Against the backdrop of the rapid development of the global shipping industry and the deep advancement of “dual carbon” goals, energy transition, energy conservation, and emission reduction have become core issues in marine transportation. As a critical component of clean and renewable energy, the efficient development and utilization of wind energy are pivotal for achieving low-carbon shipping. Exhaust turbine sails, an innovative application of active suction control in marine aerodynamic propulsion, regulate boundary layer flow through active suction to enhance wind energy utilization efficiency, which has emerging as a research hotspot in the green transformation of modern shipping. This paper aims to synthesize research on exhaust turbine sails. First, based on fundamental fluid mechanics principles, it analyzes the impact of boundary layer separation on the aerodynamic characteristics of structural bodies. Second, through case studies, it summarizes flow control effects under different suction parameters. It further introduces combined blowing and suction control strategies to explore their influence on boundary layer management. Finally, it details the research progress of exhaust turbine sails, explaining their core principle: active suction control delays or prevents boundary layer separation, effectively suppressing vortex shedding, thereby significantly reducing ship navigation resistance and enhancing lift. The study reveals that the aerodynamic performance of exhaust turbine sails is jointly influenced by oncoming flow conditions, suction power, and structural parameters, necessitating multi-objective optimization to achieve energy efficiency balance. The paper concludes by addressing key challenges in their marine applications and envisioning future directions for integrating these sails with emerging technologies, providing practical implications for promoting the green and low-carbon transformation of the shipping industry.
The avenue to synthesize eco-friendly and high-performing warm-white light emitting diodes (WLEDs) using quantum-dots for color conversion is challenging. Here, the graphene quantum dots (GQDs) are synthesized from Moringa oleifera leaves without the need of any organic solvents or reducing agents by a one-pot hydrothermal method and utilized for the design of efficient warm WLEDs. The photoluminescence of the obtained GQDs is found to be red-shifted as the excitation wavelength increases. This is ascribed to an excitation of multiple transitions due to various surface traps related to surface amino and oxygen functionalized groups as revealed from X-ray-photoelectron–spectroscopy and FTIR results. Three different concentrations of GQDs are embedded in polyvinyl-alcohol matrix acting as color-converters for the design of WLED devices. By increasing the GQDs concentration, the color correlated temperatures are tuned from 3804 to 2593 K and the luminous efficacy from 39.3 to 71.69 lm/W. Moreover, the chromaticity coordinates of the devices are shifted from (0.3825, 0.3665) to (0.4807, 0.4478). The brightness of the fabricated devices based on these green-GQDs are comparable with those of warm LEDs prepared from chemically synthesized graphene and carbon dots and can be suitable for indoor lighting applications.
Electric double-layer capacitors (EDLCs) have attracted significant interest as a promising energy storage solution because of their high-power density, exceptional charge/discharge cycle stability, and extended lifespan. Porous carbon is a key component of EDLCs given its outstanding chemical stability, high electrical conductivity, large specific surface area, and cost effectiveness. We fabricated porous carbon from oak wood as a raw material using an environment-friendly steam activation process (physical activation). Pretreatment (stabilization) was conducted using a mild acid (phosphoric acid) to achieve a high specific surface area and maintain structural stability. Oak wood-derived porous carbon (Oak-PC) produced with varying activation times following phosphate stabilization achieved high specific surface area (1050–1990 m2/ g), pore volume (0.44–0.95 cm3/ g), and carbonization yield (36%). Oak-PC retained ~ 90% of its performance at a high current density (10 A/g), demonstrating superior EDLC performance compared to that of commercial porous carbon. These results were attributed to the significant enhancement of the electrical properties of Oak-PCs, achieved by removing char through phosphate stabilization and strengthening bond stability. This study provides foundational data for developing sustainable energy storage technologies and enhancing the efficiency of next-generation energy storage systems by utilizing environmentfriendly biomass materials such as oak wood.
It is important to secure numerical accuracy while ensuring adhesion with high transparency and low yellowing properties to protect against physical impacts outside the drone. In addition, in order to derive high-quality results for preventing damage and discoloration from ultraviolet rays and atmospheric chemicals, a release layer process technology in which a silicone-based release is coated at a certain thickness and then cured at an appropriate temperature and time, and a technology for optimizing adhesion of adhesive thickness and solid content during adhesive coating were confirmed, and the protective film confirmed the results of surface suitability, retention, and stability evaluation over time for drone aircraft and external parts over a long period of time.
