산소이온전도체 13mol% CaO안정화 ZrO2에 대한 AI2O3의 첨가효과를 살펴보기 위해 출발원료분말을 (Zr0.87 Ca0.13 O1.871-x AI2O3)x,(x=0,0.01,0.02,0.03,0.05)와 같은 조성이 되도록 공침법으로 합성하고 1400˚C에서 소결시켜, AI2O3의 첨가에 따른 /grain size의 변화, AI2O3의 형태 및 존재위치, 소결밀도의 변화, 그리고 저항률의 변화를 살펴보았다. 그 결과, 결정립의 크기는 1mol% A I2O3첨가까지는 증가하였고, 2mol%첨가이상에서는 입계로 석출하기 시작한 AI2O3의 pinning효과에 기인되어 감소하였다. 또 1mol% AI2O3첨가시에 격자상수값의 급격한 감소가 보여지고, 그 이상에서는 변화가 별로 없어 13mol%CaO안정화 ZnO2의 고용도한은 최대 1mol%임을 알 수 있었다. 전기전도도 또한 1mol% AI2O3첨가시에 증가됨을 나타냈다. ZrO2에의 고용도한까지의 AI2O3첨가는 결정립성장을 촉진시키며 밀도값의 증대를 가져오고 전기전도도의 증가를 가져오는 긍정적인 효과를 나타냈다.

알루미나와 하소된 귤껍질의 소결반응에 의해 A I2 O3-CaO내화물이 제조되었다. 치밀화과정에서의 CaO의 영향과 A I2 O3-CaO 소결체의 특성을 고찰하였다. 소결체의 미세구조와 EDS 결과로 A I2 O3-CaO화합물을 확인하였다. 1450˚C에서 열처리한 소결체는 2.87/㎤의 부피비중과 12.03%의 겉보기 기공율을 가지며 압축강도는 312kg/cm2이였다. 1400˚C에서 서결체의 열팽창 계수는 6.55Kx10-6 K-1이였다.

This study was investigated to improve the phosphorus release and water quality by transformation of sedimentary P fraction for application of CaO2. For the experiment, 0.5% (w/w) of CaO2 was homogenized in the sediment and incubated with the control for 20 days. The analytical results showed that pH increased with CaO2 and redox potential (ORP) was improved in the sediment of the reactor. The growth rate of chlorophyll-a was lower in the CaO2 reactor and Dissolved Oxygen (DO) of overlying water maintained higher than that of the control. Total phosphorus (T-P) concentration in the overlying water increased from the initial concentration to 0.304mg/L in the control at 20 days. The reactor of CaO2 was lowered by 29.3%. Ex-P, Fe-P and Ca-P in sediment P fraction were increased with the CaO2. The formation of bound Fe-P and Ca-P in the sediments seemed to control the release of P by removing the Soluble Reactive Phosphorus (SRP) presented in the pore water. From the result, this indicated that the reduction of P release from the sediments seems to be effective in suppressing the eutrophication of P and improving the oxygen condition in the water quality with the application of CaO2.

콘크리트의 건조수축과 자기수축은 시멘트 재료적인 특성과 사용하는 혼수량에 따라 발생의 정도가 변화할 수 있다. 건조수축은 콘크리트의 작업성을 높이기 위하여 적정한 물이 투입되지만 이러한 물이 전량 수화과정에 필요한 것이 아니고 부분적으로 사용되고 나머지는 공극수로 남는다. 자기수축은 시멘트의 수화에 의해 초결 이후 거시적으로 생긴 체적 감소현상으로 일반적으로 건조수축에 비하여 1/10정도로 작기 때문에 균열에서 큰 영향을 미치지는 않는다. 자기수축은 건조수축과 달리 W/C가 낮고, 단위 시멘트량이 높은 콘크리트에서 많이 발생한다. 이러한 콘크리트 성능 저하 원인인 균열을 방지하기 위하여 여러가지 방법을 적용하고 있다. 수축량을 예건하여 초기 사전 팽창성을 부여함으로써 건조수축 보상을 실시하는 방법과 단위 수량을 감소하여 건조 수축량을 최소화하는 방법이 대표적이라 할 수 있고, 최근에는 균열 발생 후 특정한 환경 조건을 부여할 경우 균열을 스스로 치유하는 자기치유콘크리트의 연구도 이루어지고 있다. 본 연구에서는 타설 후 건조과정에서 발생하는 건조수축에 의한 균열발생을 최소화하기 위하여 기존 CaO를 과소(Dead Burn)화 한 팽창제를 사용하여 콘크리트의 건조 수축을 비교하고자 하였다. 과소 CaO 함유율을 결합재량의 최소 4%에서 최대 8% 까지 혼입하여 시험을 실시한 결과 흐름치로 측정한 유동성은 모두 200mm 전후로 발현되어 동등한 수준을 나타냈으며, 설계기준 강도 27 MPa에 맞는 압축강도 발현을 하였다. 건조수축성능을 평가한 결과 Plain 시험체가 최대 –600×10-6의 건조수축을 발현하였으며 과소 CaO 첨가량이 증가할수록 건조수축은 낮아져 8%를 첨가할 경우 –200×10-6으로 나타나 건조수축 제어에 효과 작용하는 것을 알 수 있었다.

