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        검색결과 61

        21.
        2020.04 KCI 등재 서비스 종료(열람 제한)
        이 논문은 T. S. 엘리엇의 시와 에세이 분석을 통해 그의 글이 담고 있는 반민족주의적 사상을 그가 꿈꾸던 유럽의 문화적 통합과 관련하여 연구한다. 이를 통해 그의 반민족주의는 일종의 확장된 민족주의이며, 그의 이러한 범민족주의는 민족주의의 원초적인 관점과 도구적 관점에 기반하였음을 밝힌다. 엘리엇은 제1차 세계 대전 후 유럽 국가들 간의 전쟁을 강하게 반대했고, 유럽은 평화를 위해 연합해야 한다고 주장했다. 그가 민족주의를 반대한 이유는 민족주의가 유럽의 문화 통일에 방해가 되기 때문이지 민족주의 자체의 논리에 결함이 있기 때문이 아니었다. 따라서 유럽 문화 통일을 주장하는 엘리엇의 반민족주의가 민족주의의 기반 위에 세워졌다는 것은 전혀 모순되지 않는다. 그의 반민족주의는 민족주의에서 중요하게 취급되는 민족 구성원의 “의지”와 민족국가의 형성과 유지에서 중요한 역할을 하는 “전통”에 관한 개념을 민족주의와 공유하고 있다. 이는 민족의 동질성 회복이라는 민족주의적 관점에서 남북통일을 생각함과 동시에 세계 평화를 위해 각 국의 민족주의를 경계해야 하는 한국 독자들에게 의미하는 바가 크다. 인류는 언제나 과거를 통해 배우기에 한국에서 엘리엇 읽기는 오늘날에도 여전히 유효한 것이다.
        22.
        2013.10 KCI 등재 서비스 종료(열람 제한)
        Microwave pyrolysis of SF6 on alumina-based catalyst doped with cerium sulfate was investigated. Silicon Carbide (SiC) used as a microwave susceptor. The catalysts were characterized by X-ray diffraction (XRD) and the destruction and removal efficiency (DRE) of SF6 was evaluated by GC-TCD. We found that the optimal cerium content was 20wt% at microwave pyrolysis of SF6. The catalysts modified by cerium showed higher DRE at lower reaction temperature compared with original catalysts. The highest DRE of SF6 on CeA (20) was 80% at 600oC reaction temperature and the DRE was up to 95% when the reaction temperature over 700oC. It showed the alumina-based with cerium promotes the removal efficiency of SF6 at a mild reaction temperature. From XRD results, modified catalysts could be higher stability because of no transformation of the crystal phase after reaction.
        23.
        2013.09 KCI 등재 서비스 종료(열람 제한)
        Tetrafluoromethane(CF4) have been widely used as etching and chemical vapor deposition gases for semiconductor manufacturing processes. CF4 decomposition efficiency using microwave system was carried out as a function of the microwave power, the reaction temperature, and the quantity of Al2O3 addition. High reaction temperature and addition of Al2O3 increased the CF4 removal efficiencies and the CO2/CF4 ratio. When the SA30 (SiC+30wt%Al2O3) and SA50 (SiC+50wt%Al2O3) were used, complete CF4 removal was achieved at 1000℃. The CF4 was reacted with Al2O3 and by-products such as CO2 and AlF3 were produced. Significant amount of by-product such as AlF3 was identified by X-ray powder diffraction analysis. It also showed that the γ-Al2O3 was transformed to α-Al2O3 after microwave thermal reaction.
        24.
        2013.08 KCI 등재 서비스 종료(열람 제한)
        Alumina-supported catalysts containing different transition metals such as Cu, Cr, Mn, Zn, Co, W were investigated for their activity in the selective oxidation of toluene. Catalytic oxidation of toluene was investigated at atmospheric pressure in a fixed bed flow reactor system over transition metals with Al2O3 catalyst. The result showed the order of catalytic activities for the complete oxidation of toluene was Mn > Cu> Cr> Co> W> Zn for 5wt.% transition metals/Al2O3. Mn/Al2O3 catalysts containing different amount of Mn were characterized by X-ray diffraction spectroscopy for decision of loading amount of metal to alumina. 5 wt.%Mn/Al2O3 catalyst exhibits the highest catalytic activity, over which the toluene conversion was up to 90% at a temperature of 289℃.
