The demand for secondary batteries is increasing rapidly with the popularization of electric vehicles and the expansion of wireless electronic devices. However, the most widely used lithium-ion batteries are subject to frequent fire incidents, limiting market growth. To avoid flammability, solid electrolyte-based systems are gaining attention for next-generation lithium-ion batteries. However, challenges such as limitations in ionic conductivity and high manufacturing costs require further research and development. In this study, we aim to identify a new nitrogen-based solid electrolyte material that has not yet been widely explored. We propose a methodology for selecting the final material through high-throughput screening (HTS), detailing the methods used for material selection and performance evaluation. In addition, we present ab initio molecular dynamics (AIMD) calculations and results for nitrogen-substituted materials with carbon and oxygen replacements, including Arrhenius plots, activation energy, and the predicted conductivity at 300K for the material with the highest Li-ion conductivity. While the performance does not yet surpass the ionic conductivity and activity of conventional solid-state electrolytes, our results provide a systematic framework for exploring and screening new solid electrolyte materials. This methodology can also be applied to the exploration of different battery materials and is expected to contribute significantly to the innovation of next-generation energy storage technologies.
This paper explores the potential application of carbon nanotubes (CNTs) in the construction industry, as CNTs can effectively serve as nano-fillers, bridging the voids and holes in cement structures. However, the limited dispersibility of CNTs in water necessitates the use of dispersing agents for achieving uniform dispersion. In this study, two kinds of cement superplasticizers, polycarboxylate ether (PCE) and sulfonated naphthalene formaldehyde (SNF) were employed as dispersing agents to improve the interfacial affinity between CNTs and cement, and to enhance the strength of the cement nanocomposites. Contact angle experiments revealed that the utilization of PCE and SNF effectively addressed the interface issues between CNTs and cement. As a result, the cement nanocomposite with a CNT to PCE ratio of 1:2 exhibited an approximately 6.6% increase in compressive strength (73.05 MPa), while the CNT:SNF 1:2 cement composite showed a 4.7% increase (71.72 MPa) compared to plain cement (68.52 MPa). In addition, the rate of crack generation in cement nanocomposites with CNTs and dispersing agents was found to be slower than that of plain cement. The resulting cement nanocomposites, characterized by enhanced strength and durability, can be utilized as safer materials in the construction industry.
본 연구는 소양강댐 하류에서 서식하는 생태계교란 생물 종인 브라운송어와 그 먹이원으로 이용되는 저서성 대형무척추동물에 대한 파악을 위해 2022년부터 2023년까지 총 8회에 걸쳐 소양강댐 하류(St.1~St.3)와 지류 (St.4)에 대해 브라운송어와 공서종, 브라운송어의 위 내용물, 저서성 대형무척추동물의 종조성 및 기능군 분석을 실시하였다. 저서성 대형무척추동물의 경우, 하루살이목에서 가장 많은 분류군이 확인되었으며(27.1%), 그 중 붙는 무리(CL)와 헤엄치는 무리(SW)가 높은 비율을 차지하는 것으로 확인되었다. 브라운송어 채집 결과, 전장은 26∼246mm까지 총 105개체가 채집되었으며, 전장-체중 관계의 매개변수 b값이 3을 초과하여 안정적인 성장이 이루어지는 것으로 확인되었다. 브라운송어의 위 내용물에 대한 먹이원 분석 결과, 빙어(0.2%, TL: 246mm)와 육상곤충(2.7%, TL: 154mm, 183∼185mm)을 섭식한 개체는 매우 적었으며 상대적으로 전장이 큰 개체에서 확인 되었다. 대부분 수서곤충(73.8%)과 물 속에서 서식하는 비곤충류(23.3%)를 섭식하는 것으로 나타났다. 브라운 송어의 전장에 따른 먹이 섭식 패턴을 파악하기 위해 위 내용물에서 확인된 종들과의 상관분석을 실시한 결과, 브라운송어의 먹이원 중 유수성 환경 선호 종들의 경우 전장과 양의 상관관계(p<0.05)를 나타낸 반면, 모래 기질 이하의 흐름이 적은 서식처를 선호하는 종들의 경우 전장과 음의 상관관계(p<0.05)를 나타냈다.
M. pruinosa has been found on 98 families and 345 species of plants, indicating a wide host range. Since its first report in a persimmon orchard in Gimhae in 2009, it had spread to 126 municipalities over 12,429 ha. Because of powerful dispersal ability, it’s difficult to control with insecticides. Therefore, it is necessary to reduce the population density through the release of M. pruinosa’s natural enemy, N. typhlocybae. N. typhlocybae females prey on or externally parasitize the nymphs of M. pruinosa. This natural enemy was introduced from Italy in 2017 through an international cooperative project between National Institute of Agricultural Sciences and University of Padova for controlling the sporadic pest, Metcalfa pruinosa. This study reported the results of mass rearing N. typhlocybae indoors and releasing them outdoors from 2020 to 2023 in 21 regions nationwide, showing an average parasitism rate of 27.3% and an average production of 7.9 cocoons per host, suggesting the possibility of their establishment in Korea.
