PURPOSES : NOx is a particle matter precursor that is harmful to humans. Various methods of removing NOx from the air have been developed. TiO2 and activated carbon are particularly useful materials for removing NOx, and the method is known as particulate matter precursor reduction. The removal of NOx using TiO2 requires sunlight for the photocatalytic reaction, whereas activated carbon absorbs NOx particles into its pores after contact with the atmosphere. The purpose of this study is to evaluate the NOx removal efficiency of TiO2 and activated carbon applied to concrete surfaces using the penetration method. METHODS : Surface penetration agents, such as silane-siloxane and silicate, were used. Photocatalyst TiO2 and adsorbent activated carbons were selected as the materials for NOx removal. TiO2 used in this study was formed by crystal structures of anatase and rutile, and plant-type and coal-type materials were used for the activated carbon. Each surface penetration agent was mixed with each particulate matter sealer at a concentration ratio of 8:2, and the mixtures were sprayed onto the surface. The NOx removal efficiency was evaluated using NOx removal efficiency equipment fabricated in compliance with the ISO 22197-1 standard. RESULTS : Anatase TiO2 showed a maximum NOx removal efficiency of 48% when 500 g/m² was applied. However, 500 g/m² of rutile TiO2 showed a NOx removal efficiency of up to 10%. When 700 g/m² of coal-based activated carbon and plant-based activated carbon was used, NOx removal efficiencies of up to 11% and 14%, respectively, were obtained. CONCLUSIONS : Rutile TiO2, a coal-based activated carbon, and plant-based activated carbon have lower NOx removal efficiencies than anatase TiO2. A lower amount of anatase TiO2 (500 g/m²), compared to the other spraying volumes, yielded the most significant NOx removal efficiency under optimal conditions. Therefore, it is recommended that 500 g/m² of anatase TiO2 should be sprayed onto concrete structures to improve the economic and long-term performance of these structures.

This paper is to investigate the retrofitting effect for a non-seismic reinforced concrete frame strengthened by perimeter steel moment frames with indirect integrity, which ameliorates the problems of the direct integrity method. To achieve this, first, full-scale tests were conducted to address the structural behavior of a two-story non-seismic reinforced concrete frame and a strengthened frame. The non-seismic frame showed a maximum strength of 185 kN because the flexural-shear failure at the bottom end of columns on the first floor was governed, and shear cracks were concentrated at the beam-column joints on the second floor. The strengthened frame possessed a maximum strength of 338 kN, which is more than 1.8 times that of the non-seismic specimen. A considerable decrease in the quantity of cracks for the strengthened frame was observed compared with the non-seismic frame, while there was the obvious appearance of the failure pattern due to the shear crack. The lateral-resisting capacity for the non-seismic bare frame and the strengthened frame may be determined per the specified shear strength of the reinforced columns in accordance with the distance to a critical section. The effective depth of the column may be referred to as the longitudinal length from the border between the column and the foundation. The lateral-resisting capacity for the non-seismic bare frame and the strengthened frame may be reasonably determined per the specified shear strength of the reinforced columns in accordance with the distance to a critical section. The effective depth of the column may be referred to as the longitudinal length from the border between the column and the foundation. The proposed method had an error of about 2.2% for the non-seismic details and about 4.4% for the strengthened frame based on the closed results versus the experimental results.