This study was conducted to evaluate water quality in the Mankyung River using multivariate analysis. The analysis data which was surveyed from January 1996 to December 2002 in Mankyung river was aquired by the ministry of environment. Twelve water quality parameters were determined on each survey. The results were summarized as follow ; Water quality in the Mankyung River could be explained up to 74.90% by four factors which were included in loading of organic matter and nutrients by the tributaries(43.28%), seasonal variation(10.40%), loading of pathogenic bacteria by domestic sewage of Gapcheon (12.41%) and internal metabolism in river(8.81%). The result of cluster analysis by station was classified into three group that has different water quality characteristics. Especially, Iksan river was appeared to considerable water quality characteristics against other station. In monthly cluster analysis, three group was classified by seasonal characteristics. Also, in yearly cluster analysis, three group was classified. It is necessary to control the pollutant loadings by domestic sewage and livestock waste for water quality management of Mankyung river.

본 연구에서는 최근 환경재료로서 관심이 모아지고 있는 다공성 콘크리트를 하천구조물(보 및 하상재료)에 적용함으로써 수질을 개선하고자 수행하였다. 먼저, 물리ㆍ화학적 특징을 평가해 본 결과, 공극률 10% 및 30%의 다공성 콘크리트의 압축강도는 일반 콘크리트의 최저 압축강도(180 kgf/)를 상회하여 하천구조물에 적용 가능하였고, 알칼리 용출에 의한 부착 미생물에의 영향도 거의 없을 것으로 판단되었다. 또한, 일반 콘크리트와 다공성 콘크리트로 하천구조

국내 정수장에서는 여과사를 이용하여 원수를 정수하는 급속 및 완속 여과시스템을 이용하고있다. 대부분의 여과사는 해사인 규사로써, 구성광물의 광물학적 특성이 매우 제한되어 중금속이나 유기 오염물의 여과능력이 높은 편이 아니다. 따라서 항상 예기치 않게 발생될 수 있는 오염된 원수를 효율적이고 경제적으로 여과할 수 있는 여과물질 개발이 요구되고 있다. 따라서 이 연구에서 해사를 대체할 수 있는 화강암 풍화산물인 장석질 모래에 일정량의 불석을 혼화하여 원수를 여과하였을 때 일어나는 지화학성의 변화 및 Cd, Cu, Pb와 같은 중금속의 제거능력을 시험하였다. 시험 대상 물질은 현재 정수장에서 사용하는 주문진 규사와 이 연구에서 제조된 장석질 여과사, 장석질 혼합사 I(불석 10% 혼화), 장석질 혼합사 II(불석 20% 혼화)이다. 장석질 혼합사 I 및 II는 주문진 규사와 장석질 여과사에 비해 대부분의 양이온 및 음이온이 높게 용출되었으며, Si, Ca, SO4 이온 용출은 Al, NO3, Fe, K, Mg, P 에 비해 높게 일어났다. 제올라이트의 함량을 높인 혼합사 II가 혼합사 I 비해 Na, Ca, Al과 같은 양이온의 용출농도가 보다 높게 일어났으며, 이 양이온들은 크리높틸로라이트 계열의 제올라이트로부터 주로 용출되었다. 주문진 규사와 장석질 여과사는 Cd, Cu, Pb에 대해 제거능이 거의 없거나 약한 제거율을 보였다. 이에 반하여 장석질 혼합사I, II는 Cd과 Cu에 대해 낮은 제거율을 보였으나 Pb에 대해서는 상대적으로 매우 높은 제거율을 보였다. 장석질 혼합사 I, II는 저농도(100 ppm)의 Cd, Cu, Pb에 대하여 비교적 높은 제거율을 보이는 것으로 나타났으며, 장석질 혼합사 II는 저농도(100 ppm)의 Pb 용액과 반응시킨 경우 상당히 높은 제거율 (90.7%)을 보였다. 고농도(500 ppm) 영역에서는 장석질 혼합사 I, II는 Cd의 흡착량이 Cu, Pb에 비하여 높게 나타났으며, 제거율도 각각 24.0%, 28.2%로 가장 높게 나타났다. 제올라이트의 혼합비가 10%에서 20%로 증가할수록 중금속의 흡착량과 제거율이 향상되었다. 이는 장석질 혼합사를 여과사로 이용 할 경우 제올라이트를 적정 비율로 혼화하면 높은 중금속 제거 효과가 있는 것으로 판단된다.

