For the spent fuel modeling, the plastic model of the cladding used in FRAPCON uses the σ􀷥 = K􀟝̃􀯡 􁉂 􀰌􁈶 􀬵􀬴􀰷􀰯􁉃 􀯠 format. Strength coefficient (K), strain hardening exponent (n), strain rate sensitivity constant (m) are derived as the function of temperature. The coefficient m related to the strain rate shows dependence on the strain rate only in the α-β phase transition section, 1,172.5~1,255 K. But this is the analysis range of the FRAPTRAN code, which is an accident condition nuclear fuel behavior evaluation code. It does not apply to evaluate spent fuel. This coefficient in FRAPCON is used as a constant value (0.015) below 750 K (476.85°C), and at a temperature above 750 K, it is assumed that it is linearly proportional to the temperature without considering the strain rate dependence, also. In order to confirm the effect of strain rate, multiple test data performed under various conditions are required. However, since the strain rate dependence is not critical and test specimen limitation in the case of spent fuel, it is needed to replace with a new plastic model that does not include the strain rate term. In the new plastic model, the basic form of the Ramberg-Osgood equation (RO equation) is the same as ε􀷤 = 􀰙􀷥 􀮾 + 􀜭􀯥 􁉀􀰙􀷥 􀮾􁉁 􀯡􀳝. If the new variable α is defined as α = 􀜭􀯥􁈺􀟪􀯢/􀜧􁈻􀯡􀳝􀬿􀬵, this equation can be transformed into ε􀷤 = 􀰙􀷥 􀮾 + 􀟙 􀰙􀷥 􀮾 􁉀 􀰙􀷥 􀰙􀰬 􁉁 􀯡􀳝􀬿􀬵 . The procedure for expressing the stress-strain curve of the cladding with the RO equation is as follows. First, convert the engineering stress-strain into true stress-strain. Second, using a data analysis program such as EXCEL or ORIGIN, obtain the slope of the linear trend-line on the linear part and use it as the elastic modulus. Third, using the 0.2% offset method, find the yield point and the yield stress. Finally, using the solver function of EXCEL, find the optimal values of α and 􀝊􀯥 that minimize the sum of errors. The applicability of the suggested RO equation was evaluated using the results of the Zircaloy-4 plate room temperature tensile test performed by the KAERI and the Zircaloy cladding uniaxial tensile test results presented in the PNNL report. Through this, the RO equation was able to express the tensile test results within the uncertainty range of ±0.005. In this paper, the RO equation is suggested as a new plastic model with limited test data due to the test specimen limitation of spent fuel and its applicability is confirmed.

For the decommissioning or continuous long-term power generation of nuclear power plants, it is necessary to transfer the spent nuclear fuel from the wet storage pool to the dry storage. Spent nuclear fuel should go through the drying process, which is the first step of dry storage. The most important part in the drying process is the removal of the residual water. The spent fuel might be stored in a dry storage system for a long time. The integrity of internal components and spent fuel cladding should be maintained during the storage period. If residual water is present, problems such as aging of metal materials, oxidation of cladding, and the hydride-reorientation could occur. The presence or absence of residual water after vacuum drying is evaluated by pressure. If there is residual water in the vacuum drying process, it evaporates easily at low pressure to form water vapor pressure and the internal pressure rises. In the recent EPRI High burn up demonstration test, the gas inside the canister that satisfied the dryness criteria was extracted and analyzed. It showed that the water content was higher than the expected value. We are conducting verification studies on the pressure evaluation method, which is an indirect evaluation method of vacuum drying. The vacuum drying test was performed on small specimens at Sandia National Laboratory, and quantitative residual water evaluation was also performed. The report did not mention a detailed method for the assessment of residual water. Based on the test results of SNL, direct residual water evaluation was performed using energy balance. If the dryness criteria were satisfied, the quantitative amount of residual water was also evaluated. As a result, almost the same result as the evaluation result of SNL was derived, and it was confirmed that most of the water was removed when the dryness criteria was satisfied.

