이 실험에서는 α-Al2O3 지지체 위에 진공 코팅(vacuum coating)과 딥 코팅(dip-coating) 기법을 사용하여 GO/γ -Al2O3 중간층을 형성하였고, 무전해도금 방식을 통해 Pd-Ag 수소 분리막을 제작하였다. Pd와 Ag는 각각 무전해도금을 통해 지지체 표면에 증착되었으며, 합금화를 위해 도금 과정 중 H2 분위기 하에서 500°C에서 18 h 동안 열처리를 진행하였다. 제 조된 분리막의 표면과 단면은 SEM을 통해 분석되었으며, Pd-Ag 분리막의 두께는 1.88 μm, GO/γ-Al2O3 중간층을 가진 Pd-Ag 분리막의 두께는 1.07 μm로 측정되었다. EDS 분석을 통해 Pd-77%, Ag-23%의 조성으로 합금이 형성된 것을 확인하 였다. 기체투과 실험은 H2 단일가스와 H2/N2 혼합가스를 이용하여 수행되었다. H2 단일가스 투과실험에서 450°C, 4 bar 조건 하에서 Pd 분리막의 최대 H2 플럭스는 0.53 mol/m²·s로, Pd-Ag 분리막의 경우 0.76 mol/m²·s로 측정되었다. H2/N2 혼합가스 실험에서 측정된 분리막의 separation factor는 450°C, 4 bar 조건에서 Pd 분리막이 2626, Pd-Ag 분리막이 13808로 나타났다.

This study aims to propose an improvement of fire safety management plans for buildings, such as apartment complexes and schools, within a 10 km radius of industrial complexes. It utilizes an off-site consequence analysis program to reflect the toxic impact on national industrial complexes and surrounding areas. The ALOHA program was utilized to analyze the impact of toxicity due to a hydrogen chloride leak, a hazardous material. The results showed that the area with AEGL-2 and above ranged from 3.1 km to 10 km, the AEGL-3 area ranged from 1.9 km to 7.3 km. The ASET was measured to be between 3 and 24 minutes. Due to the impact of toxicity, it is necessary to prepare fire safety management plans for buildings, such as apartment complexes and schools that are within a 10 km radius from industrial complexes. These safety plans incorporate the hydrogen chloride risk assessment results, ASET, weather conditions, and coordination with the local community.

In this study, numerical analysis was performed on a type IV hydrogen storage tank to analyze the temperature change of hydrogen inside the tank and the filling performance by changing the inlet nozzle outlet angle and the number of outlets. Considering the residual state of charge (SOC) inside the initial tank, the initial pressure was 10 MPa, and the temperature of hydrogen inside the tank and the SOC results were analyzed when hydrogen with a temperature of 233 K was introduced under the conditions of liner, wrap, and outside temperature of 298 K. The results of the analysis showed that the charging completion rate reached the charging limit pressure. The analysis showed that time of filling completion, when the filling limit pressure is reached, the SOC result is about 94% for all geometry change conditions, and the filling completion time increases by 5s as the number of outlets decreases. The temperature change of the wrap area at the end of filling is up to 3.6K, which shows that the outside air temperature has a negligible effect on the hydrogen temperature change inside the tank.

The government declared ‘2050 carbon neutrality’ as a national vision in October 2020 and subsequently pursued the establishment of a ‘2050 carbon neutrality scenario’ as a follow-up response. Hydrogen is considered as one of the most promising future energy carriers due to its noteworthy advantages of renewable, environmentally friendly and high calorific value. Liquid hydrogen is thus more advantageous for large-scale storage and transportation. However, due to the large difference between the liquid hydrogen temperature and the environment temperature, an inevitable heat leak into the storage tanks of liquid hydrogen occurs, causing boil-off losses and vent of hydrogen gas. Researches on insulation materials for liquid hydrogen are actively being conducted, but research on support design for minimal heat transfer and enhanced rigidity remains insufficient. In this study, to design support structures for liquid hydrogen storage tanks, a thermal-structural coupled analysis technique was developed using Ansys Workbench. Analytical models were created based on the number and arrangement of supports to propose structurally safe support designs.

Molybdenum, valued for its high melting point and exceptional physical and chemical properties, is studied in diverse fields such as electronics, petrochemicals, and aviation. Among molybdenum oxides, molybdenum dioxide stands out for its higher electrical conductivity than other transition metal oxides due to its structural characteristics, exhibiting metallic properties. It is applied as pellets to gas sensors, semiconductors, and secondary batteries for its properties. Thus, research on molybdenum dioxide compaction and pressureless sintering is necessary, yet research on pressureless sintering is currently insufficient. This study synthesized MoO₃ powder via solution combustion synthesis and reduced it using the 3% hydrogen/argon gas mixture to investigate the effect of reduction temperature on the powder. Additionally, the reduced powder was compacted and subjected to pressureless sintering with temperature as a variable. The density and the microstructure of brown parts were analyzed and discussed.

