Copper, silver, and gold-reduced graphene oxide nanocomposite (Cu-rGO, Ag-rGO, and Au-rGO) were fabricated via the hydrothermal method, which shows unique physiochemical properties. Environment friendly electromagnetic radiation was employed to synthesize rGO from GO. The nonlinear optical phenomenon of noble metal decorated rGO is predominantly due to excited state absorption, which arises from surface plasmon resonance and increases in defects at the surface due to Cu, Ag, and Au incorporation. It is found that the third-order nonlinear absorption coefficient was in the order of 10− 10 m/W, with notable enhancements in the third-order properties of Au-rGO compared to other nanocomposites and their respective counterparts. Functionalizing rGO induces defect states ( sp3), increasing NLO response. Cu, Ag, and Au exhibit higher Surface-Enhanced Raman Scattering (SERS) activity due to rGO-induced structural modifications. SERS signals are influenced by dominant signals from Au nanorods. The electronic structures for pure and doped rGO were investigated through Density Functional Theory (DFT). The computed partial density of states (PDOS) confirms the enhancement of the state in Au-doped rGO is due to the charge transference from Au to C 2p orbital. The optical absorption spectra and PDOS reveal the possibility of free carrier absorption enhancement in Au which validates experimentally observed higher two-photon absorption (β) value of Au-doped rGO. The tuning of nonlinear optical and SERS behaviour with variation in the noble metal upon rGO provides an easy way to attain tuneable properties which are exceedingly required in both optoelectronics and photonics applications.

This study pioneers a transformative approach of discarded orange peels (Citrus sinensis) into highly porous carbon, demonstrating its potential application in energy storage devices. The porous carbon structure offers a substantial surface area, making it conducive for effective ion adsorption and storage, thereby enhancing capacitance. The comprehensive characterization, including X-ray diffraction, Fourier transform infrared, Raman spectroscopy, field emission scanning electron microscopy, and XPS verifies the material’s suitability for energy storage applications by confirming its nature, functional groups, graphitic structure, porous morphology and surface elemental compositions. Moreover, the introduced plasma treatment not only improves the material’s intensity, bending vibrations, and morphology but also increases capacitance, as evidenced by galvanostatic charge–discharge tests. The air plasma-treated carbon exhibits a noteworthy capacitance of 1916F/g at 0.05A/g in 2 M KOH electrolyte. long term cyclic stability has been conducted up to 10,000 cycles, the calculated capacitance retention and columbic efficiency is 92.7% and 97.6%. These advancements underscore the potential of utilizing activated carbon from agricultural waste in capacitors and supercapatteries, offering a sustainable solution for energy storage with enhanced performance characteristics.

Forecasting port container throughput is crucial due to its impact on economic development. Socio-economic factors, which introduce uncertainty, are increasingly integrated into throughput forecasting. The complexity of common multivariate forecasting models significantly affects accuracy, yet few studies compare their performance on the same time series for throughput modeling. This study implements, evaluates, and compares the performance of eight multivariate forecasting models for port throughput within a proposed multiple-input single-output (MISO) system, chosen for their frequent use in container throughput research. It investigates two data preprocessing approaches: Random Forest Variable Importance Method (RF-VIM) and a Multi Lagged Value approach. The comparison uses six error metrics: normalized root mean squared error, mean absolute error, mean absolute percentage error, mean error, and root mean percentage error. Performances are discussed, and recommendations for adopting a suitable model are provided.

