The present study examined changes in surface shape and pore size observed in carbon black particles isothermally oxidized in an air atmosphere according to their burn-off ratio. Carbon black materials were fed into a horizontal tubular furnace in an air atmosphere when the inside temperature reached 600 °C. Subsequently, while changing the isothermal oxidation time, carbon black samples with different burn-off ratios were obtained, i.e., 10.5, 20.0, 30.4, 41.0, 49.9, 59.8, 71.1, and 81.0%. The scanning electron microscope analysis revealed that the observed carbon black particles were in the form of aggregated primary particles, and that there was no change in the particle size of these primary particles as the burn-off process proceeded. The latter observation supported the observation that pores were formed in the carbon black samples during the burn-off process. Notably, the Brunauer–Emmett–Teller analysis exhibited hysteresis curves, indicating that the corresponding adsorption isotherms were of IV-type. It was also found that the area of the hysteresis curves increased as the burn-off process proceeded. The specific surface area of the raw carbon black sample was 58.00 m2/g, while that of the 81.0% sample was about 4.1 times the figure at 240.27 m2/g. The total pore volume VT was 0.17 cm3/g for the raw sample, and it was much higher for the 81.0% sample at 0.58 cm3/g. The transmission electron microscope analysis showed that the raw carbon black particles had a spherical shape with a smooth surface, but inner pores were not observed. In the 49.9% sample, pores with a size of about 5 nm were observed inside carbon black particles. Notably, the size of the pores observed in the 81.0% sample was about 20 nm and the large pores were created by the collapsing and merging of the smaller pores by oxidation.

본 논문에서는 저차원 확률 함수를 사용하여 연속적인 선형 공극비 기울기를 갖는 기능경사재료 형태의 가상 시편을 제작 하였다. 실제 물 시멘트 비가 다른 두 종류 시멘트 풀 시편의 X-선 CT 단면 이미지를 통해 3차원 공극 분포 모델을 제작하 여 이를 기반으로 가상 시편을 제작하였다. 가상 시편이 두 실제 시편 사이에 위치하도록 공극 분포 특성을 저차원 확률 함 수와 공극비 기울기로 구성하였다. 공극 분포의 기울기는 연속적인 형태의 수직 방향의 선형 공극비 기울기로 구현하며, 이 를 위해 확률적 최적화의 목적 함수로 저차원 확률 함수와 공극비 기울기에 관한 함수를 사용하였다. 가상 시편 내 공극 분 포 특성 확인을 위해 본 연구에서는 투기율 분석을 유한요소해석을 통해 수행하였다. 공극 분포 특성과 투기율 해석 결과를 비교하여 가상 시편이 갖는 공극 분포 특성이 투기율에 미치는 영향을 확인하고, 투기율의 실제 실험 결과와 해석 결과의 비 교를 통해 해석 결과의 타당성을 입증하였다.

This study investigates experimentally Air-fuel ratio feedback control with a fuel valve in a LPG engine. The fueling valve is controlled by electronic control unit which is made with micro computer. Various control logics are employed and then PID control is adopter as a proper logic for own system and Air-fuel ratio feedback control by PID control was experimentally of various operation area with the stable control algorithm of PID control that was earned from the former experiment. On the process the experiment, determination experiment of each control part coefficient was the biggest variable among the whole result of experiment. We could know as a result of experiment that the lange of overshoot is bigger as the proportional control part os bigger integral control part is related with the delay time and coefficient of differential control part is related with the decrease of overshoot range from the experiment of various operation area we could also analyse consequently that direct fuel control in the fuel value makes more stable control status in rare operation and low load area.

This study was to investigate distribution characteristics for air pollutants and to assess probability of health effect for children in kindergartens from August, 2006 to January, 2007. The mean concentrations for standards of maintenance in kindergartens were 91.5 ㎍/㎥ for PM10, 1,185 ppm for CO2, 69.3㎍/㎥ for formaldehyde, 174 CFU/㎥ for TBC and 0.41 ppm for CO, respectively. For NO2, Rn, TVOC, and O3, the mean concentrations in kindergartens were 29.40 ppb, 1.51 pCi/ℓ, 257.3 ㎍/㎥, and 3.74 ppb, respectively. The I/O ratio of every air pollutants exceeded "1" except for O3. In results of calculated safety factor to assess probability of health effect for children by air pollutants in kindergartens, safety factor for CO2 was 1.2 for fixed point. It means that children have probability of health effect caused by CO2. In cases of Monte-Carlo analysis, safety factor for PM10 was 1.0 and safety factor for CO2 was 1.2.

The characteristics of PM10, PM2.5 and Ratio(PM2.5/PM10) of 11 urban air monitoring stations in Gyeongnam were analyzed for the last 3 years(`15~`17). The average of the all stations was PM10 45 μg/㎥, PM2.5 24 μg/㎥ and Ratio 0.54, and annual reduction rates were PM10 -2.9%, PM2.5 –2.7% and Ratio –1.2%, respectively. The seasonal characteristics of PM10 were spring 54 μg/㎥ > winter 48 μg/㎥ > summer/autumn 40 μg/㎥, PM2.5 were spring/winter 26 μg/㎥ > summer 23 > autumn 22 μg/㎥ and Ratio were summer 0.56 > winter 0.55 > autumn 0.54 > spring 0.51, respectively. The hourly characteristics of PM10 were 11 μg/㎥ higher than 09:00~12:00 at 03:00~06:00, PM2.5 were 6 μg/㎥ higher than 09:00~12:00 at 17:00~18:00 and Ratio were 0.07 higher than 04:00~06:00 at 19:00. By site, the highest concentration of PM10 was YJ site 53 μg/㎥ and PM2.5 was HW site 28 μg/㎥. And Ratio at HD site showed the largest reduction from `15 0.62 to `17 0.52.