This study analyzed the influence of ball size and process control agents on the refinement and dehydrogenation behavior of TiH2 powder. Powders milled using ZrO2 balls with diameters of 0.1 mm, 0.3 mm, and 0.3+0.5+1 mm exhibited a bimodal particle size distribution, of which the first mode had the smallest size of 0.23 μm for the 0.3 mm balls. Using ethanol and/or stearic acid as process control agents was effective in particle refinement. Thermogravimetric analysis showed that dehydrogenation of the milled powder started at a relatively low temperature compared to the raw powder, which is interpreted to have resulted from a decrease in particle size and an increase in defects. The dehydrogenation kinetics of the TiH2 powder were evaluated by the magnitude of peak shift with heating rates using thermogravimetric analysis. The activation energy of the dehydrogenation reaction, calculated from the slope of the Kissinger plot, was measured to be 228.6 kJ/mol for the raw powder and 194.5 kJ/mol for the milled powder. TEM analysis revealed that both the milled and dehydrogenated powders showed an angular shape with a size of about 200 nm.

This study investigated the operating principles of colorimetric freshness indicators, particularly those for relative humidity (RH) and hydrogen sulfide (H2S), and evaluated the applicability of commercially available indicators for food use. The findings not only provide a deeper understanding of how these indicators respond to substances, such as carbon dioxide, volatile basic nitrogen, sulfides, water activity, and ethylene gas, which are produced during quality changes in food, but also pave the way for the development of new food safety technologies. The RH indicator functions by utilizing a dye that undergoes a chemical structural change when reacting with moisture. The H2S indicator uses a dye that changes color upon detecting H2S or volatile basic nitrogen produced when food spoils. Commercial RH indicators effectively indicated changes in the water activity of almonds, pastries, and red pepper powder; however, their ability to predict them diminished during storage. Commercial H2S indicators exhibited a stronger correlation between color change and volatile basic nitrogen levels in exposure to light than without light, as demonstrated when applied to mackerel and clam. Additionally, at the point of spoilage, the degree of color change in the H2S indicators was more distinct in clam than mackerel. Although commercial RH and H2S indicators are available, they must be sensitive, accurate, and irreversibly developed in response to changes in the target food for effective application.

국제해사기구는 국제해운의 온실가스 배출을 줄이기 위한 전략을 채택하였으며, 선박 기인 온실가스 배출을 줄이기 위해 보다 강화된 목표를 설정하고 있다. 액체수소를 기화시켜 연료로 사용하는 고분자 전해질 연료전지는 이러한 규제를 준수하기 위한 유망한 기 술 중 하나로 평가받고 있다. 일반적으로 선박시스템 설계는 선급의 규정에 따라야 하지만 환경규제가 강화됨에 따라 새로운 연료와 시 스템의 도입이 가속화되고 있으며, 이로 인해 규정개발이 기술의 도입을 따라가지 못하는 경우도 발생하고 있다. 이러한 격차를 해소하기 위해, 본 연구에서는 수소 연료가스공급 시스템을 대상으로 위험요소 및 운전분석 기법(HAZOP)과 보호계층분석 기법(LOPA)을 결합하여 신기술의 안전성을 검증하는 방법을 제시하였다. 먼저 HAZOP을 통해 위험 시나리오를 식별하고, LOPA를 통해 정성적인 HAZOP 결과를 정량적으로 보완하였다. 초기사건의 빈도와 독립보호계층(IPL)들의 작동 요구시 고장 확률(PFD)을 계산하였다. 기존 IPL의 적절성을 결정 하기 위해, 예상되는 완화 정도를 가정한 허용기준과 비교하였으며, 필요한 경우, 추가 IPL을 권장하였다. 본 연구를 통해서 HAZOP-LOPA 기법이 조선해양 분야에서 신기술의 안전성을 평가할 수 있는 잠재력을 가지고 있음을 확인하였다.