Sensors for monitoring human body movements have gained much attention in the recent times especially in the health-care sector as these devices offer real-time monitoring of vital physiological signs, enabling health-care professionals to evaluate health conditions and provide remote feedback. In this work, we have fabricated carbon-nanotube (CNT)/ polydimethylsiloxane (PDMS) composite sensor through simple dispersion and freezing method for monitoring flexion movements in humans. Sensors with different CNT loadings, namely 0.1 wt %, 0.5 wt %, and 1 wt % were fabricated and analyzed to find the best performing sensor. Several characterizations like Raman, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA), tensile strength measurements, and piezoresistive studies were carried out to study the features of the sensors. Among the fabricated sensors, the one with the loading concentration of 0.5 wt% is found to be most sensitive for flexion applications with higher gauge factor of 533 at 60% strain level, response time of ~ 140 ms and lower hysteresis loss. The feasibility of the sensor for monitoring flexion like finger bending, wrist bending, elbow bending, and knee bending is also analyzed making it ideal for use in sports for athletes, physicians, and trainers to investigate physical performance and well-being.

Photoanode optimization is a fascinating technique for enlightening the power conversion efficiency (PCE) of dye-sensitized solar cells (DSSCs). In this present study, V2O5/ ZnO and reduced graphene oxide (rGO)-V2O5/ZnO nanocomposites (NCs) were prepared by the solid-state technique and used as photoanodes for DSSCs. A wet chemical technique was implemented to generate individual V2O5 and ZnO nanoparticles (NPs). The structural characteristics of the as-synthesized NCs were investigated and confirmed using powder X-ray diffraction (XRD), X-ray photoelectron spectra (XPS), and Scanning electron microscope (SEM) with energy dispersive X-ray (EDX) analysis. The average crystallite size (D) of the as-synthesized V2O5/ ZnO and rGO-V2O5/ZnO NCs was determined by Debye-Scherer’s formula. The bandgap (eV) energy was calculated from Tauc’s plots, and the bonding nature and detection of the excitation of electrons were investigated using the Ultra violet (UV) visible spectra, Fourier Transform infrared (FTIR) and photoluminescence (PL) spectral analysis. Electrical studies like Hall effect analysis and the Nyquist plots are also described. The V2O5/ ZnO and rGO-V2O5/ZnO NCs based DSSCs exhibited 0.64% and 1.27% of PCE and the short circuit current densities and open circuit voltages improved from 7.10 to 11.28 mA/cm2 and from 0.57 to 0.68 V, respectively.

This work involves the development of a novel waste-derived carbon dots (CDs) conjugated with silver (Ag) nanohybrid system-based Fluorescence Resonance Energy Transfer (FRET) sensor for the detection of melamine. CDs and Ag nanoparticles served as energy donors and energy acceptors, respectively. CDs were synthesized from orange peel waste through a combined hydrothermal and ultra-sonication route. The synthesized CDs had hydroxyl, amino, and carboxyl groups on their surface, explaining that waste-derived CDs can act as reducing and stabilizing agents and showed strong absorption and fluorescence emission at 305 and 460 nm, respectively. The bandgap, linear refractive index, conduction band, and valance band potential of CDs were observed to be 2.86, 1.849, 1.14, and 4.002 eV, respectively. No significant difference was observed in the fluorescence properties at different pH (acid and alkaline) and ionic concentrations. Given their fluorescent nature, the synthesized CDs were used for the detection of melamine. The fluorescence of CDs was found to be quenched by Ag+ due to the FRET energy transfer between CDs to Ag. Notably, the zeta potential of Ag@CDs was changed from − 28.7 mV to − 30.6 mV after the incorporation of Ag+. Ag@CDs showed excellent selectivity and sensitivity toward the sensing of melamine in the aqueous solutions with the limit of detection ~ 0.85 μM. Increasing the melamine level also raises the FL intensity of Ag@CDs. The substrate was effectively used in the detection of melamine in milk as a real application and the recovery percentage was found to be 98.03%. Moreover, other adulterants such as urea and formaldehyde can be detected selectively by Ag@CDs. Overall, the synthesized Ag@CDs can be used as an efficient material for sensing applications involving such food adulterants.

