본 연구에서는 구미에 위치한 낙동강에서 발생한 안개를 분류하였고 안개 발생 전후의 기상특성을 분석하였다. 안개는 2013년부터 2015년까지 시정계를 이용하여 관측되었다. 안개는 총 74회 발생하였고 대부분 증기안개로 분류되 었다. 관측된 증기 안개는 내륙에서 발생한 안개보다 지속시간이 길게 나타났는데 이는 지형적 특징으로 인해 야간 증 발이 다른 지역보다 강하게 나타났기 때문이다. 안개 지속시간에 대한 하천 증발 효과를 분석하기 위해 Penman- Monteith (Penman법)와 Bulk aerodynamic (Bulk법) 방법을 사용하여 증발량을 추정하였다. 이 중 Bulk법은 실제 수면 에서 측정한 증발량과 유사하게 나타났다. 따라서 Bulk법이 실제 수면 증발량 추정에 적합한 방법임을 확인할 수 있었 다. Bulk법으로 추정한 증발량은 안개 비발생일 보다 안개 발생일에 06 LST와 07 LST에 더 높게 나타났다. 안개 발 생일에 하천의 증발은 대기에 증발잠열 에너지를 공급하고 안개 내부의 난류를 유지하는 에너지원으로 작용한다. 이와 같은 결과는 안개내부의 풍속, 기온, 그리고 난류운동에너지의 증가를 통해 확인하였다.

Ni wires with a diameter and length of 0.4 and 100 mm, respectively, and a purity of 99.9% are electrically exploded at 25 cycles per minute. The Ni nanopowders are successfully synthesized by a pulsed wire evaporation (PWE) method, in which Ar gas is used as the ambient gas. The characterization of the nanopowders is carried out using X-ray diffraction (XRD) and a high-resolution transmission electronmicroscope (HRTEM). The Ni nanopowders are classified for a multilayer ceramic condenser (MLCC) application using a type two Air-Centrifugal classifier (model: CNI, MP-250). The characterization of the classified Ni nanopowders are carried out using a scanning electron microscope (SEM) and particle size analysis (PSA) to observe the distribution and minimum classification point (minimum cutting point) of the nanopowders.

디젤엔진에서는 2차 분사 시스템은 다양한 배기 시스템에 적용이 가능하고, 엔진 제어와 관계없이 독립적으로 제어가 가능하기 때문에 환원제 희석 면에서도 후분사 또는 다른 농후한 환원제 분위기 형성 방법 등에 비해 장점이 많다. 2차 분사 시스템에서는 환원제의 공급 방법에 따라서 촉매의 효율은 달라질 수밖에 없다. 환원제는 일정압력 이상으로 유지 및 최적화가 필요하고, 인젝터의 위치 및 각도의 선정은 매우 중요한 인자이다. 본 논문에서는 2차 분사 조건을 변화시켜 환원제의 농도와 양을 변화시켰다. De-NOx 촉매 시스템에서 최대의 NOx 정화 효율에 적합한 환원제 분사 조건들의 선정이 필요하고, 분무 도달거리, 분무 평균 입경, 분무각, 분사량 등의 분무 특성과 환원제의 균일 분포를 잘 파악하여야 한다. 이와 같은 목적을 위하여 2차 분사에서 충돌판 형상에 의한 분무 및 거동 특성은 가시화 방법과 디지털 화상 처리 기법을 사용하여 분석하였으며, 충돌판 형상의 영향성과 각 형상에 대한 최적 각도 범위를 도출하였다.

PVDF Membrane has been used as material for the UF membrane through in-situ interfacial polymerization (IP) because of it’s outstanding properties such as high chemical resistance, thermal stability, and mechanical strength. In this study, surface morphology change of PVDF membrane was researched depending on evaporation time. 13% PVDF 6020 was used for casting and the evaporation time period was from 5s to 600s. The surface morphology of the membrane was investigated by scanning electron microscopy (SEM) and filtration was conducted in the cross flow method to evaluate the a performance of UF membrane. As a result, average pore size was increased with longer evaporation times which caused the decrease of rejection.