        25.
        2013.07 KCI 등재 서비스 종료(열람 제한)
        Functionalized adsorbent has been synthesized by piperazine(Pz) on activated carbon. Quantitative estimations of CO2 were undertaken using gas chromatography with GC/TCD and the prepared adsorbents were characterized by BET surface area and FT-IR. It was also studied effect of various parameters such as piperazine loadings and adsorption temperature. The specific surface area decreased from 1212.0 m2/g to 969.8 m2/g by impregnation and FT-IR revealed a N-H functional group at about 1400 cm-1 to 1700 cm-1. The CO2 adsorption capacity at 20℃ and 50∼100℃ was as follow: AC > Pz(10)-AC> Pz(30)-AC> Pz(50)-AC at 20℃ and Pz(10)-AC > AC > Pz(30)-AC> Pz(50)-AC at 50∼100℃. Therefore, for high temperature flue gas condition, the Pz(10)-AC showed the highest adsorption capacity due to physical adsorption and chemical adsorption by amino-group content. The results suggest that activated carbon impregnated with Pz is an effective adsorbent for CO2 capture from real flue gases above 50℃.
        26.
        2013.01 KCI 등재 서비스 종료(열람 제한)
        Silicon carbide with aluminium oxide was used to remove the sulphur hexafluoride (SF6) gas using microwave irradiation. The destruction and removal efficiencies (DREs) of SF6 were studies as a function of various decomposition temperatures and microwave powers. The decomposition of SF6 gas was analyzed using GC-TCD. XRD (X-ray powder diffraction) and XRF (X-ray Fluorescence Spectrometer) were used to characterize the properties of aluminum oxide. DREs of SF6 were increased as the microwave powers were increased. Additive aluminium oxide on SiC increased the removal efficiencies and decreased the decomposition temperature. The XRD results show that the γ-Al2O3 was transformed to α-Al2O3 during SF6 decomposition by microwave irradiation. It was found that the best material to control SF6 was SiC with Al2O3 30 wt% in consideration of microwave energy consumption and SF6 decomposition rate.
        27.
        2012.06 KCI 등재 서비스 종료(열람 제한)
        Adsorption experiment of carbon dioxide was performed on MCM41 silica with a 30 wt .% EDA(ethylenediamine) loading at different CO2 inlet concentration and various adsorption temperature. The surface characteristics of CO2 capturing agent were carried out using BET analysis, X-ray diffraction and FT-IR. The results of BET showed 781 m2/g for MCM41 and 464 m2/g for EDA/MCM41. X-ray diffraction results reveled typical hexagonal pore system. The higher sorption capacity of EDA/MCM41 was about 80 mgco2/gsorbent with 50% CO2 inlet concentration and 303 K adsorption temperature. The isosteric heat of adsorption in 303-353 K ranged from -25.47 to -28.24 KJ/mole for EDA/MCM41, which indicates CO2-EDA/MCM41 interaction with exothermic adsorption process. Finally, the performance of EDA/MCM41 in 10 consecutive sorption-desorption runs was a stable with only a minor drop in its sorption capacity.
        28.
        2012.05 KCI 등재 서비스 종료(열람 제한)
        In this study, adsorption of polychlorinated biphenyls(PCBs) in transformer oil on powder activated carbon (PAC) and synthetic zeolite was evaluated. Adsorption characteristics of PCBs on the PAC and zeolite has been investigated in a batch system with respect to adsorbents amount and contact time. BET results showed 908 m2/g for PAC and 483 m2/g for zeolite. The adsorption capacity of PCBs increased with an increasing input amount of absorbent. The adsorption experimental results showed that PAC removed 90% of input PCBs in transformer oil while zeolite removed only 64%. Adsorption of PCBs to PAC and zeolite fit the Freundlich model well. The Freundlich parameter, Kf, for PAC and zeolite was 193.1 and 43.0 respectively, indicating that PAC is effect adsorbent for PCBs adsorption in transformer oil.
