During the operation of the nuclear power plant, various radioactive waste are generated. The spent resin, boron concentrates, and DAW are classified as a generic radioactive waste. They are treated and stored at radioactive waste building. In the reactor vessel, different types of radioactive waste are generated. Since the materials used in reactor core region exposed to high concentration of neutrons, they exhibit higher level of surface dose rate and specific activity. And they are usually stored in spent fuel pool with spent fuel. Various non-fuel radioactive wastes are stored in spent fuel pool, which are skeleton, control rod assembly, burnable neutron absorber, neutron source, in core detector, etc. The skeleton is composed of stainless 304 and Inconel-718. There are two types of control rod assembly, that are WH type and OPR type. The WH type control rod is composed of Ag-In-Cd composites. The OPR type control rod is composed of B4C and Inconel-625. In this paper, the characteristics and storage status of the non-fuel radioactive waste will be reported. Also, the management strategy for the various non-fuel radioactive waste will be discussed.

The treatment of waste generated during operation as a part of preparation for decommissioning is coming to the fore as a pending issue. Non-fuel waste stored in the spent fuel pool (SFP) of PWRs in Korea includes Dummy fuel, damaged fuel rod storage container, reactor vessel specimen cask, spent in-core instrumentation, spent control element assemblies, spent neutron source assemblies, burnable poison rods, etc. In order to treat such waste, it is necessary to classify radioactive waste level and analyze kinds of nuclide in accordance with legal requirements. In order to solve the problem, the items that KHNP-CRI is trying to conduct like followings. First, KHNP-CRI will identify the current status of non-fuel waste stored in the SFP of all domestic nuclear power plants. In order to consider the treatment of non-fuel waste, it is essential to know what kind of items and how many items are stored in the SFP. Second, to identify the dimension and characteristics of non-fuel waste stored in the SFP would be conducted. The configuration of non-fuel waste is important information to handle them. Third, the way to handle non-fuel waste would be deduced including analysis of their dimension, whether the equipment should be developed to handle each kind of non-fuel waste or not, how to transport them. In order to classify radioactive waste level and analyze the nuclide for the non-fuel waste, handling tools and the cask to transport them into the facility which nuclide analysis is able to be performed would be required. Fourth, the nuclide analysis technology would be identified. Also, domestic holding technology would be identified and which technology should be developed to classify the radioactive waste level for the non-fuel waste would be deduced. This preliminary study will provide KHNP-CRI with the insight for the nuclide analysis technology and future work which is following action for the non-fuel waste. Based on the result of above preliminary study, the feasibility of the research for the treatment of non-fuel waste would be evaluated and research plan would be established. In conclusion, the treatment of non-fuel waste stored in the spent fuel pool of domestic PWR should be considered to prepare the decommissioning. KHNP-CRI will identify the quantity, the dimension and kinds of non-fuel waste in the SFP of domestic PWR. Also, the various nuclide analysis technology would be identified and the technology which should be developed would be defined through this preliminary study.

In Korea, borated stainless steel (BSS) is used as a storage rack in spent fuel pools (SFP) to maintain the nuclear criticality of spent fuels. As the number of nuclear power plants and the corresponding amount of spent fuels increased, the density in SFP storage rack also increased. In this regard, maintaining subcriticality of spent nuclear fuels became an issue and BSS was selected as the structural material and neutron absorber for high density storage rack. Since it is difficult to replace the storage rack, corrosion resistance and neutron absorbency are required for long period. BSS is based on stainless steel 304 and is specified in the ASTM A887-89 standard depending on the boron concentration from 304B (0.20-0.29% B) to 304B7 (1.75-2.25% B). Due to the low solubility of boron in austenitic stainless steel, metallic borides such as (Fe, Cr) 2B are formed as a secondary phase. Metallic borides could cause Cr depletion near it, which could decrease the corrosion resistance of the material. In this paper, the long-term corrosion behavior of BSS and its oxide microstructures are investigated through accelerated corrosion experiment in simulated SFP conditions. Because the corrosion rate of austenitic stainless steel is known to be dependent on the Arrhenius equation, a function of temperature, the corrosion experiment is conducted by increasing the experimental temperature. Detail microstructural analysis is conducted using a scanning electron microscope, transmission electron microscope and energy dispersive spectrometer. After oxidation, a hematite structure oxide film is formed, and pitting corrosion occurs on the surface of specimens. Most of the pitting corrosion is found at the substrate surface because the corrosion resistance of the substrate, which has low Cr content, is relatively low. Also, the oxidation reaction of B in the secondary phase has the lowest Gibbs free energy compared to other elements. Furthermore, oxidation of Cr has low Gibbs free energy, which means that oxidation of B and Cr could be faster than other elements. Thus, the long-term corrosion might affect the boron content and the neutron absorption ability of the material. Using boron’s high cross-section for neutrons, the neutron absorption performance of BSS was evaluated through neutron transmission tests. The effect of the corrosion behavior of BSS on its neutron absorption performance was investigated. Samples simulated to undergo up to 60 years of degradation before corrosion through accelerated corrosion testing did not show significant changes in the neutron shielding ability before and after corrosion. This can be explained in relation to the corrosion behavior of BSS. Boron was only leached out from the secondary phase exposed on the surface, and this oxidized secondary phase corresponds to about 0.17% of the volume of the total secondary phase. This can be seen as a very small proportion compared to the total boron content and is not expected to have a significant impact on neutron absorption performance.