Due to the saturation of the on-site storage capacity of spent nuclear fuel within a few years, dry storage facility should be introduced. However, it is unclear when to start operating the dry storage facility, so in case of Kori Unit 1, which is being decommissioning, the spent fuel must be stored in the spent fuel pool of another power plant. In addition, in the case of damaged fuel, it is impossible to transfer and store it with general handling methods. Therefore, a damaged fuel canister (DFC) should be able to handle damaged or failed fuel as intact fuel, and both wet and dry storage should be possible. The canister developed by Korea Hydro & Nuclear Power is designed to satisfy criticality, shielding, cooling performance, and structural integrity in accordance with NUREG-1536 and 2215. In addition, it can be handled as existing fuel handling devices rather than new handling tools. Fastening of the DFC lid and body in the spent fuel pool is possible with a hexagonal socket wrench, one of the fuel repair tools. And it is designed to facilitate visual identification of whether it is fastenedor not. The lifting method for transferring DFC to another facility is the same as the nuclear fuel lifting method. And a unique sealing and mesh structure of the lid and body is devised to completely block leakage of nuclear fuel fragments of 0.2 mm or more during vacuum drying for dry storage. The usability of DFC has been verified through test operation of the prototype, and it will be manufactured before discharging spent fuel for the decommissioning of Kori Unit 1.

During electrorefining, fission products, such as Sr and Cs, accumulate in a eutectic LiCl-KCl molten salt and degrade the efficiency of the separation process by generating high heat and decreasing uranium capture. Thus, the removal of the fission products from the molten salt bath is essential for reusing the bath, thereby reducing the additional nuclear waste. While many studies focus on techniques for selective separation of fission products, there are few studies on processing monitoring of those techniques. In-situ monitoring can be used to evaluate separation techniques and determine the integrity of the bath. In this study, laser-induced breakdown spectroscopy (LIBS) was selected as the monitoring technique to measure concentrations of Sr and Cs in 550°C LiCl-KCl molten salt. A laser spectroscopic setup for analyzing high-temperature molten salts in an inert atmosphere was established by coupling an optical path with a glove box. An air blower was installed between the sample and lenses to avoid liquid splashes on surrounding optical products caused by laser-liquid interaction. Before LIBS measurements, experimental parameters such as laser pulse energy, delay time, and gate width were optimized for each element to get the highest signal-to-noise ratio of characteristic elemental peaks. LIBS spectra were recorded with the optimized conditions from LiCl-KCl samples, including individual elements in a wide concentration range. Then, the limit of detections (LODs) for Sr and Cs were calculated using calibration curves, which have high linearity with low errors. In addition to the univariate analysis, partial least-squares regression (PLSR) was employed on the data plots to obtain calibration models for better quantitative analysis. The developed models show high performances with the regression coefficient R2 close to one and root-mean-square error close to zero. After the individual element analysis, the same process was performed on samples where Sr and Cs were dissolved in molten salt simultaneously. The results also show low-ppm LODs and an excellent fitted regression model. This study illustrates the feasibility of applying LIBS to process monitoring in pyroprocessing to minimize nuclear waste. Furthermore, this high-sensitive spectroscopic system is expected to be used for coolant monitoring in advanced reactors such as molten salt reactors.

