In this study we examine variations in the structure of perovskite compounds of LaBa2Cu2O9, LaBa2CaCu3O12 and LaBa2Ca2Cu5O15 synthesized using the solid state reaction method. The samples’ compositions were assessed using X-ray fluorescence (XRF) analysis. The La: Ba: Ca: Cu ratios for samples LaBa2Cu2O9, LaBa2CaCu3O12 and LaBa2Ca2Cu5O15 were found by XRF analysis to be around 1:2:0:2, 1:2:1:3, and 1:2:2:5, respectively. The samples’ well-known structures were then analyzed using X-ray diffraction. The three samples largely consist of phases 1202, 1213, and 1225, with a trace quantity of an unknown secondary phase, based on the intensities and locations of the diffraction peaks. According to the measured parameters a, b, and c, every sample has a tetragonal symmetry structure. Each sample’s mass density was observed to alter as the lead oxide content rose. Scanning electron microscope (SEM) images of the three phases revealed that different Ca-O and Cu-O layers can cause different grain sizes, characterized by elongated thin grains, without a preferred orientation.

This study focuses on how the partial substitution of copper by nickel nanoparticles affects the electrical and structural properties of the Bi2Ba2Ca2Cu2.9Ni0.1O10+δ, Bi2Ba2Ca2Cu2.8Ni0.2O10+δ and Bi2Ba2Ca2Cu2.6Ni0.4O10+δ compounds. Approximate values of crystallization size and crystallization percentage for the three compounds were calculated using the Scherer, modified Scherer, and Williamson-Hall methods. A great similarity was observed in the crystal size values from the Scherer method, 243.442 nm, and the Williamson-Hall method, 243.794 nm for the second sample. At the same time this sample exhibited the highest crystal size value for the three methods. In the examination of electrical properties, the sample with 0.1 partial substitution, Bi2Ba2Ca2Cu2.9Ni0.1O10+δ was determined to be the best with a critical temperature of 100 K and an energy gap of 6.57639 × 10-21 MeV. Using the SEM technique to analyze the structural morphology of the three phases, it was discovered that the size of the granular forms exceeds 25 nm. It was determined that the samples’ shapes alter when nickel concentration rises. The patterns that reveal the distribution of the crystal structure also exhibit clear homogeneity.

목적 : 본 연구는 유발 부등상시에서 양안 시기능, 안구 운동 및 독서 능력을 평가하고자 하였다. 방법 : 양안의 원거리 나안시력이나 교정시력이 1.0 이상이고, 억제가 없는 전체 29명(평균 24.48±3.43세)의 성인을 대상으로 선정하였다. 부등상시 유발은 3% 및 6%의 부등상 교정 렌즈를 각각 가입하였으며, 40 cm에서 수평 및 수직 융합 버전스, 버전스 용이성과 입체시를 측정하였다. 안구 운동 변수와 독서 능력의 측정은 아이트 래커를 사용하였다. 결과 : 3%의 부등상을 유발하였을 때, 융합 버전스, 입체시 및 버전스 용이성에서 유의한 차이가 없었다 (p>0.050). 또한, 안구 운동 및 독서 능력의 모든 변수에서도 유의한 차이가 없었다(p>0.050). 그러나, 6%의 부 등상을 유발했을 때, 양성(BO) 및 음성(BI) 융합 버전스의 흐린점, 분리점 및 회복점에서 유의한 차이가 있었다 (p<0.050). 또한, 수직 융합 버전스의 분리점, 회복점 및 입체시에서도 유의한 차이가 있었다(p<0.050). 하지만 버전스 용이성, 안구 운동 및 독서 능력은 유의한 차이가 없었다(p>0.050). 결론 : 유발된 6%의 부등상은 수평, 수직 융합 버전스 및 입체시를 감소시켰으나, 안구 운동과 독서 능력에는 유의한 영향을 미치지 않았다. 후속 연구에서는 장시간 독서 조건에서 자각적으로 느낄 수 있는 불편함을 포함한 독서 능력의 측정 및 안구 운동 변수와 독서 능력에 유의한 영향을 줄 수 있는 유발 부등상시의 역치를 조사할 필 요가 있을 것으로 판단된다.

