The purpose of this study was to investigate the odor arising from the Cheong-ju industrial complex area for odor materials confirmation, and to predict the impact of the odor in the residential area using the CALPUFF Model. Among the odor causing substances in the area with a rising number of collective complaints due to odor, methyl sulfide, acetaldehyde, propionaldehyde, n-buthylaldehyde, n-valeraldehyde and styrene were detected. Odor causing substances detected in the area surrounding the industrial complex include ammonia, hydrogen sulfide, n-buthylaldehyde, toluene, xylene, benzene and styrene. Using the CALPUFF Model, it was predicted that 1hr average was 3.981~7.553 OU/m3 and 24hr average was 1.753~2.359 OU/m3. In terms of odor intensity, the predicted 1hr average was 0.6~0.9 and the 24hr average was 0.2~0.4.

In this study, we fabricated Nd2Fe14B hard magnetic powders with various sizes via spray drying combined with reduction-diffusion process. Spray drying is widely used to produce nearly spherical particles that are relatively homogeneous. Thus, the precursor particles were prepared by spray drying using the aqueous solution containing Nd salts, Fe salts and boric acid with the target stoichiometric composition of Nd2Fe14B. The mean particle sizes of the spray-dried powders are in the range from one to seven micrometer, which are adjusted by controlling the concentra- tions of precursor solutions. After debinding the as-prepared precursor particles, ball milling was also conducted to con- trol the particle sizes of Nd-Fe-B oxide powders. The resulting particles with different sizes were subjected to subsequent treatments including hydrogen reduction, Ca reduction and washing for CaO removal. The size effect of Nd-Fe-B oxide particles on the formation of Nd2Fe14B phase and magnetic properties was investigated.

일반적으로 액체가스운반선은 인화성 화물이나 독성물질을 운반한다. 이러한 화물들은 폭발, 화재 및 인명손상을 가져올 수 있기 때문에, 액체가스운반선의 거주구역, 서비스 구역 및 통제실은 가스의 유입이 원천적으로 차단되도록 설계한다. 이러한 이유로, IMO IGC 코드의 멤브레인형 LNG선박의 화물탱크에 설치되는 벤트 출구의 높이는 노출갑판상 B/3 또는 6m 중 큰 것 이상으로 하고 작업구역 및 전후부 통행로, 갑판상의 저장탱크 및 화물설계 액위보다 6m 이상 높게 설치하여야 한다라고 규정하고 있다. 또한 LNG 시장이 점진적으로 증가하면서, LNG선박의 크기도 증가해 왔다. 때문에 현 규정에 의하면 LNG선박의 벤트의 높이는 선박 폭(B)에 비례하기 때문에 상당히 높아져야 할 것이며, 이는 높은 벤트 마스트(Mast)로 인하여 작업의 어려움 및 전방 시야를 방해하는 등 항해의 어려움을 초래한다. 본 연구에서는 멤브레인형 LNG선의 Sea-trial시에 측정하였던 데이터 및 CFD유동해석을 통해 LNG선박 화물탱크의 벤트 출구의 높이에 대한 적합성 평가를 수행한다.

In the present study, we systematically investigated the effect of Mn addition on nitrogenation behavior and magnetic properties of Sm-Fe powders produced by reduction-diffusion process. Alloy powders with only single phase were successfully produced by the reduction-diffusion process. The coercivity of powder rapidly increased during nitrogenation and reached the maximum of 637 Oe after 16 hours. After further nitrogenation, it decreased. In contrast, the coercivity of powder gradually increased during nitrogenation for 24 hours. The coercivity of powder was higher than that of powder at the same condition of nitrogenation. It was considered that the Mn addition facilitates the nitrogenation of powder and enhances the coercivity.

In this paper, a three dimensional numerical analysis tool was applied to study the PEMFC performance characteristics. The porosity and electrical conductivity of GDL and CL as well as the relative humidity of anode and cathode channel gas were selected as simulation parameters. As the porosity of GDL and CL increases, current density and temperature increase because reactant gases diffuse well. As the electrical conductivity of GDL and CL increases, current density and temperature increase due to increased electron transfer rate. As anode relative humidity increases, current density and temperature increase. Unlike anode, current density and temperature increase when cathode relative humidity increases from 0 percent to 60 percent. Then current density and temperature decrease when cathode relative humidity increases from 60 percent to 100 percent.