        29.
        2011.07 KCI 등재 서비스 종료(열람 제한)
        Adsorption experiment of carbon dioxide was performed on MCM41 silica impregnated with two kinds of EDA(ethylenediamine) and MEA(monoethanolamine). The prepared adsorbents were characterized by BET surface area, X-ray diffraction and FT-IR. The CO2 capture study was investigated in a U type packed column with GC/TCD. The results of XRD for MCM-41 and amine-impregnated MCM41 showed typical the hexagonal pore system. BET results showed the MCM 41 impregnated amine to have a surface area of 141 m2/g to 595 m2/g and FT-IR revealed a N-H functional group at about 1400cm-1 to 1600cm-1. The CO2 adsorption capacity on EDA and MEA was as follow: MCM41-EDA30 > MCM41 -EDA40 >MCM41-EDA20 >MCM-EDA10 and MCM41-MEA40 >MCM41-MEA30 > MCM41-MEA20> MCM41-MEA10. The MCM41-EDA30 showed the highest adsorption capacity due to physical adsorption and chemical adsorption by amino-group content. The results suggest that mesoporous media with EDA is effective adsorbent for CO2 capture from flue gases.
        30.
        2011.02 KCI 등재 서비스 종료(열람 제한)
        Toluene desorption of modified activated carbon for microwave irradiation was evaluated. As a virgin GAC reacted from microwave energy, it created an "arcing" between GAC particles in desorption process. The arcing became more and more vigorous and achieved a red flame of GAC. The silica coated GAC(Si/GAC) was developed to prevent arcing phenomenon and temperature control problem. The result shows virgin GAC with 5wt%, 10wt% and 20wt% silica had no arcing and could control temperature very well. However, the adsorption rate of Si/GAC was decreased by coated silica amount due to decreasing surface area of GAC. The 5wt% Si/GAC adsorption rate was quite similar to virgin GAC adsorption rate. After adsorption, the toluene-loaded GAC and Si/GAC was reactivated by 2450MHz MW irradiation with 300W for 5 min. Quantitative desorption of the toluene was achieved at MW irradiation at 300W with desorption efficiencies as high as 98.59% to 84.65%% after four cycles.
        31.
        2011.01 KCI 등재 서비스 종료(열람 제한)
        Air quality monitoring networks are very important facilities to manage urban air pollution control and to set up an environmental policy. Since air quality monitoring network of Daegu was allocated from 1980s to mid-90s, there is need to reevaluate it and relocated its site. This study was evaluated the position of Daegu air quality monitoring station by unit environmental sensitivity index, grid emission rate, CAI (Comprehensive Air-quality Index) point. The investigation domain covered an area of 16 × 24 km centered at the metropolitan area of Daegu with grid spacing of 2 km. The location of alternative air quality monitoring networks was selected through optimization and quintiles analysis of total score. The result showed that all things considered, new air quality monitoring network need to install grid numbers 10, 28, 36, 37, 46. We also recommand three scenarios of alternative air quality monitoring network when considering unit environmental sensitivity index, emission rate and CAI point.
        32.
        2009.05 KCI 등재 서비스 종료(열람 제한)
        In this study, the characteristics of granular activated carbon (GAC) supported metal was investigated in an area influenced by flame discharge and temperature variation during irradiating microwave. The modified GAC was formulated by impregnating metal hydroxides of nickel (Ni/GAC), barium (Ba/GAC), copper (Cu/GAC), zinc (Zn/GAC), cobalt (Co/GAC) and lanthanum (La/GAC). Ba/GAC was selected as it showed lack of spark discharge and temperature increasing aspects. Comparison of adsorption and desorption amount of GAC and Ba/GAC showed that adsorption and desorption rate of the GAC were higher than those of Ba/GAC. The results show that the presence of barium can decrease adsorption/desorption rate because of plugging pore of GAC. Toluene regeneration rate of Ba/GAC was better than that of GAC due to barium loading. Finally, GAC with barium can be controled a rapid increasing temperature and spark discharge, increased the regeneration rate of toluene during desorption by irradiating microwave.