온실의 냉방부하 산정방법 개발을 위하여 열수지 방법에 기초한 냉방부하 산정식을 구성하고, 포그냉방 온실 에서 냉방부하를 실측하여 검증하였다. 포그냉방 온실의 냉각열량은 포그분사에 의한 증발수량에 물의 증발잠열을 곱하여 구할 수 있다. 여기서, 증발수량은 포그 분사량에 증발효율을 곱하면 구할 수 있으며, 즉 분무수량을 계측하고 포그시스템의 증발효율을 알면 온실의 냉방부하를 실측할 수 있다. 따라서 온실의 냉방부하 실측을 위하여 실험온실에서 포그시스템의 증발효율을 실험하고, 실험온실의 열환경 계측과 더불어 포그 분사량을 계측하여 냉방부하 산정방법을 검토하였다. 먼저 냉방부하 산정식의 환기전열량을 검토하기 위하여 냉방을 실시하지 않은 상태에서 환기량 실측 실험을 통해 비교한 결과 열수지식을 이용한 환기전열량 예측은 비교적 양호한 결과를 보이는 것으로 나타났다. 이류체 포그시스템의 증 발효율은 0.3~0.94의 범위를 보였으며 평균 0.67로 나타 났고, 환기율이 증가함에 따라 커지는 것으로 나타났다. 포그냉방을 실시하면서 온실의 환경을 계측하여 열수지 식으로 냉방부하를 계산하고, 분무량 실측치로부터 증발 냉각열량을 구하여 비교한 결과 냉방부하 계산치와 실측치는 대체로 유사한 경향을 보이는 것으로 나타났다. 냉방부하가 낮은 경우에는 실측치에 비하여 약간 크게 예측되었고, 냉방부하가 높은 경우에는 실측치보다 작게 예측되었다. 온실의 냉방시스템 설계 시에는 최대냉방부하를 이용하여 냉방설비의 용량을 결정하게 된다. 따라서 냉방부하가 큰 쪽에서 실측치보다 작게 예측되는 부분은 검토가 필요하지만 설비용량 산정시의 안전계수를 고려하면 본 연구에서 제시한 냉방부하 산정방법은 온실의 환경설계에 적용할 수 있는 것으로 판단된다.

ZnO micro/nanocrystals at large scale were synthesized through the thermal evaporation of Al-Zn mixtures under air atmosphere. The effect of synthetic temperature and time on the morphology of the micro/nanocrystals was examined. It was found that the temperature and time affected the morphology of the ZnO crystals. At temperatures below 900 oC, no crystals were synthesized. At a temperature of 1000 oC, ZnO crystals with a rod shape were synthesized. With an increase in temperature from 1000 oC to 1100 oC, the morphology of the crystals changed from rod shape to wire and granular shapes. As the time increased from 2 h to 3 h at 1000 oC, tetrapod-shaped ZnO crystals started to form. XRD patterns showed that the ZnO crystals had a hexagonal wurtzite structure. EDX analysis revealed that the ZnO crystals had high purity. It is believed that the ZnO nanowires were grown via a vapor-solid mechanism because no catalyst particles were observed at the tips of the micro/nanocrystals in the SEM images.

In this study, the synthesis of nickel nanoparticles and copper nanospheres for the potential applications of MLCC electrode materials has been studied by plasma arc evaporation method. The change in the broad distribution of the size of nickel and copper nanopowders is successfully controlled by manifesting proper mixture of gas ambiance for plasma generation in the size range of 20 to 200 nm in diameter. The factors affecting the mean diameter of the nanopowder was studied by changing the composition of reactive gases, indicating that nitrogen enhances the formation of larger particles compared to hydrogen gas. The morphologies and particle sizes of the metal nanoparticles were observed by SEM, and ultrathin oxide layers on the powder surface generated during passivation step have been confirmed using TEM. The metallic FCC structure of the nanoparticles was confirmed using powder X-ray diffraction method.

This study investigated the effect of solvent on the fabrication of Ni-free Fe-based alloy nano powders by employing the PWE (pulsed wire evaporation) in liquid and compared the alloy particles fabricated by three different methods (PWE in liquid, PWE in Ar, plasma arc discharge), for high temperature oxidation-resistant metallic porous body for high temperature soot filter system. Three different solvents (ethanol, acetone, distilled water) of liquid were adapted in PWE in liquid process, while X-ray diffraction (XRD), field emission scanning microscope (FE-SEM), and transmission electron microscope (TEM) were used to investigate the characteristics of the Fe-Cr-Al nano powders. The alloy powder synthesized by PWE in ethanol has good particle size and no surface oxidation compared to that of distilled water. Since the Fe-based alloy powders, which were fabricated by PWE in Ar and PAD process, showed surface oxidation by TEM analysis, the PWE in ethanol is the best way to fabricate Fe-based alloy nano powder.

