As the demand for nuclear power increases as a means to achieve carbon neutrality, concerns about nuclear proliferation have also grown. Consequently, significant researches have conducted to enhance nuclear non-proliferation resistance. Among these research, nuclear material attractiveness is a methodology used to evaluate how appealing a particular material is for potential use in nuclear weapons, based on the characteristics of that material. Existing nuclear material attractiveness assessments focused on materials like U, Pu, and TRU, which could be directly used in the production of nuclear weapons. However, these assessments did not consider how the properties of nuclear materials change throughout the nuclear fuel cycle, with each facility process. This study assumed a scenario of the nuclear fuel cycle of graphite reduction reactors and analyzed including enrichment facilities and PUREX. This study used the FOM (Figure-Of-Merit) method developed by LANL (Los Alamos National Laboratory) for evaluating the nuclear material attractiveness. The FOM formula consists of three parameters such as critical mass, heat content, and dose The critical mass of targe materials and the dose evaluation were conducted using the Monte Carlo N-Particle code. The heat content was calculated using the ORIGEN code embedded in the Scale code. In particular, if U-238 is dominant in the facility’s materials, such as mining and refining facilities, and critical mass evaluation is unpractical. Therefore, 1SQ (Significant Quantity) of that uranium was assumed as the critical mass value for the FOM evaluation, even though 1SQ is not identical to the critical mass As a result of this study, the attractiveness of Pu produced by PUREX among all nuclear fuel cycle facilities was 2.7616, which was the most attractive to be diverted to nuclear weapons. Through this study, it was shown that the proliferation risk of the nuclear facilities in the nuclear fuel cycle and risk of diversion among those facilities.

The damaged spent fuel rods must be stabilized by encapsulation or dry re-fabrication technologies before geological disposal. For applying the dry re-fabrication technology, we manufactured a vertical type furnace to perform the fuel material recovery from damaged fuel rods by oxidative decladding technology. As driving forces to accelerate oxidative decladding rate, magnetic vibration and pulse hammering generated by a pneumatic cylinder were used in this study. The oxidative decladding efficiency and recovery rate of fuel oxide powder with rod-cut length, oxidation temperature and time, oxygen concentration, and gas mixtures were investigated using simfuel rod-cuts in a vertical furnace for fuel material recovery and powder quality improvement. The oxidative decladding was performed for 2.5-10 h as following operation parameters: simfuel rod-cut length of 50-200 mm, oxidative temperature from 450 to 580°C, oxygen concentration of 49.5 or 75.6%, and gas mixtures in O2/Ar or O2/N2. In magnetic vibration, oxidative decladding was progressed only at bottom portion of fuel rodcut. Whereas, oxidative decladding in pulse hammering was occurred at both top and bottom portions of fuel-rod. In pulse hammering method, the oxidative decladding conditions to declad rod-cuts of 50- 200 mm in length were established to achieve both decladding efficiency of ~100% and fuel material recovery rate of > 99%. These conditions were as follows: oxidation temperature and time at 500°C and 2.5-10 h, oxygen concentration at 75.6% under O2/N2 gas mixtures. As operation conditions for a pneumatic cylinder, stroking, actuating, and waiting times were 0.5, 3, and 12 s.

The stabilization technology for the damaged spent fuel is being developed to process the damaged fuel into sound pellet suitable for dry re-fabrication. It requires several treatments including oxidative decladding followed by reduction treatment for oxidized powder closely related to the quality of oxidized powders for pellet fabrication. For the development of operating condition for the reduction treatment, in this study, we evaluated the effect of air-cylinder based vertical shaking previously applied to oxidative decladding on powder reduction. For U3O8 of 50-100 g, the reduction test were applied with and without vertical shaking at 700°C under reduction atmosphere (Ar + 4%H2) and the concentration of hydrogen in effluent was measured to evaluate the reduction reaction. It was found that the vertical shaking system has allowed the reaction time of 50 g and 100 g U3O8 reduced by 33% compared to the test in static mode. Based on XRD analysis, the better crystallinity of the products was also achieved.