파랑에너지를 차단하고 항내 정온을 확보하기 위해 설치된 외곽시설인 방파제는 불투과성이기 때문에 항만을 폐쇄성으로 만들 수 있으며, 항내ㆍ외간의 해수교환은 급격히 감소될 수 있다. 항만개발의 최근 추세는 항내의 수질 보호와 친수성이 강조되어, 기존의 불투과성 방파제의 일부에 투과성으로 설계한 제체투과성 해수교환방파제를 설치하는 것으로 나타났다. 이 경우 외해의 에너지가 항내로 전달되어 항내 오염물질의 희석률 증대와 함께 외해로 배출되도록 하고 있다. 오염이 심화된 항만(남해 동부해안에 위치한 삼천포 구항)에서 항내 수질을 개선하기 위한 방안은 육상오염원을 제거하는 것이 최선이나, 폐쇄성이 큰 항만의 경우, 외해와의 해수순환을 강화시켜야만 한다. 즉, 기존의 항만에서의 항내 수질개선을 위해서 외곽시설의 일부에 해수소통구를 두는 방법이 가장 최선이라 할 수 있다. 본 연구에서는 항내 오염이 심각한 항만을 대상으로 하여, 해수소통구를 통한 해수순환 양상을 수치계산을 통해 검토하고 수반되는 해수교환율을 검토하였다. 본 연구에서는 유한 차분법으로 수치모델을 구성하였으며, 해수소통구 도입에 따른 항내의 해수순환 및 해수교환율을 평가하였다.

It is the purpose of this study to investigate the change of stream water quality in upper stream of Dongjin river, and to give the basic information for the conservation of water quality. Water samples were taken periodically at 9 sampling sites during 8 months from March to October in 2002. The results of this study were as follows : 1. The water temperature and pH of stream water were ranged 9.0~29.4℃, 6.48~9.33, respectively. The COD values of stream water was ranged from 0.60 to 19.06. The contents of T-N and T-P mainly affected by the livestock wastes, and agricultural activity were 1.88~6.74 mg/L, ND(not deleted)~0.50 mg/L, respectively. 2. The SS, DO and BOD values of stream water were ranged 0.4mg/L~274.0mg/L, 0.5~6.0 mg/L, and 7.3~13.7 mg/L respectively. 3. The cation is one of the important components in analysis of stream water quality. The contents of analysis, Ca++, Mg++, Na+ and K+ were ranged 1.96~11.08 mg/L, 1.21~6.16 mg/L, 3.38~18.44 mg/L, 1.12~7.96 mg/L, respectively. SAR was ranged 0.31~1.63 below 2.0. The contents of cation showed in the order Na++>Ca++>K+>Mg+. 4. The contents of heavy metal Zn, Cu, and Pb were ND~0.071 mg/L, ND~0.012 mg/L, and ND~0.043 mg/L, respectively. Cd was not detected in all samples. 5. As a result of these researches showed water quality in upper stream watershed of Dongjin river more affected by livestock wastes and living sewage than agricultural activity.

