished to a high finish and visually inspected for their suitability as spatial resolution targets.

It is important to make a strategy for clearance-level radioactive waste. Sampling and disposal plans should be drawn up with characteristics of target waste. In this paper, a target clearance-level radioactive waste is used in a laboratory for experiments with Cs-137 and Co-60, unsealed radioactive sources with gamma radiation isotopes. Therefore, it is enough to analyze with HPGe to check the contaminant level. The laboratory fume hood combined multiple materials, which means some are volume contamination and others are surface contamination. The wood, plastic, and drywall boards, which are absorbent volume contaminated parts and make up PVC pipes, base cabinet doors, backside baffles, etc., will be sampled with coring methods. The metals and glasses, which are unabsorbent, surface-contaminated parts, are sampled with smear methods. The work surface, baffles, exhaust plenum, and glass sash inside parts have a high possibility of being contaminated. The hood body, flame, base cabinet, PVC pipe (the rare end of the filter), and blower transition case have a low possibility of becoming contaminated. When we checked with HPGe, except for the work surface (which was below clearance level), other parts were less than MDA. The highest radionuclide concentration was in PVC pipe: Cs-137C 3.91E-02 (Bq/g), Co-60 4.54E- 03 (Bq/g). It is less than clearance level. Therefore, the waste was applied for the clearance level radioactive wastes and got permission from the regulatory body.

The nuclear facilities at Korea Atomic Energy Research Institute (KAERI) have generated a variety of liquid radioactive waste and most of them have low-level radioactive or lower levels. Some of the liquid radioactive waste generated in KAERI is transported to Radioactive Waste Treatment Facility (RWTF) in 20 L container. Liquid radioactive waste transported in a 20 L container is stored in a Sewer Tank after passing through a solid-liquid separation filter. It is then transferred to a very low-level liquid radioactive waste Tank after removing impurities such as sludge through a pre-treatment device. The previous pre-treatment process involved an underwater pump and a cartridge filter device passively, but this presented challenges such as the inconvenience of having to install the underwater pump each time, radiation exposure for workers due to frequent replacement of the cartridge filter, and the generation of large amounts of radioactive waste from the filter. To address these challenges and improve efficiency and safety in radiation work, an automated liquid radioactive waste pre-treatment device was developed. The automated liquid radioactive waste pre-treatment device is a pressure filtration system that utilizes multiple overlapping filter plates and pump pressure to effectively remove impurities such as sludge from liquid radioactive waste. With just the push of a button, the device automatically supplies and processes the waste, reducing radiation hazards and ensuring worker safety. Its modular and mobile design allows for flexible utilization in various locations, enabling efficient pre-treatment of liquid radioactive waste. To evaluate the performance of the newly constructed automated liquid radioactive waste treatment device, samples were taken before and after treatment for 1 hour cycling and analyzed for turbidity. The results showed that the turbidity after treatment was more than about four times lower than before treatment, confirming the excellent performance of the device. Also, it is expected that the treatment efficiency will improve further as the treatment time and number of cycles increase.

The engineered barrier system (EBS) is an indispensable element of a deep geological repository (DGR) designed to prevent the discharge of radioactive materials into the environment. The buffer material is a vital component of the EBS by creating a physical and chemical barrier that prevents the migration of radioactive materials. In the disposal environment, gases can be generated from the corrosion of the canister. When the gas generation rate exceeds the diffusion rate, the buffer material’s performance can deteriorate by the physical damage induced by the increase in pore pressure. Therefore, understanding the EBS’s behavior under gas generation conditions is crucial to guarantee the longterm safety and performance of the DGR. Lab-scale and field-scale experiments have been conducted to examine the stability of the buffer material concerning gas generation and movement by the previous researchers. To evaluate long-term stability for more than 100,000 years, it is essential to assess stability using a numerical model verified by these experiments. This study investigated the effect of interfacial characteristics on the numerical modeling accuracy of experimental simulation while verifying a numerical model through field-scale experimental results. The findings of this study are expected to furnish fundamental data for establishing numerical analysis guidelines for the longterm stability assessment of disposal systems.

