세계적인 탄소중립 정책 추진과 수소 에너지 수요 증가에 따라 고분자 전해질 수전해 및 연료전지 기술 개발이 활발히 이루어지고 있다. 해당 기술의 핵심 소재인 과불소계 술폰산 이오노머는 우수한 전기화학적 특성과 화학적 안정성을 가지고 있지만, 높은 제조비용, 한정된 공급망, 강화되는 환경 규제와 같은 문제로 인해 효과적인 재활용 및 재제조 기술이 요구되고 있다. 본 연구에서는 초임계 분산 기술을 통해 전해질막 및 막-전극접합체의 제조과정에서 발생하는 고활성을 갖는 전해질막 스크랩을 연료전지 전극바인더로 재제조하는 방법을 제시하고자 한다.

This study determined the minimum size of a representative molecular structure for use in future dynamic analyses of asphalt binders. The minimum representative size, considering factors such as aging, additive types, and temperature variations, was established using density and radial distribution functions. This approach ensures that the structure reflects temperature-dependent property changes, which are critical characteristics of asphalt binders. In this study, the structure of asphalt-binder molecules was generated using the composition proposed by Li and Greenfield (2014) for AAA1. To assess the appropriateness of the molecular structure size, we generated additional structures, X2 and X3, maintaining the same composition as X1, but with two and three times the number of molecules, respectively, as suggested by Li and Greenfield (2014). Silica and lignin were considered as additives, and the aging conditions examined included unaged, short-term aging, and long-term aging. In addition, 11 temperature conditions were investigated. The density and radial distribution functions were plotted and analyzed. The variables influencing the density and radial distribution functions were set as the aging degree of the asphalt binder (unaged, short-term aging, long-term aging), 11 temperature conditions ranging from 233 to 433 K in 20 K intervals, structure size (X1, X2, and X3), and the presence of additives (no additives, silica, and lignin). For density, clear differences were observed based on the degree of aging, temperature conditions, and presence of additives, whereas the structure size did not significantly affect the density. In terms of radial distribution functions, the X1 structure reflected differences based on the degree of aging and the presence of additives but was limited in exhibiting temperature-dependent variations. In contrast, the X3 structure effectively captured temperature-dependent trends, indicating that the size of the molecular structure is crucial when evaluating energy calculations or physical tensile strength, necessitating careful assessment.

To improve the lithium-ion battery performance and stability, a conducting polymer, which can simultaneously serve as both a conductive additive and a binder, is introduced into the anode. Water-soluble polyaniline:polystyrene sulfonate (PANI:PSS) can be successfully prepared through chemical oxidative polymerization, and their chemical/mechanical properties are adjusted by varying the molecular weight of PSS. As a conductive additive, the PANI with a conjugated double bond structure is introduced between active materials or between the active material and the current collector to provide fast and short electrical pathways. As a binder, the PSS prevents short circuits through strong π‒π stacking interaction with active material, and it exhibits superior adhesion to the current collector, thereby ensuring the maintenance of stable mechanical properties, even under high-speed charging/discharging conditions. Based on the synergistic effect of the intrinsic properties of PANI and PSS, it is confirmed that the anode with PANI:PSS introduced as a binder has about 1.8 times higher bonding strength (0.4 kgf/20 mm) compared to conventional binders. Moreover, since active materials can be additionally added in place of the generally added conductive additives, the total cell capacity increased by about 12.0%, and improved stability is shown with a capacity retention rate of 99.3% even after 200 cycles at a current rate of 0.2 C.

지속저인 산업발전은 화석 연료사용과 에너지 사용을 증가시켰으며, 각 국가별 온실가스 배출은 증가하고 있는 실정이다. 국제사회는 지구 온난화 방지를 위해 1997년 교토 의정서를 채택하였고, 이산화탄소(CO2) 순 배출량 0을 목표로 하여 자체적으로 온실가스 배출 목표를 정하고 실천하고자 2015년 '파리기후변화협정'을 채택하였다. 우리나라는 2015년 '파리기후변화협정' 체결 후 2030년까지 2017년 총 배출량 대비 24.4 % 감축을 목표로 설정하였다.(외교부, 2020) 국내 사회 각 분야에서는 온실가스 감축을 위해 노력하고 있으며, 도로분야에서는 온실가스 저감을 위한 환경친화형 도로 설계와 시 공기술 개발을 위한 연구들이 검토되고 있다. 그 중 가열 아스팔트 혼합물 제조 시 사용되는 기존의 연료(중유, 벙커씨유, 정제유 등) 를 상대적으로 탄소배출량이 적은 연료(LPG, LNG)로 전환하거나, 플랜트 생산온도를 낮추어 사용되는 연료를 저감하는 방법 등 다양 한 연구를 진행하고 있다. 따라서 본 연구에서는 일반 가열 아스팔트 혼합물보다 약 50℃ 낮은 상태에서 생산할 수 있게 도와주는 탄소저감형 첨가제를 적용 한 저가열 아스팔트의 특성을 파악하고자 하였다. 기본 물성시험으로는 연화점, 신도, 회전점도를 시험하였으며, 공용성 등급 시험을 통하여 PG 등급을 확인하였다. 또한 기존에 상용화된 제품과 차이를 보기 위해, 첨가제가 투입되지 않은 일반 아스팔트와 중온 첨가 제 2종(고상형, 액상형)이 적용된 중온 아스팔트도 동일한 시험을 진행하였고, 저가열 아스팔트와 비교·분석 하였다.