The dyeing process is a very important unit operation in the leather and textile industries; it produces significant amounts of waste effluent containing dyes and poses a substantial threat to the environment. Therefore, degradation of the industrial dye-waste liquid is necessary before its release into the environment. The current is focusing on the reduction of pollutant loads in industrial wastewater through remediating azo and thiazine dyes (synthetic solutions of textile dye consortium). The current research work is focused on the degradation of dye consortium through photo-electro-Fenton (PEF) processes via using dimensionally stable anode (Ti) and graphite cathode. The ideal conditions, which included a pH of 3, 0.1 (g/L) of textile dye consortium, 0.03 (g/L) of iron, 0.2 (g/L) of H2O2, and a 0.3 mAcm-2 of current density, were achieved to the removal of dye consortium over 40 min. The highest dye removal rate was discovered to be 96%. The transition of azo linkages into N2 or NH3 was confirmed by Fourier transforms infra-red spectroscopic analysis. PEF process reduced the 92% of chemical oxygen demand (COD) of textile dye consortium solution, and it meets the kinetics study of the pseudo-first-order. The degradation of dye through the PEF process was evaluated by using the cyclic voltammetric method. The toxicity tests showed that with the treated dye solution, seedlings grew well.

Modification of the surface of raw activated carbon using chemical solvents can significantly improve the adsorption performance of activated carbon. Triethylenetetramine is one of the most important chemical solvents used to modify raw activated carbon for formaldehyde removal indoor. We conducted the liquid impregnation experiments at different initial concentrations, temperatures, adsorbent dosage and time ranges to fully investigate the adsorption of triethylenetetramine on the surface of raw activated carbon for modification. We found that the Langmuir isotherm model and pseudo-first-order kinetic model fit quite well with the experimental data and the R2 are 0.9883 and 0.9954, respectively. The theoretical maximum adsorption capacity is 166.67 mg/g. The change in Gibbs free energy (ΔG0), enthalpy change (ΔH0) and entropy change (ΔS0) were also calculated to study the direction and driving force of the liquid adsorption process. In order to understand the adsorption process at the molecular level, a new activated carbon model based on the actual physical and chemical properties of activated carbon was carefully established in the Materials Studio to simulate the liquid-phase adsorption. The pore structure, elemental composition, functional group content, density, pore volume, and porosity of the activated carbon model converge close to the actual activated carbon and the adsorption isotherms obtained from the simulation agree well with the experimental results. The results show that the adsorption of triethylenetetramine on activated carbon is a spontaneous, endothermic and monolayer physical adsorption process.

This study was conducted to determine the acceptability of locally accepted japonica rice varieties among 53 farmers in Bohol and 38 farmers in Nueva Ecija, who were further classified into adopters and non-adopters of the GUVA japonica rice variety. Snowball sampling was made on farmer adopters/cooperators of a high-quality seed multiplication and dissemination project in the said provinces. The farmer respondents were mostly male whose ages ranged from 30 to 80 years and with farm sizes from 0.5 to 16 hectares. The farmers’ rice variety and usage were assessed by comparing the GUVA japonica rice variety with their commonly planted indica rice variety based on its agronomic characteristics, yield and income potential, and seed purity concerns. The barriers/hesitations to adoption of the GUVA japonica rice variety, namely seed availability, varietal information, and market potential, must be complemented with the suggested improvements on the variety together with factors that convince the farmers for committed use of this variety. Researchers together with partner agencies must put a lot of thought on how to integrate and synchronize these concerns so that the farmers can adopt GUVA japonica rice. Interest check on the usage of GUVA japonica rice variety in rice production as well as suggested improvements were solicited as the basis for continuous R&D pursuits that would eventually promote and adopt the GUVA japonica rice variety from these provinces.