In this study, we inserted a Zn buffer layer into a AZO/p-type a-si:H layer interface in order to lower the contact resistance of the interface. For the Zn layer, the deposition was conducted at 5 nm, 7 nm and 10 nm using the rf-magnetron sputtering method. The results were compared to that of the AZO film to discuss the possibility of the Zn layer being used as a transparent conductive oxide thin film for application in the silicon heterojunction solar cell. We used the rf-magnetron sputtering method to fabricate Al 2 wt.% of Al-doped ZnO (AZO) film as a transparent conductive oxide (TCO). We analyzed the electro-optical properties of the ZnO as well as the interface properties of the AZO/p-type a-Si:H layer. After inserting a buffer layer into the AZO/p-type a-Si:H layers to enhance the interface properties, we measured the contact resistance of the layers using a CTLM (circular transmission line model) pattern, the depth profile of the layers using AES (auger electron spectroscopy), and the changes in the properties of the AZO thin film through heat treatment. We investigated the effects of the interface properties of the AZO/p-type a-Si:H layer on the characteristics of silicon heterojunction solar cells and the way to improve the interface properties. When depositing AZO thin film on a-Si layer, oxygen atoms are diffused from the AZO thin film towards the a-Si layer. Thus, the characteristics of the solar cells deteriorate due to the created oxide film. While a diffusion of Zn occurs toward the a-Si in the case of AZO used as TCO, the diffusion of In occurs toward a-Si in the case of ITO used as TCO.

The size of hydrogen molecule is not so small as to invade into the lattice of material, and therefore, hydrogen invades into the material as atom. Hydrogen movement is done by diffusion or dislocation movement in the near crack tip or plastic deformation. Hydrogen appeared to have many effects on the mechanical properties of the Cr-Mo steel alloys. The materials for this study are 1.25Cr-0.5Mo and 2.25Cr-1Mo steels used at high temperature and pressure. The hydrogen amount obtained by theoretical calculation was almost same with the result solved by finite element analysis. The distribution of hydrogen concentration and average concentration was calculated for a flat specimen. Also, finite element analysis was employed to simulate the redistribution of hydrogen due to stress gradient. The calculation of hydrogen concentration diffused into the material by finite element method will provide the basis for the prediction of delayed fracture of notched specimen. The distribution of hydrogen concentration invaded into the smooth and notched specimen was obtained by finite element analysis. The hydrogen amount is much in smooth specimen and tends to concentrate in the vicinity of surface. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

Ag2O를 첨가한 압축 벤토나이트에 대하여 관통 확산법으로 요오드 이온의 이동 특성을 관찰하였다. Ag2O를 첨가하지 않은 압축 벤토나이트와 마찬가지로 Ag2O를 첨가한 압축 벤토나이트에서도 요오드 이온은 확산에 의하여 이동하는데, Ag2O를 첨가한 압축 벤토나이트는 Ag2O를 첨가하지 않은 압축 벤토나이트에 비하여 요오드 이온의 초기 누출 시간이 지연되는 것으로 나타났다. Ag2O를 첨가한 압축 벤토나이트에서 요오드 이온의 초기 누출 시간 지연은 확산 용액으로 순수 요오드 이온 수용액을 사용하였을 때 뿐만 아니라 0.1 M NaCl-요오드 이온 수용액을 사용하였을 때에도 관찰되었다. 또한 Ag2O를 첨가한 압축 벤토나이트의 겉보기 확산 계수는 Ag2O를 첨가하지 않은 압축 벤토나이트의 겉보기 확산 계수보다 낮은 값을 나타내었다. Ag2O를 첨가하지 않은 압축 벤토나이트의 유효 확산 계수는 기존 문헌에 보고된 값 과 거의 일치하는 결과를 얻었으며, Ag2O를 첨가한 압축 벤토나이트에서 요오드 이온의 유효 확산 계수는 Ag2O 첨가에 따라 대체적으로 감소하는 경향을 나타내었다.

The microstructure and Cu diffusion barrier property of Ta-Si-N films for various Si and N compositions were studied. Ta-Si-N films of a wide range of compositions (Si: 0~30 at.%, N: 0~55 at.%) were deposited by DC magnetron reactive sputtering of Ta and Si targets. Deposition rates of Ta and Si films as a function of DC target current density for various N2/(Ar+N2) flow rate ratios were investigated. The composition of Ta-Si-N films was examined by wavelength dispersive spectroscopy (WDS). The variation of the microstructure of Ta-Si-N films with Si and N composition was examined by X-ray diffraction (XRD). The degree of crystallinity of Ta-Si-N films decreased with increasing Si and N composition. The Cu diffusion barrier property of Ta-Si-N films with more than sixty compositions was investigated. The Cu(100 nm)/Ta-Si-N(30 nm)/Si structure was used to investigate the Cu diffusion barrier property of Ta-Si-N films. The microstructure of all Cu/Ta-Si-N/Si structures after heat treatment for 1 hour at various temperatures was examined by XRD. A contour map that shows the diffusion barrier failure temperature for Cu as a function of Si and N composition was completed. At Si compositions ranging from 0 to 15 at.%, the Cu diffusion barrier property was best when the composition ratio of Ta + Si and N was almost identical.

