Spent filters contained in drums of radioactive waste generated from nuclear power plants are contaminated with various radioactive isotopes due to their use in various water purification processes in the system. Radiation doses from the spent filters can vary from low to high levels. To dispose of drums containing spent filters as radioactive waste, the inventory of radioactive isotopes in the filters must be determined. Two methods for determining the inventory are indirect measurement using scaling factors and direct analysis of filter samples. This study suggests a method to determine the appropriate sample size for each drum based on the number of filters stored in the drum, when direct analysis is used to determine the inventory of radioactive isotopes. In particular, Visual Sample Plan (PNNL) software’s Item Sampling function was used to calculate the sample size, considering the confidence level and minimum acceptable coverage rate. As a result, assuming that the number of filters packed per drum ranges from a minimum of 1 to a maximum of 30, the study suggests that a full inspection is required for drums containing 9 or fewer filters, while drums containing 10 filters should be sampled with 9 samples, 11 filters with 10 samples, 12-13 filters with 11 samples, 14-16 filters with 12 samples, 19-22 filters with 14 samples, 23-26 filters with 15 samples, and 27-30 filters with 16 samples.

In order to permanently dispose of radioactive waste drums generated from nuclear power plants, disposal suitability must be demonstrated and the nuclides and radioactivity contained in the waste drums, including those in the shielding drums, must be identified. At present, reliable measurements of the nuclide concentration are performed using drum nuclide analysis devices at power plants and disposal facilities during acceptance inspection. The essential functions required to perform nuclide analysis using the non-destructive assay system are the correction for self-attenuation and the dead time correction. Until now, measurements have mainly been performed for drums containing solid waste such as DAW drums using SGS calibration drums with ordinary iron drums. However, for drums containing non-uniform radioactive waste, such as waste filters embedded in cement within shielding drums, a separate calibration drum needs to be produced. In order to produce calibration drums for shielded and embedded waste drums, the design considered the placement of calibration sources, setting of shielding thickness, correction for medium density, and cement mixing ratio. Based on these considerations, three calibration drums were produced. First, a shielding drum with an empty interior was produced. Second, a density correction drum filled with cement was produced to create apparent density on the surface of the shielding drum. Third, a physical model drum was produced containing a mock waste filter and cement filled in the shielding drum.

Commercial operation of KORI Unit 1 ended in 2017, and the final decommissioning plan is currently under approval from the KINS. In order for the dismantling waste to go to the repository, it is judged that the radioactive waste generated during the commercial operation should be treated and disposed in advance. Among these radioactive wastes, spent filters contain various radionuclides. The radiation dose rate from the radiation coming out of the filters ranges from a low dose rate to high dose rate. Therefore, in order to handle the spent filters, a remote processing system is required to reduce the radiation exposure of workers. This paper evaluates the radioactive inventory of filters that are stored in the filter room at the KORI unit #1. For this purpose, a method for predicting the radioactivity of each nuclide in the filter, based on the radiation dose rate, has been described using the MicroShield code, which is a commercial shielding code. The information on the filters in the field has only the creation date, type, size, and surface dose rate. In order to evaluate the radioactivity inventory using such limited data, it is possible to know the nuclide radioactivity ratio in the filter. We took out some of the filters stored on site and measured from using the ISCOS system, a gamma nuclide analyzer. The radioactivity of each nuclide in the filter was inferred by modeling with the MicroShield code, based on the radiation dose rate and the radioactivity value of each nuclide measured in the field.

The spent filters used to purify radioactive materials and remove impurities from primary systems at nuclear power plants (NPPs) have been stored for long periods in filter storage rooms at NPPs due to concerns about the unproven safety of the treatment method, absence of disposal facilities, and risk of high radiation exposure. In the storage room at Kori Unit 1, there are approximately 227 spent filters of 9 different types. The radiation dose rates of filters range from 0.01 to 500 mSv/hr. Recently, a comprehensive plan has been established for the treatment and disposal of radioactive waste that has not yet been treated to facilitate decommissioning of NPPs. As a follow-up measure, compression and packaging optimization processes are being developed to treat the spent filters. KHNP plans to dispose of the spent filters after compressing, packaging, and immobilizing them. However, the spent filters are currently stored without being sorted by type or radiation intensity. If the removal and packing of the filters are done randomly without a plan for the order of withdrawal and subsequent processes, issues may arise such as a decrease in drum loading efficiency and exceeding the dose limit of the package. In this study, the number of drums needed to pack the spent filters was calculated, considering the filter size, weight, quantity, dose rate, shielding thickness of drum, and loadable quantity in a shielding drum (SD). Then, the spent filters that can be loaded on each drum were classified into one group. In addition, the withdrawal order for each group was set so that the filter withdrawal, compression, and packaging processes could be performed efficiently. The spent filter groups are as follows: (1) compression/12 cm SD (17 groups), (2) compression/16 cm SD (6 groups), (3) non-compression/ intermediate storage container (17 groups, additional radiation attenuation required due to high dose rate), and (4) unclassified (5 groups, determined after measurement due to lack of filter information). The withdrawal order of the groups was determined based on several factors, including visual identification of the filter, ease of distribution after withdrawal, work convenience, and safety. Due to the decay of radioactivity over time, the current dose rate of the spent filters is expected to be much lower than at the time of waste generation. Therefore, in the future, sample filters will be taken from the storage room to measure their radioactivity and radiation dose rate. Based on these measurements, a database of radiological characteristics for the 227 filters will be created and used to revise the filter grouping.

