In this study, factors considered to be causes of promotion of densification of sintered pellets identified during phase change are reviewed. As a result, conclusions shown below are obtained for each factor. In order for MA powder to soften, a temperature of 1,000 K or higher is required. In order to confirm the temporary increase in density throughout the sintered pellet, the temperature rise due to heat during phase change was found not to have a significant effect. While examining the thermal expansion using the compressed powder, which stopped densification at a temperature below the MA powder itself, and the phase change temperature, no shrinkage phenomenon contributing to the promotion of densification is observed. The two types of powder made of Ti-silicide through heat treatment are densified only in the high temperature region of 1,000 K or more; it can be estimated that this is the effect of fine grain superplasticity. In the densification of the amorphous powder, the dependence of sintering pressure and the rate of temperature increase are shown. It is thought that the specific densification behavior identified during the phase change of the Ti-37.5 mol.%Si composition MA powder reviewed in this study is the result of the acceleration of the powder deformation by the phase change from non-equilibrium phase to equilibrium phase.

The self-propagating high temperature synthesis approach was applied to synthesize amorphous boron nanopowders in argon atmospheres. For this purpose, we investigated the characteristics of a thermally induced combustion wave in the B2O3 + α Mg system(α = 1.0-8.0) in an argon atmospheres. In this study, the exothermic nature of the B2O3-Mg reaction was investigated using thermodynamic calculations. Experimental study was conducted based on the calculation data and the SHS products consisting of crystalline boron and other compounds were obtained starting with a different initial molar ratio of Mg. It was found that the B2O3 and Mg reaction system produced a high combustion temperature with a rapid combustion reaction. In order to regulate the combustion reaction, NaCl, Na2B4O7 and H3BO3 additives were investigated as diluents. In an experimental study, it was found that all diluents effectively stabilized the reaction regime. The final product of the B2O3 + α Mg system with 0.5 mole Na2B4O7 was identified to be amorphous boron nano-powders(< 100 nm).

In this work, effect of various process-control agents (PCAs) on the mechanical alloying of amorphous alloy of has been investigated. The dependence of the particle shape, size and crystallization behavior of the amorphous alloy powders on the type of PCAs and their concentrations was investigated by using X-ray diffraction, field-emission scanning electron microscopy and differential scanning calorimetry. It was found that the additive of toluene could affect positively the amorphization and thermally induced crystallization processes, as well as the size refinement, morphology and particle-size distribution of as-milled powders in comparison with alloy obtained without PCA.

Fe based (FeCSiBPCrMoAl) amorphous powder, which is a composition of iron blast cast slag, were produced by a gas atomization process, and sequently mixed with ductile Cu powder by a mechanical ball milling process. The Fe-based amorphous powders and the Fe-Cu composite powders were compacted by a spark plasma sintering (SPS) process. Densification of the Fe amorphous-Cu composited powders by spark plasma sintering of was occurred through a plastic deformation of the each amorphous powder and Cu phase. The SPS samples milled by AGO-2 under 500 rpm had the best homogeneity of Cu phase and showed the smallest Cu pool size. Micro-Vickers hardness of the as-SPSed specimens was changed with the milling processes.

본고에서는 고유한 원자구조에 기인한 우수한 특성으로 인해 구조재료 및 기능재료로서 그 활용이 기대되고 있는 벌크 아몰퍼스 소재에 있어 온간압출, 온간압연, 방전 플라즈마 소결(Spark Plasma Sintering)등 과냉각액체온도구간에서의 점성유동을 이용한 고화성형 공정의 최근 기술동향에 대해 간략히 소개했다.

Co-based amorphous powder was produced by a new atomization process “Spinning Water Atomization Process (SWAP)”, having rapid super-cooling rate. The composition of the alloys was ((Co0.95Fe0.05)1-xCrx)75Si15B10 (x=0, 0.025, 0.05, 0.075). The powders became the amorphous state even if particle size was up to about 500 μm. The coercive force of powders was about 0.35 - 0.7 Oe. Furthermore, Co-based amorphous powder cores with glass binders were made by cold-pressing and sintering methods. The initial permeability of the core in the frequency range up to 100 kHz was about 110, and the core loss at 100 kHz for Bm = 0.1 T was 350 kW/m3.

Using rice husks pulverized by rotating knife cutter, the raw rice husk powder was solution treated by nitric and hydrochloric acids in order to separate phytolith from organic constituents. Because of the strong resistance of organic components of rice husk to acids, the raw powder had to be boiled in concentrated acids up to 300 min. By boiling in nitric acid for 60~120 min, all organic components were resolved while amorphous silica Powder of about 20 nm in size and of higher than 99.8% in purity was left behind. Inferior to the nitric acid, hydrochloric acid was not able to resolve organic component completely leaving unresolved matter of about 40% by weight even after 300 min of boiling. From the acid treatments and impurity analyses, it is considered that most of metallic elements in rice husks are combined to organic components that are easily soluble to acids.

In this paper, we designed and fabricated the Electromagnetic(EM) wave absorber for an Electronic Toll Collection(ETC or Hi-pass) system by using Amorphous metal powder and CPE. The material properties and the absorption properties of the samples containing 50 wt.%, 60 wt.%, 70 wt.%, and 80 wt.% of Amorphous. Moreover, the EM wave absorption abilities were simulated for the different thicknesses of the EM absorbers by adopting the measured permittivity and permeability, and then the EM wave absorber was fabricated based on the simulated design values. As a result, the EM wave absorber with the composition of Amorphous metal powder : CPE = 50 : 50 wt.% with the thickness of 2.6 mm has excellent absorption ability more than 40 dB at 5.8 GHz.

본 논문에서는 항만 물류 시스템에서 사용하는 중심주파수 433 MHz에서 동작하는 전파흡수체를 설계 개발하였다. 먼저 자성손실 재료인 AMP (Amorphous Metal Powder)와 지지재인 CPE (Chlorinated Polyethylene)를 이용하여 AMP:CPE의 조성비가 각각 80:20 wt.%와 85:15 wt.%의 전파흡수체 샘플을 제작한 후, 입력임피던스를 측정하여 샘플의 재료정수를 계산하고 시뮬레이션에 의하여 최적의 전파흡수체를 설계하였다. 그 결과 AMP:CPE=85:15 wt.% 의 조성비에 두께 5.5 mm일 때 최적의 전파흡수특성이 얻어짐을 확인하고, 실제 제작하여 측정한 결과 433 MHz 주파수대역에서 17.5 dB의 흡수능이 얻어졌으며, 이는 본 연구에서 목표로 하는 15 dB 보다 우수한 결과이다.