Cellulose has experienced a renaissance as a precursor for carbon fibers (CFs). However, cellulose possesses intrinsic challenges as precursor substrate such as typically low carbon yield. This study examines the interplay of strategies to increase the carbonization yield of (ligno-) cellulosic fibers manufactured via a coagulation process. Using Design of Experiments, this article assesses the individual and combined effects of diammonium hydrogen phosphate (DAP), lignin, and CO2 activation on the carbonization yield and properties of cellulose-based carbon fibers. Synergistic effects are identified using the response surface methodology. This paper evidences that DAP and lignin could affect cellulose pyrolysis positively in terms of carbonization yield. Nevertheless, DAP and lignin do not have an additive effect on increasing the yield. In fact, combined DAP and lignin can affect negatively the carbonization yield within a certain composition range. Further, the thermogravimetric CO2 adsorption of the respective CFs was measured, showing relatively high values (ca. 2 mmol/g) at unsaturated pressure conditions. The CFs were microporous materials with potential applications in gas separation membranes and CO2 storage systems.

매년 국내로 비래해 오는 해충인 벼멸구는 그 기원이 중국 또는 중국 남부일 것으로 예상해왔으나, 이에 대한 유전학적 근거는 Mun et al. (1999)에 의해 제시된 세 가지 COI haplotype 비교가 유일하다. Mun et al. (1999)은 국내에 서 확인된 두 가지 haplotype 유형이 인도차이나반도 이남의 균일한 한 가지 haplotype 집단 유형과 중국에서 확인 된 또 다른 haplotype 집단 유형임을 근거로 국내 벼멸구의 기원을 중국으로 특정한 바 있다. 본 연구는 국내 및 동남아시아 5개국(부탄, 미얀마, 캄보디아, 라오스 및 태국)으로부터 직간접적으로 확보한 개체들을 대상으로 GBS (genotyping by sequencing) 및 NGS 기법을 통해 PCA를 포함한 다양한 집단유전학적 분석을 수행하였다. 그 결과 인도차이나반도의 벼멸구 집단은 크게 북부와 남부로 나뉘며, 국내 개체들은 북부에 비해 남부(캄보디 아, 태국)에 더 가깝다는 사실을 확인하였다. 따라서 벼멸구의 국내 비래는 중국으로부터의 기원 이전에 장마전 선이 형성될 무렵부터 인도차이나반도 남쪽의 고온다습한 서풍이 남남서풍으로 바뀌면서 중국 내륙을 거쳐 국내로 비래하는 경로를 따르는 것으로 보인다. 하지만 태안의 개체 중에는 인도차이나반도 집단들의 외군으로 확인되는 개체가 있었고, 이는 인도차이나반도 외의 샘플링되지 않은 다른 지역에서도 벼멸구가 국내로 비래할 수 있다는 가능성을 제시하였다. 따라서 국내로 유입되는 벼멸구의 유전적 기원을 확인하기 위해서는 인도차이 나반도 남쪽 지역에서 시작한 동아시아 여름 몬순의 바람이 한국으로 도착하는 경로에 위치한 다른 지역에서의 추가적인 샘플링 및 지속적인 관심과 추적이 필요할 것이다.

Luxury brands are increasingly embracing intrinsic values in their advertising campaigns. This paper reports an exploratory study examining the adoption of value-laden advertising focusing on intrinsic values. Through a content analysis of ads from 9 top luxury fashion brands, the depiction of intrinsic values was examined. Research results are discussed and academic and managerial implications are presented.

Consumer brand engagement has recently drawn attention for researches because of its importance in predicting brand loyalty. Meanwhile, social media is used as digital marketing tools for marketers to attract and engage younger consumers. This study aims to answer the question whether social marketing efforts by fashion brands on major social media platforms have influence on consumer brand engagement in the context of Vietnamese fashion brands. Social marketing efforts include five dimensions of entertainment, interaction, trendiness, customization and word-of-mouth. Although social marketing efforts has been examined in relationship with other important marketing concepts such as brand equity and customer equity (Godey et al., 2016; Kim and Ko, 2012), few studies have investigated its effect on consumer brand engagement, especially in fashion brands. Besides, Vietnam as an emerging market is witnessing considerable changes that social media brings to every field including fashion markets. It is noticeable that more and more fashion brands in Vietnam are trying to expand and advance their marketing strategies on social media to engage consumers. In this study, a self-administered online survey was delivered to Vietnamese consumers, which included 281 valid responses who followed Vietnamese fashion brands on Facebook or Instagram. The empirical results show that social media efforts engage consumers differently on brand engagement dimensions. The key finding indicates that entertainment and word-of-mouth are positively related to brand engagement in affective, cognitive and behavioral dimensions. Interaction is positively related to affective and behavioral brand engagements. Trendiness is positively related to behavioral brand engagement. Finally, customization is positively related to cognitive brand engagement.