Some Spent Fuel Pools (SFPs) will be full of Spent Nuclear Fuels (SNFs) within several years. Because of this reason, building interim storage facilities or permanent disposal facilities should be considered. These storage facilities are divided into wet storage facilities and dry storage facilities. Wet storage facility is a method of storing SNF in SFP to cool decay heat and shielding radiation, and dry storage facility is a method of storing SNF in a cask and placing on the ground or storage building. However, wet storage facilities have disadvantages in that operating costs are higher than that of dry storage facilities, and additional capacity expansion is difficult. Dry storage facilities have relatively low operating costs and are relatively easy to increase capacity when additional SNFs need to be stored. For this reason, since the 1990s, the number of cases of applying dry storage facilities has been increasing even abroad. Dry storage facilities are divided into indoor storage facilities and outdoor storage facilities, and outdoor storage facilities are mostly used to take advantage of dry storage facilities. In the case of outdoor storage facilities, the cask in which SNFs are stored is placed on a designed concrete pad. During this storage, the boring heat generated by SNFs cools into natural convection and the cask shields the radiation that SNFs generates. However, if an accident such as an earthquake occurs and the cask overturns during storage, there may be a risk of radiation leakage. Such a tip-over accident may be caused by the cask slipping due to the vibration of an earthquake, or by not supporting the cask properly due to a problem in the concrete pad. Therefore, in the case of outdoor dry storage facilities, it is necessary to evaluate the seismic safety of concrete pads. In this paper, various soil conditions were applied in the seismic analysis. Soil conditions were classified according to the shear wave velocity, and the shear wave velocity was classified according to the ground classification criteria according to the general seismic design (KDS 17 10 00). The concrete pad was designed with a size that 8 casks can be arranged at regular intervals, and 11# reinforcing bars were used for the design of the internal reinforcement of the concrete pad according to literature research. The cask was designed as a rigid body to shorten the analysis time. The soil to which the elastic model was applied was designed under the concrete pad, and infinite elements were applied to the sides and bottom of the soil. The effect on the concrete pad and cask by applying a seismic wave conforming to RG 1.60 to the bottom of the soil was analyzed with a finite element model.

In the design of a spent-fuel (SF) storage, the consideration of burnup credit brings the benefits in safety and economic views. According to it, various SF burnup measurement systems have been developed to estimate high fidelity burnup credit, such as FORK and SMOPY. Recently, there are a few attempts to localize the SF burnup measurement system in South Korea. For the localization of SF burnup measurement systems, it is very important to build the isotope inventory data base (DB) of various kinds of SFs. In this study, we performed DeCART2D/MASTER core follow calculations and McCARD single fuel assembly (FA) burnup analyses for Hanbit unit 3 and confirmed the characteristic of the isotope inventory over burnup. Firstly, the core follow calculations for Cycles 1~7 were performed using DeCART2D/MASTER code system. The core follow calculation is very realistic and practical because it considers the design conditions from its nuclear design report (NDR). Secondly, the Monte Carlo burnup analyses for single FAs were conducted by the McCARD Monte Carlo (MC) transport code. The McCARD code can utilize continuous energy cross section library and treat complex geometric information for particle transport simulation. Accordingly, the McCARD code can provide accurate solutions for burnup analyses without approximations, but it needs huge computing resources and time burden to perform whole-core follow calculations. Therefore, we will confirm the effectiveness of the single McCARD FA burnup analyses by comparing the DeCART2D/MASTER core follow results with the McCARD solution. From the results, the use of single FA burnup analyses for the establishment of the DBs will be justified. Various FAs, that have different 235U enrichments and loading pattern of fuel rods and burnable absorbers, were considered for the burnup analyses. In addition, the results of the sensitivity analyses for power density, initial enrichment, and cooling time will be presented.

This study is to investigate fuel cladding temperature in a transport system for the purpose of developing a methodology for evaluating the thermal performance of spent fuel. Detailed temperature analysis in the transport system is important because the degradation mechanism of the fuel cladding is generally sensitive to temperature and temperature history. In such a system, the magnitude of the temperature change is determined by examining the temperature sensitivity of fuel assemblies and system components including fuel cladding temperature, considering the material properties, component specifications, component aging mechanism, and heat transfer mechanism. The sensitivity analysis is performed using heat transfer models by computational fluid dynamics for the horizontal transport system. The heat transfer within the system by convection, conduction and thermal radiation is calculated by thermal-hydraulic analysis code FLUENT. The calculation region is divided into a basket cell and a transport cask. The thermal analysis of the basket cell is for predicting the fuel cladding temperature. And the reason for analyzing the transport cask is to provide the boundary condition for the basket cell by reflecting the external environmental conditions. Here, the basket cell containing the spent fuel assembly is modeled on the homogeneous effective thermal conductivity. The purpose of this analysis is to evaluate fuel cladding temperatures for the following four main items. That is the effect of surface emissivity changes in basket due to the oxide layer of the fuel cladding, the effect of degradation of the canister backfill helium gas, the effect of fuel assembly position in basket cell on fuel cladding and basket temperatures in canister, and the effect of using the homogeneous effective thermal conductivity model instead of the fuel assembly in basket cell. As a result of the analysis, the maximum temperatures in basket cells are evaluated for the above four items. Thermal margins for each item are investigated for thermal performance requirements (e.g., peak clad temperature below 400oC).

