본 연구는 학교운동장 굴취 토양(WSSPG)을 모래와 혼합 후 토양개량효과를 조사하여 잔디재배토양으로서 적합성을 조사 함으로써 천연잔디 운동장 조성 시 활용가능성을 평가하기 위해 수행되었다. 처리구는 대조구(모래 100%), WSSPG 5% 처리구 (WSSPG 5% + 모래 95%), WSSPG 10% 처리구(WSSPG 10% + 모래 90%), WSSPG 15% 처리구(WSSPG 15% + 모래 85%), WSSPG 20% 처리구(WSSPG 20% + 모래 80%), WSSPG 30% 처리구(WSSPG 30% + 모래 70%), WSSPG 40% 처리구 (WSSPG 40% + 모래 60%)로 설정하였다. WSSPG 처리 후 pH, EC, CEC등은 증대되었고, 모세관 공극, 비모세관 공극, 총공극 및 포화수리전도도는 감소하였다. WSSPG의 처리량과 토양인자간 조사에서 pH, EC, CEC 및 용적밀도는 정의 상관성 을 나타냈고, 모세관 공극, 비모세관 공극, 총공극 및 포화수리 전도도는 부의 상관성을 나타냈다. 상기 결과를 종합할 때, WSSPG는 토양 화학성을 개선하나 물리성 개선은 미미하였고, WSSPG 처리 후 토양의 물리화학성을 고려할 때, WSSPG의 최대 처리량은 약 5% 정도로 판단되었다.

Wearable thermoelectric devices offer a transformative approach to energy harvesting, providing sustainable solutions for powering next-generation technologies. In pursuit of efficient, flexible, biocompatible, and cost-effective thermoelectric materials, zinc oxide (ZnO) has emerged as a distinctive candidate due to its unique combination of favorable properties. This study explores the growth and optimization of ZnO nanorods on conductive carbon fabric (CF) using a simple microwave-assisted solvothermal technique. This method circumvents traditional complex processes that typically involve high temperatures or lengthy growth times, offering advantages such as rapid, uniform, and controllable volumetric heating. By systematically varying growth parameters, including microwave power and reaction time, we established conditions that promote the vertical alignment of ZnO nanorods, essential for enhancing thermoelectric performance. Structural and morphological analyses highlight the pivotal influence of the seed layer and growth parameters in achieving dense, uniform growth of ZnO nanorods. Interestingly, at higher microwave power levels, a transformation from nanorod structures to sheetlike morphologies was observed, likely due to Ostwald ripening, where larger particles grow at the expense of smaller ones. The optimized growth conditions for achieving superior growth and thermoelectric performance were identified as 15 min of growth at 100 W microwave power. Under these conditions, ZnO nanorods exhibited enhanced crystallinity and a higher growth rate, contributing to an improved thermoelectric power factor of 777 nW/mK2 at 373 K. This work underscores the importance of precise parameter control in tailoring ZnO nanostructures for wearable thermoelectric applications and demonstrates the potential of scalable, low-cost methods to achieve high-performance energy-harvesting materials.

TiO2/CNT/GO heterostructure nanocomposite was synthesized by solvothermal method for the removal or degradation of methylene blue (MB). The physical and chemical characteristics were assessed by various characterization techniques such as scanning electron microscopy (SEM) confirmed the external and internal morphology of the heterostructure materials with irregular shapes. Transmission electron microscopy (TEM) showed that the internal structure was preserved after incorporating CNTs and GO into TiO2, and the average particle size distribution was determined using an SEM histogram with an average particle size of 85.5 nm. Energy dispersive X-ray spectroscopy (EDS) was performed to evaluate the elemental mapping of heterojunction confirm the presence of C, O, and Ti. X-ray diffraction (XRD) revealed a crystalline nature and the size of as synthesized material was calculated as 17.08 nm. UV–vis spectroscopy (UV–vis) was conducted to observe the optical behavior and light scattering phenomena of heterostructure materials. Various factors, such as different doses of heterostructure (0.1, 0.2, and 0.3 g), dye concentration (10, 20, and 30 ppm), irradiation time (0, 30, 60, 90, and 120 min), were carried out at 25 °C. The TiO2/ CNT/GO heterostructure induced 91% methylene blue (MB) degradation in 120 min with superior cycling stability after regeneration for four cycles. The optimal reaction conditions were adopted to obtain the highest degradation rate using 0.2 g of the heterostructure, 30 ppm MB concentration, 120 min of light irradiation, and 25 °C reaction temperature. The TiO2/ CNT/GO photocatalyst exhibited enhanced kinetic performance, catalytic stability, structural reliability, and reactivity for 91% degradation efficiency of MB.