본 논문은 베율명（贝律铭）의 건축 업적에 대한 광범위한 탐구를 수행하며, 특히 전통 중국 미학과 현대주의 디자인 원 칙을 통합하는 그의 숙련을 요약하는 쑤저우 박물관 신관에 중 점을 둔다. 베율명（贝律铭）의 작품에 대한 이 철저한 검토는 고대 전통과 현대 혁신을 결혼시키는 그의 디자인 철학의 복잡 성을 풀어낸다. "留白" 개념, 대칭, 재료, 색상 및 정원의 조화 로운 통합의 복잡한 적용으로 특징 지어진 쑤저우 박물관 신관 은 문화 유산이 건축 디자인에서 어떻게 보존되고 현대화 될 수 있는지에 대한 횃불로 서 있다. 본 논문은 또한 베율명（贝 律铭）의 작품 세계의 보다 광범위한 함의와 해석을 분석하며, 문화 보존과 건축 미학의 지속적인 진화에 대한 그것의 깊은 영향을 드러낸다. 본 논문은 문화 의사소통에 대한 그의 기여 에 대해 자세히 설명하고 현대 건축을 위한 통찰력있는 교훈을 제공하며, 역사적 맥락과 현대 해석 사이의 통합 가능성을 강 조한다. 베율명（贝律铭）의 독특한 시각을 통해 쑤저우 박물 관 신관을 탐험함으로써 본 논문은 건축이 문화의 반영이자 혁 신자가 될 수 있는 방법에 대한 우리의 이해를 더해준다. 본 논문은 세계 건축 분야를 계속해서 영감을 주고 형태를 만드는 건축 비전가로서 베율명（贝律铭）의 지속적인 유산을 확증함 으로써 결론을 내린다.

Iron (Fe) is a vital element for plants and other organisms, involving in several physiological processes including respiration, chlorophyll biosynthesis, and photosynthesis. Unfortunately, how Fe accumulation regulates in response to light quality has not been well established in plants. Therefore, the aim of the study was to explore the mechanism of Fe homeostasis by light quality. In this study, we found morpho-physiological attributes were significantly improved in response to blue (λmax: 450) compared to white (λ max: 500) and red (λmax: 660) light. The root-shoot length, plant biomass, photosynthesis efficiency (Fv/Fm) and leafgreen (SPAD) significantly declined in response to white and red light. However, these parameters were improved and iron deficiency was substantially alleviated by blue light exposure in alfalfa seedlings. This study might be useful to the forage breeders and farmers for improving alfalfa yield and nutritional benefits.

Silicon (Si) has the potential to improve plant growth and stress tolerance. The study aimed to explore Si-involving plant responses and molecular characterization of different Si-responsive genes in alfalfa. In this study, the exogenous supplementation of Si enhanced plant growth, and biomass yield. Si-acquisition in alfalfa root and shoot was higher in Si-supplemented compared to silicon deficient (-Si) plants, implying Si-acquisition has beneficial on alfalfa plants. As a consequence, the quantum efficiency of photosystem II (Fv/Fm) was significantly increased in silicon-sufficient (+Si) plants. The quantitative gene expression analysis exhibited a significant upregulation of the Lsi1, Lsi2, Lsi3, NIP5;1, and NIP6;1 genes in alfalfa roots, while BOR1, BOR4, NIP2, and NIP3 showed no significant variation in their expression. The MEME results further noticed the association of four motifs related to the major intrinsic protein (MIP). The interaction analysis revealed that NIP5;1 and Lsi1 showed a shared gene network with NIP2, BOR1, and BOR4, and Lsi2, Lsi3 and NIP3-1, respectively. These results suggest that members of the major intrinsic proteins (MIPs) family especially Lsi1, Lsi2, Lsi3, NIP5;1, and NIP6;1 genes helped to pass water and other neutral solutes through the cell membrane and those played significant roles in Si uptake and transport in plants. Together, these insights might be useful for alfalfa breeding and genome editing approaches for alfalfa improvement.

