지금껏 안정적으로 폐기물을 처분해왔던 방법에 변화를 가져올 정책과 국제협정이 최근 제정 및 체결되었다. 첫 번째는 2016년 5월 29일 자원순환기본법이 제정･공포되어 2018년 1월 1일부터 시행될 예정으로 자원순환사회 기반을 구축하기 위한 제도적 기틀을 마련한 것이다. 지금까지 자원의 절약과 재활용촉진에 관한 법률에 의해 추진해오던 것에 비하면 자원순환에 관해서는 다른 법률에 우선하기에 폐기물 처분방법에 있어 변화가 있을 것으로 본다. 두 번째는 2015년 12월 프랑스 파리에서 열린 2020년 이후의 신기후체제가 논의되어 모든 국가가 온실가스 감축에 참여하는 파리협정을 체결하였다. 이로 인해 폐기물부문도 온실가스 감축을 위한 방안과 실행계획 마련이 있을 것으로 본다. 이 같은 정책과 국제협정이 지금껏 안정적으로 처분해왔던 폐기물관리에 일정부분 변화를 가져올 수밖에 없는 상황이다. 감량 목적의 단순 소각처분이 아닌 자원이 순환하고 온실가스 감축을 위해 에너지를 최대한 회수하기 위한 방안 마련이 필요한 것이다. 우리나라는 선진화된 폐기물정책 시행으로 인해 폐기물 감량이나 재활용에 있어서는 선도적 역할을 담당해오고 있으나 소각에너지 회수에 있어서는 미흡한 면이 있다. 이에 본 연구에서는 우리나라의 시도별 도시폐기물의 발생 및 처분 그리고 소각시설에 대한 현황을 2000년 이후 2014년까지 5년 주기의 변화 추이를 살펴봄으로써 앞으로 자원순환 정책과 기후변화 협약에 대응할 수 있는 방향성을 제언하고자 한다.

최근 급속한 경제 성장과 소비 수준의 상승으로 폐기물 배출량이 급격히 증가했고, 질적으로도 다양화 되고 있다. 우리나라 폐기물 처리정책의 주요내용은 자원을 효율적으로 이용함으로써 자연으로부터의 자원채취를 최소화함과 동시에 자연으로 되돌려지는 폐기물을 최소화함으로써 자연환경을 보호하고 사람의 건강을 보존하는 것이다. 선․후진국을 막론하고 폐기물관리정책의 변화과정은 비슷하다. 이러한 폐기물의 적정처리와 국가 에너지자원의 활용측면에 있어서 매우 중요한 역할을 담당하고 있는 소각시설은 현재 정부가 추진 중에 있는 ｢자원순환사회전환촉진법｣ 제정에 따라 적지 않은 변화가 있을 것으로 판단된다. ｢자원순환사회전환촉진법｣은 자원 및 에너지 소비량의 증가에 따라 계속적으로 폐기물 발생량이 증가하고 있는 국내의 사회적 구조를 고려할 때 폐기물의 발생억제 및 순환이용 촉진 등 자원순환사회 실현을 위한 기반 마련을 위하여 반드시 필요한 제도임에 틀림없다. 자원순환 성과관리제를 통하여 검토되고 있는 폐기물처분부담금(소각 또는 매립)은 에너지를 회수하지 않는 단순 소각시설의 경우 재활용비용에 버금가는 소각세를 부과한다. 그러나 일정기준 이상 에너지를 회수하여 사용하는 소각시설은 폐기물처분부담금의 감면혜택이 부여됨으로써 폐기물로부터 에너지를 회수하는 에너지회수시설과 단순 소각시설의 차별화가 뚜렷이 구분될 것으로 판단된다. 이에 본 연구에서는 생활폐기물 소각처리 시설(2개소, 3호기)을 대상으로 2015년 ｢폐기물관리법｣ 시행규칙 제3조제2항에 따른 “폐자원에너지 회수･사용률 산정방법”에 따라 에너지회수율을 산정하였다. 각각의 저위발열량 및 에너지회수･사용률 산정인자(Ep, Ew, Ei, Ef)는 3개월 동안의 계측기 측정값과 현장측정(배출가스 조성, 방열손실, 바닥재 보유열 등)결과를 바탕으로 산출하였다. 폐자원에너지 회수･사용률 산정결과로는 A시설(1호기･2호기)의 경우 생산량 기준 98.6 %, 사용량 기준 26.9 %로 산정되었다. B시설(1호기)에서는 생산량 기준 99.0 %, 사용량 기준 81.9 %로서 생산량 및 사용량 모두 높은 비율을 나타났다. 반면, A시설에서는 생산량 대비 사용량 기준 27.3 %로서 낮은 유효사용률을 나타내었으며, 유효사용률을 높이기 위해서는 다양한 방안(소내 소비감소, 소각시설의 효율적 가동, 폐열보일러의 효율 향상, 안정적인 수요처 확보 등)을 강구할 필요가 있을 것으로 판단된다.

