Tritium is a radioactive isotope of hydrogen with a half-life of about 12.3 years, and it is commonly found in the environment as a result of the production of Nuclear Power Plants. The World Health Organization (WHO) has established guidelines for the permissible levels of tritium in drinking water. The guideline value for tritium in drinking water is 10,000 Bq/L. It is important to note that the guideline value for tritium is not a legal limit, but rather a recommendation. National and local authorities may establish legal limits that are more restrictive than the WHO guideline value based on local conditions and risk assessments. The Australia and Finland have set a limit for tritium in drinking water at 76,103 Bq/L and 30,000 Bq/L respectively, which is more than three to seven times higher compare to guideline value of WHO. The United States Environmental Protection Agency (EPA) has set a maximum contaminant level (MCL) for tritium in drinking water at 20,000 picocuries per liter (pCi/L), which is equivalent to 740 Bq/L. The Health Canada has set a guideline value for tritium in drinking water at 7,000 Bq/L. Assuming drinking water corresponding to each tritium limit (or guideline value) for one year, the expected exposure dose is 0.01 mSv to 1 mSv. It means that the tritium in drinking water below the limits or guideline value does not pose a significant risk to human health.

Pressurized Heavy Water Reactors (PHWR) have stored ion exchange resins, which are used in deuteration, dehydrogenation systems, liquid waste treatment systems, and heavy water cleaning systems, in spent resin storage tanks. The C-14 radioactivity concentration of PHWR spent resin currently stored at the Wolseong Nuclear Power Plant is 4.6×10E+6 Bq/g, which exceeds the limited concentration of low-level radioactive waste. In addition, when all is disposed of, the total radioactivity of C-14, 1.48×10E+15 Bq, exceeds the disposal limit of the first-stage disposal facility, 3.04×10E+14. Therefore, it is currently impossible to dispose of them in Gyeongju intermediate- and low-level disposal facilities. As to dispose of spent resins produced in PHWR, C-14 must be removed from spent resins. This C- 14 removal technology from the spent resin can increase the utilization of Gyeongju intermediate- and low-level disposal facilities, and since C-14 separated from the spent resin can be used as an expensive resource, it is necessary to maximize its economic value by recycling it. The development of C-14 removal technology from the spent resin was carried out under the supervision of Korea Hydro & Nuclear Power in 2003, but there was a limit to the C-14 removal and adsorption technology and process. After that, Sunkwang T&S, Korea Atomic Energy Research Institute, and Ulsan Institute of Science and Technology developed spent resin treatment technology with C-14-containing heavy water for the first and second phases from 2015 to 2019 and from 2019 to the present, respectively. The first study had a limitation of a pilot device with a treatment capacity of 10L per day, and the second study was insufficient in implementing the technology to separate spent resin from the mixture, and it was difficult to install on-site due to the enlarged equipment scale. The technology to be proposed in this paper overcomes the limitations of spent resin mixture separation and equipment size, which are the disadvantages of the existing technology. In addition, since 14CO2 with high concentration is stored in liquid form in the storage tank, only the necessary amount of C-14 radioactive isotope can be extracted from the storage tank and be used in necessary industrial fields such as labeling compound production. Therefore, when the facility proposed in this paper is applied for treating mixtures in spent resin tanks of PHWR, it is expected to secure field applicability and safety, and to reflect the various needs of consumers of labeled compound operators utilizing C-14.

In this study, four technologies were selected to treat river water, lake water, and groundwater that may be contaminated by tritium contaminated water and tritium outflow from nuclear power plants, performance evaluation was performed with a lab-scale device, and then a pilot-scale hybrid removal facility was designed. In the case of hybrid removal facilities, it consists of a pretreatment unit, a main treatment unit, and a post-treatment unit. After removing some ionic, particulate pollutants and tritium from the pretreatment unit consisting of UF, RO, EDI, and CDI, pure water (2 μS/cm) tritium contaminated water is sent to the main treatment process. In this treatment process, which is operated by combining four single process technologies using an inorganic adsorbent, a zeolite membrane, an electrochemical module and aluminumsupported ion exchange resin, the concentration of tritium can be reduced. At this time, the tritium treatment efficiency of this treatment process can be increased by improving the operation order of four single processes and the performance of inorganic adsorbents, zeolite membrane, electrochemical modules, and aluminum- supported ion exchange resins used in a single process. Therefore, in this study, as part of a study to increase the processing efficiency of the main treatment facility, the tritium removal efficiency according to the type of inorganic adsorbent was compared, and considerations were considered when operating the complex process.