This study involved the heterogenization of a binder pitch (BP) using a small amount of nanocarbon to improve physical properties of the resulting graphite electrode (GE). Heterogenization was carried out by adding 0.5–2.0 wt.% platelet carbon nanofiber (PCNF) or carbon black (CB) to a commercial BP. To evaluate the physical properties of the BPs, we designed a new model graphite electrode (MGE) using needle coke as a filler. The heterogenized binder pitch (HBP) with PCNF or CB clearly increased the coking value by 5–13 wt.% compared to that of the as-received BP. Especially, the model graphite electrodes prepared with HBPs containing 1.0 wt.% PCNF or CB showed significantly improved physical properties compared to the control MGE from the as-received BP. Although the model graphite electrodes prepared with HBPs showed similar properties, they had smaller pore sizes than the control. This indicates that heterogenization of the BP can effectively decrease the pore size in the MGE matrix. Correlating the average pore sizes with the physical properties of the model graphite electrodes showed that, for the same porosity, matrices formed by the HBP with a smaller average pore size can effectively improve the apparent density, tensile strength, and oxidation resistance of the model graphite electrodes.

Cemented carbide for cutting tools, which is composed of carbide as a hard phase and metallic component as a metallic phase, mainly uses cobalt as the metallic phase due to the excellent mechanical properties of cobalt. However, as the demand for machining difficult-to-machine materials such as titanium and carbon fiber-reinforced plastics has recently increased, the development of high-hardness cemented carbide is necessary and the replacement of cobalt metal with a high-hardness alloy is required. In this study, we would like to introduce high-hardness cemented carbide fabricated using nickel-tungsten alloy as the metallic phase. First, nickel-tungsten alloy powder of the composition for formation of intermetallic compound confirmed through thermodynamic calculations was synthesized, and cemented carbide was prepared through the sintering process of tungsten carbide and the synthesized alloy powder. Through evaluating the mechanical properties of high-hardness cemented carbide with the nickel-tungsten alloy binder, the possibility of producing high-hardness cemented carbide by using the alloys with high-hardness was confirmed.

PURPOSES : This study aimed to develop a quantitative structure property relationships (QSPR) model to predict the density from the molecular structure information of the asphalt binder AAA1, a non-full connected structure mixed with a total of 12 molecules. METHODS : The partial least squares regression (PLSR) model, which models the relationship between predictions and responses and the structure of these variables, was applied to predict the density of a binder with molecule descriptors. The PLSR model could also analyze data with collinear, noisy, and multiple dimensional independent variables. The density and additive-free AAA1 binder’s molecule systems generated by an asphalt binder’s molecules-related study were used to fit the PLSR model with the molecular descriptors produced using alvaDesc software. In addition to developing the relationship, a systematic feature selection framework (i.e., the V-WSP- and PLSR-modelbased genetic algorithm (GA)) was applied to explore sets of predictors which contributed to predicting the physical property. RESULTS : The PLSR model accurately predicted the density for the AAA1 binder’s molecules using the condition of the temperature and aging level (R2 was 0.9537, RMSE was 0.00424, and MAP was 0.00323 for the test data) and provided a set of features which correlated well to the property. CONCLUSIONS : Through the establishment of the physical property prediction model, it was possible to evaluate the physical properties of construction materials without limited experiments or simulations, and it could be used to comprehensively design the modified material composition.

The lithium-ion battery has been utilized in various fields including energy storage system, portable electronic devices and electric vehicles due to their high energy and power densities, low self-discharge, and long cycle-life performances. However, despite of various research on electrode materials, there is a lack of research on developing of binder to replace conventional polymer-based binding materials. In this work, petroleum pitch (MP-50)/polymer (polyurethane, PU) composite binder for lithium-ion battery has fabricated not only to use as a binding material, but also to re-place conventional polymer-based binder. The MP-50/PU composite binder has also prepared to various ratios between petroleum pitch and polymer to optimize the physical and electro-chemical performance of the lithium-ion battery based on the MP-50/PU composite binder. The physical and electrochemical performances of the MP-50/PU composite binder-based lithium-ion battery were evaluated using a universal testing machine (UTM), charge/discharge test. As a result, lithium-ion battery based on the MP-50/PU composite (5:5, mass ratio) binder showed optimized performances with 1.53 gf mm− 1 of adhesion strength, 341 mAh g− 1 of specific discharge capacity and 99.5% of ICE value.