This study evaluated the effects of various allulose (AL)-trehalose blend ratios as sucrose replacers on the quality characteristics of Baekseolgi. Control (sucrose), single-sweetener, and blend treatments (AL0-AL100) were prepared and stored at 4oC for 0, 1, 3, and 8 days. Hardness, moisture content, color, and sensory attributes were analyzed. Hardness increased during storage in all the groups. However, the AL40-AL60 blends showed slower increases and better maintenance of their initial softness. Moisture retention tended to improve with higher allulose ratios, showing a slower decrease during storage. Sensory evaluation revealed significant differences in color, aftertaste, and overall acceptability (p< .05). The AL40-AL60 blends maintained moistness, softness, and sweetness comparable to the sucrose control, while achieving balanced acceptability. However, both allulose and trehalose have lower sweetness compared to sucrose, requiring larger quantities to achieve equivalent sweetness levels, which may raise production costs. Therefore, future studies should explore blends of allulose with higher-intensity sweeteners to reduce total sweetener usage and production costs, while retaining texture stability and flavor balance. This study provides practical formulation guidelines for sugar reduction and shelf-life improvement of traditional rice cakes, with potential for broader industrial applications.

This study assessed the processing suitability and functional potential of sweet potato paste by comparing quality characteristics across different cultivars and heat treatment methods (steaming and baking). Generally, moisture content was higher after steaming, with the ‘Bodami’ and ‘Pungwonmi’ cultivars retaining more moisture, while ‘Jinyulmi’ and ‘Danjami’ had lower moisture levels. Purple-fleshed cultivars displayed negative a* and b* values, indicating bluish hues, whereas yellow-fleshed cultivars maintained stable b* values after heating. Both °Brix and free sugar levels increased after treatment, with baking significantly elevating maltose levels and enhancing sweetness. Apparent viscosity was higher in ‘Danjami’, ‘Jinyulmi’, and ‘Bodami’, while ‘Hogammi’, ‘Hopungmi’, and ‘Sodammi’ exhibited lower viscosity. Additionally, ‘Bodami’ and ‘Danjami’ demonstrated the highest levels of polyphenols, flavonoids, and antioxidant activities, confirming their potential as valuable functional ingredients. These findings underscore the importance of selecting appropriate cultivars and heat treatments to optimize the physicochemical and functional qualities of sweet potato paste.

This study proposes a methodology for predicting the physical properties such as the density of polymer composites, including asphalt binders, and evaluates its feasibility by identifying the quantitative relationship between the structure and properties of individual polymers. To this end, features are constructed using molecular dynamics (MD) simulation results and descriptor calculation tools. This study investigates the changes in the calculated density depending on the characteristics of the training dataset and analyzes the feature characteristics across datasets to identify key features. In this study, 2,415 hydrocarbon and binder-derived polymer molecules were analyzed using MD simulations and 2,790 chemical descriptors generated using alvaDesc. The features were pre-processed using correlation filtering, PCA, and recursive feature elimination. The XGBoost models were trained using k-fold cross-validation and Optuna optimization. SHAP analysis was used to interpret feature contributions. The variables influencing the density prediction differed between the hydrocarbon and binder groups. However, the hydrogen atom count (H), van der Waals energy, and descriptors such as SpMAD_EA_LboR consistently had a strong impact. The trained models achieved high accuracy (R² > 0.99) across different datasets, and the SHAP results revealed that the edge adjacency, topological, and 3D geometrical descriptors were critical. In terms of predictive accuracy and interpretability, the integrated MDQSPR framework demonstrated high reliability for estimating the properties of individual binder polymers. This approach contributed to a molecular-level understanding and facilitated the development of ecofriendly and efficient modifiers for asphalt binders.