The separation of hydrogen isotopes is a critical issue in various fields, such as deuterium or tritium production and the treatment of radioactively contaminated water. In this presentation, we describe the pervaporative separation of hydrogen isotopes using proton conductive membranes and underlying separation mechanism. We investigated the H/D separation factors of perfluorosulfonic acid (Nafion) and polybenzimidazole membranes using pervaporation, and found that both membranes exhibited similar separation factors of approximately 1.026. Water permeation flux through the membranes was highly dependent on their thickness and type, and increased with operation temperature. However, the effect of temperature on H/D separation factor was negligible. We also demonstrated the cascade separation of H/D, indicating the potential application of multi-stage operation. We found that surface transport mechanisms such as hydron hopping contributed the most to H/D separation during the pervaporation process of proton conductive membranes.

According to IAEA PRIS, there is no record of dismantling commercial heavy water reactors among 57 heavy water reactors around the world. In Canada, which has the largest number of heavy water reactors, three of the 22 commercial heavy water reactors with more than 500 MW are permanently suspended, Gentilly unit 2 (2012), Pickering unit 2 (2007), and Pickering unit 3 (2008), all of which chose a delayed decommissioning strategy. On the other hand, Wolsong unit 1, which will be the world’s first heavy water reactor to be dismantled commercially, will be immediately carried out as a decommissioning strategy. KHNP has established various cooperation systems with advanced companies and international organizations related to overseas NPP decommission and is actively exchanging technologies. Among them, the most important focus is on research cooperation related to COG (CANDU owners Group). The first case is a joint study on Conceptual Calandria Segmentation. Four areas of process, waste management, ALARA, and cost for decommissioning reactors to be submitted to Canadian regulators for approval of Pickering and Gentilly-2’s preliminary decommissioning plan have been evaluated, and research on Wolsong unit 1 is currently underway. The second case is Decommissioning and long-term waste management R&D. Although the technical maturity is low, it studies the common interests of member companies in the decommissioning of heavy water reactor power generation companies and long-term waste management. Robotics for dismantling high-radiation structures, C- 14, H-3 measurement and removal methods, and concrete decontamination technology, which are characterized by heavy water, are being actively studied. KHNP is strengthening international cooperation with COG to prepare for the successful decommissioning of Wolsong unit 1. Based on previous studies by Pickering and Gentilly-2, an evaluation of the decommissioning of Wolsong unit 1 reactor is being conducted. In addition, it is preparing for decommissioning through experience analysis of the pressure tube replacement project.

KHNP is carrying out international technical cooperation and joint research projects to decommission Wolsong unit 1 reactor. Construction data of the reactor structures, experience data on the pressure tube replacement projects, and the operation history were reviewed, and the amount of dismantled waste was calculated and waste was classified through activation analysis. By reviewing COG (CANDU owners Group) technical cooperation and experience in refurbishment projects, KHNP’s unique Wolsong unit 1 reactor decommissioning process was established, and basic design of a number of decommissioning equipment was carried out. Based on this, a study is being conducted to estimate the worker dose of dismantling workers. In order to evaluate the dose of external exposure of dismantling workers, detailed preparation and dismantling processes and radiation field evaluation of activated structures are required. The preparation process can be divided into dismantlement of existing facilities that interfere with the reactor dismantling work and construction of various facilities for the dismantlement process. Through process details, the work time, manpower, and location required for each process will be calculated. Radiation field evaluation takes into account changes in the shape of structures by process and calculates millions of areas by process, so integrated scripts are developed and utilized to integrate input text data. If the radiation field evaluation confirms that the radiation risk of workers is high, mutual feedback will be exchanged so that the process can be improved, such as the installation of temporary shields. The results of this study will be used as basic data for the final decommissioning plan for Wolsong unit 1. By reasonably estimating the dose of workers through computer analysis, safety will be the top priority when decommissioning.