Background: The potential impact of aqueous extracts from Psidium guajava leaves on the reproductive system of female rabbits was evaluated. Methods: Twenty-eight rabbits, aged five to six months were utilized. Rabbits were divided into four groups and were randomly assigned to receive one of the following oral doses of the guava leaf extracts: 0 (control group), 10, 20, or 30 mg/kg of body weight. After a treatment period of 30 days, blood was collected via jugular venipunture and the serum was extracted for the assessment of serum biochemical traits levels. The females were bred and monitored throughout their pregnancy to ascertain reproductive outcomes. Results: The results indicated that the guava leaf extract significantly increased the body weight of the rabbits during both pre- and post-pregnancy compared to the control group (p < 0.05). The litter size at three weeks post-birth, prolificity rate, FSH, LH, and protein levels were notably higher (p < 0.05) at a dose of 20 mg/kg of body weight. The viability rate three weeks post-birth increased with escalating extract doses, and the highest values were observed at doses of 20 and 30 mg/kg of body weight (p < 0.05). Conclusions: This study demonstrated that, the aqueous extract of guava leaves appears to stimulate the production of FSH, LH and enhance body weight, prolificity, and pregnancy outcomes in mammals. As such, it is suggested that a dose of 20 mg/kg body weight could be beneficial in improving the reproductive performance of female.

Background: Efficient gene editing technology is needed for successful knock-in. Homologous recombination (HR) is a major double-strand break repair pathway that can be utilized for accurately inserting foreign genes into the genome. HR occurs during the S/G2 phase, and the DNA mismatch repair (MMR) pathway is inextricably linked to HR to maintain HR fidelity. This study was conducted to investigate the effect of inhibiting MMR-related genes using CdCl2, an MMR-related gene inhibitor, on HR efficiency in HC11 cells. Methods: The mRNA and protein expression levels of MMR-related genes (Msh2, Msh3, Msh6, Mlh1, Pms2), the HR-related gene Rad51, and the NHEJ-related gene DNA Ligase IV were assessed in HC11 cells treated with 10 μM of CdCl2 for 48 hours. In addition, HC11 cells were transfected with a CRISPR/sgRNA expression vector and a knock-in vector targeting Exon3 of the mouse-beta casein locus, and treated with 10 μM cadmium for 48 hours. The knock-in efficiency was monitored through PCR. Results: The treatment of HC11 cells with a high-dose of CdCl2 decreased the mRNA expression of the HR-related gene Rad51 in HC11 cells. In addition, the inhibition of MMR-related genes through CdCl2 treatment did not lead to an increase in knock-in efficiency. Conclusions: The inhibition of MMR-related gene expression through high-dose CdCl2 treatment reduces the expression of the HR-related gene Rad51, which is active during recombination. Therefore, it was determined that CdCl2 is an inappropriate compound for improving HR efficiency.

The disposal of organic pollutants is one of the important research topics. Some of the studies in this field are based on the degradation of organic pollutants with a catalytic agent. The cobalt tetraoxide/peroxymonosulfate system is an important catalytic system used for the radical degradation of organic pollutants. To increase the catalytic efficiency of such reactions, graphitization of activated carbon used as a support solid and nitrogen doping to the carbon structure are commonly used methods. In this study, cobalt tetraoxide production, N-doping and graphitization were carried out in a single step by heat treatment of activated carbon doped with the phthlocyanine cobalt (II) complex. The catalytic performance of the catalyst/ peroxymonosulfate system was investigated by changing the pH, catalyst, and PMS concentration parameters on rhodamine B and 1,3,5 trichlorophenol, which were used as models. It was seen that the catalysts had 97% activity on rhodamine B in 16 min and 100% on 1,3,5 trichlorophenol in 6 min. It was observed that the catalysts continued to show high catalytic activity for five cycles in reusability studies and had a very low cobalt leaching rate. These results are in good agreement with previously published studies. In line with these results, the synthesized N-doped graphitic carbon/Co3O4 catalyst can be used as an effective catalyst for wastewater treatments.

Water contamination is one of the most pressing environmental issues of the present. There is a significant amount of interest in the slow pyrolysis of biomass to produce biochar, a solid byproduct that is stable and rich in carbon. Adsorbents manufactured from hydrochars, sometimes referred to as hydrochar created by hydrothermal methods, have been tested for the removal of possible contaminants from wastewater. The hydrothermal processes of hydrothermal carbonization (HTC) and liquefaction (HTL) yield hydrochars, a distinct category of biochar. Because of its peak efficiency, large surface area, large size of pore and capacity to regenerate, hydrochar is an acceptable option for the rehabilitation of a range of pollutants. The formation, activation, identification, and use of biochar and hydrochar were highlighted in this review. The physiochemical properties of the char produced by the two processes are very different, which has an impact on their potential uses in areas like wastewater pollution remediation, soil improvement, greenhouse gas emission and carbon sequestration among others.

