Complaints about foul odors are emerging as an issue, and the number of complaints is steadily increasing every year. Biofiltration is known to remove harmful or odorous substances from the atmosphere by using microorganisms, and full-scale biofilters are being installed and operated in various environmental and industrial facilities. In this study, the current status and actual odor removal efficiency of full-scale biofilters installed in publicly owned treatment facilities such as sewage, manure, and livestock manure treatment plants were investigated. In addition, the effects of design and operating factors on their efficiency were also examined. As a result, it was found that odor prevention facilities with less than 30% odor removal efficiency based on complex odors accounted for 40%-50% of the biofilters investigated. In investigating the appropriate level of operating factors on odor removal efficiency, it was found that compliance with the recommended values p lays a significant role in improving odor removal efficiency. In the canonical correlation analysis for the on-site biofilter operation and design data, residence time and humidity were found to be the most critical factors. The on-site biofilter operation and design data were analyzed through canonical correlation analysis, and the residence time and humidity maintenance were found to be the most important factors in the design and operations of the biofilter. Based on these results, it is necessary to improve the odor removal efficiency of on-site biofilters by reviewing the effectiveness of the operation factors, improving devices, and adjusting operating methods.

This study was performed to assess particulate matter removal efficiency of domestic air cleaner products in a field condition. The assessment also included air cleaners with different air removal mechanisms. The particulate matter (PM2.5) removal test with a different air removal mechanism using air cleaners showed that the electrostatic precipitation technique showed better performance compared with HEPA filters and other types of systems. Its removal efficiency was almost 95% in one of our operation times in the given test condition. It was assumed that not only the type of removal system but also the individual design, supply and exhaust system, and the automatically controlled air volume are involved in the removal efficiency. With respect to the area of application, tests with air cleaners for 40 m2, 60 m2, and 80 m2 areas revealed that particulate matter removal efficiency increased with the air cleaner that had a broad area of application. However, particulate matter removal efficiency by air cleaners did not correspondingly increase with the increase of the area of application. Moreover, the installation location did not influence particulate matter removal efficiency. Our results are expected to be used as the basic information for indoor air quality improvement and prediction using air cleaners.

A pilot-scale biocover was installed at a sanitary landfill for municipal waste, and the removal of volatile organic compounds (VOCs) by the biocover was evaluated for a long period of 550 days. The biocover (2.5 m W × 5 m L × 1 m H) was constructed with the mixture of soil, perlite, earthworm cast and compost (6:2:1:1, v/v). The total VOCs concentration of the inlet gas into the biocover was 820.3 ppb~7,217.9 ppb, and the total VOCs concentration of the outlet gas from the surface of the biocover was 12.6 ppb~1,270.1 ppb. The average removal efficiency of total VOCs was 87.6 ± 11.0% (60.5% for minimum and 98.5% for maximum). Toluene concentration was the highest among the inlet VOCs, followed by ethylbenzene, m, p-xylene and o-xylene. These aromatic VOCs accounted for more than 50% of the total VOCs concentration. Other than these aromatic VOCs, hexane, cyclohexane, heptane, benzene, and acetone were major VOCs among the inlet VOCs. Compared with the VOC profiles in the inlet gas, the relative contribution of dichloromethane to the outlet VOCs emitted from the biocover layer increased from 0.1% to 15.3%. The average removal efficiencies of BTEX in the biocover were over 84% during the operation period of 550 days. The average removal efficiencies of hexane, cyclohexane and heptane in the biocover were 86.0 ± 18.9%, 85.4 ± 20.4% and 97.1 ± 4.0%, respectively. The removal efficiency of VOCs in the biocover decreased not only when the ambient temperature had fallen below 5oC, but also when the ambient temperature had risen above 23oC. Information on the VOCs removal characteristics of the biocover installed in the landfill field can be useful for commercializing the biocover technology for the treatment of VOCs.