This study proposes a methodology for predicting properties such as the density of polymer composites, including asphalt binders, and evaluates its feasibility by identifying the quantitative relationship between the structure and properties of individual polymers. To this end, this study investigates the variations in molecular dynamics (MD) results with molecular structural complexity and assesses the independence and correlation of variables that influence density. In this study, MD simulations were performed on hydrocarbon-based and individual asphalt binder molecules. The effects of various temperatures, molecular conditions, and structural features on the density were analyzed. MD-related variables influencing the calculated density were evaluated and compared with experimentally measured densities. The MD-calculated densities were used as target variables in a subsequent study, in which a machine learning model was applied to perform quantitative structure–property relationship analysis.The MD-calculated densities showed a strong correlation with experimental measurements, achieving a coefficient of determination of R2 > 0.95. Potential energy exhibited a tendency to cluster into 4–6 groups depending on the molecular structure. In addition, increasing molecular weight and decreasing temperature led to higher density and viscosity. Torsional energy and other individual energy components were identified as significant factors influencing both potential energy and density. This study provided foundational data for the property prediction of asphalt binders by quantitatively analyzing the relationship between the molecular structure and properties using MD simulations. Key features that could be used in the construction of polymer structure databases and AI-based material design were also proposed. In particular, the integration of MD-based simulation and machine learning was confirmed to be a practical alternative for predicting the properties of complex polymer composite systems.

건설 자재와 건설 폐기물의 환경적 영향에 대한 사회적 관심이 높아지고 있다. 고강도 콘크리트의 필요성이 점차 커짐에 따라, 본 연구에서는 서로 연관된 환경 문제에 대한 두 가지 잠재적 해결책을 검토하였다. 첫째는 재활용 콘크리트 골재의 사용량 증가 가능성이고, 둘째는 고로 슬래그를 시멘트로 활용(재활용)할 가능성이다. 일반적으로 재활용 골재를 사용하면 고강도 콘크리트의 강도 가 저하되는 것으로 알려져 왔다. 따라서, 본 연구에서는 재활용 골재 콘크리트의 배합비와 함량 변화를 분석하여 고층 건축에 재활용 골재가 실용적인지, 그리고 어떤 방식으로 활용되는지를 규명하고자 하였다.

바이오차는 현재 토양개량제이자 탄소격리재로 사용되고 있으며, 건축산업에서 탄소격리에 관한 관심이 증가하고 있다. 본 연구에서는 목질계 바이오차를 시멘트 복합체에 함유하여 탄소격리효과의 가능성을 조사하는 것을 목표로 한다. 목질계 바이오차는 고탄소 물질로 수분을 흡수하는 특성이 있으며 시멘트 복합체에 함유하고자 할 때 시멘트와 비슷한 입도를 가져야한다. 혼입방법에 따라 바이오차를 함유한 시멘트 모르타르의 압축강도 특성을 평가하였으며, 시멘트를 바이오차로 1∼5% 치환하는 경우 Plain 대비 5∼12%까지 압축강도가 증진되는 것을 확인하였다.

본 연구는 염소 도축공정 확립을 위해, 도축 과정 중 탕박(scalding) 및 박피(skinning)가 재래흑염소 등심의 저장 중 물리화학적 특성에 미치는 영향을 비교 분석하고자 수행되었다. 동일한 사양 조건에서 사육된 재래흑염소 6 두를 각각 탕박 및 박피 과정에 따라 도축한 후, 등심근을 채취하여 저장 기간 동안 이화학적 특성 변화를 관찰하여 재래흑염소에 적합한 도축 방법을 선택하고자 하였다. 그 결과, 탕박처리는 전반적으로 연도를 개선하는 데 효과적인 것으로 나타났으며, 박피 처리는 저장 중 보수력 유지에 우수하고, 색도의 선명도(a*, chroma)와 지질산화에 더 안정적인 특성을 보였다. 탕박은 소비자의 기호도 측면에서 유리한 부드러운 조직감을 제공할 수 있지만, 박피는 특히 위생적 안전성과 품질 균일성 확보 측면에서 더 바람직한 도축 방법으로 판단된다.

Efficient donor-acceptor (D-A) molecular scaffolds should be developed for the advancement of organic solar cells (OSCs). Density functional theory (DFT) and time-dependent density functional theory (TDDFT) studies provide an effective methodology to perform initial studies to design and investigate D-A molecular systems. Two fluorine-substituted bis-benzothiadiazoles (FBBTs) are designed and optimized using the DFT method. The results show better planarity for FBBT2, which is attributed to π-extension between the FBBT units. A series of D-A small molecules CB1-4 are designed utilizing FBBT2 to study the effect of systematically substituting carbazole donor and cyano-based acceptor groups on the optoelectronic properties of FBBT. DFT calculations are performed using the B3LYP functional. The designed D-A scaffolds exhibit systematic tuning of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO), HOMO-LUMO gap (from 2.333 eV to 1.825 eV). The observed HOMO-LUMO gap follows the trend CB1 > CB2 > CB4 > CB3. The Voc (open-circuit voltage) and power conversion efficiency (PCE) for CB1-4 are presented with the PC71BM acceptor. The overall trend observed for the Voc follows the order CB1 < CB4 < CB2 < CB3. The PCE trend observed using the Scharber model follows the trend CB3 > CB4 > CB2 > CB1. The results show that end cap modeling of π-extended FBBT with cyano-based acceptor groups significantly improves the observed PCE and Voc.