In this study, the material cycle model was applied to suggest alternative management of water quality for Jeju Harbor. The distribution of COD, DIN (dissolved inorganic nitrogen) and DIP (dissolved inorganic phosphorus) concentrations was reasonably reproduced by simulations on the model area of the Jeju Harbor using a material cycle model. The simulations of COD, DIN and DIP concentrations were performed under the conditions of 20～100% pollution loadings reductions from pollution sources. In case of the 100% reduction of the input loads from Sanzi river, concentrations of COD, DIN and DIP were reduced to 39%, 78% and 52%, respectively at Jeju harbor. In contrast, in case of the pollutant loadings reductions from sediment, the effect of DIN and DIP reduction relatively seemed to increase around the center of study area. The 95% reduction of the pollutant loadings from river and sediment is required to meet the COD and nutrients concentration of second grade of ocean water quality criteria.

The purpose of this study is to investigate the characteristics of water quality in Jeju harbor and to estimate pollutant loadings discharged into Jeju Harbor. To know characteristics of water quality in Jeju harbor and pollutant loadings of Sanzi river, we have investigated from August, 2000 to May, 2001. The results showed that the concentrations of COD, DIN and DIP were in the range of 1.00～4.85㎎/L (mean 2.15㎎/L), 2.14～74.0㎍-at/L(mean 12.20㎍-at/L) and 0.52～4.00㎍-at/L(mean 1.18㎍-at/L), respectively. These values were under Ⅲ class of seawater quality criteria. The ratio of nitrogen to phosphorus was lower than 16 except for Station 1 in Jeju harbor. Therefore, nitrogen was playing an important role in phytoplankton growth as limiting factor in Jeju harbor. The mean values of eutrophication index were exceeding 1, which was the eutrophication criteria. The results of estimating pollutant loadings at Sanzi river are 0.30 ton/day for COD, 300㎏/day for DIN and 18.0㎏/day for DIP, respectively.

To investigate water quality and pollution states of rivers in Gwangju city, total of 30 water samples were taken from the main stream of Yeongsan river, Hwangryong river and Gwangju stream in dry and flood seasons. Physico-chemical characteristics of above streams according to pH-Eh and Piper’s diagrams are, typically, assigned to natural river water. In the streams, BOD, COD, T-N and T-P indicating water quality mostly increase toward downstream. Notably, water qualities in area near connection between the Gwangju stream and the main stream of Yeongsan river are polluted over V level in rivers and lakes water quality standard. The pollutions are influenced by life and agricultural foul waters from Gwangju City and farming areas around upstream branches of the Yeongsan river, reasonably. Besides, heavy metals are below the standard in those streams. So, it is considered that the streams are polluted by not industrial but life/agricultural foul waters.

water quality analysis of rainwater collected from catchment equipment(2m×1m) was conducted to determine its suitability for domestic purposes, in this study. As the results of analysis, the pH of rainwater was 6.3±0.3, and the turbidity of rainwater was over the 5 times than drinking water guidelines. For the usage of rainwater as the domestic and drinking water, the rainwater is need to treat. The analysis value of BOD was about 3 mg/L and the values of heavy metal as the Pb, Cd, Fe, Mn, Cr6+ and Cu was satisfied with drinking guidelines. Overall results of analysis support the possibility of rainwater as the domestic and drinking water.

To evaluate the change for water quality after the water gate operation in Shiwha lake, in situ survey were conducted on september in 2000 and January, march, jane in 2001. Chemical characteristics and eutrophication level was estimated from the survey data. The water quality of the Shihwa lake was greatly affected by pollutant load from rainfall, and formation of stratification in summer and winter was increased to effect on nutrient release from sediment. Especially, high concentration of chlorophyll-a was occurred in autumn, due to increased nutrient, high water temperature and low salinity after rainfall runoff. The mean concentration of DIN, DIP were 0.346mg/L, 0.0217mg/L in surface water and 0.826mg/L, 0.0415mg/L in bottom water, respectively, which were over Ⅲ grade of seawater standard. Also high percentage of ammonia nitrogen to DIN in bottom water for autumn and winter was affected by released nutrient from sediment. Correlation analysis of chlorophyll-a versus TSS was shown that organic matter was affected by autochthonous organic matter stem from the algae, these factor showed reverse correlation about salinity. Closely correlations among to the water quality constituent in continuity survey was appeared. The results of eutrophication index estimation showed the high potentiality of red tide occurrence in Shiwha lake, particularity in summer or fall. Overall water quality was greatly improve to compared with measuring data during 1997～1998 at the beginning water gate operation, which reported by KORDI. Therefore, to improve of water quality in Shiwha lake, we need to establish of management plan about nutrient release from sediment, rainfall runoff, maximum of seawater exchange.