        33.
        2008.05 KCI 등재 서비스 종료(열람 제한)
        This paper describes the adsorption/desorpton efficiency of a modified activated carbon by irradiated microwave to treat toluene. By employing microwave energy, the regeneration time was considerably shortened compared with conventional thermal heating regeneration. New adsorbent called ACB(Activated Carbon-Bentonite) was prepared from powder activated carbon with mixing bentonite as a binder. Specific surface area, average pore size and total pore volume of ACB were calculated from the nitrogen adsorption/desorption isotherm. The surface of ACB was characterized with scanning electron microscope(SEM). The results showed that the specific surface area, total pore volume, average pore size of ABC was not influenced by regenerating cycle with microwave irradiation. Toluene was adsorbed onto ACB which desorbed by MW irradiation. Absorption capacity of ACB was 0.117 gtoluene/ gACB. Desorption efficiency of toluene increased as higher microwave output was applied.
        34.
        2007.12 KCI 등재 서비스 종료(열람 제한)
        This study was conducted to investigate the effect of ozonated water and ozonated water + hydrogen peroxide treatment of residual procymidone in perilla leaf containing 20 mg/L procymidone. Samples was treated with ozonated water containing 1.0, 2.0 and 3.0 mg O3/L ozone and hydrogen peroxide water containing 1.0, 2.0 and 3.0 mg H2O2/L hydrogen peroxide in pH 5, 7 and 9, respectively, at 15℃. Procymidone removal rate was 26.5% in 7 days at 15℃ and optimum condition of procymidone removal was the case of treating with ozonated water containing 2.0 mg O3/L and pH 9. As the result procymidone removal rate was about 96.5%. In this case of adding hydrogen peroxide, optimum condition of procymidone removal was 1 : 0.5~1(O3 : H2O2). However, procymidone was nearly removed with the treatment of hydrogen peroxide water only.
        35.
        2007.04 KCI 등재 서비스 종료(열람 제한)
        This study assessed the characteristic of BTEX (Benzene, Toluene, Ethylbenzene, Xylene) concentration ratios of industrial emission sources and the neighborhoods of industrial area, fuel such as gasoline, light oil, LPG, and similar gasoline, and ambient air in Daegu. The BTEX in aromatic compounds was the most abundant VOC in Daegu. The BTEX ratios were (0.2:2.6:1.0:1.8) for the neighborhoods of industrial area, (2.6:11.3:1.0:1.2) for residential area, (2.2:11.0:1.0:1.6) for commercial area, (1.0:14.9:1.0:1.3) for industrial area, and (0.2:2.6:1.0:1.8) for the neighborhoods of industrial area. Average BTEX ratios in Daegu were B/T ratio (0.1), B/EB ratio (1.5), B/X ratio (1.1), T/EB ratio (12.6), T/X ratio(10), EB/X ratio (0.7). Expecially, B/T ratio in Daegu was similar as the other cities, Bangkok, Manila, and Hongkong. Comparing other cities with B/T ratio, the main sources of VOC were vehicular exhaust and emission of industrial facilities. Furthermore, BTEX correlation were evaluated at the emission sources and regional areas. Results showed that correlation coefficient values of emission sources, fuels and neighborhood of industry were significant magnitude above 0.65(p<0.01). Also, there showed highly significant correlations among BTEX. Calculated correlation coefficients of ambient air sampling sites were 0.61~0.954 for commercial /residential area and 0.613~0.998 for industrial area. However, they showed different correlation between commercial/residental area and industrial area. It implied that the emission sources were different from each area.