생활폐기물 및 산업폐기물로부터 고형연료를 제조하는 과정에서 폐기물 반입량 대비 30 ~ 45%의 비율로 잔재물이 발생되어 매립되거나 일부는 소각장으로 반입되어 처리되고 있다. 이러한 잔재물은 함수율 40% 이상을 나타내어 그대로 매립되었을 경우 오염부하를 증가시킬 수 있으며, 매립에 의한 처분비용으로 전체 시설 운영비의 약 20%가 요구되는 실정이다. 이러한 잔재물은 양 및 질적인 측면에서 볼 때 추가 공정을 통하여 충분히 고형연료로 생산이 가능하다. Bio-drying 기술은 폐기물 내에 존재하는 생분해성 유기물질에 대한 미생물의 호기성 분해열을 이용하여 폐기물의 수분을 건조시키는 건조에너지 소모 및 설치/운영비를 최소화 할 수 있는 경제성이 우수한 기술이다. 본 연구에서는 고형연료화 시설에서 발생된 잔재물을 대상으로 Bio-drying 기술을 적용시켜 생산된 비성형 고형연료의 벤치규모 연소실험을 통해 연소 공기비에 따른 바닥재와 비산재의 발생 특성을 고찰하였다. 또한 기존 시중에 판매되고 있는 비성형 고형연료와의 연소특성 비교/분석을 통해서 Bio-dyring 고형연료의 연소특성을 파악하고 연소 조건의 최적화를 진행하였다. Bio-drying 고형연료와 판매용 고형연료의 연소 바닥재의 XRF 분석 결과 CaO, SiO2, Al2O3, Fe2O3가 주성분을 이루며 그 중에서 CaO 성분이 각각 36.6%와 48.6%로 가장 높게 나타났다.

Because methane-producing bacteria (MPB) and sulfate-reducing bacteria (SRB) compete for anaerobic utilization of organic matter, the methane generation potential (Lo) decreases logarithmically with the decrease in the COD/SO4 ratio. The Lo correction coefficient equals the Lo at a particular COD/SO4 ratio divided by the maximum Lo. An Lo correction coefficient was derived each year based on the COD/SO4 ratios of waste added to the landfill. The methane generation potential was multiplied by the Lo correction coefficient in order to correct the LFG (landfill gas) generation calculation. At the second Sudokwon landfill site (2000 ~ present), the COD/SO4 ratio decreased from 11.6 in 2000 to 4.8 in 2014. Thus, the Lo correction coefficient decreased from 0.89 in 2000 to 0.42 in 2014. The LFG 2008-2014 production correction was calculated using the model equation (Scholl canyon), and was almost the same (91 ~ 113%) as the quantity measured, including LFG that was collected, flared, or allowed to diffuse through the landfill. The methane oxidation correction factor, calculated from the concentrations of nitrogen and oxygen within the landfill gas, was between 0.92 and 1 for the first landfill site and between 0.96 and 1 for the second landfill site. Air ingress into the landfill had a negligible effect on gas generation.

This research performed the effects of the air ratio to produce the syngas from the fixed-bed gasifier for municipalsolid waste. At the inside of reactor, temperature depends on amount of the oxidant to classify four distinct process,combustion, reduction (gasification), pyrolysis and dry zone. As decreasing the air flow rate, the particulate matters hada tendency to decrease, proportionally. In this system, the producer gas needs the clean-up process over 98% efficiencyfor connecting the internal combustion engine to generate electric power. At the test 1 and 2, while the air ratio decreased,the LHV of syngas and CGE were increased. however, at the test 3, because the oxidizer had injected more less thandemanded, these showed a decreasing tendency.

This study assessed the characteristic of BTEX (Benzene, Toluene, Ethylbenzene, Xylene) concentration ratios of industrial emission sources and the neighborhoods of industrial area, fuel such as gasoline, light oil, LPG, and similar gasoline, and ambient air in Daegu. The BTEX in aromatic compounds was the most abundant VOC in Daegu. The BTEX ratios were (0.2:2.6:1.0:1.8) for the neighborhoods of industrial area, (2.6:11.3:1.0:1.2) for residential area, (2.2:11.0:1.0:1.6) for commercial area, (1.0:14.9:1.0:1.3) for industrial area, and (0.2:2.6:1.0:1.8) for the neighborhoods of industrial area. Average BTEX ratios in Daegu were B/T ratio (0.1), B/EB ratio (1.5), B/X ratio (1.1), T/EB ratio (12.6), T/X ratio(10), EB/X ratio (0.7). Expecially, B/T ratio in Daegu was similar as the other cities, Bangkok, Manila, and Hongkong. Comparing other cities with B/T ratio, the main sources of VOC were vehicular exhaust and emission of industrial facilities. Furthermore, BTEX correlation were evaluated at the emission sources and regional areas. Results showed that correlation coefficient values of emission sources, fuels and neighborhood of industry were significant magnitude above 0.65(p<0.01). Also, there showed highly significant correlations among BTEX. Calculated correlation coefficients of ambient air sampling sites were 0.61～0.954 for commercial /residential area and 0.613～0.998 for industrial area. However, they showed different correlation between commercial/residental area and industrial area. It implied that the emission sources were different from each area.