In this study, the heat transfer characteristics of a liquid hydrogen (LH2) tank with multilayer insulation (MLI) were numerically investigated. The temperature distribution inside the LH2 tank and within the MLI, as well as the temperature variation according to positional changes, heat transfer rate, and boil-off rate (BOR), were compared and analyzed. The results showed a distinct stepwise temperature drop in Case 4 with 20 MLI layers and Case 8 with 40 MLI layers, where the insulation thickness was greatest. Under the same number of layers, the temperature gradient became more gradual as the MLI thickness increased. In addition, the temperature variation in the tank head region indicated that increasing the number of MLI radiation layers reduced the radiative heat flux, resulting in a gentler temperature variation and a longer temperature drop range. Furthermore, the analysis of heat transfer and BOR showed that both rates decreased under the condition with the greatest MLI thickness and number of layers, demonstrating the best insulation performance. In particular, under the same 40-layer condition, the BOR value of Case 8 was more than three times lower than that of Case 5, indicating a significant improvement in thermal insulation efficiency.
본 연구에서는 고분자 점도 조절제를 첨가하여 졸-겔법 기반 알루미나 나노여과막을 단일 공정으로 제조하고, 코 팅층의 구조 및 성능을 제어하는 방법을 제시하였다. Hydroxypropyl cellulose (HPC, Mw ~80000) 고분자를 알루미나 졸에 첨가하여 점도를 10 mPa·s에서 최대 4200 mPa·s까지 조절하였으며, 이를 통해 알루미나 중공사 지지체 표면에 균일하고 결 함이 없는 선택층을 형성하였다. HPC 함량이 증가할수록 코팅층 두께가 증가하였으나, 기공 크기 증가에 따라 분리 성능이 저하되었다. 2:1 (졸:HPC 고분자 용액) 혼합비에서 제조된 나노여과막은 두께 3.20 μm의 얇은 선택층을 형성하여 높은 수투 과도(12.9 LMH/bar)와 우수한 제거 성능(PPG 1050 Da 제거율 60%, PEG 1500 Da 제거율 90%, MgCl2 제거율 80%)을 나타 냈다. 반면, 1:2 혼합비에서는 선택층 두께가 10.2 μm로 증가하였으나, 기공 크기가 증가하여 3400 Da MWCO와 64% 염 제 거율을 보였다. HPC 고분자를 활용한 점도 제어는 졸-겔 코팅층의 두께, 기공 구조 및 분리 성능을 효과적으로 조절할 수 있 음을 입증하였다.
The development of high specific surface area and mesoporous activated carbons is required to improve the electrochemical performance of EDLC. In this study, kenaf-derived activated carbons (PK-AC) were prepared for high-power-density EDLC via phosphoric acid stabilization and steam activation. The pyrolysis behavior of kenaf with respect to the phosphoric acid stabilization conditions were examined via TGA and DTG. The textural properties of PK-AC were studied with N2/ 77 K adsorption–desorption isotherms. In addition, the crystalline structure of PK-AC was observed via X-ray diffraction. The specific surface area and mesopore volume ratio of PK-AC were determined to be 1570–2400 m2/ g and 7.7–44.5%, respectively. In addition, PK-AC was observed to have a high specific surface area and mesopore volume ratio than commercial coconut-derived activated carbon (YP-50F). The specific capacitance of PK-AC was increased from 77.0–99.5 F/g (at 0.1 A/g) to 49.3–88.9 F/g (at 10.0 A/g) with activation time increased. In particular, K-P-15-H-9–10 observed an approximately 35% improvement in specific capacitance at a higher current density of 10.0 A/g compared to YP-50F. As a result, the phosphoric acid stabilization method was confirmed to be an efficient process for the preparation of high specific surface area and mesoporous biomass-derived activated carbons, and the kenaf-derived activated carbons prepared by this process have great potential for application as electrode active materials in high-power EDLC.
This study developed a coupled fluid-thermal analysis method for a liquid hydrogen control valve system. Using ANSYS CFX, a transient CFD analysis was performed for the control valve system, including MLI, and the thermal analysis was linked to evaluate the insulation performance of MLI. The analysis examined the pressure distribution, turbulent viscosity, and heat flux at the inlet and outlet, revealing that the highest heat flux occurred in MLI 2. This research is expected to contribute to improving the thermal shielding performance and efficient insulation design of liquid hydrogen storage systems.