초고성능 콘크리트의 시멘트량 저감을 위해 시멘트와 치환하여 사용가능한 시멘트계 재료를 사용한 연구를 사전 조사하여 플라이애시와 고로슬래그를 선정하였다. 시멘트와 실리카흄 조합으로 120 MPa 이상의 압축강도를 보인 배합을 사용해 바인더조합의 변화에 따른 압축강도, 휨강도를 평가하였다. 플 라이애시와 고로슬래그를 사용한 배합은 유동성이 향상되었으며, 플라이애시는 압축강도가 실리카흄만 사용한 경우보다 다소 감소하였으나, 고로슬래그를 사용한 실험체는 실리카흄만 사용한 실험체와 유사 한 결과를 나타내었다.

내구연한이 도래한 아스팔트 혼합물은 사용자의 주행성 및 안전성 확보를 위해 주기적인 유지·보수를 실시한다. 과거에는 유지·보수 과정에서 발생된 폐아스팔트 혼합물을 각종 건설현장에서 단순 매립재로서 활용하였으나, 재활용 아스팔트 혼합물의 배합설계 기술이 확립된 이후에는 도로포장재료로서의 재활용되어왔다. 하지만 현재 시공된 재활용 아스팔트 혼합물 또한 내구연한이 다가옴에 따라 노화된 재활용 아스팔트 혼합물의 처리방안 수립이 필요한 시점이다. 본 연구에서는 한번 재활용된 아스팔트 혼합물이 기존의 재활용 배합설계법으로 반복적인 재활용이 가능한지 검증해보고자 하였다. 이를 위해 아스팔트 혼합물의 물성을 결정하는 가장 큰 요인 중 하나인 아스팔트의 물성이 노화 및 재생을 반복할때 어떻게 변하는지를 시험을 통해 분석하였다. 아스팔트 바인더의 노화를 모사하기 위해 공용성등급시험에 사용되는 단기노화 장비(Rolling Thin Film Oven, RTFO)와 장기노화 장비(Pressure Aging Vessel, PAV)을 활용하 였다. 노화된 아스팔트의 회생을 위한 재생첨가제 사용량은 국토부 시공지침의 배합설계법을 참고하였다. 실험결과, 노화된 바인더는 회생시 원바인더에 비해  sin는 감소하였으나, 회생된 바인더 간에는 유사한 결과값을 보였다. 반면 단기노화 시료는 회생이 반복 됨에 따라  sin이 감소한 경향을 보였으며, 장기노화시료는 회생이 반복되어도  sin가 유사한 것으로 확인되었다.

2022년 기준 국내 폐타이어 발생량은 약 37만톤으로 그 중 88.9%인 약 32만 9천톤이 재활용되는 것으로 조사되었다. 하지만 이 중 약 75%가 시멘트소성로용 등 열이용 분야에 사용되었다. 폐타이어는 대부분 고무와 플라스틱으로 이루어져 있기 때문에, 고온에서 분 해되면서 다양한 유해가스와 오염물질이 발생할 수 있고, 이러한 공해물질은 적극적으로 관리되지 않으면 대기오염, 수질 오염 등 다 양한 환경문제를 발생시킬 수 있다. 때문에 친환경적이고 지속적인 재활용에 대한 필요성이 대두되고 있다. 폐타이어 고무 분말을 아스팔트 혼합물의 골재 일부로 치환하여 재활용하는 접근 방식은 환경에 미치는 영향을 완화할 뿐만 아니라 천연 자원의 고갈 측면에서도 긍정적인 영향을 미치는 것으로 판단된다. 따라서 타이어분말을 아스팔트 혼합물에 적용하는 것은 환경 문제를 해결하고 자원 효율성을 높이는 두 가지 이점을 가지고 있다. 폐타이어 분말을 아스팔트 바인더와 아스팔트 혼합물에 적용할 경우 미치는 영향을 평가하기 위하여 DSR, BBR, MSCR 등의 시험 을 진행하였으며, 아스팔트 혼합물 내 폐타이어 분말의 분포를 조사하기 위해 SEM을 실시하였다. 또한 IDEAL-CT와 IDEAL-Rutting 시 험을 통해 아스팔트 혼합물의 성능을 평가하였다.