The current storage capacity of the spent nuclear fuel at the Kori unit 2 has reached approximately 94% saturation, excluding emergency core capacity. As South Korea has not yet constructed any interim storage facilities to store spent nuclear fuel, one of possible options is to install high density storage racks in spent fuel pool at the reactor site to increase its capacity. The high density storage rack is a technology developed to allow the storage to have more spent nuclear fuel than originally planned, while still ensuring safety. It achieves this by reducing the storage gap between the spent nuclear fuel. The purpose of this study is to investigate an appropriate storage capacity for spent fuel pool in the Kori unit 2 and the factors to be considered during the high density storage rack installation. Given that the Kori unit 2 is planning continued operation and Korea Hydro & Nuclear Power (KHNP) is preparing to install a temporary storage facility for spent nuclear fuel at the Kori nuclear site, it is reasonable to consider the installation of high density storage racks in the spent fuel pool as a storage solution for these issues. When evaluating the capacity of the spent fuel pool, the amount of spent nuclear fuel generated by other reactors in Kori nuclear site and the amount of spent nuclear fuel generated by continued operation of the Kori unit 2 should be taken into account. This study aims to consider these factors and evaluate the capacity of the spent fuel pool. Furthermore, when installing high density storage rack for the spent nuclear fuel, it should be noted that the existing storage racks at the Kori unit 2 are welded to the liner plate, which may require additional cutting work. Therefore, it is necessary to review the suitable method for the cutting work. Additionally, assuming that divers need to access the area near the storage racks or cutting & welding devices require radiation protection in the area, it is essential to analyze the expected radiation level with computational code and propose appropriate measures to limit work time or establish a work zone. Thus, this study evaluates appropriate capacity of spent fuel pool and work methods for the installation of high density storage rack in the spent fuel pool at the Kori unit 2. It is expected that this paper contributes to install high density storage racks in SFP safely.

The Comprehensive Analyzer of Real Estimation for spent fuel POOL (CAREPOOL) has been developed for evaluating the thermal safety of a spent nuclear fuel pool (SFP) during the normal and accident conditions. The management of spent nuclear fuel function provides a management tool for spent nuclear fuel in the SFP. The fuel assemblies both in SFP and reactor side can be shown graphically in the screen. The loading sequence into transfer cask can be checked respectively in the CAREPOOL. A basic heat balance equation was used to estimate the SFP temperature using the heat load calculated in the previous step. The characteristics of typical SFPs and associated cooling systems at reactor sites in the Korea were applied. Accident simulation like station black out leading to loss of SFP cooling or inventory is possible. Emergency cooling water injection pipe installed subsequent to the events at Fukushima 2011 is also modeled in this system. The CAREPOOL provides four main functions- management of spent nuclear fuel, decay heat calculation by ORIGEN-S code, estimation of the time to boil/fuel uncovering by thermal-hydraulics calculations, fuel selection for periodic spent fuel transferring campaign. All of these are integrated into the GUI based CAREPOOL system. The CAREPOOL would be very beneficial to nuclear power plant operator and trainee who have responsibility for the SFP operation.

After Fukushima nuclear power plant accident in 2011, Concerns about accident of spent fuel pool increase. In Korea, the time of saturation of spent fuel pool is coming, but regulatory measures and safety evaluation are insufficient when occurring spent fuel pool accident. Thus, it is necessary to review of spent fuel pool accident in foreign countries to establish regulatory measures and safety evaluation of spent fuel pool accident suitable for domestic spent fuel pool. Therefore, we reviewed spent fuel pool accident that occurred at Fukushima Unit 4, SONGS Unit 2 and PAKS. In Japan, spent fuel pool accident occurred at Fukushima NPP in 2011. Tsunami was cause of the accident. Station Black Out occurred at Fukushima NPP and Emergency Diesel Generator lost their functions due to Tsunami. As a result, Loss of cooling happened in spent fuel pool at Fukushima NPP. For Unit 4, wall of spent fuel pool in Unit 4 was damaged due to hydrogen explosive, so loss of coolant in spent fuel pool of Unit 4 occurred. After the accident, the temperature of spent fuel pool increases to 75°C, but there was no damage to the spent fuel. In USA, spent fuel pool accident occurred at SONGS Unit 2 in 2013. The debris of nearby ocean is cause of the accident. The debris entered the system through a damaged Salt Water Cooling pump suction strainer. The debris obstructed flow through the Component Cooling Water heat exchanger and operation of Salt Water Cooling. The maximum spent fuel pool temperature during this event was 25.6°C. It was a value that satisfied the technical specifications of the SONGS NPP. In Ukraine, spent fuel pool accident occurred at PAKS in 2003. Unintentionally opened valve of cleaning tank is cause of the accident. Loss of coolant occurred in spent fuel pool of PAKS. Due to loss of coolant, spent fuels were exposed to the vapor state atmosphere, and oxidation occurred in the cladding tube of the spent fuel that rose to 1,400°C. In this study, Review of spent fuel pool accident in major foreign countries was conducted as basic studies for establishing regulatory measures and safety evaluation of spent fuel pool in Korea. Causes of each accident were different by structure of spent fuel pools. Result of this study will be contributed to establish safety measures of spent fuel pool accident suitable for domestic spent fuel pool facility.