Currently, a technique to subdivide the process refining is introduced, can be divided into the steel slag. In this study, Free-CaO in the electric arc furnace slag by the ethylene glycol method for the quantitative analysis for the expansion to proceed with construction materials.

Blast furnace slag is recycled as high value-added material, while steel slag is difficult to recycle or is recycled as low value-added one relatively due to its expansion collapsability. It's property is caused by the high content of Free-CaO and unstable steel oxides. Currently, a technique to subdivide the process refining is introduced, can be divided into the electric furnace steel slag and reducing steel slag. In this study, Free-CaO in the electric arc furnace slag by the ethylene glycol method for the quantitative evaluation for the expansion to proceed with construction materials, electric arc furnace slag oxidation is to use.

In this work, the effect of CaO and Fe2O3 on the geopolymer made from mine tailing and melting slag has been studied. Geopolymer was made from mine tailing, melting slag and blast furnace slag. The mechanical property of geopolymer prepared was affected by raw material used. Compressive strength of the geopolymer using blast furnace slag was higher than the geopolymer using melting slag. Because CaO and Fe2O3 content of two-type geopolymers was different. Therefore, the content of these controled to find out how to affect the property of geopolymer. According to the result of FT-IR(Fourier transform infrared spectroscopy), the compressive strength of geopolymer increased by activation of CS- H gel with increasing CaO content. In contrast, the compressive strength of geopolymer decreased by inhibition of geopolymerization with increasing Fe2O3 content. According to the result of XRD(X-ray diffraction), the geopolymerization was weakened by formation of olivine, goethite.

The aim of this research is to enhance the bottom environment of Geoje fish farm that has been severely contaminated. Treatment of microbial agent and/or calcium oxide significantly changed that environment: in ignition loss, either treatment (25% or 21%)showed better than mixed treatment (13.2%). In COD, the oxygen releasing agent or mixed treatment reduced the index by more than 20%. In T-P and T-N, the effects of CaO2 on them were overwhelming (50% or more) meanwhile that of the microbial agent on them was less than 20%. Also, CaO2 influenced on the microbial flora: Desulfobvibrio thermophilus, a sulfate reducing bacterium decreased in number, considering the increase of pH and rise of redox potential. In contrast, Pseudomonas sp., Pseudoalteromonas sp., Pseudomonas aeruginosa were remarkably dominant over other species with mixed treatment as a PCA analysis confirmed it.

Removal of NOx on CaO/TiO2 photocatalyst manufactured by the addition of Ca(OH)2 was measured in relation with the amount of Ca(OH)2 and calcination temperature. In case of pure TiO2, the NOx removal decreased greatly with the increase of calcination temperature from 500oC to 700oC, whereas in the photocatalyst added with Ca(OH)2, the removed amount of NOx was high and constant regardless of calcination temperature. Considering NOx removal patterns depending on the amount of Ca(OH)2 added(50, 30, 10wt%), high removal rate showed at the photocatalysts containing less than 30wt% of Ca(OH)2, and it was about 30% higher than that of pure TiO2. From the XRD patterns, it is seen that the addition of Ca(OH)2 contributes to maintaining the anatase structure that is favourable to photocatalysis. It also indicates that the possibility of the formation of calcium titanate(CaTiO3) by reacting with TiO2 above 700oC. Apart from the favourable crystalline structure, the addition of Ca(OH)2 helped increase the alkalinity of photocatalyst surface, thus promoting the photooxidation reaction of NOx.