For decontamination and quantification of trace amount of tritium in water, an efficient separation technology capable of enriching tritium in water is required. Electrolysis is a key technology for tritium enichment as it has a high H/T and D/T separation factors. To separate tritium, it is important to develop a proton exchange membrane (PEM) electrolyzer having high hydrogen isotope separation factor as well as high electrolyzer cell efficiency. However, there has not been sufficient research on the separation factor and cell efficiency according to the composition and manufacturing method of the membrane electrode assembly (MEA) Therefore, it is necessary to study the optimal composition and manufacturing method of the MEA in PEM electrolyzer. In this study, the H/D separation factor and water electrolysis cell efficiency of PEM electrolyzer were analyzed by changing the anode and cathode materials and electrode deposition method of the MEA. After the water electrolysis experiment using deionized water, the D/H ratio in water and hydrogen gas was measured using a cavity ring down spectrometer and a mass spectrometer, respectively, and the separation factor was calculated. To calculate the cell efficiency of water electrolysis, a polarization curves were obtained by measuring the voltage changes while increasing the current density. As a result of the study, the water electrolyzer cell efficiency of the MEA fabricated with different anode/cathode configurations and electrode formation methods was higher than that of commercial MEA. On the other hand, the difference in H/D separation factor was not significant depending on the MEA fabrication methods. Therefore, using a cell with high cell efficiency when the separation factor is the same will help construct a more efficient water electrolysis system by lowering the voltage required for water electrolysis.

Japan’s government has announced plan to release the contaminated water stored from the tanks of the Fukushima Daiichi nuclear power plant site into the sea in June. The contaminated water is treated by SARRY (Cesium removal facility) and ALPS (advanced liquid processing system) to remove 62 radionuclide containing Cesium, Strontium, Iodine, and so on using filtration, precipitation (or coprecipitation) and adsorption for other nuclides (except for H-3 and C-14). The total amount of the contaminated water stored at tanks is 1,328,508 m3 (as of March 23, 2023). Currently, three ALPS systems which are existing ALPS, improved ALPS, high performance ALPS have been operated to meet the regulatory standard for release to the sea. According to the release plan, they have announced that 30 nuclides and H-3 concentration of the contaminated water will be measured and assessed before/after the discharge of the contaminated water into the sea. Before the release, the contaminated water is re-treated by reverse osmosis membrane facility and additional ALPS. And then, the water will be diluted with seawater more than 100 times. The diluted water will then move through an undersea tunnel and be released about 1 kilometer off the coast.

Surface water temperature of a bay (from the south to the north) increases in spring and summer, but decreases in autumn and winter. Due to shallow water depth, freshwater outflow, and weak current, the water temperature in the central to northern part of the bay is greatly affected by the land coast and air temperature, with large fluctuations. Water temperature variations are large in the north-east coast of the bay, but small in the south-west coast. The difference between water temperature and air temperature is greater in winter and in the south-central part of the bay than that in the north to the eastern coast of the bay where sea dykes are located. As the bay goes from south to north, the range of water temperature fluctuation and the phase show increases. When fresh water is released from the sea dike, the surrounding water temperature decreases and then rises, or rises and then falls. The first mode of empirical orthogonal function (EOF) represents seasonal variation of water temperature. The second mode represents the variability of water temperature gradient in east-west and north-south directions of the bay. In the first mode, the maximum and the minimum are shown in autumn and summer, respectively, consistent with seasonal distribution of surface water temperature variance. In the second mode, phases of the coast of Seosan~Boryeong and the east coast of Anmyeon Island are opposite to each other, bordering the center of the deep bay. Periodic fluctuation of the first mode time coefficient dominates in the one-day and half-day cycle. Its daily fluctuation pattern is similar to air temperature variation. Sea conditions and topographical characteristics excluding air temperature are factors contributing to the variation of the second mode time coefficient.

After melting glass at a high temperature of about 1,100 degrees in the Cold Crucible Induction Melter (CCIM) of the vitrification facility, radioactive waste is fed into the CCIM to vitrify radioactive waste. Accordingly, since the metal sector of the CCIM contacts the high-temperature molten glass, cooling water is supplied to continuously cool the metal sector. The cooling system is divided into primary and secondary cooling water systems. The primary cooling water flows inside the metal sector of the CCIM to maintain the metal sector within normal temperature, thereby forming a glass layer between the metal sector and the high-temperature melting glass. The secondary cooling system is a system that cools the primary cooling water that cools the metal sector, and removes heat generated from the primary cooling system. In addition, it is designed to stably supply cooling water to the secondary cooling water system through an emergency cooling water system so that cooling water can be stably supplied to the secondary cooling water system in the event of secondary cooling water loss. Therefore, it is designed to maintain the facility stably in the event of loss of cooling water for the CCIM of the vitrification facility.