When a loss of coolant accident which causes a partial or a full drainage in the SFP would happen, Zircaloy-4 spent fuel cladding begin to react with high temperature air, and the heat generates by exothermic reaction between Zircaloy-4 cladding and surrounding air. Due to the heat, the ignition may occur in the surface of Zircaloy-4 cladding. If the Zr-fire phenomenon occurs during the accident in a SFP, the spent fuel cladding and pellets would be severely fragmented and powdered and it may bring about a massive release of radioactive source terms. Therefore, it is crucial to prevent the zirconium fire phenomenon for the spent fuel pool safety. However, a main cause to trigger the zirconium fire was not identified. In order to identify a possible mechanism of the Zr-fire phenomenon, OECD-NEA SFP Project I, II was initiated. In this paper, we reviewed the Zr-fire phenomenon which may occur in the spent fuel pool for complete loss of coolant accident scenario. The Spent Fuel Pool Project (hereinafter SFP project) is the experimental program to investigate the phenomena of spent fuel pool complete loss of coolant accident using a 17×17 PWR fuel assembly. In this section, the zirconium fire phenomenon which was observed from the SFP project is briefly investigated. This paper presented the fuel assembly temperature (i.e. zirconium alloy cladding temperature) and oxygen concentration profile of the SFP project phase-1 ignition test. At around 12.7 hour, the temperature abruptly increased and the oxygen concentration also dramatically decreased. This abrupt temperature escalation is the zirconium fire phenomenon. In order to investigate the mechanism of this zirconium fire phenomenon, behaviors of both temperature and oxygen concentration were fully compared. This paper reviewed the results of OECD-NEA SFP project experiment and then a mechanism of Zr-fire phenomenon was dscussed. It seems that the Zr-fire phenomenon might be a consequence of thermal mismatch between heat generation and dissipation. A large amount of heat might be generated by the air oxidation of Zircaloy-4 spent cladding immediately after the kinetic transition which is a breakaway phenomenon. This paper discussed the relationship between the breakaway phenomenon and the Zr-fire phenomenon in case of air oxidation of Zircaloy-4 spent cladding. This paper presents preliminary findings on the Zr-fire phenomenon from the open experiment data of the prototypic spent fuel severe accident scenario. These findings would enhance the understanding of Zircaloy-4 spent cladding air oxidation and severe accident scenario progression in a SFP.

In Korea, borated stainless steel (BSS) is used as spent fuel pool (SFP) storage rack to maintain nuclear criticality of spent fuels. As number of nuclear power plants and corresponding number of spent fuels increased, density in SFP storage rack also increased. In this regard, maintain subcriticality of spent nuclear fuels was raised as an issue and BSS was selected as structural material and neutron absorber for high density storage rack. Because it is difficult to replace storage rack, corrosion resistance and neutron absorbency are required for long period. BSS is based on stainless steel 304 and it is specified in the ASTM A887-89 standard depending on the boron concentration from 304B (0.20-0.29% B) to 304B7 (1.75-2.25% B). Due to low solubility of boron in austenitic stainless steel, metallic borides such as (Fe, Cr)2B are formed as secondary phase metallic borides could make Cr depletion near it which could decrease the corrosion resistance of material. In this paper, long-term corrosion behavior of BSS and its oxide microstructures are investigated through accelerated corrosion experiment in simulated SFP condition. Because corrosion rate of austenitic stainless steel is known to be dependent on the Arrhenius equation, a function of temperature, corrosion experiment is conducted by increasing the experimental temperature. Detail microstructural analysis was conducted with scanning electron microscope, transmission electron microscope and energy dispersive spectrometer. After oxidation, hematite structure oxide film is formed and pitting corrosions occur on the surface of specimens. Most of pitting corrosions are found at the substrate surface because corrosion resistance of substrate, which has low Cr content, is relatively low. Also, oxidation reaction of B in the secondary phase has the lowest Gibbs free energy compared to other elements. Furthermore, oxidation of Cr has low Gibbs free energy which means that oxidation of B and Cr could be faster than other elements. Thus, the long-term corrosion might affect to boron content and the neutron absorption ability of the material.