In recent years, waste-to-energy conversion using municipal solid waste (MSW) has been gaining attention in municipalities. Such conversion can reduce the dependency of non-renewable energy such as fossil fuels by generating solid refuse fuel (SRF) and diverting landfilling of the waste, although there is debate over the efficiency and economic aspect of the practice. With a growing interest in the conversion, D city is trying to adopt all possible measures towards achieving a material-cycle society by constructing a waste-to-energy town by 2018. The waste-to-energy town will be comprised of energy recovery facilities such as a mechanical treatment facility for fluff-type SRF with a power generation plant, and anaerobic digestion of food waste for biogas recovery. In this paper, we focus on estimating the energy recovery potentials and greenhouse gas (GHG) reduction of MSW by waste-to-energy conversion under three different scenarios. The data required for this study were obtained from available national statistics and reports, a literature review, and interviews with local authorities and industry experts. The lower heating value was calculated using the modified Dulong equation. Based on the results of this study, the energy recovery potential of MSW was calculated to be approximately 14,201-51,122 TOE/y, 12,426-44,732 TOE/y, and 8,520-30,673 TOE/y for Scenarios 1, 2, and 3, respectively. The reduction of GHG by such conversion was estimated to range from 10,074-36,938 tonCO2eq/y, depending on scenario. This study would help determine the production rate of fluff-type SRF to be converted into a form of energy. In addition, this study would aid waste management decision-makers to clarify the effectiveness of recycling of MSW and their corresponding energy recovery potentials, as well as to understand GHG reduction by the conversion.

Municipal solid waste incinerator (MSWI) fly ash was used for accelerated carbonation via bubbling of gaseous carbon dioxide (CO2) after treatment with sodium hydroxide (NaOH). The influence of alkaline concentration and volumetric flowrate of CO2 was investigated. Experimental results showed that carbonation reduced the leaching of Cu, Pb, Zn, and Cr. The pH of leachate decreased from around 12 to 10.5. The content of soluble chlorides was also decreased after carbonation. Additionally, the application of accelerated carbonation enhanced the sequestration of CO2 from MSW incineration plants. The TG/DSC analysis indicated that MSWI fly ash sequestrated approximately 185 g CO2/kg waste.

The purpose of this study was to analyze the physicochemical characteristics of bottom-ash recycling from municipal solid waste incineration (MSWI) and investigate the possibility of the use of bottom ash for Lightweight Aggregate for Structural Concrete and Bottom Ash Aggregate for Road Construction according to Korean Industrial Standards (KS). Samples were taken from the MSWI bottom ash collected at the resource recovery facilities “A” and “B.” In the results, both samples did not satisfy the criteria of the particle sizes. In particular, the two samples failed to comply with the physical and chemical characteristics criteria of the Lightweight Aggregate for Structural Concrete. On the other hand, both bottom ash samples met the physical characteristics criteria of the Bottom Ash for Road Construction. Therefore, the recycling of Bottom Ash Aggregate for Road Construction can be more a suitable method for recycling, provided that proper pre-treatment as a screening process for bottom ash is performed.

Due to the problems on BW (Bulky Waste) from SRF (Solid Refused Fuel) facilities in terms of operation andmaintenance, we investigated the characteristics of bulky waste about physical composition ratio, discharge type and ratio,etc. BW are 5.83% in MSW (Municipal Solid Waste) and composition ratio is as below; fiber (28.22%), plastic (19.18%),paper (17.95%), wood (17.02%), metal (11.49%), vinyl (3.3%), styrofoam (2.84%). Paper was mostly packing box, wood;chipboard, pieces of wood, branch, vinyl; big vinyl bag, plastic; home appliance, toy, big piece of plastic, fiber; clothing,mattress, sponge, styrofoam; pieces of styrofoam box, metal; broken metal stuff. BW has characteristics that is bulky andmainly consist of recycle waste compared with general MSW. We compare the composition ratios of only BW, MSWincluding BW and not including BW in order to extend to which variation in BW affects on physical composition ratioof general MSW. As a result of these researches, physical composition ratio between MSW not including BW and BWhas some difference but correspond closely with MSW including BW. This is because BW component ratio is so smallthat have little effect on composition ratio of total waste. Conclusively BW component and physical composition ratio,discharging type should be investigated for characterizing BW. But BW composition ratio needs not to be included onlyfor analyzing physical composition ratio of waste.