The Korea Atomic Energy Research Institute is developing a nuclide management process that separates high heat, high mobility, and long half-life nuclides that burden the disposal of spent fuel, and disposes of spent fuel by nuclide according to the characteristics of each nuclide. Various offgases (volatile and semi-volatile nuclides) generated in this process must be discharged to the atmosphere below the emission standard, so an off-gas trapping system is required. In this study, we introduce the analysis results of the parameters that affect the design of the off-gas trapping system. The analyzed contents are as follows. The physical quantities of the Cs, Tc/se, and I trapping filters according to the amount of spent nuclear fuel, the maximum exothermic temperature of the Cs trapping filter and the absorbed dose by distance by Cs radioactivity were analyzed according to the amount of spent nuclear fuel. In addition, a three-dimensional CFD (Computational Fluid Dynamics) analysis was performed according to operating parameters by simply modeling the off-gas trapping system, which is easy to modify mechanical design parameters. It is considered that the analysis results will greatly contribute to the development of the off-gas trapping system design requirements.

The purpose of this study is to provide lessons learned in the experience of improvement work of fuel handling equipment at operating nuclear power plants. The upgrade of fuel handling equipment for safety enhancement and performance improvement has been going on for 15 years since the early 2000’s. The main goal is to increase fuel loading/unloading capability of the equipment from about 2.5 fuel assemblies per hour to more than six (6). It is achieved with sequential operations of three (3) fuel handling equipment, which consists of the refueling machine, the fuel transfer system and the spent fuel handling machine. The scope of the upgrade for fuel handling equipment is summarized as follows. The PC data control system based on PLC for interlocks and high speed motor drive system is introduced for better operating efficiency. The motors and drives for bridge, trolley, and hoist are replaced with AC servomotors and drivers, respectively. The fuel transfer system has an auto-initiation feature operating from the refueling machine or the spent fuel handling machine. The winch motor and drive for the carriage of fuel transfer system is also replaced with AC servomotors and drivers. And some of HPU (hydraulic power units) equipment for each building (reactor containment building and fuel handling building) are replaced to improve their function. The considerations for improvement of fuel handling equipment are as belows. 1) Fuel handling should be consistent with the instructions provided by the fuel designer and/or manufacturer, which are for Standard type fuel and Westinghouse type fuel, used in domestic nuclear power plants. Each fuel has unique design characteristics, which are PLC setpoints for overload and underload, slow speed zones for a bridge, trolley and hoist, allowable acceleration/deceleration value in handling, hoist elevation and manual speed in off-index operation at reactor. 2) The interlock system should be designed in accordance with design criteria specified by the utilities of nuclear power plant. 3) Performance should be improved according to the operating characteristics of the fuel handling equipment. High-speed and optimization of FTS upender and carriage are essential for operating performance so that its modification should be considered first. And the low speed and range in the operation mechanism of the hoist should be designed to comply with guidelines. 4) The accident analysis through self-diagnosis function and operation history in modification at domestic operating nuclear power plants would be good lessons learned. It is advisable to utilize such various information as it can help to improve reliability of nuclear fuel handling operation and power plant operation rate.