Sodium-ion batteries (SIBs) offer a viable alternative to partially or fully replace lithium ion batteries (LIBs) due to their lower cost and increased safety. This paper outlines the compositional optimizations, crystallographic evaluations, and electrochemical behavior of a novel mixed NASICON polyanionic compound, NaFe2PO4(SO4)2 (NFPS). X-ray photoelectron spectrometry (XPS) results showed that cobalt doping produces a higher concentration of oxygen defects compared to undoped samples. Scanning electron microscopy (SEM) analysis results revealed that the modified sample has more uniform pores and pore distribution. Brunauer-Emmett-Teller (BET) measurements showed that doping of Co2+ reduces the specific surface area of NFPS-Co0.08 compared to NFPS. This shortens the sodium ion diffusion pathway and promotes ion dynamics. The addition of Co2+ to the sample significantly improved its performance during galvanostatic charge-discharge tests. The electrochemical activity also is significantly enhanced by Co2+ doping. Na0.84Co0.08Fe2PO4(SO4)2 exhibits superior rate and cycling performance compared to pristine NFPS. After 80 cycles at 25 mA g-1, NFPS-Co0.08 retained discharge specific capacity of 60.8 mA h g-1, which is 1.24 times greater than that of NFPS.

This study examines the effect of delayed quenching (DQ) temperature on the microstructure and mechanical properties of API X70 linepipe steels. Three types of steels were fabricated by varying the DQ conditions: Base (without DQ), LDQ (low-temperature delayed quenching at 700 °C), and HDQ (high-temperature delayed quenching at 740 °C). The microstructures were characterized using optical microscopy, scanning electron microscope (SEM), and electron back-scattered diffraction (EBSD), and their mechanical properties were evaluated through tensile and Charpy impact tests. The Base specimen exhibited the finest effective grain size and the highest bainite fraction, resulting in superior yield strength and impact toughness. In contrast, the LDQ specimen showed increased pearlite content and coarser grains, leading to the highest tensile strength due to work hardening, but reduced impact properties due to crack initiation at the pearlite regions. The HDQ specimen, with the highest ferrite fraction, showed the best ductility and acceptable strength, as well as improved lowtemperature toughness owing to increased resistance to cleavage propagation. EBSD analysis confirmed that finer grains and higher fractions of high-angle grain boundaries play a crucial role in enhancing impact energy and lowering the ductile-to-brittle transition temperature (DBTT). These findings highlight the importance of optimizing DQ parameters to achieve a balanced combination of strength–toughness in high-strength linepipe steels.

Since the first introduction of plastics, the issue of recycling has been repeatedly discussed. Plastics with limited biodegradability accumulate in the soil and ocean when deposited in landfills, causing environmental problems, and when incinerated emit a large amount of carbon. In particular, polyethylene terephthalate (PET) is now an indispensable material in daily life, and the waste it generates is also significant. In response, we sought a way to use PET waste as a concrete additive. Typically, adding PET damages the physical strength of concrete, and to solve this problem, gamma ray irradiation was first applied to the PET. The overall peak intensity of the fourier transform infrared spectroscopy (FT-IR) absorption spectrum of gamma-ray-irradiated PET increased, and the surface hydrophilicity of the material increased. In addition, it was confirmed that surface roughness increased when PET was irradiated with gamma rays. The strength of concrete mixed with gamma-irradiated PET was measured, and the compressive strength increased compared to concrete mixed with non-gamma-irradiated PET, and in the case of fibrous PET, the flexural strength increased.