        37.
        2006.06 KCI 등재 서비스 종료(열람 제한)
        The purposes of this paper were to monitor the temperature rising courses and spark discharge of the modified granular activated carbon (GAC) by microwave (MW) irradiation and to evaluate absorption of benzene. The GAC coated on SiO2, boron, talc, ferrite was named as the modified GAC. Thermal and spark discharge measurement of virgin GAC and modifed GAC has been carried out using a MW device operating at 2450 MHz under various energy conditions. The results of this paper as follows. First, the modified GAC is more efficient than the virgin GAC in temperature control. Temperature gradient of the modified GAC is more lower than that of virgin GAC. The temperature gradient of GAC was observed in the following order : virgin GAC, Mn-Zn ferrite/GAC, Ni-Zn ferrite,/GAC, SiO2/GAC, Boron/GAC, Talc/GAC. Second, the spark discharge of the modified GAC was diminished, compared with that of virgin GAC. Because of its excellent electrical insulating properties, the coating material prevents the spark discharge. Finally, the benzene adsorption capacity of the modified GAC decreased due to diminishing of adsorption site by the coating material. Considering the temperature gradient and spark discharge of GAC, the GAC coated SiO2 would be appropriate absorbent under irradiation of MW.
        38.
        2006.04 KCI 등재 서비스 종료(열람 제한)
        Adsorption characteristics of benzene by zeolite were investigated using irradiating microwave. Experimental apparatus was applied to a U-type fix-bed column equipped with microwave system. Zeolite, itself, seems to be inappropriated to remove benzene because of a hygroscopic property. Microwave irradiation to zeolite, however, brings about decreasing H2O adsorption and increasing benzene adsorption. This causes that the dipole material such as H2O was vibrated and heated by irradiation of microwave and desorbed from zeolite. And then, benzene starts to be absorbed by zeolite. In this study, the results showed that the selective adsorption of benzene was occurred by the microwave irradiation and the adsorption capacity of benzene was increased by increasing microwave energy. As a results, it was found that the zeolite could be used to adsorb benzene with microwave and this method make it feasible simultaneously to adsorb and desorb benzene.
        39.
        2006.04 KCI 등재 서비스 종료(열람 제한)
        A (5 wt.%)Mn-(1 wt.%)V2O5/TiO2 catalyst were prepared by co-precipitation method and used for low-temperature selective catalytic reduction (SCR) of NOx with ammonia in the presence of oxygen. The properties of the catalysts were studied by X-ray diffraction (XRD), temperature programmed reduction (TPR) and scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS). The experimental results showed that (5 wt.%)Mn-(1 wt.%)V2O5/TiO2 catalyst yielded 81% NO conversion at temperature as low as 150℃ and a space velocity of 2,400 h-1. Crystalline phase of Mn2O3 was present at ≥15% Mn on V2O5/TiO2. XRD confirmed the presence of manganese oxide (Mn2O3) at 2θ=32.978°(222). The XRD patterns presented of (5 wt.%)Mn-(1 wt.%)V2O5/TiO2 did not show intense or sharp peaks for manganese oxides and vanadia oxides. The TPR profiles of (5 wt.%)Mn-(1 wt.%)V2O5/TiO2 catalyst showed main reduction peak of a maximum at 595℃.
        40.
        2005.07 KCI 등재 서비스 종료(열람 제한)
        Catalytic combustion of toluene was investigated on CuOx/SnO2-ZrO2, CuOx/SnO2, CuOx/ZrO2 catalysts prepared by impregnation. Characteristics of catalysts loaded on binary support and single support were observed by TPR, TPO, XRD, XPS techniques. The results on catalytic combustion showed that binary supports improve the activity of copper in the combustion of toluene. The reason for high catalytic activity on toluene combustion of CuOx/SnO2-ZrO2 catalyst was ascribed to oxidation·reduction activity at low temperatures and stability of oxidation state after reduction.
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