In this study, an aerosol process was introduced to produce CaCO3. The possibility of producing CaCO3 by the aerosol process was evaluated. The characteristics of CaCO3 prepared by the aerosol process were also evaluated. In the CaCO3 prepared in this study, as the heat treatment proceeded, the calcite phase disappeared. The portlandite phase and the lime phase were formed by the heat treatment. Even if the CO2 component is removed from the calcite phase, there is a possibility that the converted CO2 component could be adsorbed into the Ca component to form a calcite phase again. Therefore, in order to remove the calcite phase, carbon components should be removed first. The lime phase was formed when CO2 was removed from the calcite phase, while the portlandite phase was formed by the introducing of H2O to the lime phase. Therefore, the order in which each phase formed could be in the order of calcite, lime, and portlandite. The reason for the simultaneous presence of the portlandite phase and the lime phase is that the hydroxyl group (OH−) introduced by H2O was not removed completely due to low temperature and/or insufficient heating time. When the sufficient temperature (900°C) and heating time (60 min) were applied, the hydroxyl group (OH−) was removed to transform into lime phase. Since the precursor contained the hydrogen component, it could be possible that the moisture (H2O) and/or the hydroxyl group (OH−) were introduced during the heat treatment process.
In this study, an enthalpy exchanger was coated by silver nano particles via spark discharge method and its antimicrobial and heat exchange efficiencies were evaluated. A method utilizing thermophoretic force was used to improve coating efficiency. Four spark discharge systems were parallel connected and generated silver nano aerosol particles (number concentration of 1.65×108 particles/cc, mode diameter of 31 nm). The coating efficiency was evaluated according to various face velocities (V=0.25~1 m/s) and temperature gradients ((Thot-Tcold)/Thot=0~0.09). The maximum coating efficiency was 90.8 % when the face velocity was 0.25 m/s and the temperature gradient was 0.09 (Thot=30℃, Tcold=2℃). Silver nano particles were coated onto the enthalpy exchange element and two different coating amounts of silver nano particles (0.11 ㎍/cm3 , 0.22 ㎍/cm3 ) were tested. For evaluation of antimicrobial efficiency, the suspension test method with E. coli was used. After the suspension test method, CFU(colony forming unit)s of each test sample were counted and colony ratio was calculated. The colony ratio was decreased more quickly when the amount of coated silver particles was increased. When the contact time between each sample and suspension was over 3 hours, antimicrobial efficiencies of coated samples were more over 99.9 % for both amount of silver nano particle(0.11 ㎍/cm3 , 0.22 ㎍/cm3 ). The coating of silver nano particles did not affect the heat exchange efficiency.
The 21st Century Frontier Program, which is one of the R&D programs funded by Korean government, was launched in 1999 to elevate the status of Korean science and engineering capabilities to the advanced nation in the strategic fields. Currently, 23 different fields of science and engineering programs are carried out by researchers in institutes, universities and industries. Center for Advanced Materials Processing (CAMP) was formulated in 2001 to develop the advanced materials as well as to improve the parts manufacturing process. The main role of CAMP is proposing and forecasting the long term vision in Materials Processing Technology and also supporting the project teams for their best performance in R&D. The CAMP program consists of 5 research areas such as, Multi-layer Ceramic Electronic Parts, Powder Formed Precision Parts, 3 Dimensional Polymer Based Composites, Functional Metal Sheets, Parts Integration Technology. An introduction of R & D activities at CAMP, specially focusing on powder metallurgy, wil be presented.