The bentonite buffer material is a crucial component for disposing of high-level radioactive waste (HLW). Several additives have been proposed to enhance the performance of bentonite buffer materials. In this study, unconfined compression tests were conducted on bentonite mixtures as well as pure bentonite buffer material. Joomunjin and silica sands were added at a 30% ratio, and graphite was added at 3% along with bentonite. The unconfined compression strength (UCS) and elastic modulus of pure bentonite were found to be 20% to 50% higher than those of bentonite mixtures under similar dry density and water content conditions. This decrease in strength can be attributed to the reduced cross-sectional area available for bearing the applied load in the bentonitemixture. Furthermore, the 3% graphite-bentonite mixture exhibited a 10% to 30% higher UCS and elastic modulus compared to the 30% sand-bentonite mixtures. However, since the strength properties of additive-bentonite mixtures are lower than those of pure bentonite, it is essential to evaluate thermohydraulic-mechanical functional criteria when considering the use of bentonite mixtures as buffer materials.
2022년 10월부터 2023년 5월까지 친환경 딸기재배 농가에서 점박이응애는 칠레이리애응애와 사막이리응애, 진딧물은 콜레마니진디벌을 대상으로 하는 천적처리구와 유기농자재를 사용하는 관행방제구에서 천적의 해 충 밀도억제 효과를 조사하였다. 천적처리구에서 점박이응애 성충 밀도는 잎당 1.5마리 이하, 알은 4개 이하로 관리되었고, 사막이리응애는 잎당 최대 0.4마리까지 증가하여 점박이응애 밀도억제에 많은 영향을 미친것으로 보인다. 반면, 관행방제구에서 점박이응애 밀도는 천적 방사구에 비하여 오히려 많은 발생량을 보였지만, 3월 9일부터는 사막이리응애의 증가와 유기농자재의 효과로 점박이응애 밀도는 급격하게 감소하였다. 진딧물 천적 처리구에서 진딧물 밀도는 1월부터 발생하였으며 3월 상순에 잎당 0.3마리까지 증가하였으나 이후 감소하였고, 콜레마니진디벌은 진딧물 발생이 많지 않아 3.9마리/㎡(2회) 방사하는 데 그쳤다. 한편, 관행방제구 포장의 진딧 물은 유기농자재의 영향으로 거의 발생하지 않았다.
Mass production of high-quality carbon nanotubes (CNTs) remains a challenge, requiring the development of new wetimpregnated catalyst suitable for the catalytic chemical vapor deposition (CCVD) of CNTs in a fluidized bed reactor. For the successful development of a new catalyst, a highly robust system to synthesize CNTs must be established. Here, we systematically investigated the robustness of CNT synthesis by CCVD using a wet-impregnated catalyst. We statistically tested four factors that could potentially affect the robustness of CNT synthesis system, focusing on carbon yield and IG/ID. First, we tested the effect of vacuum baking before CNT growth. F test and CV equality test concluded that vacuum baking recipe did not significantly reduce the variability of the CNT synthesis. Second, we tested the batch-to-batch variation of catalysts. The results of t test and one-way analysis of variance indicate that there is significant difference in carbon yield and IG/ID among catalysts from different batches. Third, we confirmed that there is spatial non-uniformity of wet-impregnated catalysts within a batch when they are produced in large scale. Finally, we developed a multi-step heating recipe to mitigate the temperature overshooting during the CNT synthesis. The multi-step recipe increased the mean of carbon yield, but did not influence the variability of CNT synthesis. We believe that our research can contribute to the establishment of a robust CNT synthesis system and development of new wet-impregnated catalysts.
Removing CO2 gas to address the global climate crisis is one of the most urgent agendas. To improve the CO2 adsorption ability of activated carbon, nitrogen plasma surface treatment was conducted. The effect of nitrogen plasma treatment on the surface chemistry and pore geometry of activated carbon was extensively analyzed. The porosity and surface groups of the activated carbon varied with the plasma treatment time. By plasma treatment for a few minutes, the microporosity and surface functionality could be simultaneously controlled. The changed microporosity and nitrogen groups affected the CO2 adsorption capacity and CO2 adsorption selectivity over N2. This simultaneous surface etching and functionalization effect could be achieved with a short operating time and low energy consumption.
According to the Nuclear Safety and Security Commission (NSSC) Notice No. 2021-26 “Delivery Regulations for the Low- and Intermediate Level Radioactive Waste (LILW)”, the activity of 3H, 14C, 55Fe, 58Co, 60Co, 59Ni, 63Ni, 90Sr, 94Nb, 99Tc, 129I, 137Cs, 144Ce, and gross alpha must be identified. Currently, the scaling factor of the dry active waste (DAW) for LILW is applied as an indirect evaluation method in Korea. The analyses are used the destructive methods and 55Fe, 60Co, 59Ni, 63Ni, 90Sr, 94Nb, 99Tc, and 137Cs, which are classified as nonvolatile nuclides, are separated through sequential separation and then measured by gamma detector, liquid scintillation counter (LSC), alpha/beta total counter (Gas Proportional Counter, GPC), and ICP-MS. We will introduce how to apply the existing nuclide separation method and improve the measurement method to supplement it.