A high-pressure in-situ permeation measuring system was developed to evaluate the hydrogen permeation properties of polymer sealing materials in hydrogen environments up to 100 MPa. This system employs the manometric method, utilizing a compact and portable manometer to measure the permeated hydrogen over time, following high-pressure hydrogen injection. By utilizing a self-developed permeation-diffusion analysis program, this system enables precise evaluation of permeation properties, including permeability, diffusivity and solubility. To apply the developed system to high-pressure hydrogen permeation tests, the hydrogen permeation properties of ethylene propylene diene monomer (EPDM) materials containing silica fillers, specifically designed for gas seal in high-pressure hydrogen environments, were evaluated. The permeation measurements were conducted under pressure conditions ranging from 5 MPa to 90 MPa. The results showed that as pressure increased, hydrogen permeability and diffusivity decreased, while solubility remained constant regardless of pressure. Finally, the reliability of this system was confirmed through uncertainty analysis of the permeation measurements, with all results falling within an uncertainty of 11.2 %.

We investigated three fan-shaped jets observed above sunspot light bridges or nearby sunspot regions. The study aimed to explore the dynamics and physical properties of jets’ features that appear as blob-like structures at the tips of the jets, which we call ‘dark blobs’. A transparent region is observed beneath the dark blobs, creating a visible gap between the dark blobs and the trailing body of the jets. These phenomena were studied in chromospheric and transition region imaging and spectral high-resolution co-observations from the Visible Imaging Spectrometer of the Goode Solar Telescope at the Big Bear Solar Observatory and the Interface Region Imaging Spectrograph (IRIS), together with data from the Atmospheric Imaging Assembly (AIA) on board the Solar Dynamics Observatory. We analyzed the jets’ morphology and fine structure. We obtained the spatial scale and the dynamics of the dark blobs that are seen mostly in the wings of the Hα line and have a cross-section of about 0.2′′–0.3′′. The dark blobs and the transparent regions are seen bright (in emission) in the IRIS slit-jaw 1330 Å, 1400 Å, and AIA 304 Å images. The IRIS Si iv 1394 Å spectrum of the brightenings showed blue-shifted emission of about 16 km s−1 with non-thermal velocities of up to 40 km s−1. We also estimated the electron density of the blue-shifted brightenings to be 1012.1±0.2 cm−3. Our findings likely suggest that we detect the observational signatures of shock waves that generate and/or contribute to the evolution of fan-shaped jets.

Electrochemical treatment has a significant effect on the properties of carbon fibers (CFs). In this study, the effect of mild electric field action on the microstructure and properties of polyacrylonitrile (PAN)-based high-modulus CFs (HMCFs) and high-strength CFs (HSCFs) was investigated. Under the action of a mild electric field, CFs did not show obvious defects, but their microstructure, mechanical properties and electrical properties were affected. For HMCFs, the graphitization degree in both axial and radial directions of the fibers had a decreasing trend, the grain spacing increased, and the grain size and degree of orientation decreased, which led to a decrease in the tensile strength, tensile modulus and axial conductivity. However, for HSCFs, the pattern of change was exactly opposite to that of HMCFs. The results of this study can provide useful guidance for optimizing the production process and surface modification of CFs.

As a key component of composite materials, the interface quality is crucial for determining the mechanical properties of composites. Carbon fiber sizing treatment significantly enhances the fiber-matrix interface, a process extensively utilized in the carbon fiber industry. This study synthesized an environmentally friendly waterborne polyurethane sizing agent and investigated the impact of molecular weight, a critical factor, on composite performance by varying the soft segment type in the polyurethane. This research provides insights into cost-effective and eco-friendly surface treatment methods for carbon fibers and the design of robust interface structures.

In recent years, there has been growing interest in the potential applications of carbon-based non-metallic catalysts in various fields, such as electrochemical energy storage, electrocatalysis, thermal catalysis, and photocatalysis, owing to their unique physical and chemical properties. Modifying carbon catalyst surfaces or incorporating non-metallic heteroatoms, such as nitrogen (N), phosphorus (P), boron (B), and sulfur (S), into the carbon structure has emerged as a promising approach to improve the catalytic performance. This method enables the adjustment of the electronic structure of the carbon catalyst's surface, leading to the formation of new active sites or the reduction of side reactions, ultimately enhancing the catalyst's performance. Here, the preparation methods for doped non-metallic heteroatom carbon catalysts have been systematically explored, encompassing techniques, such as impregnation, pyrolysis, chemical vapor deposition (CVD), and templating. Finally, the existing challenges in the application of non-metallic atomic catalysts have been discussed, insights into potential future development opportunities and new preparation methods of carbon catalysts in the future have been offered.