As the amount of on-site Spent Nuclear Fuel (SNF) in storage increases due to the continued operation of Nuclear Power Plants (NPPs) in Korea, the on-site wet storage pool is expected to become saturated. Therefore, a facility for safely storing the spent nuclear fuel is required so that there is no problem with operation of the NPP until permanent disposal of SNF. Prior to the construction of such a facility, the safety analysis of the interim storage facility and verification of the safety of the spent fuel storage system (e.g. cask, silo) to be used are required according to Article 63 of the Nuclear Safety Act. In this process, analysis of the Structures, Systems, and Components (SSCs) of the storage system is needed. Based on the analysis, it is necessary to efficiently classify SSCs that are important to safety in order to differentiate management that more thoroughly manages those important to safety. In Korea, according to the notice of the Nuclear Safety and Security Commission, the components performing essential safety functions for the safe storage of spent fuel storage system are to be classified as “important safety equipment”. 10 CFR Part 72, a federal regulation related to interim storage facilities in the United States, also requires the identification of SSCs that fall under “Important to Safety (ITS)”, which is like domestic case. In addition, it has been confirmed that there are cases in which detailed classification according to Reg Guide 7.10 and NUREG-CR/6407 is added in Safety Analysis Report. However, these existing classification methods are not only classified as a single grade except for the method according to the Reg guide, but all are classified according to a qualitative standard. Qualitative criteria may cause ambiguity in judgment, resulting in subjective judgment of the person who proceeds in the classification process. Therefore, in this study, a new classification method is proposed to solve the problem according to the qualitative classification method. Assessing the level of radiological harm to the general public due to the assumption of failure of SSC in the spent fuel storage system is used as a quantitative evaluation standard.

Under the circumstance of energy transition policy of the previous government in which nuclear energy portion will be gradually reduced, some R&D study looking for alternatives other than Pyro- SFR recycling could be very valuable and timely suitable. New alternative study started to evaluate the possibility of it if there are some advantages in terms of waste burden in case that the spent fuel are appropriately treated and disposed of in a disposal site, instead of recycling of spent nuclear fuels (SNF). The alternative study separate the fission products (minor actinides and rare earths) from SNF in a molten salt medium. The molten salt coming from the alternative study is radioactive and heat generating because it contains the fission products chlorides. It is necessary to collect the fission products from the waste molten salt for minimization of the high-level waste volume and to generate a final waste form containing the fission products compatible to the disposal site. Based on the results of a review for various precipitation methods, phosphorylation (phosphate precipitation) of metal chlorides selected as a proper treatment method for recovering of the fission products in a molten salt. Phosphate precipitation has the potential for removing most of fission product elements from a molten salt arising from the treatment of spent nuclear fuel. The performance of phosphate precipitation method evaluated using a salt mixture with the actinide and rare earth chlorides. The molten salt containing uranium as surrogate of the actinides and three rare earths (Nd, Ce, La) chloride was used for testing a phosphate precipitation method at experimental condition (temperature 500°C, salt stirring 200~300 rpm, and 1~1.2 eq. of phosphorylation agent). A cyclic voltammetry (CV) method monitored in-situ phosphate precipitation progress for determining the precipitation rate and conversion ratio evaluated. The phosphorylation reaction increased greatly at a salt stirring 300 rpm.

Based on the results of a review for various precipitation methods phosphorylation (phosphate precipitation) of metal chlorides considered as a proper treatment method for recovering of the fission products in a molten salt. In previous precipitation tests, the powder of lithium phosphate (Li3PO4) added into LiCl-KCl molten salt containing metal chlorides as a precipitation agent. The reaction of metal chlorides containing actinides and rare earths to recover with lithium phosphate in a molten salt known as solid-liquid reaction. The powder of lithium phosphate disperse in a molten salt by stirring thoroughly in order to enhance the precipitation reaction. As a result, metal phosphates as the reaction products precipitate on the bottom of the vessel and cutting at the lower part of the salt ingot considered as one of the recovery method of the precipitates. Recently, the vacuum distillation of upper part of the salt proposed as another recovering method. Cutting method of precipitate at the lower part of the salt ingot would be difficult to handle the increased size of the salt ingot produced from the practical scale equipment. In this presentation, a new method for collecting the precipitates of phosphorylation reaction into a small vessel is introduced with test results in a molten salt containing uranium and rare earths such as Nd, Ce, and La. As the first step of a series of test lithium phosphate ingot was prepared by melting the powder at a temperature 1,300°C, and the ingot put into LiCl-KCl molten salt at 500°C for more than three hours to examine the shape of ingot to be deformed or not. The phosphorylation experiments using lithium phosphate ingots carried out to collect the metal phosphate precipitates and the test result of this new method was feasible.