Municipal Solid Wastes (MSW) are disposed of three types (recycling, incineration, landfill). The ashes made after the incineration are also recycled to minimize the volume of waste owing to reducing the amount of landfill. However, MSW incinerations (MSWI) in Seoul are not satisfied with the policy of Korea as a result of experiments about the chemical characteristics of the ash (Ignition loss, pH, Chloride, Cyanide, metals leaching). So, according to the policy, the MSWI in Seoul must be pretreated so as to recycle the MSWI. There are many pretreatments, three pretreatments (washing, weathering, CO2 aging) of which are selected through the literature review. Through Washing, the value of pH and chloride decrease. The optimal ratio (S/L) and time of Washing treatment is 1 : 10 (S/L) and 60 minutes, respectively. The CO2 aging method compensates the defect of weathering method which is required to react long-period time. After CO2 aging, pH and some Heavy metals decrease. So, We will compare and evaluate pre-treatment methods and we find the best method or new method.

Incineration allows for the recovery of energy from combustible waste. It would be highly beneficial to society if this heat could be used efficiently. However, due to the difficulties involved with storing and transporting heat energy, consumers would need to live near incineration facilities in order to make efficient use of this heat energy. Moreover, it is usually difficult to achieve a balance between heat demand and supply. For instance, although there is a significant demand for heat in Northern Europe, the demand for electricity in that region is larger than the demand for heat in Central/Southern Europe. Hence, the preferred form of energy recovery differs depending on the nation or regional conditions. However, there are no limitations with regard to electricity because it can be used in a variety of ways. As a result, leading countries such as those in the European Union and the United States have been developing technologies and building facilities to recover electricity. In Korea, stable operation (steam condition 200-300℃, 20-25bar) was given priority over energy recovery because the country’s background with regard to the measure for dioxin is different from that of Europe or the United States. In addition, the produced energy has been mostly self-consumed rather than sold. While Korea is implementing incineration energy recovery, the country’s incineration power generation is considerably lower than that of leading nations. According to the 6thbasic plan for power supply(2013–2027), which was announced in 2013, the government of Korea is planning to secure a power generation capacity of 688 MW (as of 2012, a level of 74 MW was attained) from waste. Accordingly, this paper examined trends and efficiency improvements for incineration power generation in leading countries.

The components of municipal solid waste incineration bottom ash produced over 3 million ton every year are similarto the components of geological features, therefore it is suitable to be used as the raw materials of lightweight aggregate.Development of lightweight aggregate using this bottom ash will be helpful to solve landfill and environmental problems.Lightweight aggregate was developed at 1,110oC by using clay, kaolin, bentonite and silica as the raw material to 50%of municipal solid waste incineration bottom ash. Silicon carbide (SiC) was used as a blowing agent. Optimal mixingratio is bottom ash 50%, kaolin 22%, clay 22%, bentonite 6% and blowing agent 0.1%. As the result of quality test,produced lightweight aggregate met the all appraisal standards. The result of heavy metal leaching test was much lowerthan the elution reference value of ceramic manufactures made by using bottom ash.

This research performed physico-chemical analysis of MSW(municipal solid waste) for design and operation ofgasification generation system. The MSW sample was analyzed by proximate, ultimate, heat value method and sampledeach residential type classified apartment, house, urban and rural in by seasonal generation According to statistics of 2010MSW generation in Korea, On average, Namwon generated about 101.4 ton of trash and recycled almost 57.5 ton ofthis material per day, equivalent to a 56.7 percent recycling rate. It was recycled 0.73 kilograms out of individual wastegeneration of 1.29 kilograms per person per day. In 2011, On average, Namwon generated about 46.7 ton without recycledmaterial per day, and individual generation was 0.60 kilograms. It was virtually identical with statistics data in 2010. Inthe physico-chemical analysis results, it was composed of 84.1 percent of combustible and 15.9 percent of Non-combustible. On average, heat value was 2,529kcal per kilogram in condition of LHV and wet. The MSW sample wasincluded 32.0 percent of moisture, 21.9 percent of ash, 26.8 percent of carbon, 14.4 percent of oxygen, 3.7 percent ofhydrogen and 1.3 percent of others. Estimate of technical potential energy of MSW was 1,278 toe per year, equivalentto a 33.3 percent of total potential energy.