Hydrogen is considered as one of the most promising future energy carriers due to its noteworthy advantages of renewable, environmentally friendly and high calorific value. However, the low density of hydrogen makes its storage an urgent technical problem for hydrogen energy development. Compared with the density of gas hydrogen, the density of liquid hydrogen is more than 1.5 times higher. Liquid hydrogen is thus more advantageous for large-scale storage and transportation. However, due to the large difference between the liquid hydrogen temperature and the environment temperature, an inevitable heat leak into the storage tanks of liquid hydrogen occurs, causing boil-off losses and vent of hydrogen gas. Researches on insulation materials for liquid hydrogen are actively being conducted, but research on support design for minimal heat transfer and enhanced rigidity remains insufficient. In this study, to design support for liquid hydrogen storage tank, technique of thermal-structural coupled analysis including geometry, mesh, and boundary condition were developed using Ansys workbench, and equivalent stress and deformation distributions were analyzed.

Environmental pollution has led to global warming, which threatens human life. In response, hydrogen is gaining attention as a next-generation energy source that does not emit carbon. Due to its explosive nature, special care must be taken in the safe storage and transportation of hydrogen. Among various storage methods, liquefied storage, which can reduce its volume to 1/800, is considered efficient. However, since its boiling point reaches -253°C, the design of an insulation system is essential. For the design of insulation systems applied to large containers, a membrane-type design is required, which necessitates the use of cryogenic adhesives. To evaluate whether the cryogenic adhesive is properly implemented, assessments such as tensile and shear tests are necessary. This study presents a methodology for shear evaluation. Conventional methods for shear evaluation of adhesives result in slippage, preventing proper assessment. Therefore, a method involving drilling holes in the gripper and pulling from the holes must be applied. Optimal design concerning the size and location of the holes is required, and this study derives optimal values based on finite element analysis. By conducting experiments based on the results of this study, it is expected that the risk of gripper damage will be minimized, allowing for accurate evaluation of the adhesive’s performance.

In this paper, a shot peening was conducted to improve fatigue life by increasing resistance to hydrogen embrittlement of STS316 steel, which is widely used in hydrogen environments. First, considering the efficiency of the shot peening process, an effective Almen intensity was selected and applied to the specimen surface. Second, the specimen was hydrogen embrittled at room temperature (25°C) and high temperature (60°C) using electrochemical hydrogen charging. Third, the mechanical property tests (tensile, hardness, roughness) and 4-points rotational bending fatigue tests of the specimen were performed. All mechanical properties decreased, but the fatigue life of the shot peened specimens improved at the both temperature conditions. Ultimately, the fatigue characteristics against hydrogen embrittlement of STS316 steel, which is used in various industrial fields, are improved through an effective shot peening process, and the effect is believed to be very significant.

STCW 협약 A-VI에 의거, 승선 필수 증서를 발급받기 위해 소화 과정 최저 훈련 이수를 거치게 되는 공간이 수소화 훈련장 이다. 선박 화재의 상황과 유사한 장소에서 발생한 화재 진압 훈련을 위한 실습 장소의 특성상, 재실자의 안전을 보장할 수 있는 운영 을 위해 안전성을 수치화하여 평가하고 기준을 수립하는 연구의 필요성이 대두되었다. 화재 안전 평가를 위해 FDS를 기반으로 한 Pyrosim을 활용하여 제연설비 유무에 따른 Case를 설정, vector의 분석을 통한 연기 유동 및 열기에 대한 평가를 수행하였다. 피난 안전 평가는 Pathfinder를 통해 허용 피난시간, 총 피난시간을 수치화된 결과로 해석, 비교하여 안전성을 분석하였다. 각 Case에 대한 안전성 을 평가함으로 제연설비별 기능의 적정성을 수치, 시각적으로 나타내었으며, 현재 운영 상태는 안전성이 양호한 것으로 평가하였다. 집 진설비가 정지한 비상상황은 각 피난시간과 111.2초의 여유시간으로 나타내어 수소화 훈련장의 비상상황에 대한 피난시간의 기준으로 활용할 것을 제시하였다.

The PCHE(Printed Circuit Heat Exchanger)-type heat exchanger, which was fabricated by etching and diffusion bonding, was used to hydrogen station, VHTR(Very High Temperature Reactor), SMR and so on. The hydrogen station equipped with PCHE-type heat exchanger is necessary to inject the hydrogen gas into facilities, for instance, such as HFCV(Hydrogen Fuel Cell Vehicle) and power systems. The purpose of this study is to investigate the thermal characteristics of thin plate of PCHE depending on constraint conditions through numerical analysis. As the results, it showed that thermal stress of thin plate, which was not performed diffusion bonding at all, was larger than that, which was performed perfect diffusion bonding, and its maximum difference was about 3 times. Further it was confirmed that the thermal characteristics of thin plate could be obtained by investigating the heat flux.