In case a spent nuclear fuel transport cask is lost in the sea due to an accident during maritime transport, it is necessary to evaluate the critical depth by which the pressure resistance of the cask is maintained. A licensed type B package should maintain the integrity of containment boundary under water up to 200 m of depth. However, if the cask is damaged during accidents of severity excessing those of design basis accidents, or it is submerged in a sea deeper than 200 m, detailed analyses should be performed to evaluated the condition of the cask and possible scenarios for the release of radioactive contents contained in the cask. In this work, models to evaluate pressure resistance of an undamaged cask in the deep sea are developed and coded into a computer module. To ensure the reliability of the models and to maintain enough flexibility to account for a variety of input conditions, models in three different fidelities are utilized. A very sophisticated finite element analysis model is constructed to provide accurate response of containment boundary against external pressure. A simplified finite element model which can be easily generated with parameters derived from the dimensions and material properties of the cask. Lastly, mathematical formulas based on the shell theory are utilized to evaluate the stress and strain of cask body, lid and the bolts. The models in mathematical formula will be coded into computer model once they show good agreement with the other two model with much higher fidelity. The evaluation of the cask was largely divided into the lid, body, and bottom, bolts of the cask. It was confirmed that the internal stress of the cask was increased in accordance with the hydrostatic pressure. In particular, the lid and bottom have a circular plate shape and showed a similar deformation pattern with deflection at the center. The maximum stress occurred where the lid was in the center and the bottom was in contact with the body. Because the body was simplified and evaluated as a cylinder, only simple compression without torsion and bending was observed. The maximum stress occurred in the tangential direction from the inner side of the cylinder. The bolt connecting the lid and the body was subjected to both bending and tension at the same time, and the maximum stress was evaluated considering both tension and bending loads. In general, the results calculated by the formulas were evaluated to have higher maximum stresses than the analysis results of the simplified model. The results of the maximum stress evaluation in this study confirms that the mathematical models provide conservative results than the finite element models and can be used in the computer module.

Considering the domestic condition with small land area and high population density, it is necessary to develop technology that can reduce the disposal area than the deep geological disposal method. For this, KAERI is developing a nuclide management process that can reduce the environmental burden of spent fuel, and establishing an evaluation model that can evaluate the performance of various process options. It is expected that an optimal option of the nuclide management process can be derived from disposal perspective by applying the evaluation model. The mass flow between processing steps of the radionuclide management process is the basic quantity required to quantify the evaluation criteria. Therefore, we built a generalized block model on GoldSim, which can simulate mass flow of various radionuclide management process options. In addition to the mass flow, this model was established to derive the amount of wastes generated by each processing step, the composition of nuclides, and radiological properties (decay heat, radioactivity, etc.). The mass flow and waste property derived from the models are closely related to the factors that determine the area of disposal concepts. Based on this, a disposal area calculation model was established as a model to evaluate the effectiveness of the radionuclide management process on environmental burden reduction. For verification, three process options, which can manage radionuclides having high decay heat (Cs, Sr) or large volume (U), were selected and evaluated as reference processes. And two disposal options, deep geological disposal and deep borehole disposal concepts were considered to be linked with the processes. As a result, it was confirmed that the disposal area could be reduced in the process separating radionuclides having high decay heat. In the future, other evaluation models for economic viability and safety will be added in the GoldSim model.

As an alternative technology for the efficient disposal of spent nuclear fuel, various process flows can be selected based on the recovered and separated radioactive nuclide group. This is to examine the efficiency of the disposal area of spent nuclear fuel when various disposal technologies and several treatment processes are applied to spent nuclear fuel, compared to the deep geological disposal of burying the entire spent fuel in the ground. Above all, the biggest advantage of the optional treatment processes is that it can be applied to various disposal methods (deep borehole disposal, deep geological disposal) because it can process spent fuel in various sizes and separate into some groups according to the properties of radionuclides. These optional processes are not new technology and currently available as of today, and the level is classified based on the stepwise separation of high heat emission nuclides and long half-life nuclides. This is to increase the efficiency of the disposal of spent nuclear fuel by separating and managing high-risk radionuclides separately. Relatively various optional processes are possible depending on the level, and characteristic analysis is performed on wastes treated with alternative technologies. The mass balance for each option process is completed, and the amount of waste is also calculated accordingly. These are used as basic data for waste disposal area and economic evaluation. Besides it is easy to process spent fuel of various sizes suitable for deep geological disposal or deep borehole disposal technology when an optional treatment technology is applied to spent fuel. However, since this selective process is based on the process structure constructed in a broad framework, it is considered that additional follow-up studies are needed not only on detailed technology but also on the flow and amount of waste.