Prior studies have focused primarily on the issue of consumers’ privacy concerns in personalized advertising, but little is known about the effect of transparency awareness using data collection notifications on consumers. This study focuses on the relationship between consumers’ perceptions of the AI algorithms underlying online behavioral advertising (OBA) and the advertising effects. Our research model indicates that displaying data collection notifications regarding OBA and personalized ads increases favorable perceptions of AI systems, such as transparency. Moreover, the model suggests that personalized ads induce higher perceived surveillance than non-personalized ads.

We investigated the electronic and mechanical properties of single-walled carbon nanotubes (SWCNTs) with different tube diameters using density functional theory (DFT) and molecular dynamics (MD) simulation, respectively. The carbon nanotubes’ electronic properties were derived from the index number ( n 1 , n 2 ), lattice vectors, and the rolled graphene sheet orientation. For (6,1) SWCNT, ( n 1-n 2)/3 is non-integer, so the expected characteristic is semiconducting. We have considered (6,1) Chiral SWCNT with different diameters ‘d’ (4.68 Å, 4.90 Å, 5.14 Å, 5.32 Å, 5.53 Å) corresponds to respective bond lengths ‘  ’ (1.32 Å, 1.38 Å, 1.45 Å, 1.50 Å and 1.56 Å) and then analyze the electronic properties from the Linear Combination of Atomic Orbitals (LCAO) based on DFT. We have used both the DFT-1/2 and GGA exchange energy correlation approximations for our calculation and compared the results. In both cases, the energy bandgap is decreasing order with the increase in bond lengths. The lowest value of formation energy was obtained at the bond length  = 1.45 Å ( d = 5.14 Å). For the mechanical properties, we have calculated Young’s modulus using molecular dynamics (MD) simulations. From our calculation, we have found that the (6,1) SWCNT with bond length 1.45 Å ( d = 5.14 Å) has Young’s modulus value of 1.553 TPa.

The carbon-based nanostructures are in limelight due to their widespread applications in nano-to-micro-scale technologies. The carbon dots are known for their unique physical, electrical, optical, chemical and biological properties. The carbon dots (CDs) are being produced through several well-developed synthesis methods, one of which is the green sonochemical. This method is preferred over others because it is a green source of energy, facile, fast, low-temperature process, non-toxic and less expensive. Despite the fact of using 90% less energy than other methods, this method has been overlooked in the published literature. It is possible to prepare pure and doped CDs of low toxicity and controlled physicochemical properties through sonochemical method. In recent years, sonochemically produced CDs have been tuned and characterized for a variety of applications. This review has explored the merits and demerits of sonochemical method in comparison to the other methods for the synthesis of pure CDs and their nanocomposites. The role of multiple factors in tailoring the specific parameters of CDs for their application in antibacterial, polymerization, tissue engineering, catalysis, bio-imagining, supercapacitors, drug delivery and electric devices is also elaborated in this review. This review also concludes on future directions in the applications of sonochemically produced CDs.

We report the comparative study of electronic and optical properties of (6,1) SWCNT from GGA and DFT-1/2 methods. (6,1) SWCNT is a low-bandgap semiconductor, which falls within ( n1 − n2)/3≠ integer. The calculated bandgaps are 0.371 eV and 0.462 eV from GGA and DFT-1/2, respectively. Thus, DFT-1/2 enhanced the electronic bandgap by 24.52%. From both GGA and DFT-1/2 approaches (6,1) SWCNT exhibits an indirect bandgap along Γ − Δ symmetry. However, the percentage change in direct–indirect bandgap is negligibly small, i.e., 4.1% and 3.7% from GGA and DFT-1/2, respectively. The refractive index measured along x-axis ( n x ) approaches unity, indicating transparent behaviour, while that along z-axis ( n z ) goes as high as ∼3.82 for photon energy 0.0 − 0.15 eV, exhibiting opaque behaviour. Again, the value of n z drops below unity at photon energy ∼0.18 eV and again approaches ∼ 1 for higher energy ranges. The optical absorption is highly anisotropic and active within the infrared region.