매년 국내로 비래해 오는 해충인 벼멸구는 그 기원이 중국 또는 중국 남부일 것으로 예상해왔으나, 이에 대한 유전학적 근거는 Mun et al. (1999)에 의해 제시된 세 가지 COI haplotype 비교가 유일하다. Mun et al. (1999)은 국내에 서 확인된 두 가지 haplotype 유형이 인도차이나반도 이남의 균일한 한 가지 haplotype 집단 유형과 중국에서 확인 된 또 다른 haplotype 집단 유형임을 근거로 국내 벼멸구의 기원을 중국으로 특정한 바 있다. 본 연구는 국내 및 동남아시아 5개국(부탄, 미얀마, 캄보디아, 라오스 및 태국)으로부터 직간접적으로 확보한 개체들을 대상으로 GBS (genotyping by sequencing) 및 NGS 기법을 통해 PCA를 포함한 다양한 집단유전학적 분석을 수행하였다. 그 결과 인도차이나반도의 벼멸구 집단은 크게 북부와 남부로 나뉘며, 국내 개체들은 북부에 비해 남부(캄보디 아, 태국)에 더 가깝다는 사실을 확인하였다. 따라서 벼멸구의 국내 비래는 중국으로부터의 기원 이전에 장마전 선이 형성될 무렵부터 인도차이나반도 남쪽의 고온다습한 서풍이 남남서풍으로 바뀌면서 중국 내륙을 거쳐 국내로 비래하는 경로를 따르는 것으로 보인다. 하지만 태안의 개체 중에는 인도차이나반도 집단들의 외군으로 확인되는 개체가 있었고, 이는 인도차이나반도 외의 샘플링되지 않은 다른 지역에서도 벼멸구가 국내로 비래할 수 있다는 가능성을 제시하였다. 따라서 국내로 유입되는 벼멸구의 유전적 기원을 확인하기 위해서는 인도차이 나반도 남쪽 지역에서 시작한 동아시아 여름 몬순의 바람이 한국으로 도착하는 경로에 위치한 다른 지역에서의 추가적인 샘플링 및 지속적인 관심과 추적이 필요할 것이다.

Due to the rise of global environmental awareness and concerns, many journal articles related to “fashion sustainability” have been disseminated over the last 20 years. According to Google Search Trends (2010-2021), the number of searches for “sustainable fashion,” “fashion clothing” and “fast fashion” has increased since 2016, particularly “sustainable fashion.” Despite a substantial amount of published papers, many research studies are fragmented and disconnected due to their specific research objectives, focuses, and approaches (Tian et al., 2018). A systematic literature review can identify key research themes, trends, and developmental patterns while also illuminating the complexity of the subjects. This study has three overarching objectives: (1) to provide a comprehensive report of scholarly articles published from 2010 to 2021 focusing on fashion sustainability research, (2) to identify research trends in fashion and sustainability, and (3) to identify significant sustainable and non-sustainable attributes in clothing selection, evaluation, and consumption processes.

Based on expectancy theory, this study examines the extent to which franchisees share innovative ideas within the franchise system as a function of their expectation that the ideas are adopted (success expectancy), and their belief that such effort benefits their own personal interests (valence) under different service industries. In addition, satisfaction is considered as an additional motivator that may promote the sharing of ideas. We argue how can the decision maker (franchisor) be aware and take advantage of unknown innovative ideas the franchisees may have.

The rapid digital transformation and the ever-changing needs of consumers have provided both academia and practice a stimulating setting and chance for grasping evolving opportunities and reinventing the traditional marketing approaches. Agility is one emergent approach to manage challenges like increasing uncertainty or high volatility. Due to its relative novelty, the extant academic literature on marketing agility is narrow, and although the operationalization of the construct is slowly expanding, there is yet the need for further refinement of the definition, the construct, terminology, and its dimensions. Similarly, in practitioner circles there is a growing “buzz” about implementing agile practices (e.g., continuous feedback-learning cycles, collaboration, flexibility, and speed) in the field of marketing to manage changing market environments. What exactly makes an organization, a department, or a team agile is, however, still blurred.

Entomophagy (or insects eating) is seen as a new, sustainable, and promising protein alternative for consumers in Western countries. Although eating insects is not new for many cultures (e.g., Asian culture), it represents a novel and unconventional eating practice in the Western world (e.g., United States and Europe), often characterized by food taboos and by a negative advertising in the media.