This study was conducted to evaluate water quality in the Keum River using multivariate analysis. The analysis data in Keum river made use of surveyed data by the ministry of environment from January 1994 to December 2001. Thirteen water quality parameter were determined on each sample. The results was summarized as follow; Water quality in the Keum River could be explained up to 71.39% by four factors which were included in loading of organic matter and nutrients by the tributaries (32.88%), seasonal variation (16.09%), loading of pathogenic bacteria by domestic sewage of Gapcheon (13.39%) and internal metabolism in estuary as lakes(9.03%). For spatial variation of factor score, four group was classified by each factor characterization. Station 1 and 2 was influenced by Daechung dam, station 3 was affected by domestic sewage of Gapcheon, station 10～12 was affected by estuary dyke and the rest station. The result of cluster analysis by station was classified into four group that has different water quality characteristics. In monthly cluster analysis, three group was classified according to seasonal characteristic. Also, in yearly cluster analysis, three group was classified. It is necessary to control the pollutant loadings by Gapcheon inflow domestic sewage in Daejeon city for the sake of water quality management of Keum river.

용담댐 건설 후 방류 유량 및 방류 수질의 변화에 따라 계산된 금강상류의 모의결과를 이용하여 대청호 수질 변화를 예측하였다. 용담댐의 방류수량, 수질 그리고 대청호의 유량 시나리오는 이 은형 등(2002)이 금강의 모의를 위해 사용한 것과 동일하게 보았으며, 각 경우의 결과를 연구기간중의 실측수질과 실측유량을 사용했을 경우의 결과와 비교하였다. 용담호 방류량의 변화는 대청호 입구 수질에 크게 영향을 미치는 것으로 나타났으나, 대청호댐 부근의 수질에는 영

용담댐의 건설에 따른 방류조건의 변화가 대청호의 유입수질에 미치는 영향을 파악하기 위하여 WASP5 모델을 이용하여 BOD, 총인 그리고 총질소 농도를 예측하였다. 수질 예측 시나리오는 크게 다음과 같이 세 가지로 구분하였다; 첫째, 금강의 유량이 대청댐의 운영이 시작된 이래 최대 갈수년(1994)과 최대 풍수년(1987)과 같다고 보는 두 가지 조건, 둘째 용담댐에서 방류되는 유량을 연구기간 중(1998년) 실측된 유량과 같다고 보는 경우와 용담댐 방

하천에서 동수역학적 흐름해석 및 오염물질의 이송-확산 해석을 수행하고, 불확실도 해석기법을 이용하여 신뢰도 해석을 수행할 수 있는 2차원 수질관리모형인 UUWQM(Unsteady/Uncertainty Water Quality Model) 모형을 개발하였다. 본 모형의 실제 적용을 위해 낙동강 중류부의 성주에서 현풍까지 35km 구간에 대하여 2차원 동역학적 흐름해석과 수질해석이 실시되었다. 민감도 분석을 통해 수질모형에 기여도가 큰 입력변수들을 결정하였

하천에서의 수질변동을 예측하기 위해 FOEA(First-Order Error-Analysis)와 Monte Carlo 모의를 적용한 추계학적 모형을 개발하였다. 영향메트릭스(Influential matrix)를 이용한 민감도 분석을 실시하여 주요 반응계수를 결정하였고, BFGS(Broyden-Fletcher-Goldfarb-Shanno) 최적화 기법을 사용하여 주요 반응계수 값을 산정하였다. 본 모형을 확정론적 수질해석과 동일한 실제 하도구간에 적용하여

