In order to optimize the manufacturing of polypropylene-derived few-layer graphene, an innovative utilization of nonsupported iron oxide nanoparticles generated under various fuel environment conditions was studied. Three distinct fuel combustion environment circumstances (fusion, fuel shortage, and fuel excess) produced a variety of Fe2O3 nanoparticles for cost-effective and green graphene deposition. XRD, H2- TPR, Raman, and TGA measurements were used to characterize both new and spent catalysts. Remarkably, the microstructure of the generated Fe2O3 nanoparticles could be controlled by the citric acid/iron nitrate ratio, ranging from spheroids ( Fe2O3(0)) to sheets ( Fe2O3(0.5-0.75)) and a hybrid microstructure that consists of sheets, spheroids, and interconnected strips ( Fe2O3(1-2)). According to fuel situation (citric acid/iron nitrate ratio, Fe2O3( 0-2)), various graphitization level and yields of graphene derivatives including sheets, ribbons, and onions have been developed. With the ideal fuel/oxidant ratio (ɸ = 1), the Fe2O3( 0.75) catalyst demonstrated the best catalytic activity to deposit the largest yield of highly graphitized few graphene layers (280%). Lean and rich fuel conditions (1 > ɸ > 1) have detrimental effects on the amount and quality of graphene deposition. It is interesting to note that in addition to graphene sheets, an excess of citric acid caused the production of metallic cores, hollow, and merged carbon nano-onions, and graphene nano-ribbons. It was suggested that carbon nano-onions be converted into graphene nano-ribbons and semi-onion shell-like graphene layers.

Background: Electrophototherapeutic resources are widely used in the treatment of shoulder injuries, despite some contradictory results. Objects: This scoping review aims to evaluate the existing electrophysical resources associated or not with physical exercise (EX), propose a dosage and to evaluate the methodological quality, for managing pain, range, and muscle strength in patients with subacromial impingement syndrome (SIS). Methods: Randomized clinical trials (RCTs), non-RCTs (NRCTs) and systematic reviews of electrophototherapeutic interventions in people with SIS were included, with no restrictions on age, sex, year or language. The outcomes were pain intensity, range of motion, and muscle strength. The databases searched were PubMed, Scopus, Embase, Cochrane, Web of Science, LILACS, PEDro, Google Scholar, Open Grey, LIVIVO, CAPES Catalogue of Theses and Dissertations, and citation search. The search was carried out on January 26, 2023 and updated on March 5, 2024. The risk of bias of the included studies was assessed individually using the Cochrane risk of bias tools for randomized trials (RoB 2) and for non-randomized trials (ROBINS-I) and the AMSTAR-2 tools for systematic review studies. Results: Twenty studies were included (14 RCTs, one NRCT, and 5 review studies). The electrophototherapeutic resources used were photobiomodulation, high-intensity laser therapy (HILT), laser associated with light-emitting diode, Multiwave Locked System laser, extracorporeal shockwaves (ESWs), low-frequency electrical current stimulation, therapeutic ultrasound and radiotherapy. Ten clinical studies applied EX in their intervention, in addition to electrophototherapeutic resources. Conclusion: Photobiomodulation, HILT and ESWs have been shown to be effective in treating SIS, however, there was great heterogeneity in the quality of the studies included, with some risks of bias. The additional effects of electrophototherapeutic resources to EX for patients at different stages of SIS are still uncertain, and the dosimetric parameters were presented in tables in the text.