The purpose of this study intends to development of a lap scale 1-ton standard combustion chamber. The manufactured standard combustion chamber analyzes pilot combustion tests and emission standard data of MGO fuel oil. The actual capacity of the standard combustion chamber is about 900L, total weight of 265kg. As a result of the pilot combustion test, the O2 was about 8.01% and the CO2 was about 9.34%. In the case of NOx, it was about 33.50 ppm, and SOx (SO2) was about 0.76ppm. The combustion efficiency was about 72.41%, the exhaust gas temperature was 366.7℃, and the combustion chamber internal temperature was about 448.0℃.

The types of fuel loaded and burned in domestic nuclear power plants are WH-type and OPR/ APR-type nuclear power plants, with a total of 19 types. In the case of spent nuclear fuel released in Korea, the low combustion level of 45,000 MWD/MTU or less accounts for about 75%. In terms of fuel type, WH 17×17 and CE 16×16 fuels account for about 85% of all spent nuclear fuels. The thickness of the oxide film of the fuel cladding can make the fuel rod vulnerable during reactor operation, directly affecting the integrity of the fuel rods. so, it is a very important design factor in design. Therefore, the fuel rod design code that predicts and evaluates this has also been developed to accurately predict fuel rod corrosion. And it’s being applied to the design. In this study, the ECT probe measured by inserting it between fuel rods. The thickness of the fuel cladding oxide film was measured for spent nuclear fuel. When reloading operational nuclear fuel, the IAEA recommends an oxide film thickness of up to 100 micrometers. In this study, it was confirmed that spent nuclear fuels keeping integrity burned for 2-3 cycles were sufficiently maintained within the limit. However, the difference could be confirmed according to the characteristics of the coating material, the combustion cycle, and the use of poison rods. For the reliability of the data, symmetrical to the quadrant fuels were selected, and the fuel burned at the same period was measured. The method of selecting the target fuel can produce meaningful results.

A solution combustion process for the synthesis of hollandite (BaAl2Ti6O16) powders is described. SYNROC (synthetic rock) consists of four main titanate phases: perovskite, zirconolite, hollandite and rutile. Hollandite is one of the crystalline host matrices used for the disposal of high-level radioactive wastes because it immobilizes Sr and Lns elements by forming solid solutions. The solution combustion synthesis, which is a self-sustaining oxi-reduction reaction between a nitrate and organic fuel, generates an exothermic reaction and that heat converts the precursors into their corresponding oxide products in air. The process has high energy efficiency, fast heating rates, short reaction times, and high compositional homogeneity. To confirm the combustion synthesis reaction, FT-IR analysis was conducted using glycine with a carboxyl group and an amine as fuel to observe its bonding with metal element in the nitrate. TG-DTA, X-ray diffraction analysis, SEM and EDS were performed to confirm the formed phases and morphology. Powders with an uncontrolled shape were obtained through a general oxide-route process, confirming hollandite powders with micro-sized soft agglomerates consisting of nano-sized primary particles can be prepared using these methods.

Combustion method has been widely used in the analysis of 3H and 14C in various types of radioactive wastes since X. Hou reported the analysis of 3H and 14C in graphite and concrete for decommissioning of nuclear reactor. In this work, it was demonstrated that the validation result of combustion method for the simultaneous analysis of 3H and 14C in non-combustible radioactive wastes. To validate the combustion method, 3H and 14C spiked to sea sand and soil were prepared and each simulated sample was combusted with the accordance to a combustion temperature program. The validation of combustion method was assessed by the radioactivity recovery, radioactivity deviation, and relative standard deviation of measured radioactivity. The results of radioactivity recovery, radioactivity deviation, and relative standard deviation of 14C were 100~105%, less than 7%, less than 5%, respectively. In addition, 3H showed about 90% of radioactivity recovery, less than 20% of radioactivity deviation, and less than 5% of relative standard deviation. It will be provided that the validation results of combustion method in detail.

The ZnO–Na2Ti6O13 composites were synthesized by facile solution combustion method with different molar concentrations of sodium titanate which is prepared by hydrothermal route. The formation of the composites was confirmed by the X-ray diffraction (XRD) analysis. Field emission scanning electron microscope (FESEM) and transmission electron microscope (TEM) results revealed that the synthesized composites exhibit porous morphology, whereas the pristine Na2Ti6O13 nanoparticles have whisker like morphology. Diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) studies were utilized to compute the bandgap and the presence of defects in the composites respectively. The photocatalytic activity of ZnO–Na2Ti6O13 catalyst was investigated through the degradation of 4-nitrophenol under solar light over a period of 180 min and the composite with 0.05 M of Na2Ti6O13 showed higher degradation efficiency (96%) than the other concentrations of Na2Ti6O13 and pristine ZnO. The reduced bandgap, high charge transfer, more oxygen vacancies and the production of high superoxide anion radicals have profound effect on the higher photocatalytic efficiency of the composite with 0.05 of M Na2Ti6O13.