Geologic disposal at deep depth is an acceptable way to dispose of high-level radioactive waste and isolate it from the biosphere. The geological repository system comprises an engineered barrier system (EBS) and the host rock. The system aims to delay radionuclide migration through groundwater flow, and also, the flow affects the saturation of the bentonite in the EBS. The thermal conductivity of bentonite is a function of saturation, so the temperature in the EBS is directly related to the flow system. High-temperature results in the two-phase flow, and the two-phase flow system also affects the flow system. Therefore, comprehending the influencing parameters on the flow system is critical to ensure the safety of the disposal system. Various studies have been performed to figure out the complex two-phase flow characteristics, and numerical simulation is considered an effective way to predict the coupled behavior. DECOVALEX (DEvelopment of COupled models and their VALidation against EXperiments) is one of the most famous international cooperating projects to develop numerical methods for thermo-hydro-mechanicalchemical interaction, and Task C in the DECOVALEX-2023 has the purpose of simulating the Fullscale Emplacement (FE) experiment at the Mont-Terri underground research laboratory. We used OGS-FLAC, a self-developed numerical simulator combining OpenGeoSys and FLAC3D, for the simulation and targeted to analyze the effecting parameters on the two-phase flow system. We focused on the parameters of bentonite, a key component of the disposal system, and analyzed the effect of compressibility and air entry pressure on the flow system. Compressibility is a parameter included in the storage term, defining the fluid storage capacity of the medium. While air entry pressure is a crucial value of the water retention curve, defining the relation between saturation and capillary pressure. From a series of sensitivity analyses, low compressibility resulted in faster flow due to low storage term, while low air entry pressure slowed flow inflow into the bentonite. Low air entry pressure means the air easily enters the medium; hence the flow rate becomes lower based on the relativity permeability definition. Based on the sensitivity analysis, we further investigate the effect of shotcrete around the tunnel and excavation damaged zone. Also, long-term analysis considering heat decay of the radioactive waste will be considered in future studies.

IAEA safety standards document and international programs (such as BIOMASS) related to the assessment of the biosphere around High Level Radioactive Waste (including Spent Nuclear Fuel) repositories require the assessment of the biosphere to use the assumption that the current natural environment and human society will be maintained, and at the same time, the evolution of the distant future changes also need to be taken into account. In Korea, which has not designated candidate disposal sites, it is necessary to investigate and predict the current state and future changes of the natural environment throughout Korea and apply it practically to Biosphere assessment (for BDCF derivation) for candidate disposal sites suitability assessment and Safety Case (for performance assessment) preparation for design, construction, operation, and post-closure management. To this end, the natural environment in the fields of Topography, Geology, Soil, Ecology, Weather and Climate, Animals and Plants, Hydrology, Ocean, Land-use, etc. and human society in the fields of Population Distribution, Spatial-Planning, Urban Form, Industrial-Structure, Lifestyle etc. are being investigated in the context of current status, past change records, and future change potential in the Korean Peninsula. This paper summarizes those investigations to date. This study referred Biomass-6 [IAEA] and National Atlas I (2019)/II (2020)/III (2021) [National Geographic Information Institute of the Korea Ministry of Land, Infrastructure and Transport].

There have been a variety of issues related to spent nuclear fuel in Korea recently. Most of the issues are related to intermediate storage and disposal of spent nuclear fuel. However, recently, various studies have been started in advanced nuclear countries such as the United States to reduce spent nuclear fuel, focusing on measures to reduce spent nuclear fuel. In this study, a simple preliminary assessment of the thermal part was performed for the consolidation storage method which separates fuel rods from spent nuclear fuel and stores them. The preliminary thermal evaluation was analyzed separately for storing the spent fuel in fuel assembly state and separating the fuel rods and storing them. The consolidation storage method in separating the fuel rods was advantageous in terms of thermal conductivity. However, detailed evaluation should be performed considering heat transfer by convection and vessel shape when storing multiple fuel bundles simultaneously.

Molten Salt Reactor (MSR) is one of Generation-IV nuclear reactors that uses molten salts as a fuel and coolant in liquid forms at high temperatures. The advantages of MSR, such as safety, economic feasibility, and scalability, are attributed from the fact that the molten salt fuel in a liquid state is chemically stable and has excellent thermo-physical properties. MSR combines the fuel and coolant by dissolving the actinides (U, Th, TRU, etc.) in the molten salt coolant, eliminating the possibility of a core meltdown accident due to loss of coolant (LOCA). Even if the molten salt fuel leaks, the radioactive fission products dissolved in the molten salt will solidify with the fuel salt at room temperature, preventing potential leakage to the outside. MSR was first demonstrated at ORNL starting with the Aircraft Reactor Experiment (ARE) in 1954 and was extended to the 7.4 MWth MSRE developed in 1964 and operated for 5 years. Recently, various start-ups, including TerraPower, Terrestrial Energy, Moltex Energy, and Seaborg, have been conducting research and development on various types of MSR, particularly focusing on its inherent safety and simplicity. While in the past, fluoride-based molten salt fuels were used for thermal neutron reactors, recently, a chlorine-based molten salt fuel with a relatively high solubility for actinides and advantageous for the transmutation of spent nuclear fuel and online reprocessing has been developing for fast neutron spectrum MSRs. This paper describes the development status of the process and equipment for producing highpurity UCl3, a fuel material for the chlorine-based molten salt fuel, and the development status of the gas fission product capturing technologies to remove the gaseous fission products generated during MSR operation. In addition, the results of the corrosion property evaluation of structural materials using a natural circulation molten salt loop will also be included.