Experimental measurements of flame shape and heat transfer characteristics were performed for impinged inverse diffusion flame(IDF) using propane as a fuel. The purpose of this study is to identify the favorable co-axial inverse diffusion flame structure for impingement heating. The flame consisted of an entrainment zone and mixing and combustion zone. The heat flux which represents heat transfer rate is measured by using a heat flux sensor that is located at the center of the impingement plate. The inverse diffusion flame structure has been classified into six modes. In these modes, several favorable flames for impingement heating were identified. In this study, the parameters are overall equivalent ratio(Φ), nozzle to impingement plate distance(h/d), vertical distance from the stagnation point and Reynolds number(Re) of combustion air.

본 연구는 지붕개폐형 구조물에서 지붕을 개폐함으로써 나타나는 음장의 특성변화를 파악하기 위하여 1/20스케일의 축소모형을 제작하고 이를 대상으로 개폐율을 조절하면서 음장변화를 측정 분석하였다. 공간의 음향설계 시 사용되는 기존의 설계 및 평가파라메타들을 검토한 결과, 잔향음의 감쇠과정이 비선형적이며 기존의 잔향감 평가파라메타인 잔향시간에 의해서 적절한 설계 및 성능평가가 이루어지기 어려울 것으로 분석되었다. 특히 비선형적 감쇠구간에 대한 선형적 curve-fitting에 의해 실제 청감과는 거리가 먼 매우 긴 잔향시간이 도출되어 실질적인 효용성이 의심된다. 따라서 잔향시간(T30)을 음향설계 및 평가과정에서 중요설계변수로 활용 시 완공 후 얻게 되는 음장특성과 상이한 결과를 초래할 가능성이 있다. EDT의 경우 전체적으로 초기감쇠시간은 개폐율이 증가할수록 짧아지는 경향을 나타내었다. 주파수별로 저주파수대역에서의 감쇠율이 가장 높게 나타났으며 고주파수 대역으로 갈수록 감쇠율은 둔화되는 것으로 평가되었다. 명료도 관련 파라메타인 D50 또한 개폐에 따른 음장의 변화를 효과적으로 나타내고 있는 것으로 분석되었다. 객석부위별로는 지붕개폐면에 직접 노출되지 않는 객석에서 개폐율 증가에 따라 선형적인 감쇠현상이 나타나고 있으나, 직접 노출되는 객석의 경우에는 40%이상의 개폐율에서는 명료도와 잔향감에 영향을 거의 미치지 않는 것으로 나타났다.

최근 다양한 목적의 대공간 사용이 보편화되고 있다. 이들 공간에 대한 다목적요구로 인해 최근 건립되는 대형 스포츠시설들은 스포츠뿐만 아니라 공연과 같은 다양한 이벤트를 수용하도록 요구받고 있다. 다양한 이벤트 상태의 제공을 위해서 건물의 일부를 부분적으로 개폐하는 방식의 사용이 빈번해지고 있으며 이와 같은 부분적 개폐는 자유음장과 확산음장의음향적 연결을 초래하여 음향설계단계에서 어려움을 초래할 것으로 예상된다. 본 연구에서는 1/10 축소모형을 이용하여 확산음장과 자유음장의 음향적 연결에 따른 음장의 음향특성을 측정 분석하였다. 연구결과, 저중주파수 대역에서의 잔향시간은 개구율이 증가함에 따라 고주파수 대역에서보다 빠른 감쇠를 나타내었다. 또한 EDT는 모든 주파수대역에서 개구율 증가에 선형적으로 비례하여 감쇠하는 것으로 나타났다. 명료도는 개구율이 12.5%에 이르기까지 거의 영향을 받지 않으며 그 이후에는 선형적으로 비례하여 증가하였다. 에너지 감쇠패턴의 분석결과, 이중 및 삼중의 감쇠패턴이 나타나고 있으며, Schroeder 적분에 의한 잔향시간의 산출은 부적절한 것으로 판단된다. 따라서 부분적 개방형 공간의 잔향예측에 있어서 EDT가 보다 적절한 것으로 판단된다.

The diffusion behavior of phenol, toluene and benzoic acid in aqueous SDS solution was examined. It showed a similar experimental results for phenol and toluene. The diffusion coefficients of the solutes were characterized by the presence of two distinct regions: below the cmc and above the cmc. For phenol and toluene, it remained approximately unchanged when the SDS concentration was below the cmc. Above the cmc there was an apparent decrease in the diffusion coefficients of the two solutes with increasing SDS concentration. However, for benzoic acid the diffusion behavior was different from that of phenol and toluene. The diffusion coefficient of benzoic acid decreased slightly with increasing SDS concentration, however the diffusion coefficient was almost constant above the cmc. For benzoic acid the diffusion behavior was dependent on the joint contribution of benzoic acid molecules as well as the benzoate ions.