This study describes the design and corrosion-resistant materials for a high-efficiency waste-to-energy (WtE) plant. WtEtechnology is one of the most robust and effective alternative energy options to reduce CO2 emissions and to conservelimited fossil fuel resources, which are used by traditional power plants. The recently published 3rd edition of the CEWEP(confederation of european waste-to-energy plants) energy efficiency report demonstrated the energy efficiency criterion(R1 formula) that was introduced in the waste framework directive and has proven to be an incentive for WtE plants inEurope to improve their energy efficiency. The design combines the optimal use of the corrosion resistant properties ofinconel with an efficient boiler design (Amsterdam) and turbine layout. It uses a steam-steam reheater to realize thisefficiency as well as high availability and low maintenance. The high-efficiency WtE plant is an economical choice thatmakes a very positive contribution to sustainable electricity production.

Recycling the bottom ash from MSWI (Municipal solid waste incinerators) ash is required to reduce the secondary pollution. We characterized the bottom ash and investigated the possibility of application for subsidiary ceramic raw materials. Major components of bottom ash are analyzed as CaO, Al2O3, SiO2, P2O5, MgO, Fe2O3, which are the same components of the earth’s crust. This similarity of components implied that bottom ash could be recycled as ceramic products through systematic treatment. Considering the plasticity and water absorption results, the ceramics, which are the mixture with 74 wt % bottom ash and 26 wt% Pink Kaolin, showed 1.39% water absorption after sintering 1150oC for 1h. This result indicated the possibility of recycling of bottom ash for subsidiary ceramic raw materials.

With total four lysimeters, having a decreased reaction rate of municipal solid waste (MSW) through the 1st study, the effects of foodwaste leachate (FWL) injection on the degradation of MSW and FWL were estimated for 533days. Average methane potential of FWL injected in lysimeters investigated through the Biochemical Methane Potential (BMP)test was 368.2 mL-CH4/g-VS. The amounts of methane generated in lysimeters injected simultaneously with FWL and leachate were higher than that of FWL injected each lysimeter. The pH levels of leachate generated in each lysimeter maintained a range of 7.2 ~ 8.1. CODCr concentrations were 1,640 ~ 2,275 mg/L initially, and were rising to 4,640 ~ 5,950 mg/L as increasing FWL injection amount. Whereafter those repeated fluctuation in a range of 2,400 ~ 5,600 mg/ L as methane productions in each lysimeter increase. BOD5/CODCr ratios were kept below 0.1 during the test period. Settlement analysis results of MSW in each lysimeter indicated that the simultaneous injections with FWL and leachate in each lysimeter promoted the degradation of not only FWL itself, but MSW. This became clear when the methane balance in lysimeter under rich-organic condition is established.

Results for application of RDF(Refuse Derived Fuel) to selected wastes in metropolitan and small and medium cities are as follows. The physical characteristics of waste are paper, plastic, food waste, and so on. The proximate analysis in P city showed 20.2% of moisture, 71% of combustible material, and 8.8% of ash on annual average. That in G city showed 31.6% of moisture, 59.5% of combustible material, and 8.9% of ash. Ultimate analysis in P city showed 52.04% of carbon, 7.02% of hydrogen, 28.80% of oxygen, 0.66% of nitrogen, and 0.09% of sulfur. Heating value was 3,363 kcal/kg. Ultimate analysis in G city showed 50.85% of carbon, 6.56% of hydrogen, 29.86% of oxygen, 0.79% of nitrogen, and 0.12% of sulfur. Heating value in the G city was somewhat lower than that in the P city with 2,632 kcal/kg. Thus, application of RDF in metropolitan city was more effective than that in small and medium cities. Heating value in mixture for the P city was lower than that in waste of the volume rate waste charge system alone by 143 kcal/kg. In proximate analysis, moisture, and combustible material were likely to be more adequate to RDF.