This study investigated the effect of wire diameter and applied voltage on the fabrication of Ni-free Fe-based alloy nano powders by employing the PWE (pulsed wire evaporation) in liquid, for high temperature oxidation-resistant metallic porous body for high temperature particulate matter (or soot) filter system. Three different diameter (0.1, 0.2, and 0.3 mm) of alloy wire and various applied voltages from 0.5 to 3.0 kV were main variables in PWE process, while X-ray diffraction (XRD), field emission scanning microscope (FE-SEM), and transmission electron microscope (TEM) were used to investigate the characteristics of the Fe-Cr-Al nano powders. It was controlled the number of explosion events, since evaporated and condensed nano-particles were coalesced to micron-sized secondary particles, when exceeded to the specific number of explosion events, which were not suitable for metallic porous body preparation. As the diameter of alloy wire increased, the voltage for electrical explosion increased and the size of primary particle decreased.

Multi-source evaporation is one of the methods to improve the thickness uniformity of thin films deposited by evaporation. In this study, a simulator for the relative thickness profile of a thin film deposited by a multi-source evaporation system was developed. Using this simulator, the relative thickness profiles of the evaporated thin films were simulated under various conditions, such as the number and arrangements of sources and source-to-substrate distance. The optimum conditions, in which the thickness uniformity is minimized, and the corresponding efficiency, were obtained. The substrate was a 5th generation substrate (dimensions of 1300 mm × 1100 mm). The number of sources and source-to-substrate distance were varied from 1 to 6 and 0 to the length of the major axis of the substrate (1300 mm), respectively. When the source plane, the area on which sources can be located, is limited to the substrate dimension, the minimum thickness uniformity, obtained when the number of sources is 6, was 3.3%; the corresponding efficiency was 16.6%. When the dimension of the source plane is enlarged two times, the thickness uniformity is remarkably improved while the efficiency is decreased. The minimum thickness uniformity, obtained when the number of sources is 6, was 0.5%; the corresponding efficiency was decreased to 9.1%. The expansion of the source plane brings about not only the improvement of the thickness uniformity, but also a decrement of the efficiency and an enlargement of equipment.

Soybean lecithin liposomes composed phosphatidyl choline, phosphatidyl ethanolamine, phosphatidyl inositol and phosphatidic acid were prepared by using the previously developed supercritical reverse phase evaporation method. The effect of phospholipid composition on the formation of liposomes and physicochemical properties were examined by means of trapping efficiency measurements, transmission electron microscopy, dynamic light scattering and zeta potential measurements. The trapping efficiency of liposomes for D-(+)-glucose made of CNA-Ⅰ which contains approximately 95% phosphatidyl choline is higher than that of CNA-II and CNA-O which contain approximately 32% phosphatidyl choline. However there is no any difference between the trapping efficiency of liposomes for D-(+)-glucose made of CNA-II which has saturated hydrocarbons tails and that of liposomes made of CNA-O which has unsaturated hydrocarbon chains. The electron micrographs of liposomes made of CNA-II and CNA-O show small spherical liposomes with diameter of 0.1~0.25μm, while that of CNA-I shows large unilamellar liposomes with diameter of 0.2~1.2μm. These results clearly show that phospholipid structure of phosphatidylcholine allows an efficient preparation of large unilamellar liposomes and a high trapping efficiency for water soluble substances. Liposomes made of CNA-II and CNA-O remained well-dispersed for at least 14 days, while liposome suspension made of CNA-I separated in two phase at 14 days due to aggregation and fusion of liposomes. The dispersibility of liposomes made of CNA-I is lower than that of CNA-II and CNA-O due to the smallar zeta potential of CNA-I.

Ethylene glycol-based Cu nanofluids were prepared by pulsed wire evaporation (PWE) method. The structural properties of Cu nanoparticles were studied by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The average diameter and Brunauer Emmett Teller (BET) surface area of Cu nanoparticles were about 100 nm and , respectively. The thermal conductivity and viscosity of copper nanofluid were measured as functions of Cu concentration and temperature. As the volume fraction of Cu nanoparticles increased, both the enhanced ratios of thermal conductivity and viscosity of Cu nanofluids increased. As the temperature increased, the enhanced ratio of thermal conductivity increased, but that ratio of viscosity decreased.

Boron doped fullerene C60 (B:C60) films were prepared by the thermal evaporation of C60 powder using argon plasma treatment. The morphology and structural characteristics of the thin films were investigated by scanning electron microscope (SEM), Fourier transform infra-red spectroscopy (FTIR) and x-ray photo electron spectroscopy (XPS). The electrochemical application of the boron doped fullerene film as a coating layer for silicon anodes in lithium ion batteries was also investigated. Cyclic voltammetry (CV) measurements were applied to the B:C60 coated silicon electrodes at a scan rate of 0.05 mVs-1. The CV results show that the B:C60 coating layer act as a passivation layer with respect to the insertion and extraction of lithium ions into the silicon film electrode.