The saturation rates of the spent fuel (SF) wet storage at the Kori Nuclear Power Plant (NPP), Hanbit, and Hanul are 83.3%, 74.2%, and 80.8% as of the fourth quarter of 2021. The storages of Kori NPP and Hanbit NPP are expected to be saturated in 2031, and Hanul is expected to be saturated in 2032. Therefore, the construction of an interim storage facility to store the SF temporarily stored in the NPP was planned, and preparations for the safe transport of the SF are required. In this paper, radiological preliminary assessment using NRC-RADTRAN in the process of sea transport of SF from the wet storage or ISFSI of the Hanbit NPP to the optional interim storage facility was performed. Since domestic SF transport vessels are not currently in operation, the specifications of the UK Pacific Grebe vessel which can carry up to 20 casks were used. The transport cask used the specifications of KORAD-21, a transport container developed in Korea. Because it can carry more SF assemblies than the existing KN-18. In addition, a land transport safety test was conducted in 2020 and a sea transport test is planned. The sea transport route was entered by referring to the transport route of domestic low and intermediate level waste. The accidents rate was calculated using statistics on maritime accidents from 2017 to 2021. The probability accidents along the transportation route were evaluated as 3.152E -10. When transporting to an interim storage facility, the SF expected to be the main transport target was selected as WH 17X17, combustion 45,000 MWD/MTU, and concentration of 4.5%. The source term was calculated and entered according to this data and the release fraction was entered with reference to the DOE report. In the case of normal transport without accident, the individual dose of the crew member and public residents were estimated to be 0.0525% and 0.000492% of the annual limit of 1 mSv/yr for the general public. Under the accident conditions, the annual individual doses of residents were 0.0011%, 0.0023%, 0.0034%, and 0.0046% of the annual limit of 1 mSv/yr when carrying 5, 10, 15, and 20 casks. Currently, the site of the interim storage facility has not been precisely determined, but a preliminary radiation assessment through sea transport resulted in a significantly lower than the limit. Combined scenario sea transport followed by land transport will be carried out in the next stage of study.

In Korea, borated stainless steel (BSS) is used as spent fuel pool (SFP) storage rack to maintain nuclear criticality of spent fuels. As number of nuclear power plants and corresponding number of spent fuels increased, density in SFP storage rack also increased. In this regard, maintain subcriticality of spent nuclear fuels was raised as an issue and BSS was selected as structural material and neutron absorber for high density storage rack. Because it is difficult to replace storage rack, corrosion resistance and neutron absorbency are required for long period. BSS is based on stainless steel 304 and it is specified in the ASTM A887-89 standard depending on the boron concentration from 304B (0.20-0.29% B) to 304B7 (1.75-2.25% B). Due to low solubility of boron in austenitic stainless steel, metallic borides such as (Fe, Cr)2B are formed as secondary phase metallic borides could make Cr depletion near it which could decrease the corrosion resistance of material. In this paper, long-term corrosion behavior of BSS and its oxide microstructures are investigated through accelerated corrosion experiment in simulated SFP condition. Because corrosion rate of austenitic stainless steel is known to be dependent on the Arrhenius equation, a function of temperature, corrosion experiment is conducted by increasing the experimental temperature. Detail microstructural analysis was conducted with scanning electron microscope, transmission electron microscope and energy dispersive spectrometer. After oxidation, hematite structure oxide film is formed and pitting corrosions occur on the surface of specimens. Most of pitting corrosions are found at the substrate surface because corrosion resistance of substrate, which has low Cr content, is relatively low. Also, oxidation reaction of B in the secondary phase has the lowest Gibbs free energy compared to other elements. Furthermore, oxidation of Cr has low Gibbs free energy which means that oxidation of B and Cr could be faster than other elements. Thus, the long-term corrosion might affect to boron content and the neutron absorption ability of the material.

