The adsorption performance of cupper and zinc ions(Cu2+ and Zn2+) in aqueous solution was investigated by an adsorption process on reagent grade Na-A zeolite(Z-WK) and Na-A zeolite (Z-C1) prepared from coal fly ash. Z-C1 was synthesized by a fusion method with coal fly ash from a thermal power plant. Batch adsorption experiment with Z-C1 was employed to study the kinetics and equilibrium parameters such as initial metal ions concentration and adsorption time of the solution on the adsorption process. Adsorption rate of metal ions occurred rapidly and adsorption equilibrium reached at less than 120 minutes. The kinetics data of Cu2+ and Zn2+ ions were well fitted by a pseudo-second-order kinetics model more than a pseudo-first-order kinetics model. The equilibrium data were well fitted by a Langmuir model and this result showed Cu2+ and Zn2+ adsorption on Z-C1 would be occupied by a monolayer adsorption. The maximum adsorption capacity(qmax) by the Langmuir model was determined as Cu2+ 99.8 mg/g and Zn2+ 108.3 mg/g, respectively. It appeared that the synthetic zeolite, Z-C1, has potential application as absorbents in metal ion recovery and mining wastewater.

Dynamic simulator can be a helpful tool for understanding underwater robotic system's dynamics. However, due to difficulties in modeling dynamics of vehicle/manipulator and interaction between them, dynamic simulation is not easy. This is true even when fluid dynamics are not considered during the simulation. In this paper, two schemes are introduced for dynamic simulation of underwater robotic systems. One is principle of dynamical balance, which is an easy and powerful tool for formulating dynamic equations of composite systems such as underwater vehicle- manipulator system. In the dynamic modeling, this principle gives us the closed-form of dynamic equations on matrix Lie group. The other is geometric integration algorithm, called 4-th order explicit Munthe-Kaas method. By this method, the derived differential equations can be integrated preserving geometric structure. Adopting these two schemes, dynamic simulation of underwater vehicle- manipulator system can be conducted more easily and more reliably.

본 연구에서는 점진적인 유량 및 압력이 변화하는 상수관망에서 Rigid Water Column Theory를 이용하여 정상모형의 확장기간 모의해석보다 정확하고 수충격 해석보다는 계산비용 및 노력 측면에서 효율적으로 장시간 부정류 해석 모형을 개발하였다. 개발된 모형을 이용하여 실제관망에 대하여 24 시간 열 수요량을 고려한 부정류 해석 및 밸브폐쇄로 인한 수충격해석 모의에 적용하였고 해석 결과는 다음과 같다. 24 시간 일변화 모의의 경우에 수요량이 증

The objectives of this study were to investigate the desulfurization kinetics of paper sludge and limestone in a fluidized bed reactor according to bed temperature and air velocity. The experimental results were presented as follows ; First, the bed temperature had a great influence on the desulfurization efficiency of limestone and paper sludge. In paper sludge, the optimum condition in desulfurization temperature was at 800℃ and in limestone, that was at 850℃ or 900℃. Second, as air velocity increased, the desulfurization efficiency(or the absorbed amount of sulfur dioxide) by limestone and paper sludge decreased. And the absorbed amount of sulfur dioxide by paper sludge was larger than that of by limestone. Third, as the velocity increased and the optimum desulfurization temperature became, ks and the removal efficiency increased. So, ks, kd highly depended on the air velocity and bed temperature.