The influence of the polarity of the spreading solvent on the properties of the monolayer of poly(styrene-co-acrylonitrile)'s with various acrylonitrile contents was studied. The surface pressure - area isotherm and the apparent dipole moment - area isotherm were obtained and analyzed when the mixtures of methylene chloride and N-N-dimethylformamide used as spreading solvent. The isotherms were strongly influenced by the polarity of the solvent.

최근 공학분야에서 다루어지고 있는 문제의 규모가 대형화하고 있으며 이러한 대형구조물의 구조설계는 부재의 강도설계 및 절점의 변위조절을 위하여 많은 수의 구조해석을 요구한다. 한 대의 개인용 컴퓨터에 의한 대형구조물의 구조해석은 대용량의 기억장치와 많은 계산 시간이 요구되므로 반복적 해석이 필요한 대형구조물의 설계에 효율적으로 이용되기 어려운 실정이다. 따라서, 본 논문에서는 이러한 문제에 대한 대안으로 다수의 개인용 컴퓨터들을 네트워크로 연결하여 고성능 병렬연산시스템을 구성하고 이에 적합한 두 가지 형태의 분산구조방정식해법들을 반복법인 PCG 알고리즘을 이용하여 개발하였다. 대형구조물을 위한 분산구조해석법은 구조해석 과정에 요구되는 각 컴퓨터 상호 간의 통신회수와 통신량을 최소화할 수 있도록 개발되었다. 분산구조해석법의 성능은 대규모 3차원 트러스 구조물 및 144층 가새 튜브구조물의 구조해석에 적용하여 분석하였다.

Polyoxyethylene monooleate was prepared by addition of ethylene oxide to oleic acid. And also, polyoxyethylene monooleate type oil dispersant was prepared by blending polyoxyethylene monooleate, n-paraffine, sorbitan monooleate, sorbitan monopalmitate, and palm oil. Dispersion efficiency test was carried out by vertical shaking flask and swirling flask methods. Low toxic oil dispersant was prepared with polyoxyethylene monooleate, which has high biodegradability and excellent dispersion efficiency on crude oils and weathered W/O emulsions with high viscosity, and its dispersion efficiency was measured to various crude oils and weathered oils.

The sodium α-sulfo fatty acid vinyl ester oligomers, which are oligomer type surfactants were prepared by polymerization with fatty acid vinyl acetate. The α-sulfonation of fatty acid vinyl ester oligomers were carried by direct addition of sulfur trioxide. The dispersing performance of oligomer type anionic surfactants and sodium dodecyl sulfate(SDS) in the aqueous suspension of iron oxide and titanium dioxide particles was evaluated by particle size distribution and zeta-potential measurement. As results, the particles of iron oxide and titanium dioxide were flocculated by addition of small amount of oligomer type anionic surfactants and sodium dodecyl sulfate(SDS), then the flocks redispersed by more addition of oligomer type anionic surfactants and SDS. The flocculation, redispersion process was observed in lower concentration range of oligomer type anionic surfactants than SDS. Especially, the dispersing action of sodium α-sulfo palmitic acid vinyl ester oligomer was better than sodium α-sulfo lauric acid vinyl ester oligomer.

(Fe0.98Mn0.02)xSi2(x≤1) 조성으로, 용융법으로 제조한 α-Fe2Si5상의 잉곳을 730~850˚C에서 4~20시간 열처리하거나, 기계적 합금화로 제조한 ε-FeSi과 Si상으로 구성된 분말을 760~850˚C에서 10분간 가압통전소결하므로써 β-FeSi2기지상에 Si이 분산된 미세조직을 얻을 수 있었다. 조성, 열처리 온도와 소결 온도에 따라 Si 분상의 크기와 간격이 각기 0.05~0.27μm와 0.2~0.6μm 범위에서 변화하였다. 이와 같은 Si 분산상에 의해 β-FeSi2의 격자 열전도도가 감소되어 성능지수가 향상될 수 있을 것으로 기대된다.