The lithium ion battery has applied to various fields of energy storage systems such as electric vehicle and potable electronic devices in terms of high energy density and long-life cycle. Despite of various research on the electrode and electrolyte materials, there is a lack of research for investigating of the binding materials to replace polymer based binder. In this study, we have investigated petroleum pitch/polymer composite with various ratios between petroleum pitch and polymer in order to optimize the electrochemical and physical performance of the lithium-ion battery based on petroleum pitch/polymer composite binder. The electrochemical and physical performances of the petroleum pitch/polymer composite binder based lithium-ion battery were evaluated by using a charge/discharge test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and universal testing machine (UTM). As a result, the petroleum pitch(MP-50)/polymer(PVDF) composite (5:5 wt % ratio) binder based lithium-ion battery showed 1.29 gf mm-1 of adhesion strength with 144 mAh g-1 of specific dis-charge capacity and 93.1 % of initial coulombic efficiency(ICE) value.

세라믹 분리막은 높은 열적, 화학적 안정성을 갖기 때문에 극한의 조건에서 운전되는 다양한 산업 공정에 적용할 수 있다. 그러나 투과도와 기계적 강도의 trade-off 현상에 의한 세라믹 분리막 활용에 제약이 있어, 고투과성-고강도 분리막 의 개발이 필요하다. 본 연구에서는 상전이-압출법으로 알루미나 중공사 분리막을 제조하고, 고분자 바인더의 종류와 그 혼합 비에 따른 분리막의 특성 변화를 관찰하였다. 용매인 DMAc (Dimethylacetamide)와 고분자 바인더의 한센 용해도 인자를 비 교하면, PSf (polysulfone)가 DMAc와 높은 용해도 특성을 갖기 때문에 도프 용액의 점도와 토출압력이 높게 나타나 분리막 내부가 치밀한 구조로 형성되기 때문에 높은 기계적 강도를 갖으나 수투과도가 감소하는 것으로 확인되었다. 그에 반해, PES (polyethersulfone)를 이용하여 분리막을 제조하면 기계적 강도가 다소 감소하고 수투과도가 증가하는 것으로 나타났다. 따라 서 분리막 성능과 물성을 최적화하기 위해 PSf와 PES를 혼합하여 분리막을 제조하였으며, 9:1로 혼합하여 제조된 분리막에 서 최적화된 수투과도와 기계적 강도를 얻을 수 있었다.

This paper proposes the optimal molecular weight for a petroleum-based binder pitch to enhance the density and strength of the prepared graphite block. The effect of the molecular weight on the binder properties, which was quantified using solvent fractionation, was considered based on the evaluation of the coking and viscosity characteristics. The affinity of the pitch to coke influenced the carbonization yield of the block, and the proportion of closed pores was reduced via the use of a highaffinity binder pitch. In addition, the viscosity was found to influence the uniformity of the coke and pitch dispersions, and numerous open pores were formed in the graphite block under high-viscosity conditions. In terms of the molecular weight, a reduction in the content of the insoluble 1-methyl-2-pyrrolidone (NMP) fraction, which was the heaviest fraction present in the pitch, was found to reduce the affinity of the binder to coke while increasing its viscosity. Therefore, the density and strength of the prepared graphite block were reduced upon increasing the insoluble NMP content of the binder pitch. Consequently, it was necessary to control the content of this fraction within < 13.81 wt% to obtain high-density and high-strength graphite blocks.

In this study, we successfully grafted chitosan (CS) onto multi-walled carbon nanotubes (MWCNTs) to enhance their properties and potential applications in the biomedical field. FTIR spectroscopy confirmed the successful covalent bonding of CS onto MWCNTs, indicated by the new absorption peak of the amide bond (–CONH–). Thermal analysis showed that the modified MWCNTs (MWCNT-CS) had significant weight loss around 260 °C, suggesting the decomposition of hydroxypropyl chitosan, and confirming its presence in the nanocomposite. SEM images revealed that CS grafting improved the dispersibility of MWCNTs, a property crucial for their use as nanofillers in polymers. Moreover, the micro-tensile bond strength of dentin surface increased with increasing MWCNT-CS concentrations, indicating the potential of MWCNT-CS as a pretreatment for dentin bonding. After simulated aging, the bond strength remained significantly higher for MWCNT-CS groups compared to those without pretreatment. In biocompatibility assessment using the MTT assay, MWCNT-CS showed higher cell viability than MWCNT, suggesting improved biocompatibility after CS modification. The results of this study suggest that CS-modified MWCNTs could be promising materials for applications in dentin bonding, dentin mineralization, bone scaffolding, implants, and drug delivery systems.