Long-term evolution of the surface environments can affect the safety of deep geological disposal. Therefore, it is important to understand the water balance components constituting the water cycle among atmosphere, surface, and subsurface. In Finand, the surface and near-surface hydrological model (SHYD) was developed to calculate the water balance of Olkiluoto Island. Through the intensive site investigations, the data sets as input for the site scale model in present-day conditions have been collected such as transpiration and meteorological data. In this study, weighing lysimeter method was selected to quantify small-scale soil water balance of the vadose zone in the UNsaturated zone In-situ Test facility (UNIT) around KAERI Underground Research Tunnel. Hydrological components such as precipitation, evapotranspiration (ET) and leachate were derived from water balance analysis on the lysimeter measurements in UNIT. Among the hydrological components, actual ET accounts for more than 50% of the annual precipitaion, and thus plays an important role on predicting the hydrological evolution in the future. In this context, actual ET measured from the weighing lysimeter was compared with potential ET estimated from meteorological data using FAO-56 Penman-Monteith method.

Bentonite, a material mainly used in buffer and backfill of the engineering barrier system (EBS) that makes up the deep geological repository, is a porous material, thus porewater could be contained in it. The porewater components will be changed through ‘water exchange’ with groundwater as time passes after emplacement of subsystems containing bentonite in the repository. ‘Water exchange’ is a phenomenon in which porewater and groundwater components are exchanged in the process of groundwater inflow into bentonite, which affects swelling property and radionuclide sorption of bentonite. Therefore, it is necessary to assess conformity with the performance target and safety function for bentonite. Accordingly, we reviewed how to handle the ‘water exchange’ phenomenon in the performance assessment conducted as part of the operating license application for the deep geological repository in Finland, and suggested studies and/or data required for the performance assessment of the domestic disposal facility on the basis of the results. In the previous assessment in Finland, after dividing the disposal site into a number of areas, reference and bounding groundwaters were defined considering various parameters by depth and climate change (i.e. phase). Subsequently, after defining reference and bounding porewaters in consideration of water exchange with porewater for each groundwater type, the swelling and radionuclides sorption of bentonite were assessed through analyzing components of the reference porewater. From the Finnish case, it is confirmed that the following are important from the perspective of water exchange: (a) definition of reference porewater, and (b) variations in cation concentration and cation exchange capacity (CEC) in porewater. For applying items above to the domestic disposal facility, the site-specific parameters should be reflected for the following: structure of the bedrock, groundwater composition, and initial components of bentonite selected. In addition, studies on the following should be required for identifying properties of the domestic disposal site: (1) variations in groundwater composition by subsurface depth, (2) variations in groundwater properties by time frame, and (3) investigation on the bedrock structure, and (4) survey on initial composition of porewater in selected bentonite The results of this study are presumed to be directly applied to the design and performance assessment for buffer and backfill materials, which are important components that make up the domestic disposal facility, given the site-specific data.

The stabilization techniques are highly required for damaged nuclear fuel to strengthen safety in terms of transportation, storage, and disposal. This technique includes recovering fuel materials from spent fuel, fabrication of stabilized pellets, and fabrication of fuel rods. Thus, it is important to identify the leaching behavior of the stabilized pellets to verify their stability in humid environments which are similar to storage conditions. In this study, we introduce various leaching experiment methods to evaluate the leaching behavior of the stabilized pellets, and determine the most suitable leaching test methods for the pellets. Also, we establish the leaching test conditions with various factors that can affect the dissolution and leaching behavior of the stabilized pellets. Accordingly, we prepare the simulated high- (55 GWd/tU) and low- (35 GWd/tU) burnup nuclear fuel (SIMFUEL) and pure UO2 pellets sintered at 1,550°C and 1,700°C, respectively. Each pellet is placed in a vessel and filled with DI water and perform the leaching test at three different temperature to verify the leaching mechanism at different temperature range. Based on the standard leaching test method (ASTM C1308-21), the test solution is removed from the pellet after specific time intervals and replaced in the fresh water, and the vessel is placed back into the controlled-temperature ovens. The test solutions are analyzed by using ICP-MS.