The characteristics of drinking groundwater quality at Chung Cheong Nam Do was analyzed by investigating the 3,086 groundwater data which were carried out the water quality inspection from Jan. 1998 to Dec. 1998. It was found that all the mean concentration of items was not over the drinking water quality standard except Zn at Yeongee area. The highest mean concentration of nitrate was 8.2 ㎎/ℓ at Hongsung area. And the mean concentrations of nitrate and ammonium at Sucheon, Yesan, Yeongee were relatively higher. It was considered that the groundwater of that area was contaminated by breeding livestock as farm pollutants. The mean concentrations of chloride, hardness and evaporation residual at coastal regions were higher than inland regions. Especially the mean concentration of chloride was 2.5 times higher. It was considered that the groundwater at coastal regions was affected by seawater. It was found that the correlation between Fe and Mn was relatively high(r=0.776) and the correlation between hardness and evaporation residual was very high(r=0.983). The rainfall series and detection rate of E-coli had the hydrologic persistence. The correlation between the detection rate and rainfall series over 150 mm was very high (r=0.9146). Therefore it is surely required to control the groundwater sanitation in the rainy season.

In order to provide the basic information on the environmental pollution of Kyungsan province, the contents of Pb, Cd, Cr, Cu, Mn and Zn in soil, stream water, aquatic sediment and groundwater were investigated, and also the values of pH, COD, KMnO4-C, NH3-N, NO2-N, NO3-N and Cl- of stream water and groundwater were determined. The results were as follows. The values of COD, NH3-N, NO2-N and NO3-N of the stream waters were very low. The contents of Pb, Cd, Cr, Cu and Zn in the stream waters were respectively at range of 0.014～0.063 ㎎/ℓ, 0.004～0.007 ㎎/ℓ, 0～0.045 ㎎/ℓ, 0～0.008 ㎎/ℓ and 0.001～0.175 ㎎/ℓ, and these values were much lower than those of contaminated stream water in Korea. The contents of Cd, Cr, Cu and Zn in the soils were respectively at range of 0.12～0.71 ppm, 0.88～2.65 ppm, 2.86～22.33 ppm and 3.89～26.39 ppm, and these values were much lower than those of ordinary polluted areas in Korea. The contents of Cd, Cr, Cu, As, Zn and Mn in the aquatic sediments were respectively at range of 3.05～3.81 ppm, 14.6～70.6 ppm, 13.74～61.59 ppm, 76.8～465.5 ppm, 12.56～190.83 ppm and 333.3～1188.3 ppm. The values of pH, KMnO4-C, NH3-N and NO3-N of the groundwaters were respectively at range of 7.6～8.4, 0～3.95 ㎖, 0.05～0.15 ㎎/ℓ and 0.05～0.42 ㎎/ℓ. The contents of Pb, Cd and Cr in the groundwaters were respectively at range of 0.015～0.061 ㎎/ℓ, 0.006～0.009 ㎎/ℓ and 0.005～0.045 ㎎/ℓ.

본 연구의 목적은 유한요소법에 의한 이차원 오염물 이송에 대한 등수역학적 수치모형을 개발하는 것으로서 개발된 모형을 이용하여 지류와 폐수처리장으로부터의 오염물이 주하도로 유입되는 경우에 대한 수질해석을 수행하였다. 본 연구에서는, 합리적인 매개변수산출을 위한 보정과 모형의 신뢰성과 정확도를 위한 검증을 수행하였다. 또한, 실제 유역인 한강하류부에 본 모형을 적용한 결과 하도를 따라서 실제적인 오염물 분포양상을 재현하였으며 계산값과 실측값의 비교에서 잘