3D printing technology is a processing technology in which 3D structures are formed by fabricating multiple 2D layers of materials based on 3D designed digital data and stacking them layer by layer. Although layers are stacked using inkjet printing to release various materials, it is still rare for research to successfully form a product as an additive manufacture of multi-materials. In this study, dispersion conditions are optimized by adding a dispersant to an acrylic monomer suitable for inkjet printing using Co3O4 and Al2O3. 3D structures having continuous composition composed of a different ceramic material are manufactured by printing using two UV curable ceramic inks whose optimization is advanced. After the heat treatment, the produced structure is checked for the formation and color of the desired crystals by comparing the crystalline analysis according to the characteristics of each part of the structure with ceramic pigments made by solid phase synthesis method.

Two new synergists are proposed for pigment dispersion in pigment ink. Benzoic acid was applied to Pigment Yellow 74 (PY-74) and Pigment Yellow 150 (PY-150) as a hydrophilic functional group to synthesize (E)-4-(((3-(2-(2-methoxy-4-nitrophenyl)hydrazono)-4-oxopent-1-en-2-yl)(2-methoxyph enyl)am-ino)methyl)benzoic acid (PY-74BA) and (E)-4-((2,4,6-trioxo-5-((2,4,6-trioxohexahydropyrimidin-5-yl)di-azenyl)tetrahydropyrimidin-1(2H)-yl)methyl)ben zoic acid (PY-150BA). Whereas pigment showed extremely low solubility in water and organic solvents like DMSO, DMF and methanol, two synergists were found to have higher solubility than pigment. This result can be interpreted as reduction of particle aggregation by increased polarity. Two synergists applied to pigment ink are expected to improve dispersion property and storage stability of ink.

인쇄에서 종이의 인쇄적성은 인쇄품질을 결정하는 중요한 요소이며, 이를 보완하기 위해 많은 연 구들이 진행되어 왔다. 특히, 잉크젯에 의한 종이의 인쇄적성은 앞으로 전자융합산업의 발달을 고려해본 다면 더욱 주요한 연구가 될것이다. 따라서, 본 연구는 잉크젯 시스템에서 사용하는 CMYK 프로세스 잉 크의 인쇄적성을 파악하고 종이의 특성에 따라 색재현 정도를 ICC 프로파일값을 활용하여 분석하고자 하 였다. 잉크젯의 토출 특성을 이해하기 노즐에서의 잉크 유동을 시뮬레이션 하였고 종이의 재질이 다른 두 종(갱지 및 인화지)의 피인쇄체 위에 각기 다른 망점으로 인쇄하여 색재현 평가를 실시하였다. 각 종이의 관련 특징들 즉, 거칠음도, 투기도, 광택도 및 압축도,과 이에따른 색재현 특성을 ICC 프로파일모니터링에 쓰이는 ΔE값으로 표현하였다. 그 결과 상대적으로 종이의 낮은 거칠음도와 투기도 그리고 높은 압축력을 가지는 인화지에서 더 높은 색재현이 이루어짐을 알 수 있었다.

The goal of this study is optimization of transparency liquid chemical coating process. At coating process in the maintenance of the coating gap is an important factor. Specially, at a small split from the substrate using the existing methods is difficult to maintain the uniformity of coating. In this study, slit coating uniformity and compare inkjet uniformity and thickness profile was analyzed using alpha-step. Also, the pencil hardness test and the color difference measurement were performed. As a result, changes of the coating process need to be made depending on the type of substrate and inkjet coating was suitable for substrate of a small split.

Inkjet printing was successfully done using Cu nano powder ink after these Cu nano powders were dry-coated with 1-octanethiol for oxidation prevention. 1-octanethiol, which is Self-Assembled Multi-layers (SAMs), was coated approximately 10-nm thick on the surface of Cu nano powders. 1-Octanol, which has the same chain length as that for 1-octanethiol, was used as a solvent to make the ink for inkjet printing. As a result, the fabricated ink was dispersed for about 4 weeks, and after printing and heat treatment at for 4 hours, the resistivity for the printed pattern was measured to be .