The dynamic interaction of liquid droplets emerging from the gas diffusion layer surface is modeled to study the behavior of liquid water inside the gas channel of a polymer electrolyte membrane fuel cell with the volume of fluid (VOF) formulation. The surface contact angle of gas diffusion layer is varied as 45, 90, and 140 degrees. The air inlet velocity in the gas channel is varied as 5, 10, and 15 m/s. The water inlet velocity from micro pores is varied as 0.5, 1, and 2 m/s. As the contact angle increases, water coverage ratio increases. As the air inlet velocity and the water inlet velocity increase, water droplets move faster toward the channel exit as evidenced from the water front location plots. In summary, the hydrophobic wall contact angle and higher air/water inlet velocities provide better water removal characteristics.
A three dimensional numerical analysis was performed to study the effect of cathode inlet relative humidity on PEMFC performance characteristics. As cathode inlet relative humidity increases from 0 percent to 60 percent, the current density increases. Then, as cathode inlet relative humidity increases from 60 percent to 100 percent, the current density decreases. The two dimensional contour map analysis shows that the flooding phenomenon in cathode gas channel, gas diffusion layer, and catalyst layer leads to the decrease of current density.
A 2D axisymmetric numerical analysis was performed to study the characteristics of charge process inside solar thermal storage tank. The porosity and heat transfer coefficient of filler material as well as inlet velocity of heat transfer fluid are selected as simulation parameters. The porosity is varied as 0.2, 0.5, and 0.8 to account for the effect of filler granule geometry. Two levels of the heat transfer coefficient is adopted to assess the heat transfer between heat transfer fluid and filler material. The inlet velocity is varied as 0.00278, 0.0278, and 0.278m/s. As both of the porosity and the heat transfer coefficient increase, the discrepancy of the temperature distributions between the filler and heat transfer fluid decreases. As the inlet velocity increases, the penetration depth of the heat transfer fluid increases proportionally.
A 2D axisymmetric numerical analysis was performed to study the characteristics of charge process inside solar thermal storage tank. The interfacial area density and inertial resistance of filler material are selected as simulation parameters. The interfacial area density is varied as 800, 2000, and 4000 1/m. The inertial resistance is varied as 1, 3, and 5 1/m. When the interfacial area density increases from 800 to 4000 1/m, the discrepancy of the temperature distributions between the filler and heat transfer fluid decreases. As inertial resistance increases from 1 to 5, both of the temperature and fluid flow pattern changes considerably.
A three dimensional numerical analysis was performed to study the PEMFC performance characteristics. Operating pressure and operating temperature were selected as simulation parameters. Operating pressure was varied as 1, 2, 3, 4, and 5 atm. Operating temperature was varied as 323, 333, 343, 353, and 363 K. For a constant cell voltage condition, the maximum current density was obtained at operating pressure of 5 atm and operating temperature of 323 K. As operating pressure increases, current density increases because concentration of reactant gases increases. As operating temperature increases, current density decreases because concentration of reactant gases decreases due to high overpotential condition for the considered PEMFC.
In this paper, a three dimensional numerical analysis tool was applied to study the PEMFC performance characteristics. The porosity and electrical conductivity of GDL and CL as well as the relative humidity of anode and cathode channel gas were selected as simulation parameters. The porosity of GDL and CL was varied as 0.3, 0.5, and 0.7. The relative humidity of anode and cathode was varied as 0, 20, 40, 60, 80, and 100 percent. The electrical conductivity of GDL and CL was varied as 1, 5, 10, 50, 102, and 104 1/Ω·m. For a constant cell voltage condition, the maximum current density was obtained at GDL porosity of 0.7, anode relative humidity of 100 percent, cathode relative humidity of 60 percent, and electrical conductivity of 104 1/Ω·m for GDL and CL. As the porosity of GDL and CL increases, current density increases because reactant gases diffuse well. As the electrical conductivity of GDL and CL increases, current density increases due to increased electron transfer rate. As anode relative humidity increases, current density increases. Unlike anode, current density increases when cathode relative humidity increases from 0 percent to 60 percent. Then current density decreases when cathode relative humidity increases from 60 percent to 100 percent.
In this paper, a three dimensional numerical analysis tool was applied to study the PEMFC performance characteristics. The porosity and electrical conductivity of GDL and CL as well as the relative humidity of anode and cathode channel gas were selected as simulation parameters. As the porosity of GDL and CL increases, current density and temperature increase because reactant gases diffuse well. As the electrical conductivity of GDL and CL increases, current density and temperature increase due to increased electron transfer rate. As anode relative humidity increases, current density and temperature increase. Unlike anode, current density and temperature increase when cathode relative humidity increases from 0 percent to 60 percent. Then current density and temperature decrease when cathode relative humidity increases from 60 percent to 100 percent.
Recently, ultrafine grained (ufg, typically 100 > d > 500 nm) Ti-Fe eutectic materials have been highlighted due to their extraordinarily high strength and good abrasion resistance compared to conventional coarse grained (cg, d > 1μm) materials. However, these materials exhibit limited plastic strain and toughness during room temperature deformation due to highly localized shear strain. Several approaches have been extensively studied to overcome such drawbacks, such as the addition of minor elements (Sn, Nb, Co, etc.). In this paper, we have investigated the influence of the addition of Gd and Y contents (0.3-1.0 at.%) into the binary Ti-Fe eutectic alloy. Gd and Y are chosen due to their immiscibility with Ti. Microstructural investigation reveals that the Gd phase forms in the eutectic matrix and the Gd phase size increases with increasing Gd content. The improvement of the mechanical properties is possibly correlated to the precipitation hardening. On the other hand, in the case of Ti-Fe-Y alloys, with increasing Y contents, primary phases form and lamellar spacing increases compared to the case of the eutectic alloy. Investigation of the mechanical properties reveals that the plasticity of the Ti-Fe-Y alloys is gradually improved, without a reduction of strength. These results suggest that the enhancement of the mechanical properties is closely related to the formation of the primary phase.