This study examined the quality characteristics of rice layer cakes prepared using various levels of allulose (ALL). ALL was used to substitute 0% (control group), 25% (ALL-25 group), 50% (ALL-50 group), 75% (ALL-75 group) and 100% (ALL- 100 group) of white sugar (WS) in the manufacture of rice layer cake. The substitution of WS with ALL decreased the pH of the cake batter but increased its specific gravity (p<0.001). The ALL-100 group exhibited higher moisture content than the control (p<0.05), and baking loss increased with increasing ALL levels (p<0.01). The volume index of the cake decreased significantly as the proportion of ALL increased (p<0.001). Low lightness, high redness, and high yellowness were observed in the experimental groups at higher proportions of ALL (p<0.001). The ALL-100 group exhibited significantly higher hardness, adhesiveness, cohesiveness, springiness, gumminess, and chewiness than the other groups (p<0.05). Sensory evaluation revealed that cakes with higher ALL levels had stronger perceived intensity with respect to “color,” “sweet aroma,” and “salty taste.” The acceptance test indicated that the ALL-25 group was comparable to or more acceptable than the control in all attributes except for color.
Marine biomass (MB) offers an environmentally friendly and readily available carbon source from the ocean. However, the high concentration of alkali and alkaline earth metals (AAEMs) in MB typically reduces the carbon yield and inhibits micropore formation during heat treatment due to catalytic gasification. In this study, we successfully synthesized activated carbon (AC) with a high specific surface area (> 1,500 m2/ g) and significant mesopore content (60%, mean pore size: 3.4 nm) from MB by employing preheating, controlled acid purification, and CO₂ activation. The formation of mesopores in the MB-derived AC was driven by catalytic gasification induced by intrinsic and residual AAEMs during preheating and physical activation processes. We evaluated the potential of the MB-derived AC as an electrode material for electric doublelayer capacitors (EDLCs). The material demonstrated high specific capacitance values of 25.9 F/g and 29.4 F/g at 2.7 V and 3.3 V, respectively, during charge–discharge cycles. These high capacitance values at elevated voltages were attributed to the increased number of solvated ions (e.g., 1.93 mmol/g at 3.3 V) present in the mesopores. Fluorine-19 nuclear magnetic resonance (19F solid-state NMR) analysis revealed a substantial increase in solvated ion concentration within the mesopores of the MB-derived AC electrode at 3.3 V, demonstrating enhanced ion mobility and diffusion. These findings highlight the potential of MB-derived AC as a promising electrode material for high-voltage energy storage applications.
Efforts to mass-produce high-quality graphene sheets are crucial for advancing its practical and industrial applications across various fields. In this study, we present an innovative electrochemical exfoliation method designed to enhance graphene quality and increase yield. Our approach combines two key techniques: expanding the tightly packed graphite interlayer used as the electrode medium and precisely controlling voltage polarity. The dual-exfoliation technique optimizes the use of anions and cations of varying sizes in the electrolyte to facilitate meticulous intercalation, allowing ions to penetrate deeply and evenly into the graphite interlayer. The newly designed dual-exfoliation technique using biased switching polarity minimizes the generation of oxygen-containing radicals, while the incorporation of expanded graphite accelerates exfoliation speed and reduces oxidation, maintaining high graphene purity. With these improvements, we produced 1–3 layer graphene sheets with minimal defects ( ID/IG ≈ 0.13) and high purity (C/O ratio ≈ 20.51), achieving a yield 3.1 times larger than previously reported methods. The graphene sheets also demonstrated excellent electrochemical properties in a three-electrode system, with an electrical conductivity of 92.6 S cm− 1, a specific capacitance of 207.4 F g− 1, and a retention of 94.8% after 5,000 charge/discharge cycles, highlighting their superior stability and performance.
Area-selective atomic layer deposition (AS-ALD) is a bottom-up process that selectively deposits thin films onto specific areas of a wafer surface. The surface reactions of AS-ALD are controlled by blocking the adsorption of precursors using inhibitors such as self-assembled monolayers (SAMs) or small molecule inhibitors. To increase selectivity during the AS-ALD process, the design of both the inhibitor and the precursor is crucial. Both inhibitors and precursors vary in reactivity and size, and surface reactions are blocked through interactions between precursor molecules and surface functional groups. However, challenges in the conventional SAM-based AS-ALD method include thermal instability and potential damage to substrates during the removal of residual SAMs after the process. To address these issues, recent studies have proposed alternative inhibitors and process design strategies.