Under the Foreign Trade Act, an export license from the Nuclear Safety Commission is required to export items specified in Part 10 of Schedule 2 of the Public Notice of Exportation and Importation of Strategic Items (Trigger List Items). In the case of nuclear materials, deuterium, and heavy water, its cumulative amount determines whether it is trigger list item. An export license is required only if the cumulative amount exported to a single end-user country from January 1st to December 31st exceeds the regulation criteria. The reason for this cumulative control is to exclude small amounts of materials from the scope of control as they are considered less important in view of nuclear proliferation, but to prevent the possibility of acquiring large quantities of materials by importing small amounts several times. As a result, export control of nuclear material, deuterium, and heavy water requires different considerations than other Trigger List Items. First, materials exported by different companies must be consolidated to manage the cumulative amount. Second, it is necessary to continuously follow up the actual export status. If the material is not exported after it was classified as ‘non-Trigger List Items’, it should not be included in the cumulative amount. Third, there may be a difference between the accumulated quantities aggregated at the time of the classification and the time of the actual export. The classification should be changed if an export of the classified material is postponed or another export of same materials occurs before the export of the classified material. Fourth, the classification result of these materials should not be reused. Generally, the classification result could be reused within the expiration date (2 years) but in the case of substances. However, the reuse of classification result for materials should be limited as the classification results could be change depending on the cumulative amount. In addition, the sharing of classification results between different entities should also be restricted. The government approval procedures are required even for export of small amounts of nuclear materials which are less than the regulation criteria. The cumulative quantities of nuclear materials are systematically managed in the Nuclear Export & imPort control System (NEPS) through these procedures. NEPS is also linked to the custom clearance system of Korea Customs Service, which enables to track actual exports and the time of exports. However, cumulative quantities for the heavy water and deuterium are managed individually by classification reviewers. The annual export plans are received in advance from major entities which deal with the materials for nuclear uses, and the cumulative quantities for each application are managed manually. The systematic management has not been required as there were a few cases of exporting small quantities. However, systematic management may be required in the future as overseas expansion attempts from various companies in the nuclear field has been increasing. In addition, further study is needed on the criteria and system for calculating the cumulative amount. The time of aggregate the cumulative amount should be clarified by considering the difference between the time of classification and actual export. It is required to devise an efficient way to follow up the actual export.

Owing to the increase in saturation rate of the spent fuel storage pond in the Kori nuclear power plant, the interim spent fuel dry storage facility is scheduled to be constructed at the Kori site. To implement safeguards in the new dry storage facility effectively, the concept of “Safeguards-by- Design” (SBD) should be applied to reflect nuclear safeguard provisions in the earliest design stages. Detailed design information pertaining to dry storage facilities has not been determined; however, the design information related to safeguards have been inferred using case studies and interviews with nuclear power plant operators worldwide. On the basis of the results of the case studies on spent fuel dry storage facilities for light water reactors, most countries apply the metal cask method in containment buildings considering safety. Furthermore, Korean operators are also considering the same method owing to tight licensing schedules and safety issues. Using the Facility Safeguardability Assessment (FSA) methodology (one of the safeguard evaluation methodologies), the difference in design between the heavy water reactor spent fuel dry storage facility, an established IAEA safeguards approach reference nuclear facility, and the light water reactor spent fuel dry storage facility (the new nuclear facility) were analyzed. Two major differences were noted as issues pertaining to potential safeguards. First, the difference in design and transport method in terms of the difference in size and weight of the spent nuclear fuel is important; light water reactor fuel is 20 times heavier than heavy water reactor that needs partial defect inspection in assemblies. Second, the difference in safeguard approach owing to the difference between the modular storage method in heavy water reactor and the container type storage method in light water reactor must be considered; movable storage cask renders the IAEA surveillance approach difficult. The results of this study can be used to identify the safeguards requirements in advance, enabling the operator to design new dry storage facilities resulting in timely and cost-effective implementation.

Water electrolysis holds great potential as a method for producing renewable hydrogen fuel at large-scale, and to replace the fossil fuels responsible for greenhouse gases emissions and global climate change. To reduce the cost of hydrogen and make it competitive against fossil fuels, the efficiency of green hydrogen production should be maximized. This requires superior electrocatalysts to reduce the reaction energy barriers. The development of catalytic materials has mostly relied on empirical, trial-and-error methods because of the complicated, multidimensional, and dynamic nature of catalysis, requiring significant time and effort to find optimized multicomponent catalysts under a variety of reaction conditions. The ultimate goal for all researchers in the materials science and engineering field is the rational and efficient design of materials with desired performance. Discovering and understanding new catalysts with desired properties is at the heart of materials science research. This process can benefit from machine learning (ML), given the complex nature of catalytic reactions and vast range of candidate materials. This review summarizes recent achievements in catalysts discovery for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The basic concepts of ML algorithms and practical guides for materials scientists are also demonstrated. The challenges and strategies of applying ML are discussed, which should be collaboratively addressed by materials scientists and ML communities. The ultimate integration of ML in catalyst development is expected to accelerate the design, discovery, optimization, and interpretation of superior electrocatalysts, to realize a carbon-free ecosystem based on green hydrogen.