본 연구는 냉동공조용 열교환기 내 스케일 형성으로 열전달 과정에서 열저항으로 작용하여 냉동공조시스템의 냉각성능이 떨어져 이를 해결하기 위해 전기분해 원리를 이용하여 배관 내 스케일을 자동 제거하는 시스템을 개발하여 그 성능을 실험을 통해 확인하고자 한다. 이전까지는 배관 내 스케일을 2∼3 년에 한번씩 브러시나 분사 노즐에 의해 기계적으로 배관 내를 청소를 하거나 화학약품을 이용하여 세관하였다. 이러한 세관은 시간이 경과하면 또 관이 오염되어 전열성능이 떨어지고 냉각장치의 운전을 정지하여 반복해야하는 여러 가지 문제점을 안고 있었다. 따라서 시스템의 정지없이 전기분해 원리를 이용하여 만들어진 처리수를 순환시킴으로서 스케일의 원인물질은 Ca, Mg, SiO2를 고형물 형태로 석출시켜 배관계 외부로 배출시킴으로서 배관내 스케일 발생을 차단하고 기 형성된 스케일을 제거하여 배관의 전열 성능을 유지하고자 하는 것이다. 실험한 결과, 새 배관의 열전달율을 100으로 기준할 경우, 스케일이 형성된 배관의 열전달율은 86.66%이었으며, 스케일이 형성된 배관을 1개월 동안 처리수를 가동했을 경우 열전달율은 90.5%의 수준까지 회복되었으며, 2개월간 운전한 경우 97.86%의 수준까지, 3개월 운전했을 경우 98.72% 까지 열전달율이 회복되었다. 비교적 짧은 실험기간이지만 배관내 형성된 스케일의 제거효과를 파악하였으며, 전열성능에도 영향을 미치고 있음을 확인하였다.

Mill scale, an iron waste, was used to separate magnetite particles for the adsorption of phosphate from aqueous solution. Mill scale has a layered structure composed of wustite (FeO), magnetite (Fe3O4), and hematite (Fe2O3). Because magnetite shows the highest magnetic property among these iron oxides, it can be easily separated from the crushed mill scale particles. Several techniques were employed to characterize the separated particles. Mill scale-derived magnetite particles exhibited a strong uptake affinity to phosphate in a wide pH range of 3-7, with the maximum adsorptive removal of 100%, at the dosage of 1 g/L, pH 3-5. Langmuir isotherm model well described the equilibrium data, exhibiting maximum adsorption capacities for phosphate up to 4.95 and 8.79 mg/g at 298 and 308 K, respectively. From continuous operation of the packed-bed column reactor operated with different EBCT (empty bed contact time) and adsorbent particle size, the breakthrough of phosphate started after 8-22 days of operation. After regeneration of the column reactor with 0.1N NaOH solution, 95-98% of adsorbed phosphate could be detached from the column reactor.

방사능 오염 토양 복원을 위해 실험실 규모의 동전기 복원장치를 제작하여 가동 하던 중 토양 내 존재하던 금속이온의 용출로 금속 산화물이 발생하여 음극의 전류 흐름을 차단하는 문제가 발생하였다. 전류의 차단으로 토양 내 우라늄 제거 능력이 상실되어 이러한 문제를 해결하는 해결 방안을 모색하여 개선된 동전기 복원 장치를 제작하였다. 개선된 실험실 규모 동전기 복원 장치를 이용하여 토양복원 실험을 25 일간 수행 하였을 때 우라늄 잔류 농도는 0.81 Bq/g으로 약 96.8%의 제거 효율을 보였으며, 초기 우라늄 농도 50 Bq/g 일 때 우라늄 규제 해제 농도인 1 Bq/g 이하로 제거 되기 까지는 34 일의 복원 기간이 필요하고, 초기 우라늄 농도 75 Bq/g, 100 Bq/g 일 때 각 42 일, 49 일이 필요한 것으로 나타났다.