The emergence of Mo2C- based catalysts in recent years has been favored as promising contender within diverse class MXenes. In terms of rapid development in the photocatalytic application, these intriguing compounds exhibit excellent photocatalytic performance because of their superior optical properties and peculiar structure characteristics. Unfortunately, a systematic review of Mo2C- based catalysts is lacking. In this review, we abstract the implication of structure—property relationship of emerging Mo2C- based MXenes materials and their applications toward the photocatalytic hydrogen evolution reaction (HER). Furthermore, synthetic pathways to prepare high-quality, low cost Mo2C- based MXenes materials and their outcomes for high HER applications are systematically described. Finally, several insights are provided into the prospects and future challenges for the development of highly reactive Mo2C- based MXenes materials, which present large range opportunities in this promising 2D materials for green and clean energy in environmental fields. This review provides a comprehensive scientific guide to the preparation, modification, and photocatalytic HER of MXenes-based materials.

Decabromodiphenyl ether (BDE209) is a persistent aromatic compound widely associated with environmental pollutants. Given its persistence and possible bioaccumulation, exploring a feasible technique to eradicate BDE209 efficiently is critical for today’s environmentally sustainable societies. Herein, an advanced nanocomposite is elaborately constructed, in which a large number of titanium dioxide ( TiO2) nanoparticles are anchored uniformly on two-dimensional graphene oxide (GO) nanosheets ( TiO2/GO) via a modified Hummer’s method and subsequent solvothermal treatment to achieve efficient photocatalytic degradation BDE209. The obtained TiO2/ GO photocatalyst has excellent photocatalytic due to the intense coupling between conductive GO nanosheets and TiO2 nanoparticles. Under the optimal photocatalytic degradation test conditions, the degradation efficiency of BDE209 is more than 90%. In addition, this study also provides an efficient route for designing highly active catalytic materials.

Reliable, inexpensive, environment-friendly, and durable properties of carbon materials with unique and outstanding photoelectric performance is highly desired for myriad of applications such as catalysis and energy storage. Since lattice modulation is a vital method of surface modification of materials, which form by an external force during the synthesis process, causing the internal compression and stretching, leading to lattice sliding event. In this review, we present a summary of different methods to tailor the lattice modulation in 2D carbon-based materials, including grain/twin boundary, lattice strain, lattice distortion, and lattice defects. This overview highlights the implication control of the diverse morphologies of nanocrystals and how to tailor the materials properties without adding any polymers. The improvement in the performance of 2D carbon materials ranges from the enhancement of charge transport and conductivity, structural stability, high-performance of light absorption capacity, and efficient selectivity promote the future prospect of 2D carbon materials broaden their applications in terms of energy conversion and storage. Finally, some perspectives are proposed on the future developments and challenges on 2D carbon materials towards energy storage applications.

There has been a tectonic shift in the trade relationship between the United States (US) and China. This can be seen in the passage of new US legislation, recent US trade restrictions on exports and investment transactions with China, and worsening US relations with the World Trade Organization (WTO), particularly with its dispute resolution system. The Trump administration initiated a haphazard tariff and trade war with China, reversing decades of US trade policy pursuant to its long-standing stances of supporting free trade. To the dismay of many in the trade community within the US and globally, the trade actions by President Trump have been significantly extended and broadened by the Biden administration in its first two years, despite the expectation that it would reverse many of Trump’s policies. In this article, I present seven observations concerning President Trump’s and President Biden’s trade policies.

In recent years, various steps have been taken to build strong and effective intra-BRICS economic cooperation. Brazil, Russia, India, China, and South Africa have been meeting since 2009 and gained a lot of weightages on different areas of economic relevance. In this course, the contribution of India is very significant. The paper therefore aims to elucidate the bilateral relations of India with its BRICS counterparts. The study begins by stressing the importance of BRICS as a group and its importance in the context of India. The authors hold a descriptive methodology by adopting secondary data from various sources. The paper gives an overview of the individual bilateral relationship of India in terms of trade. Further, the study suggested how a change of policy and infrastructural development can make the relationship of India with BRICS counterparts much stronger and sustainable.