In this paper, the formation and characterization of Pt2, Pt3 as well as Pt4 atomic clusters in cup-stacked carbon nanotubes (CSCNTs) are evaluated by DFT to examine the adsorption capacity under the clusters. The results show that the Pt clusters move toward the bottom edge or form rings in the optimized stable structure. Pt far from the carbon substrate possesses more active electrons and adsorption advantages. The three clusters can adsorb up to 17, 18, and 16 hydrogen molecules. Loading metal clusters at the bottom edge maintains a relatively good adsorption property despite the low binding energy through comparative studies. The adsorption capacity does not increase with the number of Pt for metal aggregation reducing the hydrogen adsorption area thus impacting the hydrogen storage ability and the aggregation phenomenon limiting the action of Pt metal. During adsorption, chemisorption occurs only in the Pt2 cluster, while multiple hydrogen molecules achieve physiochemical adsorption in the Pt3 and Pt4 clusters. Compared with the atomic loading of the dispersion system in equal quantities, the dispersion system features higher molecular stability and can significantly reduce the energy of the carbon substrates, providing more sites for hydrogen adsorption in space.

In this paper, we investigate asteroseismic scaling-relations of evolved stars in star clusters observed by Kepler/K2, aiming to address the issue of whether observed stellar oscillations are influenced by environmental factors, as there are interesting phenomena relating to the stellar pulsations observed in star clusters. Specifically, we compare statistical properties of distributions including Δν, νmax, HGauss, δνenv, and δν02 derived from red giant branch (RGB) and red clump (RC) stars in two pairs of star clusters: NGC 2682 - NGC 6819 and NGC 1817 - NGC 6811. We have found that the slopes of relations between νmax and Δν and between HGauss and νmax associated with RC stars in the more compact star clusters, NGC 2682 and NGC 1817, are in common less steep compared with those for NGC 6819 and NGC 6811. It is also found that the slopes of the relation between δνenv and νmax from RC stars in the more compact star clusters are in common steeper compared with those for the others. For the relation between δν02 and Δν obtained from RGB stars, the slope resulting from NGC 2682 and NGC 6819 is indistinguishable. The Kolmogorov–Smirnov tests conducted on RC stars in the pairs of NGC 2682 and NGC 6819, as well as NGC 1817 and NGC 6811, indicate that all the seismic quantities considered in this paper are drawn from different distributions. We conclude, therefore, that the properties of star clusters should be considered when asteroseismic data obtained from stars within star clusters are interpreted.

This study investigates the impact of magnetic turbulence on cosmic ray (CR) electrons through Fermi-II acceleration behind merger-driven shocks in the intracluster medium and examines how the ensuing synchrotron radio emission is influenced by the decay of magnetic energy through dissipation in the postshock region. We adopt simplified models for the momentum diffusion coefficient, specifically considering transit-time-damping resonance with fast-mode waves and gyroresonance with Alfvén waves. Utilizing analytic solutions derived from diffusive shock acceleration theory, at the shock location, we introduce a CR spectrum that is either shock-injected or shock-reaccelerated. We then track its temporal evolution along the Lagrangian fluid element in the time domain. The resulting CR spectra are mapped onto a spherical shell configuration to estimate the surface brightness profile of the model radio relics. Turbulent acceleration proves to be a significant factor in delaying the aging of postshock CR electrons, while decaying magnetic fields have marginal impacts due to the dominance of inverse Compton cooling over synchrotron cooling. However, the decay of magnetic fields substantially reduces synchrotron radiation. Consequently, the spatial distribution of the postshock magnetic fields affects the volume-integrated radio spectrum and its spectral index. We demonstrate that the Mach numbers estimated from the integrated spectral index tend to be higher than the actual shock Mach numbers, highlighting the necessity for accurate modeling of postshock magnetic turbulence in interpreting observations of radio relics.

Single-atom Pd clusters anchored on t-BaTiO3 material was synthesized using hydrothermal and ultrasonic methods for the effective piezoelectric catalytic degradation of pollutants using vibration energy. XRD patterns of BaTiO3 loaded with monoatomic Pd were obtained before and after calcining, and showed typical cubic-phase BTO. TEM and HAADF-STEM images indicated single-atom Pd clusters were successfully introduced into the BaTiO3. The piezoelectric current density of the prepared Pd-BaTiO3 binary composite was significantly higher than that of the pristine BaTiO3. Under mechanical vibration, the nanomaterial exhibited a tetracycline decomposition rate of ~95 % within 7 h, which is much higher than the degradation rate of 56.7 % observed with pure BaTiO3. Many of the piezo-induced electrons escaped to the Pd-doped BaTiO3 interface because of Pd’s excellent conductivity. Single-atom Pd clusters help promote the separation of the piezo-induced electrons, thereby achieving synergistic catalysis. This work demonstrates the feasibility of combining ultrasonic technology with the piezoelectric effect and provides a promising strategy for the development of ultrasonic and piezoelectric materials.

본 연구에서는 대학 평생교육체제 사업에 참여하는 성인학습자의 학업중단 현상을 방지하기 위한 토 대를 마련하고자 성인학습자를 심리적 특성별로 집단을 분류하고, 그에 따른 학업지속의향 및 소진의 차 이가 있는지를 확인하였다. 이를 위해 지방소재 A 대학 성인학습자를 대상으로 설문을 진행하였고, 그 결과 108명의 데이터를 수집․분석하였다. 성인학습자의 심리적 특성(대학생활적응, 사회적지지, 학업열 의, 학업목표)으로 집단을 분류하는 군집분석을 실시하였고, 그후 이를 독립변인, 학업지속의향과 학업소 진을 종속변으로 두어 일원분산분석을 진행하였다. 그 결과 고위험집단, 위험잠재집단, 성장가능집단, 고 성장가능집단으로 4개의 군집으로 분류되었다. 그리고 이 군집별 학업지속의향, 학업소진의 차이분석 결과 통계적으로 유의하게 나타났다. 이러한 결과를 바탕으로 성인학습자 개인적 특성에 따른 군집에 따른 맞춤형 지원이 필요하다는 결론을 내렸고, 개인적 특성에 따른 군집유형을 좀 더 다각화하고 위계적으로 분류하며 맞춤형 밀착지원이 필요하다고 제언하였다.