Radiation dose rates for spent fuel storage casks and storage facilities of them are typically calculated using Monte Carlo calculation codes. In particular, Monte Carlo computer code has the advantage of being able to analyze radiation transport very similar to the actual situation and accurately simulate complex structures. However, to evaluate the radiation dose rate for models such as ISFSI (Independent Spent Fuel Storage Installation) with a lot of spent fuel storage casks using Monte Carlo computational techniques has a disadvantage that it takes considerable computational time. This is because the radiation dose rate from the cask located at the outermost part of the storage facility to hundreds of meters must be calculated. In addition, if a building is considered in addition to many storage casks, more analysis time is required. Therefore, it is necessary to improve the efficiency of the computational techniques in order to evaluate the radiation dose rate for the ISFSI using Monte Carlo computational codes. The radiation dose rate evaluation of storage facilities using evaluation techniques for improving calculation efficiency is performed in the following steps. (1) simplified change in detailed analysis model for single storage cask, (2) create source term for the outermost side and top surface of the storage cask, (3) full modeling for storage facilities using casks with surface sources, (4) evaluation of radiation dose rate by distance corresponding to the dose rate limit. Using this calculation method, the dose rate according to the distance was evaluated by assuming that the concrete storage cask (KORAD21C) and the horizontal storage module (NUHOMS-HSM) were stored in the storage facility. As a result of calculation, the distance to boundary of the radiation control area and restricted area of the storage facility is respectively 75 m / 530 m (KORAD21C case), and 20 m / 350 m (NUHOMS-HSM case).

Spent nuclear fuels in Korea are temporarily stored at the nuclear power plant site and it is expected that will become saturated from 2031. Deep geological disposal in engineered barrier system (EBS) is one of the most important options for disposing spent nuclear fuel. The disposal canister is the first barrier that prevents leakage of nuclides in the spent nuclear fuel to the environment. Therefore, the corrosion behavior of the canister materials are significant factors in determining the overall disposal period. Oxygen-free copper is the most widely used material for disposal canisters, and manufacturing methods include forging, cold spray, and electro-deposition. In this study, corrosion behavior of materials that have the potential to replace oxygen-free copper manufactured using various 3D printing method were analyzed. As a result of electrochemical analysis of various materials such as copper manufactured by the Atmospheric Plasma Spray (APS) process and Inconel 718 manufactured by the Direct Energy Deposition (DED) process, the possibility of replacing oxygen-free copper was confirmed.

Montmorillonite plays a key role in engineered barrier systems in the high-level radioactive waste repository because of its large sorption capacity and high swelling pressure. However, the sorption capacity of montmorillonite can be largely varied dependent on the surrounding environments. This study conducted the batch simulation for U(VI) sorption on Na-montmorillonite by utilizing the cation exchange and surface complexation coupled (2SP-NE-SC/CE) model and evaluated the effects of physicochemical properties (i.e., pH, temperature, competing cations, U(VI) concentration, and carbonate species) on U(VI) sorption. The simulation demonstrated that the U(VI) sorption was affected by physicochemical properties: the pH and temperature relate to aqueous U(VI) speciation, the competing cations relate to the cation exchange process and selectivity, the U(VI) concentration relates to saturation at sorption sites. For example, the Kd (L kg−1) of Na-montmorillonite represented the largest values of 2.7×105 L kg−1 at neutral pH condition and had significantly decreased at acidic pH<3, showing non-linear and diverse U(VI) sorption at the ranged pH from 2 to 11. Additionally, the U(VI) sorption on montmorillonite significantly decreased in presence of carbonate species. The U(VI) sorption for long-term in actual porewater chemistry and temperature of high-level radioactive waste repository represented that the sorption capacity of Na-montmorillonite was affected by various external properties such as concentration of competing cation, temperature, pH, and carbonate species. These results indicate that geochemical sorption capacity of bentonite should be evaluated by considering both geological and aquifer environments in the high-level radioactive waste repository.