Material balance evaluation is an important measure to determine whether or not nuclear material is diverted. A prototype code to evaluate material balance has been developed for uranium fuel fabrication facility. However, it is difficult to analyze the code’s functionality and performance because the utilization of real facility data related to material balance evaluation is very limited. It is also restricted to deliberately implement various abnormal situations based on real facility data, such as nuclear diversion condition. In this study, process flow simulator of uranium fuel fabrication facility has been developed to produce various process data required for material balance evaluation. The process flow simulator was developed on the basis of the Simulink-SimEvents framework of the MathWorks. This framework is suitable for batch-based process modeling like uranium fuel fabrication facility. It dynamically simulates the movement of nuclear material according to the time function and provides process data such as nuclear material amount at inputs, outputs, and inventories required for Material Unaccounted For (MUF) and MUF uncertainty calculation. The process flow simulator code provides these data to the material balance evaluation code. And then the material balance evaluation code calculates MUF and MUF uncertainty to evaluate whether or not nuclear material is diverted. The process flow simulator code can simulate the movement of nuclear material for any abnormal situation which is difficult to implement with real process data. This code is expected to contribute to checking and improving the functionality and performance of the prototype code of material balance evaluation by simulating process data for various operation scenarios.

In this study, a new manufacturing process for a multilayer-clad electrical contact material is suggested. A thin and dense BCuP-5 (Cu-15Ag-5P filler metal) coating layer is fabricated on a Ag plate using a high-velocity oxygen-fuel (HVOF) process. Subsequently, the microstructure and bonding properties of the HVOF BCuP-5 coating layer are evaluated. The thickness of the HVOF BCuP-5 coating layer is determined as 34.8 μm, and the surface fluctuation is measured as approximately 3.2 μm. The microstructure of the coating layer is composed of Cu, Ag, and Cu-Ag-Cu3P ternary eutectic phases, similar to the initial BCuP-5 powder feedstock. The average hardness of the coating layer is 154.6 HV, which is confirmed to be higher than that of the conventional BCuP-5 alloy. The pull-off strength of the Ag/BCup-5 layer is determined as 21.6 MPa. Thus, the possibility of manufacturing a multilayer-clad electrical contact material using the HVOF process is also discussed.

Structural characterization of pyrolysis fuel oil (PFO) was conducted via 1H NMR and 13C NMR to elucidate its molecular structure and evaluate the feasibility of using PFO as a raw material for mesophase pitch synthesis. The average structural parameters were calculated based on the data from elemental analysis and matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOF-MS), as well as 1H NMR and 13C NMR data. The resultant structural features of PFO were compared with those of fluidized catalytic cracking-decant oil (FCC-DO). Based on the calculated parameters, we proposed average molecular models of PFO and FCC-DO. The molecular model of PFO showed that it had an aromatic structure consisting of three aromatic rings and one naphthenic ring fused with one pericondensed and two catacondensed aromatic carbons, as well as a short alkyl side chain (with only a methyl group). This structural feature of PFO demonstrated that it is highly favorable for use as a raw material for mesophase pitch synthesis. The empirical findings in this study provide an in-depth understanding of the molecular structure of PFO as well as FCC-DO and can offer insights for future research on the utilization of PFO and other petroleum heavy oils.

Sediment works as a resource for electric cells. This paper was designed in order to verify how sediment cells work with anodic material such as metal and carbon fiber. As known quite well, sediment under sea, rivers or streams provides a furbished environment for generating electrons via some electron transfer mechanism within specific microbial population or corrosive oxidation on the metal surfaces in the presence of oxygen or water molecules. We experimented with one type of sediment cell using different anodic material so as to attain prolonged, maximum electric power. Iron, Zinc, aluminum, copper, zinc/copper, and graphite felt were tested for anodes. Also, combined type of anodes-metal embedded in the graphite fiber matrix-was experimented for better performances. The results show that the combined type of anodes exhibited sustainable electricity production for ca. 600 h with max. 0.57 W/㎡ Al/Graphite. Meanwhile, graphite-only electrodes produced max. 0.11 W/㎡ along with quite stationary electric output, and for a zinc electrode, in which the electricity generated was not stable with time, therefore resulting in relatively sharp drop in that after 100 h or so, the maximum power density was 0.64 W/㎡. It was observed that the corrosive reaction rates in the metal electrodes might be varied, so that strength and stability in the electric performances(voltage and current density) could be affected by them. In addition to that, COD(chemical oxygen demand) of the sediment of the cell system was reduced by 17.5∼36.7% in 600 h, which implied that the organic matter in the sediment would be partially converted into non-COD substances, that is, would suggest a way for decontamination of the aged, anaerobic sediment as well. The pH reduction for all electrodes could be a sign of organic acid production due to complicated chemical changes in the sediment.