In this study, the process of compressing/packaging the spent filters of Kori Unit 1, which was conceptually presented in the previous study, is advanced so that disposal suitability for each step can be secure efficiently. In particular, the differences between the previous study and this study are that the disposable filters are screened using an In-Situ Object Counting System (ISOCS), and the method of collecting representative samples for development of scaling factor is specified. The process of compressing/packaging the spent filters consists of 7 stages as follows. 1) Collecting: The spent filters temporarily stored in the filter room are collected by dose and type remotely using a robot system to minimize the radiation exposure of workers according to a pre-established packaging plan. 2) Screening: The gamma activity concentration of the spent filters received by the robot system is measured by ISOCS. The spent filters below the low-level waste concentration limit and the surface dose are transferred into the compression system, while the others are returned in the filter room again. 3) Sampling: The external perforator drilling/cutting the filter was developed for sampling required for the new scaling factors. Since the sampling is collected remotely, the risk of exposure to workers can be reduced. The newly developed scaling factor will be used to verify the disposal suitability of the packages. 4) Compression: According to the pre-established plan, the spent filter collected by dose and type, is supplied to the compression system considering the dose and radionuclide inventory. Whether to additionally store the compressed filter in the drum is determined by checking the accumulated dose. 5) Immobilization: Immobilization with a safety material is necessary when inhomogeneous wastes, like spent filters, have the total radionuclide concentration with a half-life of more than 20 years is 74,000 Bq/g or more and for filling rate or non-dispersible treatment of particulates. 6) Packaging and Analysis: Waste information is labelled onto the package after the measurements of surface dose rate and surface contamination. Finally, using the drum assay system, the gamma radionuclide concentration is measured to identify at least 95% of the total radioactivity concentration of the package. 7) Temporary Storage and Delivery: The packages are moved to temporary storage in the plant prior to disposal. After establishing the plan for delivery and applying for a takeover request to KORAD, if the acceptance inspection is passed, the packages are transported to the disposal facility.

As the decommissioning of Kori Unit 1 progresses, securing technology for treatment and disposal of radioactive wastes that have not been disposed of so far, such as spent filters, is recognized as an urgent task. In this study, a method of confirming the disposal suitability of spent filters was presented by reviewing the waste characteristics as presented in the waste acceptance criteria (WAC). The waste characteristics to be satisfied to ensure disposal suitability of waste are largely classified into general requirements, solidification and immobilization requirements, radiological requirements, physical requirements, chemical requirements, and biological requirements. First, the general requirement is to prove that the prohibited waste form has not been introduced into items related to waste form and packaging, and to confirm the suitability of disposal through step-by-step packaging photos, generation information, X-ray inspection, and visual inspection. Second, in the solidification and immobilization requirements, spent filters are non-homogeneous waste, and if the total radioactivity concentration of nuclides with a half-life of more than 20 years is 74,000 Bq·g−1 or more, they must be immobilized. Third, in order to meet the characteristic criteria for nuclides and radioactivity concentration, sampling and scaling factors development are required and based on this, nuclides must be identified and demonstrated to be below the disposal concentration limits. Surface dose rate and surface contamination should be measured in accordance with standardized procedures and disposal suitability should be confirmed through document tests recording the measured values. Fourth, in order to satisfy the physical requirements of the particulate matter and filling rate characteristics, the spent filter must be immobilized, if necessary, thereby ensuring disposal suitability. Meanwhile, free water in the spent filter should be removed through pre-drying and dehydration, and the disposal suitability should be confirmed by applying a test. Fifth, the criteria for chelating agents should be checked for disposal suitability through operation records and component analysis of spent filters, and documents, that can prove harmful substances are removed in advance and no harmful substances are included in the package, should be provided. Lastly, in biological requirements, if the spent filters contain corrosive or infectious substances, they should be removed in advance and disposal suitability should be confirmed by providing documents that can prove that such substances are not included in the package.