The treatment of piggery wastes was carried out at pilot scale using a multilayered metal-activated carbon system followed by carbon bed filtration. The physicochemical properties were obtained from treated samples with aqueous solutions containing metallic ions such as Ag+, Cu2+, Na+, K+ and Mn2+, which main obsevations are subjected to inspect surface properties, color removal properties by Uv/Vis and EDX. Multilayered metal-activated carbons were contacted with waste water to investigation of the simultaneous catalytic effect for the COD, BOD, T-N and T-P removal. The removal results for the piggery waste using multilayered metal-activated carbon bed was achieved the satisfactory removal performance under permitted values of Ministry of Environment of Korea. The high efficiency of the multilayered metal-activated carbon bed was determined by the performance of this material for trapping, catalytic effect and adsorption of organic solid particles.

In this research, the target process was a modified type of a conventional aeration tank with four different influent feeding points and alternated aeration to obtain nitrogen removal. For more accurate switching of influent feeding, the process was operated under a designed control strategy based on monitoring of NH4-N and NOX-N concentrations in the tank. However, the strategy did have some limitations. For example, it was not sensitive to detecting the end of each reaction when losing the balance between nitrification and denitrification of each opposite part of biological tank. To overcome the limitations of the existing control strategy, a diagnosis-based control strategy was suggested in this research using the diagnosis results classified as normal (N), ammonia accumulation (AA) and nitrate accumulation (NA). Using the pre-designed rules for control actions, the aeration and volume of the aerated part of the reactor could be increased or decreased at a fixed mode time. In simulations of the suggested diagnosis-based control strategy, the NH4-N and NOX-N removal rates in the reactor were maintained at higher levels than those of the existing control strategy.

In this study, the International Maritime Organization (IMO)’s guideline MEPC. 277 (64) was developed and evaluated for the removal efficiency of T-N in a SBR and MBR combined process. This combined process of resized equipment based on large capacity water treatment device for a protection of marine aquatic life. In this experiment, T-N concentration of influent and effluent was measured through with the artificial wastewater. The SBR reactor operation time was varied according to the C : N : P ratios so that different conditions for mixing and aeration period in mins (90 : 60, 80 : 40, 70 : 50) and two C: N: P ratios (10 : 5 : 3, 10 : 3 : 1) were used. During experiment in the reactor’s aeration and anoxic tank DO concentrations were 3 mg/L and 0.2 mg/L respectively. Furthermore, in the reactor MLSS concentration was 2000 mg/L and flowrate was 2 L/hr. Experiment results showed that C : N : P, 10 : 3 : 1 ratio with 90 mins mixing and 60 mins aeration maximized removal efficiency at 97.3% T-N as compared to other conditions. The application of the SBR and MBR combined process showed efficient results.

This research aims to investigate the behavior of organic matter that causes bacterial re-growth and the formation of disinfectant by-products such as THM in water treatment, and to optimize conditions for a more efficient and conventional water facility. THM removed 51 % and 12 % through coagulation/sedimentation and filtration using a selected conventional system. In this experiment, the removal ratio of DOC was highest at 68 % when the Gt value was 42,000 and lowest at 41 % when the Gt value was 30,000. 77-84 % of total DOC was removed during coagulation/sedimentation, and 15-23 % was removed during filtration. When Gt values were between 30,000 and 66,000, over 50 % of high molecular matter above 10 K during coagulation/sedimentation was removed. Turbidity removed 98 % when the Gt value was 66,000. As the Gt value increased, the turbidity removal ratio increased. Turbidity removed over 20 % during the filtration process.

The purpose of this study was to investigate the characteristics of removal efficiency for aromatic hydrocarbons using a high-temperature fiber filter on a laboratory scale. The main elemental compositions of a high-temperature fiber filter are aluminium and silica, which can act as the catalysts. Benzene, toluene and o-xylene among aromatic hydrocarbons were used in this experiment. For 3㎝ thickness of fiber filter, these compounds were removed more than 90% at the face velocities of 3㎝/sec and 5㎝/sec above 450℃. For 4㎝ thickness of it, the removal efficiencies of these compounds were almost 90% from 400℃ at the same face velocities, suggesting that it may be due to increasing the contact time between the fiber filter and aromatic hydrocarbons. The pressure drop ranged from 22 to 48㎜H2O for 3㎝ thickness of fiber filter. However, for 4㎝ thickness of it, it was about two times(41-89㎜H2O) higher than that for 3㎝ fiber thickness.