In preparation of porous carbon materials microwave oven brightening is one of the warming modes used ever. The various procedures that take place in microwave combustion process include carbonization, incitation, and recovery and thus carbon is defined. This paper compares ideal conditions of traditional warming methods, as well as their implementation potential, losses, and specifications. This porous carbon with heat treatment possesses various properties and they are well suited for energy applications which require constrained space such as hydrogen storage in solid-state and supercapacitors. The enhanced properties are chemical and thermal stability, ready availability, low framework density and ease of processability. The recent trend in class of porous carbons is Activated Carbons that are employed traditionally as adsorbents or catalyst supporters but currently, they found potent applications in fabricating for hydrogen storage materials and supercapacitors. These activated carbons are much enhanced form in class of porous carbon materials and they possess the capability to enable hydrogen economy, where the energy carrier is hydrogen. Therefore, the utility of activated carbons as a source for energy storage experiences a rapid growth at current trend and they possess significant advances. This investigation is based on detailed cost development data and electrical imperativeness applications.

Diesel engine has the advantages of strong power, low fuel consumption and good durability, so it has been widely used in transportation, automobile, ship and other fields. However, the nitrogen oxides(NOx) and particulate matter(PM) emitted by diesel engines have become one of the main causes of air pollution. Especially during idling, the engine temperature is low, and there are more residual exhaust gases in the combustion chamber, resulting in the formation of more harmful emissions. In this study, performance of a single cylinder, four-stroke, direct injection (DI) diesel engine fueled with diesel–biodiesel mixtures has been experimentally investigated. The findings show that a remarkable improvement in PM–NOx trade-off can be achieved by burning diesel-bioethanol blend fuels.

Diesel engine has the advantages of strong power, low fuel consumption and good durability, so it has been widely used in transportation, automobile, ship and other fields. However, the nitrogen oxides(NOx) and particulate matter(PM) emitted by diesel engines have become one of the main causes of air pollution. Especially during idling, the engine temperature is low, and there are more residual exhaust gases in the combustion chamber, resulting in the formation of more harmful emissions. In this study, performance of a single cylinder, four-stroke, direct injection (DI) diesel engine fueled with diesel–biodiesel mixtures has been experimentally investigated.

In this study, the effects of fuel injection pressure changed from 45 to 65 MPa on combustion and emission characteristics were investigated in a common rail direct injection (CRDI) diesel engine fueled with diesel and palm oil biodiesel blends. The engine speed and engine load were controlled at constant 1700rpm and 100Nm, respectively. The tested fuel were PBD20 (20 vol.% palm oil biodiesel blended with 80 vol.% diesel fuel). The main and pilot injection timing was fixed at 3.5°CA BTDC and 27°CA BTDC (before top dead center), respectively. The experimental results show that the combustion pressure and heat release rate increased. In addition, the indicated mean effective pressure (IMEP) and maximum combustion pressure increased with an increase of the fuel injection pressure. Hydrocarbon (HC), smoke opacity and carbon monoxide (CO) decreased, but oxides of nitrogen (NOx) emissions increased as fuel injection pressure increased.

In this study, the combustion characteristics of low calorific gas (LCG) fuels are investigated by numerical simulation. PREMIXED code is used to predict the flame structure and NO emission with two mechanisms, which are GRI 3.0 and USC II chemical reaction mechanisms for CH4 and LCG 8000 and LCG 6000, respectively. Also, elementary reactions related with production and destruction for OH radical are studied because OH radical is dominant for burning velocity and NO emission. As results, the production and the destruction of OH radical for CH4 and LCG 8000 using GRI 3.0 are dominated by reactions of No. 4, No. 2 and No. 3 and by No. 5, No. 3 and No. 7, respectively. For LCG 6000 using USC II, reactions of No. 3, No. 4 and No. 11 and of No. 7, No. 8 and No. 12 dominates to the production and the destruction, respectively. In addition, NO emissions for LCG gas fuel are generated by thermal NO because the flame temperatures are over 1800 K.