보수성 포장재가 지표면 열수지와 중규모 순환장에 미치는 영향을 파악하기 위하여 수치실험과 야외 관측을 실시하였다. 수치실험에 이용된 모형은 LCM(Local Circulation Model)이며, 야외 관측은 대기가 안정되어 날씨가 맑은 2007년 7월 19일 실시되었다. 야외 관측실험에서 보수성 포장재 지표면 온도의 최대치는 1430 LST에서 41.2˚C이고, 보수성 재료가 도포되어 있지 않은 일반 아스팔트보다 16.1˚C 낮게 관측되었다. 수치실험에서는 증발효율 0.3을 가정한 case BET03에서 관측과 가장 유사한 값을 나타내었다. 이때 현열과 잠열플럭스는 각각 227 와 229 W/m2이다. 수치실험 결과, 보수성 포장재는 낮은 지표면 온도, 혼합고와 관련된 잠열플럭스를 높이는 경향이 나타난다. 보수성 포장재에 의한 잠열플럭스의 불연속은 교외풍과 같은 중규모 순환장의 발달을 강화시키는 역할을 한다.

The silver nanofluids were synthesized by the pulsed wire evaporation (PWE) method in a liquid-gas mixture. The size and microstructure of nanoparticles in the deionized water were investigated by a particle size analyzer (PSA), transmission electron microscope (TEM), and scanning electron microscope (SEM). Also, the synthesized nanofluids were investigated in order to assess the stability of dispersion of nanofluid by the zetapotential analyzer and dispersion stability analyzer. The results showed that the spherical silver nanoparticle formed in the deionized water and mean particle size was about 50 nm. Also, when explosion times were in the range of 20~200 times, the absolute value of zeta potential was less than -27 mV and the dispersion stability characteristic of low concentration silver nanofluid was better than the high concentration silver nanofluid by turbiscan.

Carbon-coated Cu nanopowders with core/shell structure have been successfully fabricated by pulsed wire evaporation (PWE) method, in which a mixed gas of Ar/ (10 vol.%) was used as an ambient gas. The characterization of the samples was carried out using x-ray diffraction (XRD), scanning electron microscope (SEM), and high resolution transmission electron microscope (HRTEM). It was found that the nanoparticles show a spherical morphology with the size ranging of 10-40 nm and are covered with graphite layers of 2-4 nm. When oxygen-passivated Cu nanopowders were annealed under flowing argon gas (600 and 800), the crystallinity of phase and the particle size gradually increased. On the other hand, carbon-coated Cu nanopowders remained similar to as-prepared case with no additional oxide or carbide phases even after the annealing, indicating that the metal nanoparticles are well protected by the carbon-coating layers.

Ba(Ti,Sn)O3 thin films, for use as dielectrics for MLCCs, were grown from Sn doped BaTiO3 sourcesby e-beam evaporation. The crystalline phase, microstructure, dielectric and electrical properties of films wereinvestigated as a function of the (Ti＋Sn)/Ba ratio. When BaTiO3 sources doped with 20~50mol% of Sn wereevaporated, BaSnO3films were grown due to the higher vapor pressure of Ba and Sn than of Ti. However, itwas possible to grow the Ba(Ti,Sn)O3 thin films with ≤15mol% of Sn by co-evaporation of BTS and Ti metalsources. The (Ti＋Sn)/Ba and Sn/Ti ratio affected the microstructure and surface roughness of films and thedielectric constant increased with increasing Sn content. The dielectric constant and dissipation factor ofBa(Ti,Sn)O3 thin films with ≤15mol% of Sn showed the range of 120 to 160 and 2.5~5.5% at 1KHz,respectively. The leakage current density of films was order of the 10−9~10−8A/cm2 at 300KV/cm. The researchresults showed that it was feasible to grow the Ba(Ti,Sn)O3 thin films as dielectrics for MLCCs by an e-beamevaporation technique.

The production of tin oxide (SnO2) microrods on iridium (Ir)-coated substrates was achieved through the thermal evaporation of Sn powders in which a sufficiently high O2 partial pressure was employed. Scanning electron microscopy revealed that the product consisted of microrods with diameters that ranged from 0.9 to 40 μm. X-ray diffraction, high-resolution transmission electron microscopy, and selected area electron diffraction indicated that the microrods were SnO2 with a rutile structure. As the microrod tips were free of metal particles, it was determined that the growth of SnO2 microrods via the present route was dominated by a vapor-solid mechanism. The thickening of rod-like structures was related to the utilization of sufficiently high O2 partial pressure during the synthesis process, whereas low O2 partial pressure facilitated the production of thin rods.