Low toxic concentrated oil dispersant using n-Paraffin and Di(ethylene glycol)mono butylether mixed solvent was prepared, and tested by oil dispersant performance test method, and oil dispersant efficiency was measured using vertical shaking method to 3 kinds of Crude oil, Bunker oil and W/O emulsions with different physical properties by appling the prepared dispersant. Although toxicity test was performed with Flat fish and Rock fish by appling the mixed oils emulsified using prepared oil dispersant, couldn't find the toxicity to them. Concentrated oil dispersant prepared has a good dispersion efficiency of 97.2% after 0.5min settling time and 28.3% after 10min settling time to Bunker B oil with 10% water solution. Especially, the concentrated oil dispersant showing the low toxicity to Oryzias Latipes(24hr, TLm) was 54,000 ppm and to Brine Shrimp Artemia(24hr, TLm) was 51,000ppm, and also, it was completely biodegradated to 99.1% after 7~8days.

The analytical solutions of the Fraunhofer Diffraction(FD) theory and the principle for measurement of the dispersion relation of plasma wave is presented. Especially, the method for measurement of low-frequency wave is discussed. The wavenumbers of the density fluctuations are obtained from the curve fitting between the expremental FD profile and theoretical one for each frequency component. In measurement of the wavenumber of the low -frequency region, the information of the wavenumber is easily obtained from the ratio of the intensity at = 0 to the intensity at =0.5. The millimeter wave FD apparatus was designed to measure low-frequency density fluctuations. The determined wavenumbers are in the range of =0.1~ 1.0cm. Thus, the millimeter wave FD method was shown to be useful for the measurement of low-frequency density fluctuations, which are impossible to be measured by using a convention. Thomson scattering. The obtained dispersion relations will be useful information for plasma waves.

Fluorescent anionic oligo surfactants were synthesized by the condensing products of long chain alkylvinylether-maleic anhydride cooligomers and resorcinol including dye structures. Their various surface activities and dispersing action were studied on the aqueous solution. These oligo surfactants exhibited a remarkable surface tension lowering property, lower foaming and a large dispersing action for the particles of α-copper phthalocyanine blue. Further it was ascertained that the binding of oligo surfactant onto the pigment surface caused the deviation towards lower wavelengths at the maximum fluorescent intensity as compared with aqueous oligo surfactant solutions, These surface active properties of the oligo surfactants may be attributed to rigid and hydrophobic structure of dye groups, besides surface-active groups of alkylether groups and carboxylic group of the anionic oligo surfactants.

NiAl powders containing oxide dispersoids have been produced by mechanical alloying process in a controlled atmosphere using high energy attrition mill. The powders have been consolidated by hot extrusion and hot pressing followed by isothermal annealing to induce microstructure coarsening to improve high temperature properties. Grain growth and dispersoid coarsening kinetics have been investigated as functions of annealing time and temperature. Coarsening of dispersion strengthen NiAl and dispersoid has been discussed. Some clues of secondary recrystallization have been investigated. Mechanical property measurements have been also made and correlated with the microstructures.

분말야금법으로 제조된 A6061기 입자분산강화 복합재의 열간압술가공에 있어서 압출특성에 미치는 강화입자의 종류, 빌렛특성 및 암술조건의 영향에 대하여 조사하였다. A6061기 복합재료의 열간 압술 전단 변형저항에 미치는 강화입자종류의 영향은 Si Cw > A12 O3f > A12 O3f > Si Cp의 순으로 되었으며, 모든 강화입자에서 부피분율이 증가함에 따라서 Kw값도 증가하였다. 압출조건, 강화입자의 첨가량 및 첨가입자의 평균입도에 관계없이 A12 O3p가 첨가된 복합재의 열간압출가공에 필요한 소요압력은 Si Cp의 경우보다 컸다. 압출압력은 압출 다이스 반각이 커질수록 감소하는 경향은 나타났다. 이것은 다이스 반각에 의해 생성되는 빌렛과의 접촉면적이 증가하여 전단마찰응력(m k3)이 상승하기 때문이다. 압출시 압출온도 상승은 저온에서 ~50˚C 정도 증가하였으며, 압출온도가 500˚C 이상이 되면 압출재 표면에 극심한 tearing이 발생하였다. 강화입자의 첨가량이 증가할수록 이 현상은 더 심하게 되었다.게 되었다.