Nanostructured ZnO materials have been studied extensively because of their functional properties. This paper presents a composite material of zinc oxide quantum dots (ZnO QDs) and porous carbon using a one-step carbonization process. The direct carbonization of a metal–organic complex generates mesostructured porous carbon with a homogeneous distribution of ZnO QDs. The structural and morphological properties are investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The resulting ZnO QDs@porous carbon composite delivers a high specific capacity of 990 mAh g−1 at 100 mA g−1, 357 mAh g−1 at 2 A g−1, and high reversibility when evaluated as an anode for lithium ion batteries.

Using UV nanoimprint lithography(UV-NIL), 1-dimensional(1-D) pattern structures were fabricated on a hybrid mixture thin film of lanthanum oxide and a UV-curable resin. 1-D pattern on a wafer fabricated by the laser interference lithography was transferred to polydimethylsiloxane and this is used as a mold of UV-NIL process. Conducting an X-ray photoelectron spectroscopy, C 1s and La 3d spectra were analyzed, and it was confirmed that hybrid thin film was successfully deposited on glass substrate. Also, transferred pattern structure was observed by using an atomic force microscopy. Through this, it was revealed that agglomerations between 1-D pattern were increased as UV irradiation time increased and this phenomenon disrupted the quality of NIL process. Additionally, liquid crystal(LC) cells with patterned hybrid thin films were fabricated and LC alignment performances were investigated. Using the polarizing optical microscopy and the crystal rotation method, LC alignment state and pretilt angles were observed. Consequently, the uniform homogeneous LC alignment was achieved at UV irradiation time of 1min and 3min where high resolution pattern transfer was observed.

토양검정에 의한 유기자원 시비처방 효과를 구명하기 위하여 유기자원의 질소, 인산, 칼륨 성분 함량에 무기화율을 적용하여 시비량을 설정하고 골든퀸 벼를 대상으로 포장시험을 실시하였다. 1. 초장, 분얼수, 엽색도와 이삭수, 볏짚수량 및 벼 수량은 유기자원과 화학비료처리간 차이가 없었다. 등숙율은 화학비료구에서 가장 낮았으며, 천립중은 무처리구에서 가장 높았다. 2. 현미쌀의 미량원소 중 철은 시비구에서 높았고, 아연은 유기자원구에서 가장 높았으며, 무처리구에서 가장 낮았다. 3. 수확 후 토양화학성 중 산도는 화학비료구에서 높았다. 칼슘과 마그네슘은 시비구에서 높았고, 유효규산함량은 유기자원>화학비료>무처리 순으로 높았다. 4. 벼 수량과 양(+)의 상관이 인정된 토양 화학성은 칼슘, 마그네슘과 유효규산 함량이며, 수량 구성요소로는 이삭수였다. 등숙율과 천립중은 음(-)의 상관이 인정되었다. 벼 수량과 가장 높은 상관을 보인 이삭수(r=0.98)는 토양 칼슘, 마그네슘 및 토양 유효규산과 양(+)의 상관이었다. 5. 화학비료를 대체하기 위하여 토양검정 후 유기자원에 무기화율을 적용하여 시비처방을 한 결과 벼 생육, 볏짚 및 벼 수량에서 유기자원구와 화학비료구의 차이가 없었으며, 현미 쌀의 아연성분과 토양 유효규산함량은 유기자원구에서 더 높아 유기자원으로 화학비료를 대체할 수 있다.

Dry etching of copper thin films is performed using high density plasma of ethylenediamine (EDA)/ hexafluoroisopropanol (HFIP)/Ar gas mixture. The etch rates, etch selectivities and etch profiles of the copper thin films are improved by adding HFIP to EDA/Ar gas. As the EDA/HFIP concentration in EDA/HFIP/Ar increases, the etch rate of copper thin films decreases, whereas the etch profile is improved. In the EDA/HFIP/Ar gas mixture, the optimal ratio of EDA to HFIP is investigated. In addition, the etch parameters including ICP source power, dc-bias voltage, process pressure are varied to examine the etch characteristics. Optical emission spectroscopy results show that among all species, [CH], [CN] and [H] are the main species in the EDA/HFIP/Ar plasma. The X-ray photoelectron spectroscopy results indicate the formation of CuCN compound and C-N-H-containing polymers during the etching process, leading to a good etch profile. Finally, anisotropic etch profiles of the copper thin films patterned with 150 nm scale are obtained in EDA/HFIP/Ar gas mixture.

The emission of particulate matter and volatile organic compounds (VOCs) from a motor vehicle painting booth was quantitatively evaluated. Most particulate matter was emitted during the spraying process, in which the PM10 concentration was 16.5 times higher than that of the drying process. When the paint was being sprayed, the particles with a diameter of 1.0~2.5 μm accounted for 39.4% and particles greater than 2.5 μm in diameter accounted for 30.6% of total particles. On the other hand, small particles less than 0.5 μm in diameter accounted for 52.4% of total particles during the drying process. In contrast to the particulate matter, high concentrations of VOCs were emitted during both spraying and drying processes. Butyl acetate, xylene, toluene, and m-ethyltoluene were the most abundant VOCs emitted from the motor vehicle painting booth. Additionally, xylene, butyl acetate, toluene, and 1,2,3-trimethylbenzene were the dominant ozone precursors. Especially, xylene exhibited the highest ozone production contribution (32.5~44.4%) among 34 species of the ozone precursors. The information obtained in this study can be used to establish a suitable management strategy for air pollutants from motor vehicle painting booths.