This study established a process to ensure the disposal suitability of spent filters stored in the untreated state in Kori unit 1 and presented the following procedures and requirements for confirming the disposal suitability for each process. The process for securing spent filter disposal suitability consists of collecting spent filters, compression, immobilization, analysis and packaging, and storage stages. The requirements for confirming the acceptance criteria for each process are as follows. (1) Collecting: Since the high radioactivity spent filters are being stored in the filter room of Kori unit 1, those are collected by a remote system to minimize the exposure dose of workers due to spent filter handling. In order to satisfy the surface dose rate requirements, spent filters with a surface dose rate of 10 mSv·hr−1 or more are classified and collected, and stored temporary storage place until a separate treatment plan is determined. The checkpoints in this process are the surface dose rate, etc. (2) Compression: The collected spent filters are analyzed gamma nuclides such as Co-60 and Cs-137, using a field-applicable nuclide analyzer, and then applying the scaling factors to determine whether it is disposable. Spent filters whose radioactivity concentration is confirmed to be less than the disposal concentration limit is compressed into compression ratios determined by surface dose rate. The checkpoints in this process are nuclide information, surface dose rate, compression ratio, spent filter loading quantity, etc. (3) Immobilization: A spent filter is a non-homogeneous waste that is immobilized with a proven safety material such as cement if the total radioactivity concentration of nuclides with a half-life of more than 20 years is 74,000 Bq·g−1. Meanwhile, immobilization of inhomogeneous waste can be considered to satisfy disposal criteria such as particulate matter and filling rate. The checkpoints in this process are the immobilizing material, filling rate, etc. (4) Analysis and Packaging: Immobilized drums shall be determined to be 95% or more of the total radioactivity of waste packages by measuring the radioactivity concentration of nuclides using a nuclide analysis device. Finally, measure the surface dose rate and surface contamination of the package, and attach the package label recording the identification number, date, total radioactivity, surface dose rate, and surface contamination information to the packaging container. (5) Storage: Packaging containers are moved to and stored in a temporary waste storage or storage area before disposal.

The spent filters stored in Kori Unit 1 are planned that compressed and disposed for volume reduction. However, shielding reinforcement is required to package high-dose spent filters in a 200 L drum. So, in this study suggests a shielding thickness that can satisfy the surface dose criteria of 10 mSv·h−1 when packaging several compressed spent filters into 200 L drums, and the number of drums required for the compressed spent filter packaging was calculated. In this study, representative gamma-emitting nuclides in spent filter are assumed that Co-60 and Cs-137, and dose reduction due to half-life is not considered, because the date of occurrence and nuclide information of the stored spent filter are not accurate. The shielding material is assumed to be concrete, and the thickness of the shielding is assumed to 18 cm considering the diameter of the spent filter and compression mold. Considering the height of the compressed spent filter and the internal height of the shielding drum, assuming the placement of the compressed spent filter in the drum in the vertical direction only, the maximum number of packaging of the compressed spent filter is 3. When applying a 18 cm thick concrete shield, the maximum dose of the spent filter can packaged in the drum is 125 mSv·h−1, so when packaging 3 spent filters of the same dose, the dose of a spent filter shall not exceed 41 mSv·h−1 and not exceed 62 mSv·h−1when packing 2 spent filters. Therefore, the dose ranges of spent filters that can be packaged in a drum are classified into three groups: 0–41 mSv·h−1, 41–62 mSv·h−1, and 62–125 mSv·h−1based on 41 mSv·h−1, 62 mSv·h−1, and 125 mSv·h−1. When 227 spent filters stored in the filter room are classified according to the above dose group, 207, 3 and 4 spent filters are distributed in each group, and the number of shielding drums required to pack the appropriate number of spent filters in each dose group is 75. Meanwhile, 8 spent filters exceeding 125 mSv·h−1 and 5 spent filters that has without dose information are excluded from compression and packaging until the treatment and disposal method are prepared. In the future, we will segmentation of waste filter dose groups through the consideration of dose reduction and horizontal placement of compressed spent filters, and derive the minimum number of drums required for compressed spent filter packaging.

Currently, treatment and disposal suitability verification methods have not been established for radioactive waste, such as spent filters temporarily stored in each plant, so the WCP (Waste Certification Program) can be applied to verify the suitability of non-conforming waste at the site. In this study, WCP components such as certification organizations, certification methods, certification documents, and quality assurance (QA) plan that should be considered when developing WCP applicable to spent filter disposal were reviewed and presented. First, a certification organization consists of a certification organization that performs certification work, a certification support organization related to waste generation and treatment, and a quality control organization for waste certification. Especially, the support organization should support the implementation of WCP, so that spent filter processing procedures such as generation information management and immobilization can be properly packaged and transported. Second, in identifying the waste characteristics of the certification method, each characteristic identification procedure and certification method of the acceptance criteria should be described, evidence examining the suitability of general, radiological, physical, chemical, and biological requirements, and processes related to measurement and sampling should be established. In identifying characteristics, satisfaction of waste form, free water requirements, and whether it is subject to immobilization should be checked priorly, and a method of confirming particulate matter and securing filling rate when packaging compressed filters should be included. It is very important to develop a technology for verifying the safety and quality of the immobilized material because immobilization of the filters can be a processing method that satisfies various characteristic criteria. Meanwhile, it is essential to collect samples and develop scaling factors to identify the nuclides of filters and prove that they are below the concentration limits. For chemical and biological requirements, the characteristics are identified through generation information documents, corrective actions are taken and documented in case of nonconformance. Third, certification documents should include immobilization procedure manual, characteristic report, and characteristic test manuals such as free water, particulate matter and filling rate, radiation measurement method manual for packages, profile, and generation documents. Fourth, the QA plan should analyze the QA system of the plants, check the QA inspection details, establish general requirements for QA of spent filter disposal, and specify step-by-step certification work QA activities. In this study, considerations to ensure the disposal suitability at all stages from generation to disposal of spent filter were presented, and development of a WCP could contribute to preventing nonconformance.